Reactive Polymers, Ion Exchangers, Sorbents最新文献

筛选
英文 中文
[Poly(styryl)phenanthroline]palladium catalyst. Synthesis and some of its applications in vinylic substitution reactions with organic halides 聚(苯乙烯基)邻二氮杂菲钯催化剂。有机卤化物取代乙烯基反应的合成及其应用
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90250-4
Zhang Zhuangyu, Hu Hongwen, Kao Tsi-Yu
{"title":"[Poly(styryl)phenanthroline]palladium catalyst. Synthesis and some of its applications in vinylic substitution reactions with organic halides","authors":"Zhang Zhuangyu,&nbsp;Hu Hongwen,&nbsp;Kao Tsi-Yu","doi":"10.1016/0167-6989(88)90250-4","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90250-4","url":null,"abstract":"<div><p>A polymer-bound phenanthroline palladium catalyst, <figure><img></figure>-ph-phen -Pd (reduced), has been synthesized although the precise form of the Pd has not yet been established unambiguously. The catalyst is very stable to air and moisture and can be stored for long periods. It was characterized by IR, DRS, ESCA, electron microscopy, and elemental analysis. The catalyst showed high activity for vinylic substitution reactions of iodobenzene with olefins. In general, smaller amounts of catalyst were used than those in homogeneous reactions, while the yields were about equal or a little higher. The catalyst can be recovered and reused, with tributylamine as the base: however, the catalytic activity was dramatically reduced after three runs as a result of leaching of palladium from the polymer support. Bromobenzene can also be induced to react with styrene using this catalyst in the absence of phosphine ligands.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90250-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91679357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Polymer-bound pyrrole compounds. III [1]. Synthesis and properties of polystyrene-bound porphyrins and metalloporphyrins 聚合物结合的吡咯化合物。三世[1]。聚苯乙烯结合卟啉和金属卟啉的合成与性能
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90249-8
Pilar Castan, Josep M. Ribo, Francesc R. Trull
{"title":"Polymer-bound pyrrole compounds. III [1]. Synthesis and properties of polystyrene-bound porphyrins and metalloporphyrins","authors":"Pilar Castan,&nbsp;Josep M. Ribo,&nbsp;Francesc R. Trull","doi":"10.1016/0167-6989(88)90249-8","DOIUrl":"10.1016/0167-6989(88)90249-8","url":null,"abstract":"<div><p>Several porphyrins and metalloporphyrins have been reversibly and covalently attached to a functionalized insoluble polystyrene matrix, α-[(4-bromomethyl-3-nitrobenzamido)benzyl]-poly(styrene-co-divinylbenzene). Insertion and removal of Zn(II) on the supported species has been successfully achieved. The products have been identified by alkaline detachment as well as spectroscopically.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90249-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91489551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Polybenzimidazole resin-based new chelating agents. Ferric ion selectivity of resins with immobilized oligoamines 聚苯并咪唑树脂基新型螯合剂。固定化低聚胺树脂的铁离子选择性
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90253-X
M. Chanda , K.F. O'Driscoll, G.L. Rempel
{"title":"Polybenzimidazole resin-based new chelating agents. Ferric ion selectivity of resins with immobilized oligoamines","authors":"M. Chanda ,&nbsp;K.F. O'Driscoll,&nbsp;G.L. Rempel","doi":"10.1016/0167-6989(88)90253-X","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90253-X","url":null,"abstract":"<div><p>Microporous polybenzimidazole of 250–500 μm bead size from Celanese has been epoxidized and subsequently aminolyzed with ethylenediamine and diethylenetriamine to obtain sorbents having high capacity, selectivity and sorption rate for ferric ion from acidic sulfate solutions. The ferric ion sorption capacity of these sorbents is more than twice that obtained with normal chelating resins. The chelation properties of the new sorbents can be used as a means of removing the ferric ion selectivity from mixtures in acidic sulfate solution containing a wide range of mono- and multivalent metal ions, including some which normally form strong chelate complexes.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90253-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91679353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
[Poly(styryl)phenanthroline]palladium catalyst. Synthesis and some of its applications in vinylic substitution reactions with organic halides 聚(苯乙烯基)邻二氮杂菲钯催化剂。有机卤化物取代乙烯基反应的合成及其应用
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90250-4
Zhang Zhuangyu, H. Hongwen, Kao Tsi-yu
{"title":"[Poly(styryl)phenanthroline]palladium catalyst. Synthesis and some of its applications in vinylic substitution reactions with organic halides","authors":"Zhang Zhuangyu, H. Hongwen, Kao Tsi-yu","doi":"10.1016/0167-6989(88)90250-4","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90250-4","url":null,"abstract":"","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88183057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Ion-exchange properties of zirconium phosphate-phosphite, a layered compound with asymmetrical layers 不对称层状化合物磷酸锆-亚磷酸酯的离子交换性质
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90252-8
G. Alberti, U. Costantino, F. Marmottini, G. Perego
{"title":"Ion-exchange properties of zirconium phosphate-phosphite, a layered compound with asymmetrical layers","authors":"G. Alberti,&nbsp;U. Costantino,&nbsp;F. Marmottini,&nbsp;G. Perego","doi":"10.1016/0167-6989(88)90252-8","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90252-8","url":null,"abstract":"<div><p>Zirconium phosphate-phosphite of composition Zr(HPO<sub>4</sub>)<sub>0.7</sub>(HPO<sub>3</sub>)<sub>1.3</sub> · 0.5H<sub>2</sub>O possesses a peculiar layer structure in which there is a regular alternation of an interlayer region of zirconium phosphate type with another of zirconium phosphite type. The ion-exchange properties of this particular inorganic layered compound towards alkali metal ions have been examined and many comparisons with analogous properties of α-zirconium phosphate are reported. It was found that, although only the phosphate regions are involved in the ion exchange processes, the presence of the adjacent phosphite regions strongly affects both the selectivity and rate of exchange as well as the phase transitions occurring in the salt conversion. A discussion of the different ion-exchange processes taking place in the phosphate regions of zirconium phosphate-phosphite and in the same regions of the pure α-zirconium phosphate is made on the basis of the particular layered structure of α-zirconium phosphate phosphite. Although the ion-exchange capacity of this latter exchanger is less than one half of that of pure α-Zr(HPO<sub>4</sub>)<sub>2</sub> · H<sub>2</sub>O, it can be considered a better exchanger for large cations.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90252-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91679354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Chemical modification of 3-mercaptopropionic acid-substituted poly(chlorotrifluoroethylene) 3-巯基丙酸取代聚三氟氯乙烯的化学改性
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90248-6
Richard T. Taylor, Michael W. Pelter
{"title":"Chemical modification of 3-mercaptopropionic acid-substituted poly(chlorotrifluoroethylene)","authors":"Richard T. Taylor,&nbsp;Michael W. Pelter","doi":"10.1016/0167-6989(88)90248-6","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90248-6","url":null,"abstract":"<div><p>When poly(chlorotrifluoroethylene) is reacted with the dianion of 3-mercaptopropionic acid, a substituted polymer with pendant carboxylic acid functionality is produced. Further reactions, such as esterification and reduction to the alcohol, can be performed on the acid groups. Chemical transformation of the alcohol produced the corresponding tosylate, halide, trimethylsiloxy, and trichloroacetate derivatives. By increasing the variety of functionality available, the possible utilizations of these polymers as reactive polymers and as solid phases in chromatography are thus increased.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90248-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91758881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gas separation by adsorption processes: by Ralph T. Yang, Butterworth, Stoneham, MA, x + 352 pages, hardcover, $52.95 吸附过程中的气体分离:Ralph T. Yang著,Butterworth, Stoneham, MA, x + 352页,精装,52.95美元
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90256-5
F. Helfferich
{"title":"Gas separation by adsorption processes: by Ralph T. Yang, Butterworth, Stoneham, MA, x + 352 pages, hardcover, $52.95","authors":"F. Helfferich","doi":"10.1016/0167-6989(88)90256-5","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90256-5","url":null,"abstract":"","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78495463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Modified anion-exchange resins for improved chromate selectivity and increased efficiency of regeneration 改性阴离子交换树脂提高铬酸盐选择性和再生效率
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90255-3
Arup K. Sengupta, Tushar Roy, Derek Jessen
{"title":"Modified anion-exchange resins for improved chromate selectivity and increased efficiency of regeneration","authors":"Arup K. Sengupta,&nbsp;Tushar Roy,&nbsp;Derek Jessen","doi":"10.1016/0167-6989(88)90255-3","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90255-3","url":null,"abstract":"<div><p>Experimental results are provided to show that a modified strong-base resin with tripropyl quaternary ammonium functionality offers greater chromate selectivity and improved efficiency of regeneration over widely used commercially available anion-exchange resins with trimethyl quaternary ammonium or dimethyl tertiary amine functionality. Use of this new, modified resin is likely to be more economic for decontaminating chromate-laden industrial wastewaters.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90255-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91679355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Chemical modification of 3-mercaptopropionic acid-substituted poly (chlorotrifluoroethylene) 3-巯基丙酸取代聚三氟氯乙烯的化学改性
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90248-6
R. Taylor, Michael W. Pelter
{"title":"Chemical modification of 3-mercaptopropionic acid-substituted poly (chlorotrifluoroethylene)","authors":"R. Taylor, Michael W. Pelter","doi":"10.1016/0167-6989(88)90248-6","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90248-6","url":null,"abstract":"","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81309228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gold extraction with poly(diallylamine) resins 聚二烯丙胺树脂萃取金
Reactive Polymers, Ion Exchangers, Sorbents Pub Date : 1988-12-01 DOI: 10.1016/0167-6989(88)90254-1
J.H. Hodgkin, R. Eibl
{"title":"Gold extraction with poly(diallylamine) resins","authors":"J.H. Hodgkin,&nbsp;R. Eibl","doi":"10.1016/0167-6989(88)90254-1","DOIUrl":"https://doi.org/10.1016/0167-6989(88)90254-1","url":null,"abstract":"<div><p>Weak-base poly(diallylamine) resins have been synthesised and tested for gold adsorption properties in metal-containing solutions ranging all the way from strong acid (aqua regia) to strong base (complex cyanide solutions, pH 7–14). These resins show high capacity, up to 5 mmol/g dry resin, and good gold-selective properties for much of this pH range and in many different types of solution, including contaminated wastes. However, the slow dissolution of uncrosslinked polymer chains trapped in the resin matrix limits the gold adsorption properties at low gold concentrations (below 5 mg/dm<sup>3</sup>).</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1988-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90254-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91679356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信