聚合物结合的吡咯化合物。三世[1]。聚苯乙烯结合卟啉和金属卟啉的合成与性能

Pilar Castan, Josep M. Ribo, Francesc R. Trull
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引用次数: 7

摘要

几种卟啉和金属卟啉已被可逆共价地附着在一个功能化的不溶性聚苯乙烯基体α-[(4-溴甲基-3-硝基苄基)苄基]-聚苯乙烯-共二乙烯基苯上。成功地实现了Zn(II)在载体上的插入和去除。产物经碱性分离和光谱鉴定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polymer-bound pyrrole compounds. III [1]. Synthesis and properties of polystyrene-bound porphyrins and metalloporphyrins

Several porphyrins and metalloporphyrins have been reversibly and covalently attached to a functionalized insoluble polystyrene matrix, α-[(4-bromomethyl-3-nitrobenzamido)benzyl]-poly(styrene-co-divinylbenzene). Insertion and removal of Zn(II) on the supported species has been successfully achieved. The products have been identified by alkaline detachment as well as spectroscopically.

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