聚二烯丙胺树脂萃取金

J.H. Hodgkin, R. Eibl
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引用次数: 12

摘要

已经合成了弱碱型聚二烯丙胺树脂,并对其在含金属溶液中的金吸附性能进行了测试,从强酸(王水)到强碱(pH值为7-14的复合氰化物溶液)。这些树脂表现出高容量,高达5毫摩尔/克的干树脂,在这个pH范围内和许多不同类型的溶液(包括受污染的废物)中具有良好的选金性能。然而,树脂基体中非交联聚合物链的缓慢溶解限制了低金浓度(低于5 mg/dm3)下的金吸附性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Gold extraction with poly(diallylamine) resins

Weak-base poly(diallylamine) resins have been synthesised and tested for gold adsorption properties in metal-containing solutions ranging all the way from strong acid (aqua regia) to strong base (complex cyanide solutions, pH 7–14). These resins show high capacity, up to 5 mmol/g dry resin, and good gold-selective properties for much of this pH range and in many different types of solution, including contaminated wastes. However, the slow dissolution of uncrosslinked polymer chains trapped in the resin matrix limits the gold adsorption properties at low gold concentrations (below 5 mg/dm3).

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