Radiation Physics and Chemistry (1977)最新文献_第2页

Picosecond-pulse radiolysis studies to understand the primary processes in radiolysis 皮秒脉冲辐射分解研究，了解辐射分解的主要过程

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90197-9

Charles D. Jonah, Michele A. Lewis

引用次数: 6

IMRP 5 awards for contributions to the field of radiation processing IMRP 5奖，奖励对辐射处理领域的贡献

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90241-9

引用次数: 0

Spectral properties and kinetics of cationic transients generated in electron-pulse-irradiated alkanes 电子脉冲辐照烷烃中阳离子瞬变的光谱特性和动力学

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90199-2

R. Mehnert, O. Brede, W. Naumann

引用次数: 14

The contribution of radiation chemistry to enact the hygienic safety standard of irradiated food 辐射化学对制定辐照食品卫生安全标准的贡献

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90264-X

Wu Jilan, Ha Hongfei, Yuan Rongyao

引用次数: 2

Radiation chemistry of Na3IrCl6 solutions: Catalysed H2 formation by radicals and postirradiation reduction of IrCl3-6 by propanol-2 Na3IrCl6溶液的辐射化学:自由基催化H2生成和辐射后丙醇-2还原IrCl3-6

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90227-4

German Mills, Arnim Henglein

{"title":"Radiation chemistry of Na3IrCl6 solutions: Catalysed H2 formation by radicals and postirradiation reduction of IrCl3-6 by propanol-2","authors":"German Mills, Arnim Henglein","doi":"10.1016/0146-5724(85)90227-4","DOIUrl":"10.1016/0146-5724(85)90227-4","url":null,"abstract":"<div>1-Hydroxy-1-methyl ethyl radicals produced in the irradiation of Na3IrCl6 solutions containing propanol-2 and acetone react very slowly with the IrCl3-6 anion (k of the order 100 M-1 s-1). The product of the reaction is a compound which reacts very efficiently with the radicals and thereby catalyses the formation of hydrogen. This compound is supposed to be an iridium hydride. No iridium is produced at small Na3IrCl6 concentrations and a maximum H2 yield of 3.7 H2/100 eV is observed at concentrations of IrCl3-6 between 2 and 5 times 10-4 M. At higher concentrations, iridium metal starts to be formed. A faster formation of iridium occurs in solutions of Na3IrCl6(>10-3 M) containing only propanol-2 as additive. In these solutions, the reduction of IrCl3-6 takes place thermally after initiation with λ radiation (some 104 rads). The postirradiation effect is inhibited by O2, N2O, CH3I, CH2CHCN, H2 and CO. A mechanism for the reduction of IrCl3-6 by propanol-2 is proposed, in which an IrI complex produced by radiation acts as the catalyst.</div>","PeriodicalId":101054,"journal":{"name":"Radiation Physics and Chemistry (1977)","volume":"26 4","pages":"Pages 391-399"},"PeriodicalIF":0.0,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0146-5724(85)90227-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53763144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 11

The isothermal luminescence of γ-irradiated poly(methyl methacrylate) in the presence of aromatic hydrocarbons at 77 K γ辐照聚甲基丙烯酸甲酯在77 K时芳烃存在下的等温发光

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90182-7

I Zuchowicz, J Mayer, J Kroh

引用次数: 4

Low dose-rate radiolysis of nitrogen: Yield of nitrogen atoms, N(4S) and N(2D,2P) 低剂量率氮的放射性分解:氮原子N(4S)和N(2D,2P)的产率

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90035-4

R.Glen Macdonald, Orval A. Miller

引用次数: 6

Tunneling recombination luminescence of glassy polyethylene adipate γ-irradiated at low temperature and effect of electron scavengers 低温辐照下玻璃态己二酸聚乙烯γ-隧穿复合发光及电子清除剂的影响

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90066-4

Kazuo Gouda, Yoshimasa Hama

{"title":"Tunneling recombination luminescence of glassy polyethylene adipate γ-irradiated at low temperature and effect of electron scavengers","authors":"Kazuo Gouda, Yoshimasa Hama","doi":"10.1016/0146-5724(85)90066-4","DOIUrl":"10.1016/0146-5724(85)90066-4","url":null,"abstract":"<div>The isothermal luminescence (ITL) from glassy polyethylene adipate (PEA) γ-irradiated at 77 K was observed over a long period of time, together with effect of the electron scavengers on it. The decay behavior of ITL is similar to that of polyethylene terephthalate or polycrystalline PEA obtained previously, so that the decay obeys the decay function I(t) = I0/(1 + αt)m. The detailed discussion on the parameters included in the decay function is given. Differences in the parameters between different materials or different physical states are found not to be very large, except the parameter I0. Addition of biphenyl into PEA enhances considerably the intensity of ITL and causes the luminescence center to exchange from the ester cation into the biphenyl cation. In the biphenyl doped PEA, the possibility of the triplet-triplet energy transfer from the excited ester group to the biphenyl and the positive charge transfer from the ester cation to the biphenyl are shown.</div>","PeriodicalId":101054,"journal":{"name":"Radiation Physics and Chemistry (1977)","volume":"26 3","pages":"Pages 285-294"},"PeriodicalIF":0.0,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0146-5724(85)90066-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53754631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Radiolysis of aqueous solution of cyanide ion 氰化物离子水溶液的放射性溶解

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90223-7

Qi Shengchu, Wu Jilan

引用次数: 0

Application of nanosecond electron pulses to determine electrical properties of semiconductors 纳秒级电子脉冲测定半导体电性能的应用

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0146-5724(85)90163-3

J.W. Leonhardt, R. Goeldner, J. Boes, R. Mehnert

引用次数: 0