{"title":"皮秒脉冲辐射分解研究,了解辐射分解的主要过程","authors":"Charles D. Jonah, Michele A. Lewis","doi":"10.1016/0146-5724(85)90197-9","DOIUrl":null,"url":null,"abstract":"<div><p>The use of pulse radiolysis to learn about processes which occur before the beginning of chemical times is discussed. Two examples, the distance distribution of positive and negative ions in<em>n</em>-hexane and the identity of the “dry electron” are discussed in detail. It is shown that the dry electron which reacts is not quasi-free, but instead must be associated with the solvent. Thus, the name “dry electron” is somewhat of a misnomer.</p></div>","PeriodicalId":101054,"journal":{"name":"Radiation Physics and Chemistry (1977)","volume":"26 5","pages":"Pages 485-489"},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0146-5724(85)90197-9","citationCount":"6","resultStr":"{\"title\":\"Picosecond-pulse radiolysis studies to understand the primary processes in radiolysis\",\"authors\":\"Charles D. Jonah, Michele A. Lewis\",\"doi\":\"10.1016/0146-5724(85)90197-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The use of pulse radiolysis to learn about processes which occur before the beginning of chemical times is discussed. Two examples, the distance distribution of positive and negative ions in<em>n</em>-hexane and the identity of the “dry electron” are discussed in detail. It is shown that the dry electron which reacts is not quasi-free, but instead must be associated with the solvent. Thus, the name “dry electron” is somewhat of a misnomer.</p></div>\",\"PeriodicalId\":101054,\"journal\":{\"name\":\"Radiation Physics and Chemistry (1977)\",\"volume\":\"26 5\",\"pages\":\"Pages 485-489\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0146-5724(85)90197-9\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiation Physics and Chemistry (1977)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0146572485901979\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiation Physics and Chemistry (1977)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0146572485901979","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Picosecond-pulse radiolysis studies to understand the primary processes in radiolysis
The use of pulse radiolysis to learn about processes which occur before the beginning of chemical times is discussed. Two examples, the distance distribution of positive and negative ions inn-hexane and the identity of the “dry electron” are discussed in detail. It is shown that the dry electron which reacts is not quasi-free, but instead must be associated with the solvent. Thus, the name “dry electron” is somewhat of a misnomer.