皮秒脉冲辐射分解研究,了解辐射分解的主要过程

Charles D. Jonah, Michele A. Lewis
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引用次数: 6

摘要

讨论了利用脉冲辐射分解来了解发生在化学时代开始之前的过程。以正负离子在正己烷中的距离分布和“干电子”的同一性为例进行了详细的讨论。结果表明,发生反应的干电子不是准自由的,而必须与溶剂相结合。因此,“干电子”这个名称有点用词不当。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Picosecond-pulse radiolysis studies to understand the primary processes in radiolysis

The use of pulse radiolysis to learn about processes which occur before the beginning of chemical times is discussed. Two examples, the distance distribution of positive and negative ions inn-hexane and the identity of the “dry electron” are discussed in detail. It is shown that the dry electron which reacts is not quasi-free, but instead must be associated with the solvent. Thus, the name “dry electron” is somewhat of a misnomer.

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