Journal of Membrane Science Letters最新文献_第3页

Chemically recyclable nanofiltration membranes fabricated from two circular polymer classes of the same monomer origin 用同源的两种环状聚合物制成的化学可循环纳滤膜

Journal of Membrane Science Letters Pub Date : 2024-01-28 DOI: 10.1016/j.memlet.2024.100067

Rifan Hardian , Abdul Ghaffar , Changxia Shi , Eugene Y.-X. Chen , Gyorgy Szekely

{"title":"Chemically recyclable nanofiltration membranes fabricated from two circular polymer classes of the same monomer origin","authors":"Rifan Hardian , Abdul Ghaffar , Changxia Shi , Eugene Y.-X. Chen , Gyorgy Szekely","doi":"10.1016/j.memlet.2024.100067","DOIUrl":"https://doi.org/10.1016/j.memlet.2024.100067","url":null,"abstract":"<div>Nanofiltration is widely used in various industries to separate solutes from solvents. To foster a circular economy, establishing a closed-loop lifecycle for the membrane materials is highly important. In this study, we fabricated recyclable nanofiltration membranes from chemically recyclable polymers —polyester P(BiL=)ROP and poly(cyclic olefin) P(BiL=)ROMP— using γ-butyrolactone as a green solvent. These two polymers, of two different polymer classes, were obtained from a single monomer, which could be recycled back to the same monomer, exhibiting the unique “one monomer–two polymers–one monomer” closed-loop chemical circularity. The effect of physical treatment, such as annealing, hot-pressing, and air exposure on the morphological characteristics and performance of the nanofiltration membranes was investigated. We revealed the interplay between membrane pore size, thickness, density and the molecular sieving performance of the nanofiltration membranes. Solute rejections were mainly governed by the membrane pore size. However, solvent flux was mainly governed by the membrane density that determines the free volume interconnectivity. The membranes exhibited a tunable molecular weight cutoff between 553 and 777 g mol−1 and methanol permeance between 5.9 and 9.8 L m–2 h–1 bar−1. The membranes exhibited excellent long-term nanofiltration stability over 1 week. The combination of the green solvent used for membrane fabrication and the circular life cycle of the polymer membrane brings one step closer to closing the circularity loop of membrane technology.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772421224000011/pdfft?md5=0b32a437a36e2bfd642434e9d558e37d&pid=1-s2.0-S2772421224000011-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139675111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Strong improvement of permeability and rejection performance of graphene oxide membrane by engineered interlayer spacing 工程层间距对氧化石墨烯膜的渗透性和截留性能有明显的改善

Journal of Membrane Science Letters Pub Date : 2023-11-01 DOI: 10.1016/j.memlet.2023.100065

Zafar Khan Ghouri , Khaled Elsaid , David James Hughes , Mohamed Mahmoud Nasef , Ahmed Abdel-Wahab , Ahmed Abdala

{"title":"Strong improvement of permeability and rejection performance of graphene oxide membrane by engineered interlayer spacing","authors":"Zafar Khan Ghouri , Khaled Elsaid , David James Hughes , Mohamed Mahmoud Nasef , Ahmed Abdel-Wahab , Ahmed Abdala","doi":"10.1016/j.memlet.2023.100065","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100065","url":null,"abstract":"<div>Advanced membranes fabricated from multilayer/laminated graphene oxide (GO) are promising in water treatment applications as they provide very high flux and excellent rejection of various water pollutants. However, these membranes have limited viability, and suffer from instabilities and swelling due to the hydrophilic nature of GO. In this work, the permeability and rejection performance of laminated GO membranes were improved via functionalization with ethylenediamine (EDA) and polyethyleneimine (PEI). The membranes are fabricated via the pressure-assembly stacking technique, and their structure is well characterized. The performance, rejection, and stability of the fabricated functionalized GO membranes were evaluated. Pillaring the GO layers using diamine and polyamine resulted in exceptionally high water permeability of 113 L/m2h (LMH) compared to only 28 LMH for the pristine GO membrane while simultaneously satisfying high rejection of multivalent salts of 79.4, 35.4, and 19.6 % for Na2SO4, MgCl2, and NaCl, respectively. The results obtained indicate that proper functionalization of GO provides a roadmap for the potential commercialization of such advanced membranes in water treatment applications.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772421223000296/pdfft?md5=ae9c343111f99b1f2fe6702a287518b3&pid=1-s2.0-S2772421223000296-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138475117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unexpected high performance of ZIF-8 membranes for 1,3-butadiene purification 用于1,3-丁二烯净化的ZIF-8膜的意外高性能

Journal of Membrane Science Letters Pub Date : 2023-11-01 DOI: 10.1016/j.memlet.2023.100066

Jun-Wei Wang , Zhiqin Qiang , Xiaoli Ma

{"title":"Unexpected high performance of ZIF-8 membranes for 1,3-butadiene purification","authors":"Jun-Wei Wang , Zhiqin Qiang , Xiaoli Ma","doi":"10.1016/j.memlet.2023.100066","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100066","url":null,"abstract":"<div>The purification of 1,3-butadiene from C4 hydrocarbon mixtures currently relies on energy-intensive extractive distillation. In this study, we employed ZIF membranes for this challenging separation for the first time, unveiling their superior capability in isolating 1,3-butadiene from other C4 hydrocarbons with similar sizes, including 1-butene, isobutene, and n-butane. This strong sieving effect was evident from two types of ZIF-8 membranes: one with low crystallinity fabricated via the all-vapor-phase ligand-induced permselectivation (LIPS) method and another with high crystallinity synthesized through the seeded growth method. The gas permeances decreased with increasing kinetic diameters, following the order of 1,3-butadiene (4.31 Å) > 1-butene (4.46 Å) > n-butane (4.687 Å) > isobutene (4.84 Å). The LIPS-ZIF-8 membrane exhibited a high 1,3-butadiene permeance of approximately 1.43 × 10−7 mol/m2 s Pa (∼430 GPU) and ideal separation factors of 18, 56, and 134 for 1,3-butadiene over 1-butene, n-butane, and isobutene, respectively. In separating four-component C4 mixtures, these membranes could enrich 1,3-butadiene content from 50% in the feed to 96–98% in the permeate through a single separation step. This unprecedented performance is attributed to differences in C4 diffusivities that span several orders of magnitude.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772421223000302/pdfft?md5=75d81704b3c5649106631bfdf9dd7c37&pid=1-s2.0-S2772421223000302-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138475118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Engineering organic solvent reverse osmosis in hybrid AlOxHy / polymer of intrinsic microporosity 1 (PIM-1) membranes using vapor phase infiltration 工程有机溶剂反渗透在混合AlOxHy /聚合物的固有微孔1 (PIM-1)膜上的气相渗透

Journal of Membrane Science Letters Pub Date : 2023-11-01 DOI: 10.1016/j.memlet.2023.100064

Yi Ren , Benjamin C. Jean , Woo Jin Jang , Akriti Sarswat , Young Joo Lee , Emily K. McGuinness , Kshitij Dhavala , Mark D. Losego , Ryan P. Lively

{"title":"Engineering organic solvent reverse osmosis in hybrid AlOxHy / polymer of intrinsic microporosity 1 (PIM-1) membranes using vapor phase infiltration","authors":"Yi Ren , Benjamin C. Jean , Woo Jin Jang , Akriti Sarswat , Young Joo Lee , Emily K. McGuinness , Kshitij Dhavala , Mark D. Losego , Ryan P. Lively","doi":"10.1016/j.memlet.2023.100064","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100064","url":null,"abstract":"<div>A solvent-free post-treatment process known as vapor phase infiltration (VPI) is used to engineer the organic solvent reverse osmosis (OSRO) performance of polymer of intrinsic microporosity 1 (PIM-1) membranes via infiltration of trimethylaluminum (TMA) metal-organic vapor. The infiltration of inorganic aluminum constituents hybridizes the pure polymer PIM-1 into an organic-inorganic material (AlOxHy/PIM-1) with enhanced chemical stability. A homogenous distribution of inorganic loading in PIM-1 is achieved due to the reaction-limited infiltration mechanism, and the OSRO performance is enhanced as a result. OSRO separations of ethanol/isooctane mixtures using these membranes are shown to be capable of breaking the azeotropic composition with a separation factor for ethanol over isooctane greater than 5 and an ethanol permeance of 0.1 Lm–2h–1bar–1. Thus, these organic-inorganic hybrid membranes created via VPI show promise as an alternative method for separating azeotropic liquid mixtures.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772421223000284/pdfft?md5=4d4422eeb6acb25bb572afab669923ad&pid=1-s2.0-S2772421223000284-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92103017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recycling of end-of-life polymeric membranes for water treatment: Closing the loop 回收报废聚合物膜用于水处理:关闭循环

Journal of Membrane Science Letters Pub Date : 2023-09-21 DOI: 10.1016/j.memlet.2023.100063

Chenxin Tian , Jiansuxuan Chen , Zhiyu Bai, Xueye Wang, Ruobin Dai, Zhiwei Wang

{"title":"Recycling of end-of-life polymeric membranes for water treatment: Closing the loop","authors":"Chenxin Tian , Jiansuxuan Chen , Zhiyu Bai, Xueye Wang, Ruobin Dai, Zhiwei Wang","doi":"10.1016/j.memlet.2023.100063","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100063","url":null,"abstract":"<div>Polymeric membranes have garnered widespread adoption in applications such as desalination, wastewater treatment, and water reuse. Nevertheless, the current disposal practices for these end-of-life (EoL) polymeric membranes, primarily landfill and incineration, are neither economically nor environmentally sustainable. To address this challenge, we first analyzed the factors leading to the EoL phase for these membranes; an understanding that is critical in developing or selecting appropriate recycling technologies. We further proposed a technological framework to guide recycling choices based on the specific state of the EoL membrane. In cases where the membrane exhibits significant breakage, dissolution using eco-friendly solvents, followed by membrane re-preparation, is recommended. For membranes without substantial breakage, regeneration, upcycling, or downcycling strategies can be deployed based on scenarios. We underscored the crucial role of irrecoverable foulant removal within the regeneration technology. Additionally, the reaction interface must be suitably remediated before the application of upcycling technology to EoL microfiltration/ultrafiltration membranes. The downcycling strategy, facilitated by NaOCl oxidation, is readily applicable to EoL nanofiltration/reverse osmosis membranes. This brief frontier review aims to serve as a valuable reference for recycling end-of-life water treatment polymeric membranes.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49735116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

RO membrane with a surface tethered polymer brush layer for enhanced rejection of nitrate, boron, and arsenic 具有表面系留聚合物刷层的反渗透膜，可增强对硝酸盐、硼和砷的去除

Journal of Membrane Science Letters Pub Date : 2023-09-09 DOI: 10.1016/j.memlet.2023.100062

Yian Chen , Yoram Cohen

引用次数: 0

Revisiting experimental techniques and theoretical models for estimating the solubility parameter of rubbery and glassy polymer membranes 回顾了估算橡胶和玻璃聚合物膜溶解度参数的实验技术和理论模型

Journal of Membrane Science Letters Pub Date : 2023-08-27 DOI: 10.1016/j.memlet.2023.100060

Matthew T. Webb , Lucas C. Condes , William J. Box , Harold G. Ly , Sepideh Razavi , Michele Galizia

{"title":"Revisiting experimental techniques and theoretical models for estimating the solubility parameter of rubbery and glassy polymer membranes","authors":"Matthew T. Webb , Lucas C. Condes , William J. Box , Harold G. Ly , Sepideh Razavi , Michele Galizia","doi":"10.1016/j.memlet.2023.100060","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100060","url":null,"abstract":"<div>Estimation and correlation of the Hildebrand solubility parameter (<math><mi>δ</mi></math>) of polymers and small molecules is a common practice in membrane material science and is accomplished by experimental and numerical routes. In this paper, we revisit, update, and compare both routes to enhance the accuracy in the determination of <math><mi>δ</mi></math>. Best practices for the experimental determination of polymer solubility parameters are provided, and the viability of Dynamic Light Scattering (DLS) was demonstrated as an alternative to conventional time- and material-consuming techniques, such as Ubbelohde viscometry and swelling measurements. Glassy and rubbery polymers, including high fractional free volume (FFV) microporous polymers such as PIM-1 and poly(1-trimethylsilyl-1-propyne) (PTMSP), are among the samples included in this study with great relevance to membrane science. In an attempt to enhance the accuracy of numerical estimate of polymer solubility parameters via the group contribution method, we provide updated group contribution parameters, along with their uncertainty, according to the technique recently reported by Smith et al. These updated group contribution parameters result in a mean absolute relative error of 9.0% in predicting the solubility parameter on a test set of 40 polymers, which is on par with the average 10% error reported previously. We also show, using machine learning techniques, that augmenting the group contribution model with extra parameters or non-linear relationships does not improve its accuracy. Results of the updated group contribution technique and dynamic light scattering measurements were compared to experimental viscometry on four test polymers, and the difference between the three techniques is compared.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49717346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Positively charged thin-film composite hollow fiber nanofiltration membrane via interfacial polymerization and branch polyethyleneimine modification for Mg2+/Li+ separation 正电荷薄膜复合中空纤维纳滤膜通过界面聚合和分支聚乙烯亚胺改性进行Mg2+/Li+分离

Journal of Membrane Science Letters Pub Date : 2023-08-26 DOI: 10.1016/j.memlet.2023.100061

Enlin Wang , Shaoxiao Liu , Liyang Liu , Lihui Han , Baowei Su

{"title":"Positively charged thin-film composite hollow fiber nanofiltration membrane via interfacial polymerization and branch polyethyleneimine modification for Mg2+/Li+ separation","authors":"Enlin Wang , Shaoxiao Liu , Liyang Liu , Lihui Han , Baowei Su","doi":"10.1016/j.memlet.2023.100061","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100061","url":null,"abstract":"<div>It is a vital technical challenge to extract lithium from salt-lake brine which has very high Mg2+ / Li+ mass ratio via green and low-cost methods, as these two cations have quite similar ionic hydration radius. Positively charged nanofiltration membranes can separate Li+ and Mg2+ through Donnan exclusion. In this work, a kind of hollow fiber nanofiltration membrane with positively charged skin layer was successfully fabricated via interfacial polymerization followed by a surface modification with branched polyethyleneimine (BPEI). The resultant membrane has a large number of amine groups, and thus shows positively charged surface with high rejection for divalent cation ions via Donnan exclusion. This gives it very high selectivity for the separation of Li+ ions from salt-lake brine. Under optimized conditions, it achieves a water permeance of up to 126.2 L m-2 h-1 MPa−1 at a transmembrane pressure difference of 4 bar, and a MgCl2 rejection of 94.6% with 2000 mg L-1 aqueous MgCl2 solution as feed. Meanwhile, it achieves a Mg2+ / Li+ selectivity of nearly 24 for MgCl2 and LiCl salt mixture solution with an overall concentration of 2000 mg L-1 and a Mg2+ / Li+ mass ratio of 150 : 1 as feed, which is high as compared with most of the literature, demonstrating its potential in the practical application of Mg2+ and Li+ separation.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49717343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lithium recovery from brines by lithium membrane flow capacitive deionization (Li-MFCDI) – A proof of concept 锂膜流动电容去离子(Li-MFCDI)从盐水中回收锂——概念验证

Journal of Membrane Science Letters Pub Date : 2023-08-12 DOI: 10.1016/j.memlet.2023.100059

H.M. Saif, J.G. Crespo, S. Pawlowski

{"title":"Lithium recovery from brines by lithium membrane flow capacitive deionization (Li-MFCDI) – A proof of concept","authors":"H.M. Saif, J.G. Crespo, S. Pawlowski","doi":"10.1016/j.memlet.2023.100059","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100059","url":null,"abstract":"<div>The demand of lithium for electric vehicles and energy storage devices is increasing rapidly, thus new sources of lithium (such as seawater and natural or industrial brines), as well as sustainable methods for its recovery, will need to be explored/developed soon. This work presents a novel electromembrane process, called Lithium Membrane Flow Capacitive Deionization (Li-MFCDI), which was tested to recover lithium from a synthetic geothermal brine containing a much higher mass concentration of sodium than lithium (more than 650 times). Specifically, a ceramic lithium-selective membrane was integrated into a flow capacitive deionization (FCDI) cell, which was specifically designed, and 3D printed, to allow simultaneous charging and regeneration of the employed flow electrodes. Despite the extremely high Na+/Li+ mass ratio in the feed stream, 99.98% of the sodium was rejected and the process selectivity for lithium over other monovalent cations was 141 ± 5.85 for Li+/Na+ and 46 ± 1.46 for Li+/K+. The Li-MFCDI process exhibited a stable behaviour over a 7-day test period, and the estimated energy consumption was 16.70 ± 1.63 kWh/kg of Li+ recovered in the draw solution. These results demonstrate promising potential of the Li-MFCDI for the sustainable lithium recovery from saline streams.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49717178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green chemistry-based fabrication of hollow fiber and flat sheet polyimide membranes for CO2/CH4 separation 基于绿色化学的CO2/CH4分离中空纤维和平板聚酰亚胺膜的制备

Journal of Membrane Science Letters Pub Date : 2023-08-11 DOI: 10.1016/j.memlet.2023.100057

George V. Theodorakopoulos, Dionysios S. Karousos, Charitomeni M. Veziri, Evangelos P. Kouvelos, Andreas A. Sapalidis, Evangelos P. Favvas

{"title":"Green chemistry-based fabrication of hollow fiber and flat sheet polyimide membranes for CO2/CH4 separation","authors":"George V. Theodorakopoulos, Dionysios S. Karousos, Charitomeni M. Veziri, Evangelos P. Kouvelos, Andreas A. Sapalidis, Evangelos P. Favvas","doi":"10.1016/j.memlet.2023.100057","DOIUrl":"https://doi.org/10.1016/j.memlet.2023.100057","url":null,"abstract":"<div>In this work, the successful fabrication of polymeric hollow fiber (HF) and flat sheet (FS) membranes was examined by employing γ-butyrolactone (GBL)-a green and environmentally friendly solvent- for the polymer's dissolution following the principles of green chemistry and sustainability regarding the membrane preparation. In addition, the ternary phase diagram of the P84/GBL/water was constructed and the viscosity of dope solution was measured for different concentrations and temperatures. Their morphological characteristics of the prepared polyimide membranes were investigated through SEM analysis. CO2/CH4 separation measurements under continuous flow were performed to evaluate the efficiency of the membranes for a binary 10/90 vol.% CO2/CH4 gas mixture. The developed green HF and FS membranes exhibited comparable, and in some cases even superior, performance compared to membranes prepared using the conventional and highly toxic NMP solvent, making them highly promising candidates for CO2/CH4 separation, with a real mixture separation factor of ∼58.</div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49735003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0