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Elementary electrochemistry 基本的电化学
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80113-4
Roger Parsons
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引用次数: 0
On the determination of kinetic parameters from potential-step and voltage-step measurements 用电位阶跃法和电压阶跃法测定动力学参数
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80008-6
K.B. Oldham, R.A. Osteryoung
{"title":"On the determination of kinetic parameters from potential-step and voltage-step measurements","authors":"K.B. Oldham,&nbsp;R.A. Osteryoung","doi":"10.1016/0022-0728(66)80008-6","DOIUrl":"10.1016/0022-0728(66)80008-6","url":null,"abstract":"<div><p>An analysis of published data shows that in the determination of rate constants from experimental potential-step and voltage-step measurements, extrapolations have not always been wisely made. Two methods of avoiding the difficulties are proposed and each has been applied to various data.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 397-405"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80008-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53127990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
B. Lovreček and D. Cipriš, Electrochemical studies of quinoline and isoquinoline B. lovre<e:1> ek和D. cipriv，喹啉和异喹啉的电化学研究
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80015-3
{"title":"B. Lovreček and D. Cipriš, Electrochemical studies of quinoline and isoquinoline","authors":"","doi":"10.1016/0022-0728(66)80015-3","DOIUrl":"https://doi.org/10.1016/0022-0728(66)80015-3","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Page 471"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80015-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"137353222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
K.F. Blurton and A.C. Riddiford, shapes of practical rotating disc electrodes K.F. Blurton和A.C. Riddiford，实用旋转圆盘电极的形状
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80014-1
{"title":"K.F. Blurton and A.C. Riddiford, shapes of practical rotating disc electrodes","authors":"","doi":"10.1016/0022-0728(66)80014-1","DOIUrl":"https://doi.org/10.1016/0022-0728(66)80014-1","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Page 471"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80014-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"137353221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Consecutive electrochemical processes in controlled potential electrolysis 可控电位电解中连续的电化学过程
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80012-8
John G. Mason
{"title":"Consecutive electrochemical processes in controlled potential electrolysis","authors":"John G. Mason","doi":"10.1016/0022-0728(66)80012-8","DOIUrl":"10.1016/0022-0728(66)80012-8","url":null,"abstract":"<div><p>The fundamental relations pertaining to the controlled potential electrolysis of a reaction path which involves two consecutive irreversible electrochemical reactions have been derived. The results show that in the true mass transport limiting current region, the conditions are such that no intermediates appear and plots of log <em>i</em> <em>vs.</em> <em>t</em> should be linear. This result is contrary to previous findings. The conditions necessary for the isolation of intermediates are discussed.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 462-466"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80012-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128177","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Electrometric studies on potassium aquopentacyano iron(II) aquopentacyano铁钾(II)的电滴定研究
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80013-X
Wahid U. Malik, Hari Om
{"title":"Electrometric studies on potassium aquopentacyano iron(II)","authors":"Wahid U. Malik,&nbsp;Hari Om","doi":"10.1016/0022-0728(66)80013-X","DOIUrl":"10.1016/0022-0728(66)80013-X","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 467-471"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80013-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Alternating current polarography with multi-step charge transfer 多步电荷转移的交流极谱法
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80011-6
Hoying L. Hung, Donald E. Smith
{"title":"Alternating current polarography with multi-step charge transfer","authors":"Hoying L. Hung,&nbsp;Donald E. Smith","doi":"10.1016/0022-0728(66)80011-6","DOIUrl":"10.1016/0022-0728(66)80011-6","url":null,"abstract":"<div><p>A theory is presented for the a.c. polarographic wave arising from a two-step charge transfer process in which rate control is exerted by diffusion and charge transfer. Predictions of the theory are examined in detail. It is found that: (a) conditions for pure diffusion control depend markedly on the relative values of the standard potentials associated with the two charge transfer steps; (b) many features potentially useful in mechanistic diagnosis are predicted for the a.c. polarographic read-out and ambiguity between single-step and two-step mechanisms is highly unlikely; (c) as one would expect, relative and absolute values of the rate and thermodynamic parameters associated with the charge transfer steps have a profound influence on the predicted a.c. polarographic-behavior; (d) despite the complexities and variety of behavior predicted, simple rationalization of many of the predictions is possible; (e) the problem of evaluating rate parameters from experimental data appears amenable to solution.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 425-461"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80011-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 33
Electrons and chemical bond 电子和化学键
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80016-5
K.W. Dunning
{"title":"Electrons and chemical bond","authors":"K.W. Dunning","doi":"10.1016/0022-0728(66)80016-5","DOIUrl":"10.1016/0022-0728(66)80016-5","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Page 472"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80016-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Polarography of neodymium, samarium, ytterbium and europium in acetonitrile 钕、钐、镱和铕在乙腈中的极谱分析
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80009-8
E.J. Cokal, E.N. Wise
{"title":"Polarography of neodymium, samarium, ytterbium and europium in acetonitrile","authors":"E.J. Cokal,&nbsp;E.N. Wise","doi":"10.1016/0022-0728(66)80009-8","DOIUrl":"10.1016/0022-0728(66)80009-8","url":null,"abstract":"<div><p>Europium, samarium, and ytterbium can be determined in rare-earth mixtures by polarography in specially purified solutions on the perchlorates. The polarographic waves correspond to the reduction of the tripositive ions to dipositive species. Water and traces of acid interfere but their effect can be made negligible by adding an excess of non-reducible rare earths. The half-wave potential of the Sm(II) - (O) polarogram in acetonitrile was found to be −1.55 V <em>vs.</em> the aqueous S.C.E.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 406-415"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80009-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
Further considerations on redox titration equations 对氧化还原滴定方程的进一步考虑
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-06-01 DOI: 10.1016/0022-0728(66)80010-4
James A. Goldman
{"title":"Further considerations on redox titration equations","authors":"James A. Goldman","doi":"10.1016/0022-0728(66)80010-4","DOIUrl":"10.1016/0022-0728(66)80010-4","url":null,"abstract":"<div><p>The results of an investigation into the dependence of the equivalence-point potential upon concentration and upon the equilibrium constant for the general redox reaction are presented. For symmetrical and homogeneous reactions, the equivalence-point potential is always concentration independent. The quantitative evaluation of the magnitude of the slope of the tangent to the titration curve at the equivalence point for homogeneous and symmetrical reactions is discussed as well as the rigorously calculated values of the potential at 50% and 200% titrated.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 416-424"},"PeriodicalIF":0.0,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80010-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
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