{"title":"用电位阶跃法和电压阶跃法测定动力学参数","authors":"K.B. Oldham, R.A. Osteryoung","doi":"10.1016/0022-0728(66)80008-6","DOIUrl":null,"url":null,"abstract":"<div><p>An analysis of published data shows that in the determination of rate constants from experimental potential-step and voltage-step measurements, extrapolations have not always been wisely made. Two methods of avoiding the difficulties are proposed and each has been applied to various data.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 6","pages":"Pages 397-405"},"PeriodicalIF":0.0000,"publicationDate":"1966-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80008-6","citationCount":"20","resultStr":"{\"title\":\"On the determination of kinetic parameters from potential-step and voltage-step measurements\",\"authors\":\"K.B. Oldham, R.A. Osteryoung\",\"doi\":\"10.1016/0022-0728(66)80008-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An analysis of published data shows that in the determination of rate constants from experimental potential-step and voltage-step measurements, extrapolations have not always been wisely made. Two methods of avoiding the difficulties are proposed and each has been applied to various data.</p></div>\",\"PeriodicalId\":100778,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry (1959)\",\"volume\":\"11 6\",\"pages\":\"Pages 397-405\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-0728(66)80008-6\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry (1959)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022072866800086\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022072866800086","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
On the determination of kinetic parameters from potential-step and voltage-step measurements
An analysis of published data shows that in the determination of rate constants from experimental potential-step and voltage-step measurements, extrapolations have not always been wisely made. Two methods of avoiding the difficulties are proposed and each has been applied to various data.
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