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Journal of Electroanalytical Chemistry (1959)最新文献

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Controlled chronopotentiometric stripping of metals deposited on the hanging mercury-drop electrode 控制计时电位剥离金属沉积在悬挂汞滴电极
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80102-X
Wiktor Kemula, Jerzy W. Strojek
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引用次数: 18
Characterization of bacterial pigments by single-sweep polarography 细菌色素的单扫极谱表征
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80109-2
G.C. Whitnack, Giorgio Soli
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引用次数: 0
“Metallkomplex” elektroden 综合金属电极:i、Ag(NH3)2、NH3电气，应用于研究复杂的双金属金属
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80107-9
Constantin Luca, Vasile Magearu, Grigore Popa
{"title":"“Metallkomplex” elektroden","authors":"Constantin Luca,&nbsp;Vasile Magearu,&nbsp;Grigore Popa","doi":"10.1016/0022-0728(66)80107-9","DOIUrl":"10.1016/0022-0728(66)80107-9","url":null,"abstract":"<div><p>Es wird ein neuer Elektrodentypus, unter dem Namen “Metallkomplex” Elektrode, untersucht, deren Potential von der Aktivität des Liganden in der Lösung einer Komplexverbindung abhängt.</p><p>Diese Elektroden ermöglichen die direkte potentiometrische Bestimmung einer grossen Zahl von Anionen oder neutralen Molekeln, desgleichen erlauben sie die Untersuchung der Bildungsprozesse der Komplexverbindungen sowie auch die Bestimmung der Gleichgewichtskonstanten.</p><p>In dieser Arbeit wurde die Ag[Ag(NH<sub>3</sub>)<sub>2</sub>]<sup>+</sup>, NH<sub>3</sub> Elektrode untersucht und die Möglichtkeit ihrer Verwendung bei der Bestimmung der sukzessiven Bildungskonstanten der komplexen Zn(II), Co(II) und Ni(II)-Ammoniakate, wobei eine sehr gute Übereinstimmung mit den Daten aus der Fachliteratur zu verzeichnen ist.</p><p>Dieser Elektrodentypus bietet eine Reihe von Vorteilen im Vergleich mit andern Elektroden, sowohl bei analytischen Bestimmungen als auch bei der Untersuchung der Bildungsreaktionen vieler komplexer Verbindungen.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 45-54"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80107-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53133262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Flame spectroscopy 火焰光谱法
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80114-6
G. Nickless
{"title":"Flame spectroscopy","authors":"G. Nickless","doi":"10.1016/0022-0728(66)80114-6","DOIUrl":"10.1016/0022-0728(66)80114-6","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 75-76"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80114-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53133392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Electrochemical behaviour of cadmium 镉的电化学行为
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80110-9
H.H. Bauer
{"title":"Electrochemical behaviour of cadmium","authors":"H.H. Bauer","doi":"10.1016/0022-0728(66)80110-9","DOIUrl":"10.1016/0022-0728(66)80110-9","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 64-67"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80110-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53133357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Ohmic drop distortion of anodic stripping curves from a thin mercury-film electrode 汞膜电极阳极剥离曲线的欧姆跌落畸变
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80103-1
W.T. De Vries, E. Van Dalen
{"title":"Ohmic drop distortion of anodic stripping curves from a thin mercury-film electrode","authors":"W.T. De Vries,&nbsp;E. Van Dalen","doi":"10.1016/0022-0728(66)80103-1","DOIUrl":"10.1016/0022-0728(66)80103-1","url":null,"abstract":"<div><p>An exact treatment of the effect of uncompensated ohmic drop on anodic stripping curves from a plane, thin mercury-film electrode is given. The decrease in peak current caused by the ohmic drop can be 2.5–3 times larger than in the corresponding case of semi-infinite linear diffusion (“normal” linear-sweep voltammetry) Practical implications of the results, as well as the case of spherical micro-electrodes, are discussed briefly.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 9-14"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80103-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
A cell with solid microelectrode with periodical renewal of the diffusion layer 具有扩散层周期性更新的固体微电极的电池
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80106-7
Danilo Cozzi, Giorgio Raspi, Lamberto Nucci
{"title":"A cell with solid microelectrode with periodical renewal of the diffusion layer","authors":"Danilo Cozzi,&nbsp;Giorgio Raspi,&nbsp;Lamberto Nucci","doi":"10.1016/0022-0728(66)80106-7","DOIUrl":"10.1016/0022-0728(66)80106-7","url":null,"abstract":"<div><p>A new cell with a platinum microelectrode is described: the diffusion layer is renewed by the periodical movement of the electrolyte caused by the displacement of a piston. A magnetic field causes the piston displacement. The diffusion current intensities, both instantaneous and average, may be calculated with a good agreement by the simple equation of spherical diffusion. The cell allows many possibilities of regulation both in the period of the electrode washing and in that during which the electrode is in the stationary electrolyte. Moreover, the flow speed of the solution may be easily regulated. This new cell is particularly interesting for the study of many electrochemical processes characterized by a high redox potential.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 36-44"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80106-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53133134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 66
Clarification of a supplementary polarographic device for automatic recording of capacitance 澄清一种用于自动记录电容的辅助极谱装置
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80111-0
E.M.L. Valeriote, R.G. Barradas
{"title":"Clarification of a supplementary polarographic device for automatic recording of capacitance","authors":"E.M.L. Valeriote,&nbsp;R.G. Barradas","doi":"10.1016/0022-0728(66)80111-0","DOIUrl":"10.1016/0022-0728(66)80111-0","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 67-69"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80111-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53133364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Adsorption et impedanck faradique 吸附和法拉第冲击：I.Etudk理论
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80104-3
A.M. Baticle, F. Perdu
{"title":"Adsorption et impedanck faradique","authors":"A.M. Baticle,&nbsp;F. Perdu","doi":"10.1016/0022-0728(66)80104-3","DOIUrl":"10.1016/0022-0728(66)80104-3","url":null,"abstract":"<div><p>From measurements of the faradaic impedance ot an electrochemical reaction with sinusoidal current it is possible to determine the partial processes of this reaction and to calculate the different kinetic parameters. The processes considered are: diffusion; charge transfer; adsorption of the reacting species. The calculation can be adapted to the determination of the double-layer capacity of an electrode in presence of a reaction controlled by diffusion and charge transfer.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 15-26"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80104-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
The effect of antimony and different anions on the potential of lead 锑和不同阴离子对铅电势的影响
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-07-01 DOI: 10.1016/0022-0728(66)80105-5
E.M. Khairy , A.A.Abdul Azim, K.M. El Sobki
{"title":"The effect of antimony and different anions on the potential of lead","authors":"E.M. Khairy ,&nbsp;A.A.Abdul Azim,&nbsp;K.M. El Sobki","doi":"10.1016/0022-0728(66)80105-5","DOIUrl":"10.1016/0022-0728(66)80105-5","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"12 1","pages":"Pages 27-35"},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80105-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53133069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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