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Journal of Electroanalytical Chemistry (1959)最新文献

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Une nouvelle technique de l'electrolyse: l'electrode a convection thermique application aux methodes electrochimiques d'analyse 一种新的电解技术:热对流电极在电化学分析方法中的应用
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80001-3
L. Ducret, C. Cornet
{"title":"Une nouvelle technique de l'electrolyse: l'electrode a convection thermique application aux methodes electrochimiques d'analyse","authors":"L. Ducret,&nbsp;C. Cornet","doi":"10.1016/0022-0728(66)80001-3","DOIUrl":"10.1016/0022-0728(66)80001-3","url":null,"abstract":"<div><p>In this new electrolysis technique, the mechanical stirring generally used in electrochemical methods of analysis is replaced by thermal stirring obtained by creating a temperature gradient between a stationary electrode and an initially immobile solution. The heating of the electrode by the Joule Effect is the simplest means of realising this. Experience has shown that this method of stirring gives excellent reproducibility of results and confers great stability on the electrolysis current of the imposed potential. The applications of this technique that spring to mind are mainly, the following of intensity-potential curves of various oxidation-reduction systems and the graphical representation of coulometry at constant potential by the simple plot of log <em>i</em> = <em>f</em>(<em>t</em>).</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 317-339"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80001-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53127773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Polarography of europium in formamide 乙酰胺中铕的极谱分析
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80004-9
J.N. Gaur, K. Zutshi
{"title":"Polarography of europium in formamide","authors":"J.N. Gaur,&nbsp;K. Zutshi","doi":"10.1016/0022-0728(66)80004-9","DOIUrl":"10.1016/0022-0728(66)80004-9","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 390-392"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80004-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53127856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Electrode kinetic aspects of electrochemical energy conversion 电化学能量转换的电极动力学方面
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80003-7
J.O'M. Bockris, S. Srinivasan
{"title":"Electrode kinetic aspects of electrochemical energy conversion","authors":"J.O'M. Bockris,&nbsp;S. Srinivasan","doi":"10.1016/0022-0728(66)80003-7","DOIUrl":"10.1016/0022-0728(66)80003-7","url":null,"abstract":"<div><p>The basic similarities and dissimilarities among the three electrochemical devices-electrochemical substance producer, electrochemical electricity producer and electrochemical electricity storer — are presented. Expressions are derived for the terminal cell potential, differential resistance, efficiency and power of an electrochemical electricity producer as a function, of the current drawn from it. These expressions have been used in numerical calculations to examine the effect of the various factors (<em>e.g.</em>, exchange currents, limiting currents, ohmic internal resistance) on the performance of the electrochemical energy converter. Analytical expressions for the maximum power, the terminal cell potential and the current, when the power is a maximum, are derived for two special cases.</p><p>The importance of electrocatalysis from the point of view of improving the performance of electrochemical electricity producers is stressed. Recent work on the kinetics of the important oxygen electrode reaction and on the mechanism of electroorganic oxidation is discussed. Some models of electrode design for increasing the apparent current density (and thereby reduce efficiency and power losses) are dealt with theoretically.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 350-389"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80003-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 34
Chemical instrumentation course 化学仪器课程
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80007-4
{"title":"Chemical instrumentation course","authors":"","doi":"10.1016/0022-0728(66)80007-4","DOIUrl":"https://doi.org/10.1016/0022-0728(66)80007-4","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Page 396"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80007-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"137370116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The polarographic investigation of the composition and stability constants of the benzoate complexes of cadmium 镉的苯甲酸盐配合物组成及稳定性常数的极谱研究
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80098-0
D.S. Jain, J.N. Gaur
{"title":"The polarographic investigation of the composition and stability constants of the benzoate complexes of cadmium","authors":"D.S. Jain,&nbsp;J.N. Gaur","doi":"10.1016/0022-0728(66)80098-0","DOIUrl":"10.1016/0022-0728(66)80098-0","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 310-312"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80098-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Chemical Thermodynanics, Basic Theory and Methods 化学热力学，基本理论与方法
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80101-8
Roger Parsons
{"title":"Chemical Thermodynanics, Basic Theory and Methods","authors":"Roger Parsons","doi":"10.1016/0022-0728(66)80101-8","DOIUrl":"https://doi.org/10.1016/0022-0728(66)80101-8","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Page 316"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80101-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136939967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A simple device1 for tast-polarography using knock-off electrodes 一种使用假电极进行快速极谱分析的简单装置
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80092-X
P.O. Kane
{"title":"A simple device1 for tast-polarography using knock-off electrodes","authors":"P.O. Kane","doi":"10.1016/0022-0728(66)80092-X","DOIUrl":"10.1016/0022-0728(66)80092-X","url":null,"abstract":"<div><p>A simple method of converting an existing polarograph for Tast-polarography is described. It is based on the use of a mechanical knock-off electrode and concomitant mechanical switching of the servo-motor of the polarograph recording potentiometer. Typical polarograms show that this device gives greater legibility than normal undamped operation without the distortion usually associated with heavy damping.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 276-281"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80092-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Bibliografia Polarografica (1922–1963), Parts I and II, Supplement No. 16 极谱文献(1922-1963)，第一和第二部分，补编第16号
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80100-6
T. Biegler
{"title":"Bibliografia Polarografica (1922–1963), Parts I and II, Supplement No. 16","authors":"T. Biegler","doi":"10.1016/0022-0728(66)80100-6","DOIUrl":"10.1016/0022-0728(66)80100-6","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Page 315"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80100-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The polarographic measurement of the formation constants of zinc and cadmium complexes with biologically important compounds 锌和镉与重要生物化合物配合物形成常数的极谱测定
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80096-7
Irwin H. Suffet, William C. Purdy
{"title":"The polarographic measurement of the formation constants of zinc and cadmium complexes with biologically important compounds","authors":"Irwin H. Suffet,&nbsp;William C. Purdy","doi":"10.1016/0022-0728(66)80096-7","DOIUrl":"10.1016/0022-0728(66)80096-7","url":null,"abstract":"<div><p>The polarography of zinc and cadmium in orthophosphate buffers of various pH-values has been studied. Infra-red studies of the colloidal suspension formed at pH 7.4 have shown this to be a mixture of the metal mono- and di-hydrogen orthophosphates. The nature and stability of complexes formed between zinc and cadmium and several groups of biologically important compounds has been examined. These compounds include cysteine, penicillamine, salicylates and hydroxyquinones. Finally, the polarography of alloxan has been examined briefly and complex formation between certain metals and alloxan at pH 7.4 has been attempted.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 302-307"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80096-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Suspensionselektrode zur charakterisierung der pulverkatalysatoren "选择催化剂
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80097-9
K. Schwabe, A. Staško
{"title":"Suspensionselektrode zur charakterisierung der pulverkatalysatoren","authors":"K. Schwabe,&nbsp;A. Staško","doi":"10.1016/0022-0728(66)80097-9","DOIUrl":"10.1016/0022-0728(66)80097-9","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 308-309"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80097-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
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