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Journal of Electroanalytical Chemistry (1959)最新文献

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Polarographisches halbstufenpotential des 1. angeregten singulettzustandes 第一次上学倡导的singulettzustandes
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80005-0
G. Löber
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引用次数: 1
Une nouvelle technique de l'electrolyse: l'electrode a convection thermique application aux methodes electrochimiques d'analyse 一种新的电解技术:热对流电极在电化学分析方法中的应用
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80001-3
L. Ducret, C. Cornet
{"title":"Une nouvelle technique de l'electrolyse: l'electrode a convection thermique application aux methodes electrochimiques d'analyse","authors":"L. Ducret,&nbsp;C. Cornet","doi":"10.1016/0022-0728(66)80001-3","DOIUrl":"10.1016/0022-0728(66)80001-3","url":null,"abstract":"<div><p>In this new electrolysis technique, the mechanical stirring generally used in electrochemical methods of analysis is replaced by thermal stirring obtained by creating a temperature gradient between a stationary electrode and an initially immobile solution. The heating of the electrode by the Joule Effect is the simplest means of realising this. Experience has shown that this method of stirring gives excellent reproducibility of results and confers great stability on the electrolysis current of the imposed potential. The applications of this technique that spring to mind are mainly, the following of intensity-potential curves of various oxidation-reduction systems and the graphical representation of coulometry at constant potential by the simple plot of log <em>i</em> = <em>f</em>(<em>t</em>).</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 317-339"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80001-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53127773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Polarography of europium in formamide 乙酰胺中铕的极谱分析
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80004-9
J.N. Gaur, K. Zutshi
{"title":"Polarography of europium in formamide","authors":"J.N. Gaur,&nbsp;K. Zutshi","doi":"10.1016/0022-0728(66)80004-9","DOIUrl":"10.1016/0022-0728(66)80004-9","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 390-392"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80004-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53127856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Electrode kinetic aspects of electrochemical energy conversion 电化学能量转换的电极动力学方面
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80003-7
J.O'M. Bockris, S. Srinivasan
{"title":"Electrode kinetic aspects of electrochemical energy conversion","authors":"J.O'M. Bockris,&nbsp;S. Srinivasan","doi":"10.1016/0022-0728(66)80003-7","DOIUrl":"10.1016/0022-0728(66)80003-7","url":null,"abstract":"<div><p>The basic similarities and dissimilarities among the three electrochemical devices-electrochemical substance producer, electrochemical electricity producer and electrochemical electricity storer — are presented. Expressions are derived for the terminal cell potential, differential resistance, efficiency and power of an electrochemical electricity producer as a function, of the current drawn from it. These expressions have been used in numerical calculations to examine the effect of the various factors (<em>e.g.</em>, exchange currents, limiting currents, ohmic internal resistance) on the performance of the electrochemical energy converter. Analytical expressions for the maximum power, the terminal cell potential and the current, when the power is a maximum, are derived for two special cases.</p><p>The importance of electrocatalysis from the point of view of improving the performance of electrochemical electricity producers is stressed. Recent work on the kinetics of the important oxygen electrode reaction and on the mechanism of electroorganic oxidation is discussed. Some models of electrode design for increasing the apparent current density (and thereby reduce efficiency and power losses) are dealt with theoretically.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 350-389"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80003-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 34
Chemical instrumentation course 化学仪器课程
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80007-4
{"title":"Chemical instrumentation course","authors":"","doi":"10.1016/0022-0728(66)80007-4","DOIUrl":"https://doi.org/10.1016/0022-0728(66)80007-4","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Page 396"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80007-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"137370116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Introduction to electroanalysis 电分析概论
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80006-2
T. Biegler
{"title":"Introduction to electroanalysis","authors":"T. Biegler","doi":"10.1016/0022-0728(66)80006-2","DOIUrl":"10.1016/0022-0728(66)80006-2","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Page 396"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80006-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53127970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rate studies on the iodination of tetraorganolead compounds 四有机铅化合物碘化的速率研究
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-05-01 DOI: 10.1016/0022-0728(66)80002-5
L. Rïccoboni, G. Pilloni, G. Plazzogna, G. Tagliavini
{"title":"Rate studies on the iodination of tetraorganolead compounds","authors":"L. Rïccoboni,&nbsp;G. Pilloni,&nbsp;G. Plazzogna,&nbsp;G. Tagliavini","doi":"10.1016/0022-0728(66)80002-5","DOIUrl":"10.1016/0022-0728(66)80002-5","url":null,"abstract":"<div><p>The analytical technique of biamperometric titration, has been utilized to obtain kinetic data in different polar solvents on the reaction, R<sub>4</sub>Pb + I<sub>2</sub> = R<sub>3</sub>Pb<sup>+</sup>I<sup>−</sup> + RI, where R is CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub> or <em>n</em>-C<sub>3</sub>H<sub>7</sub>.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 5","pages":"Pages 340-349"},"PeriodicalIF":0.0,"publicationDate":"1966-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80002-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53128212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
A general equation for the description of redox titration curves 描述氧化还原滴定曲线的一般方程
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80090-6
James A. Goldman
{"title":"A general equation for the description of redox titration curves","authors":"James A. Goldman","doi":"10.1016/0022-0728(66)80090-6","DOIUrl":"10.1016/0022-0728(66)80090-6","url":null,"abstract":"<div><p>An equation is presented for the description of the entire titration curve obtained in homogeneous and symmetrical redox reactions. This equation permits the rigorous calculation of the progress of the titration from the corresponding value of the potential. The form of the equation is investigated in detail at some points of interest. Also discussed, is the relationship between the exact form of the equation and the commonly used equations.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 255-261"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80090-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Effect of some tetraalkylammonium hydroxides on the electrode kinetics of the chromi-chromocyanide couple 某些四烷基氢氧铵对铬-铬氰化物偶联电极动力学的影响
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80099-2
Anna Maria Giuliani
{"title":"Effect of some tetraalkylammonium hydroxides on the electrode kinetics of the chromi-chromocyanide couple","authors":"Anna Maria Giuliani","doi":"10.1016/0022-0728(66)80099-2","DOIUrl":"10.1016/0022-0728(66)80099-2","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 313-315"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80099-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
The polarographic investigation of the composition and stability constants of the benzoate complexes of cadmium 镉的苯甲酸盐配合物组成及稳定性常数的极谱研究
Journal of Electroanalytical Chemistry (1959) Pub Date : 1966-04-01 DOI: 10.1016/0022-0728(66)80098-0
D.S. Jain, J.N. Gaur
{"title":"The polarographic investigation of the composition and stability constants of the benzoate complexes of cadmium","authors":"D.S. Jain,&nbsp;J.N. Gaur","doi":"10.1016/0022-0728(66)80098-0","DOIUrl":"10.1016/0022-0728(66)80098-0","url":null,"abstract":"","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 310-312"},"PeriodicalIF":0.0,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80098-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"53132596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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