{"title":"描述氧化还原滴定曲线的一般方程","authors":"James A. Goldman","doi":"10.1016/0022-0728(66)80090-6","DOIUrl":null,"url":null,"abstract":"<div><p>An equation is presented for the description of the entire titration curve obtained in homogeneous and symmetrical redox reactions. This equation permits the rigorous calculation of the progress of the titration from the corresponding value of the potential. The form of the equation is investigated in detail at some points of interest. Also discussed, is the relationship between the exact form of the equation and the commonly used equations.</p></div>","PeriodicalId":100778,"journal":{"name":"Journal of Electroanalytical Chemistry (1959)","volume":"11 4","pages":"Pages 255-261"},"PeriodicalIF":0.0000,"publicationDate":"1966-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-0728(66)80090-6","citationCount":"16","resultStr":"{\"title\":\"A general equation for the description of redox titration curves\",\"authors\":\"James A. Goldman\",\"doi\":\"10.1016/0022-0728(66)80090-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An equation is presented for the description of the entire titration curve obtained in homogeneous and symmetrical redox reactions. This equation permits the rigorous calculation of the progress of the titration from the corresponding value of the potential. The form of the equation is investigated in detail at some points of interest. Also discussed, is the relationship between the exact form of the equation and the commonly used equations.</p></div>\",\"PeriodicalId\":100778,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry (1959)\",\"volume\":\"11 4\",\"pages\":\"Pages 255-261\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-0728(66)80090-6\",\"citationCount\":\"16\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry (1959)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022072866800906\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry (1959)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022072866800906","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A general equation for the description of redox titration curves
An equation is presented for the description of the entire titration curve obtained in homogeneous and symmetrical redox reactions. This equation permits the rigorous calculation of the progress of the titration from the corresponding value of the potential. The form of the equation is investigated in detail at some points of interest. Also discussed, is the relationship between the exact form of the equation and the commonly used equations.