International Journal of Inorganic Materials最新文献_第5页

Intercalation chemistry of superconducting zirconium and hafnium nitride halides 超导氮化锆和铪卤化物的插层化学

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00135-0

M.R Palacı́n , J Oró-Solé , M Vlassov , B Martı́nez , D Beltrán-Porter , M.T Caldés , A Fuertes

{"title":"Intercalation chemistry of superconducting zirconium and hafnium nitride halides","authors":"M.R Palacı́n , J Oró-Solé , M Vlassov , B Martı́nez , D Beltrán-Porter , M.T Caldés , A Fuertes","doi":"10.1016/S1466-6049(01)00135-0","DOIUrl":"10.1016/S1466-6049(01)00135-0","url":null,"abstract":"<div>Lithium intercalation in MNX (M=Zr, Hf; X=Cl, Br) may lead to superconducting compounds with critical temperatures up to 24 K. Electrochemical lithiation experiments agree with the results obtained with chemical methods, as samples with larger capacity on discharge are also those having larger lithium contents after chemical lithiation. Variations exist in the electrochemical profiles of different batches for these compounds indicating differences in the intercalation reaction pathway. High-resolution electron microscopy images confirm the structural model isotypic to SmSI for β-MNX phases. The major part of crystals from ZrNX as well as from the HfNCl samples showing a high lithium intercalation degree exhibit a regular stacking of the layers, being almost free of defects. In contrast, samples with low lithium uptakes show a high proportion of crystals with a HfO2 layer at their thin edges. In agreement with these results, magnetic measurements for LixHfNCl indicate, in contrast to LixZrNX compounds, small superconducting fractions and very broad transitions consistent with a distribution of critical temperatures and a heterogeneous nature of the samples.</div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1291-1293"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00135-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89579675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Epitaxy induced phase stabilization: a comparative experimental and elasticity-based theoretical study on MBE grown PbSe/CaF2/Si epilayer 外延诱导相稳定:MBE生长PbSe/CaF2/Si薄膜的实验与弹性理论对比研究

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00142-8

G Breton , T Maurice , P Masri , S Charar , M Averous

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引用次数: 3

Notes for Authors–International Journal of Inorganic Materials 作者说明-国际无机材料杂志

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00206-9

引用次数: 0

Importance of soft solution processing for advanced BaZrO3 materials 软溶工艺对先进BaZrO3材料的重要性

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00122-2

B Robertz, F Boschini, R Cloots, A Rulmont

引用次数: 27

High temperature electrical conductivity in the Ag solubility limit region in ZnS and in CdSe 在ZnS和CdSe中Ag溶解度极限区域的高温电导率

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00137-4

K Lott , T Nirk , M Raukas , O Volobujeva , A Öpik , A Vishnjakov

引用次数: 0

Typical features of nitrogen in nitride-type compounds 氮类化合物中氮的典型特征

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00145-3

Roger Marchand, Franck Tessier, André Le Sauze, Nadège Diot

引用次数: 46

Phase equilibria in the system La2O3–SrO–Mn3O4 in air 空气中La2O3-SrO-Mn3O4体系的相平衡

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00156-8

Peter Majewski, Darja Benne, Lars Epple, Fritz Aldinger

引用次数: 12

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00125-8

A Misiuk , H.B Surma , M Lopez

引用次数: 6

NTC characteristics of bismuth based ceramic at high temperature 铋基陶瓷高温NTC特性研究

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00132-5

A Basu, A.W Brinkman, T Hashemi

{"title":"NTC characteristics of bismuth based ceramic at high temperature","authors":"A Basu, A.W Brinkman, T Hashemi","doi":"10.1016/S1466-6049(01)00132-5","DOIUrl":"10.1016/S1466-6049(01)00132-5","url":null,"abstract":"<div>NTC characteristics of a ceramic based on Bi2O3 doped with TiO2, Ta2O5 and WO3 have been studied over a temperature range of 100 to 700°C. The material was pressed into pellets and sintered in air from 700 to 1000°C at 100°C intervals for 14 h. The microstructure was studied using SEM and evidence of a sintered body with grain sizes approximately 7–10 μm was observed in the material fired at 1000°C. XRD analysis indicated the emergence of a monophase material when sintered at 1000°C, which clearly verified along with the SEM studies, the completion of the sintering process. Electrical characterisation of the material was done by measuring the resistance and the capacitance over a temperature range of 100 to 700°C, in air. The material showed good NTC characteristics over the whole range of temperature with thermistor constants B=4840 K and ΔE=386 meV. The capacitance changed significantly over the temperature range (∼10−11 F at 100°C to ∼10−6 F at 700°C).</div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1219-1221"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00132-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82719158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 22

Antimony dopant redistribution during copper silicide formation 硅化铜形成过程中锑掺杂物的重分布

International Journal of Inorganic Materials Pub Date : 2001-12-01 DOI: 10.1016/S1466-6049(01)00141-6

M Benkerri , R Halimi , A Bouabellou , A Mosser , J.P Sens

引用次数: 3