International Journal of Inorganic Materials最新文献

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Elimination of silicon hillocks using an alkaline complexant etching system 用碱性络合剂蚀刻系统消除硅丘
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00117-9
Carmen Moldovan, Rodica Iosub, Mircea Modreanu
{"title":"Elimination of silicon hillocks using an alkaline complexant etching system","authors":"Carmen Moldovan,&nbsp;Rodica Iosub,&nbsp;Mircea Modreanu","doi":"10.1016/S1466-6049(01)00117-9","DOIUrl":"10.1016/S1466-6049(01)00117-9","url":null,"abstract":"<div><p>This paper presents the results obtained in silicon hillock elimination using alkaline solutions: KOH, NaOH, LiOH·H<sub>2</sub>O with an added complexant. The added complexant in alkaline solutions is azocalix[4]arene. The alkaline solutions were compared and analysed with and without added complexant for their effect on hillocks. The behaviour of these solutions is explained using the theory of molar conductivity. The results show that use of the complexant permits control of the etching process, yielding a smooth silicon surface, almost free of hillocks. A comparison between the alkaline etchants (KOH, NaOH, LiOH·H<sub>2</sub>O) is made and the influence of the cations in silicon etching process is explained.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1173-1176"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00117-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82775503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Ordered mesoporous materials: composition and topology control through chemistry 有序介孔材料:化学组成与拓扑控制
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00114-3
J. El Haskouri , S. Cabrera , M. Caldés , J. Alamo , A. Beltrán-Porter , M.D. Marcos , P. Amorós , D. Beltrán-Porter
{"title":"Ordered mesoporous materials: composition and topology control through chemistry","authors":"J. El Haskouri ,&nbsp;S. Cabrera ,&nbsp;M. Caldés ,&nbsp;J. Alamo ,&nbsp;A. Beltrán-Porter ,&nbsp;M.D. Marcos ,&nbsp;P. Amorós ,&nbsp;D. Beltrán-Porter","doi":"10.1016/S1466-6049(01)00114-3","DOIUrl":"10.1016/S1466-6049(01)00114-3","url":null,"abstract":"<div><p>The atrane route constitutes a very versatile technique to obtain ordered mesoporous materials. A wide diversity of silica and silica-doped materials can be prepared by bringing into play fundamental synthesis parameters (like temperature, concentration and pH) which, in turn, allow modulation of the resulting material topology.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1157-1163"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00114-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74561521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 18
Liquid phase sintering of NiCuZn ferrite and its magnetic properties NiCuZn铁氧体的液相烧结及其磁性能
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00123-4
Yuh-Ruey Wang, Sea-Fue Wang
{"title":"Liquid phase sintering of NiCuZn ferrite and its magnetic properties","authors":"Yuh-Ruey Wang,&nbsp;Sea-Fue Wang","doi":"10.1016/S1466-6049(01)00123-4","DOIUrl":"10.1016/S1466-6049(01)00123-4","url":null,"abstract":"<div><p><span>The influence of glass additives on the densification, microstructural evolution and magnetic properties of NiCuZn ferrites were investigated. Two glass systems including PbO·SiO</span><sub>2</sub> and PbO·B<sub>2</sub>O<sub>3</sub><span> were used to reduce the sintering temperature of a NiCuZn ferrite. The PbO·SiO</span><sub>2</sub><span> glass system was shown to be an effective additive to obstruct the grain boundary movement and prevent the abnormal grain growth. In addition, it significantly lowers the sintering temperature of the ferrite. Ferrites sintered with PbO·SiO</span><sub>2</sub> have higher resistivity, higher <em>Q</em> and higher <em>H</em><sub>c</sub> compared with those of PbO·B<sub>2</sub>O<sub>3</sub> systems. These results also indicated that the ratio of modifier to glass-former did not significantly change the densification behavior, microstructural evolution and magnetic properties of the NiCuZn ferrite.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1189-1192"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00123-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88164687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
The role of oxygen in formation of radiative recombination centers in ZnSe1−xTex crystals 氧在ZnSe1−xTex晶体辐射复合中心形成中的作用
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00138-6
V.D Ryzhikov , N.G Starzhinskiy , L.P Gal’chinetskii , V.I Silin , G Tamulaitis , E.K Lisetskaya
{"title":"The role of oxygen in formation of radiative recombination centers in ZnSe1−xTex crystals","authors":"V.D Ryzhikov ,&nbsp;N.G Starzhinskiy ,&nbsp;L.P Gal’chinetskii ,&nbsp;V.I Silin ,&nbsp;G Tamulaitis ,&nbsp;E.K Lisetskaya","doi":"10.1016/S1466-6049(01)00138-6","DOIUrl":"10.1016/S1466-6049(01)00138-6","url":null,"abstract":"<div><p>The present study was aimed at revealing the influence of oxygen on formation of alloy ZnSe–ZnTe as well as on development of luminescence centers under thermal treatment of scintillators based on isovalently doped ZnSe crystals. The presence of oxygen in ZnSe(Te) crystals as ZnO phase has been shown to hinder formation of (V′<sub>Zn</sub>Te<sup><em>x</em></sup><sub>Se</sub><span>)′ type luminescence centers responsible for luminescence band peaked at 635–640 nm, which is the principal emission band of this scintillator. In ZnSe(Te) crystals doped by mechanically stimulated ion implantation with active forms of oxygen (O′, O</span><sup><em>x</em></sup>, O′<sub>2</sub>, etc.), luminescence quenching effects are not observed. However, the luminescence band in these crystals is blueshifted towards 600–610 nm. Strong luminescence band peaked at <em>λ</em><sub>max</sub>=590–610 nm is observed in Te-free ZnSe crystals doped with oxygen in active forms. The experimental results are interpreted by formation of centers (Zn<sub>i</sub><sup>⋅</sup>O<sup><em>x</em></sup><sub>i</sub>)<sup>⋅</sup> or (Zn<sub>i</sub><sup>⋅</sup>O<sup><em>x</em></sup><sub>Se</sub>)<sup>⋅</sup>. Having larger charge carrier capture cross-section than (Zn<sup>⋅</sup><sub>i</sub>V′<sub>Zn</sub>Te<sup><em>x</em></sup><sub>Se</sub>)<sup><em>x</em></sup>, the oxygen-containing centers determine kinetics of luminescence in ZnSe<sub>1−<em>x</em></sub>Te<sub><em>x</em></sub> crystals (<em>x</em><span>&lt;0.001) treated by active forms of oxygen during mechanical activation of the initial raw material for crystal growth.</span></p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1227-1229"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00138-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74171611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
High temperature electrical conductivity in Ga and In solubility limit region in ZnS Ga的高温电导率和ZnS的in溶解度极限区
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00159-3
K. Lott , M. Raukas , O. Volobujeva , A. Vishnjakov , A. Grebennik
{"title":"High temperature electrical conductivity in Ga and In solubility limit region in ZnS","authors":"K. Lott ,&nbsp;M. Raukas ,&nbsp;O. Volobujeva ,&nbsp;A. Vishnjakov ,&nbsp;A. Grebennik","doi":"10.1016/S1466-6049(01)00159-3","DOIUrl":"10.1016/S1466-6049(01)00159-3","url":null,"abstract":"<div><p>High temperature electrical conductivity (HTEC) and solubility measurements of Ga and In were performed in ZnS. To investigate Ga and In solubility in ZnS under the controlled vapour pressure of Zn, a special construction of quartz ampoules were used. Ga and In solubility isotherms in ZnS are given. At high temperatures and at low concentrations, Ga and In act as a single donor. At high zinc pressures, outdiffusion of gallium<span> and indium occurs. The change of the solubility of Ga or In is reflected in ZnS HTEC isotherms. If doped at the same doping conditions, ZnS:Ga and ZnS:In had the same HTEC absolute values despite the differences in Ga and In solubilities.</span></p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1345-1347"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00159-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79113023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Stress-induced transformation of microdefects in neutron irradiated Czochralski silicon 中子辐照恰克拉尔斯基硅微缺陷的应力诱导转变
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00146-5
J Bak-Misiuk , C.A Londos , A Misiuk , L.G Fytros , H.B Surma , J Trela , K Papastergiou , J Domagala
{"title":"Stress-induced transformation of microdefects in neutron irradiated Czochralski silicon","authors":"J Bak-Misiuk ,&nbsp;C.A Londos ,&nbsp;A Misiuk ,&nbsp;L.G Fytros ,&nbsp;H.B Surma ,&nbsp;J Trela ,&nbsp;K Papastergiou ,&nbsp;J Domagala","doi":"10.1016/S1466-6049(01)00146-5","DOIUrl":"10.1016/S1466-6049(01)00146-5","url":null,"abstract":"<div><p>Microstructure of neutron irradiated Cz-Si has been examined after out-annealing of irradiation-induced defects and pressure treatment at 1170 K-1 GPa. X-ray diffuse scattering and defect dimensions are related to oxygen concentration and to stress-induced oxygen precipitation. The pressure treatment results in diminished diffuse scattering and defect dimensions.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1307-1309"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00146-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80788476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intercalation chemistry of superconducting zirconium and hafnium nitride halides 超导氮化锆和铪卤化物的插层化学
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00135-0
M.R Palacı́n , J Oró-Solé , M Vlassov , B Martı́nez , D Beltrán-Porter , M.T Caldés , A Fuertes
{"title":"Intercalation chemistry of superconducting zirconium and hafnium nitride halides","authors":"M.R Palacı́n ,&nbsp;J Oró-Solé ,&nbsp;M Vlassov ,&nbsp;B Martı́nez ,&nbsp;D Beltrán-Porter ,&nbsp;M.T Caldés ,&nbsp;A Fuertes","doi":"10.1016/S1466-6049(01)00135-0","DOIUrl":"10.1016/S1466-6049(01)00135-0","url":null,"abstract":"<div><p>Lithium intercalation in MNX (M=Zr, Hf; X=Cl, Br) may lead to superconducting compounds with critical temperatures up to 24 K. Electrochemical lithiation experiments agree with the results obtained with chemical methods, as samples with larger capacity on discharge are also those having larger lithium contents after chemical lithiation. Variations exist in the electrochemical profiles of different batches for these compounds indicating differences in the intercalation reaction pathway. High-resolution electron microscopy images confirm the structural model isotypic to SmSI for β-MNX phases. The major part of crystals from ZrNX as well as from the HfNCl samples showing a high lithium intercalation degree exhibit a regular stacking of the layers, being almost free of defects. In contrast, samples with low lithium uptakes show a high proportion of crystals with a HfO<sub>2</sub> layer at their thin edges. In agreement with these results, magnetic measurements for Li<sub><em>x</em></sub>HfNCl indicate, in contrast to Li<sub><em>x</em></sub>ZrNX compounds, small superconducting fractions and very broad transitions consistent with a distribution of critical temperatures and a heterogeneous nature of the samples.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1291-1293"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00135-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89579675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Epitaxy induced phase stabilization: a comparative experimental and elasticity-based theoretical study on MBE grown PbSe/CaF2/Si epilayer 外延诱导相稳定:MBE生长PbSe/CaF2/Si薄膜的实验与弹性理论对比研究
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00142-8
G Breton , T Maurice , P Masri , S Charar , M Averous
{"title":"Epitaxy induced phase stabilization: a comparative experimental and elasticity-based theoretical study on MBE grown PbSe/CaF2/Si epilayer","authors":"G Breton ,&nbsp;T Maurice ,&nbsp;P Masri ,&nbsp;S Charar ,&nbsp;M Averous","doi":"10.1016/S1466-6049(01)00142-8","DOIUrl":"10.1016/S1466-6049(01)00142-8","url":null,"abstract":"<div><p><span><span>Modern epitaxial growth<span> techniques show that material-phase stabilization can be achieved by epitaxial growth provided that suitable substrate (s) are used. Buffer layers (BL) play a vital role in epitaxial growth optimisation. By applying through the BL/s </span></span>heterostructure continuity conditions on relevant strain-related features, we perform a self-consistent growth-optimisation strategy involving BL compositions. The calculation of these strain-related phase-dependent features enables to achieve an approach of as-grown material phase determination based on epitaxy experiments and theoretical previsions. To illustrate this methodology, we have investigated the lead salt IV–VI PbSe/CaF</span><sub>2</sub><span>/Si(111) epilayer grown by MBE. For the optimised BL, a thin CaFSe layer has been grown under Se flux of CaF</span><sub>2</sub> layer before deposition of the PbSe layer. The efficiency of the continuity conditions in optimising MBE growth is shown by characterising all samples by high-resolution X-ray diffraction, atomic force microscopy for structural quality and Hall effect for electrical properties.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1237-1239"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00142-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91461696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Notes for Authors–International Journal of Inorganic Materials 作者说明-国际无机材料杂志
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00206-9
{"title":"Notes for Authors–International Journal of Inorganic Materials","authors":"","doi":"10.1016/S1466-6049(01)00206-9","DOIUrl":"https://doi.org/10.1016/S1466-6049(01)00206-9","url":null,"abstract":"","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages XXVII-XXIX"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00206-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138344986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxygen-related micro-defects in Czochralski silicon annealed at enhanced stress conditions 在强化应力条件下退火的直克拉氏硅中的氧相关微缺陷
International Journal of Inorganic Materials Pub Date : 2001-12-01 Epub Date: 2001-11-19 DOI: 10.1016/S1466-6049(01)00125-8
A Misiuk , H.B Surma , M Lopez
{"title":"Oxygen-related micro-defects in Czochralski silicon annealed at enhanced stress conditions","authors":"A Misiuk ,&nbsp;H.B Surma ,&nbsp;M Lopez","doi":"10.1016/S1466-6049(01)00125-8","DOIUrl":"10.1016/S1466-6049(01)00125-8","url":null,"abstract":"<div><p><span>Effect of enhanced (up to 1.2 GPa) hydrostatic argon pressure on creation of oxygen-related micro-defects (such as oxygen clusters, OC’s, and precipitates, OP’s) in Cz–Si during high temperature–high pressure treatment, HT–HP, at up to 1400 K, was investigated by chemical selective etching, FTIR, and photoluminescence, PL, methods. Cz–Si contained interstitial oxygen, O</span><sub>i</sub>, with a concentration, <em>c</em><sub>0</sub>, up to 1.1×10<sup>18</sup> cm<sup>3</sup>; prior to the HT–HP treatment some samples were pre-annealed at (720, 830) K–10<sup>5</sup> Pa to create nucleation centres for O<sub>i</sub> precipitation. The HT–HP treatment results in decrease of <em>c</em><sub>0</sub>, revealing defect-related PL bands and enhanced (in comparison to effect of annealing at 10<sup>5</sup> Pa) creation of oxygen-related micro-defects.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1197-1199"},"PeriodicalIF":0.0,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00125-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80116339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
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