Roger Marchand, Franck Tessier, André Le Sauze, Nadège Diot
{"title":"氮类化合物中氮的典型特征","authors":"Roger Marchand, Franck Tessier, André Le Sauze, Nadège Diot","doi":"10.1016/S1466-6049(01)00145-3","DOIUrl":null,"url":null,"abstract":"<div><p><span>Nitride and oxynitride materials have attractive properties directly related to the role played by nitrogen. In particular, a comparison between oxynitrides and oxides highlights the characteristics of a nitrogen N</span><sup>3−</sup>/oxygen O<sup>2−</sup> substitution: an increase in the anionic formal charge, a greater covalent character, a higher cross-linking density in glasses, a reducing character due to the N<sup>3−</sup>/N<sup>0</sup> redox couple, and modified acid–base properties. Each specific character is illustrated by appropriate examples.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 8","pages":"Pages 1143-1146"},"PeriodicalIF":0.0000,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00145-3","citationCount":"46","resultStr":"{\"title\":\"Typical features of nitrogen in nitride-type compounds\",\"authors\":\"Roger Marchand, Franck Tessier, André Le Sauze, Nadège Diot\",\"doi\":\"10.1016/S1466-6049(01)00145-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>Nitride and oxynitride materials have attractive properties directly related to the role played by nitrogen. In particular, a comparison between oxynitrides and oxides highlights the characteristics of a nitrogen N</span><sup>3−</sup>/oxygen O<sup>2−</sup> substitution: an increase in the anionic formal charge, a greater covalent character, a higher cross-linking density in glasses, a reducing character due to the N<sup>3−</sup>/N<sup>0</sup> redox couple, and modified acid–base properties. Each specific character is illustrated by appropriate examples.</p></div>\",\"PeriodicalId\":100700,\"journal\":{\"name\":\"International Journal of Inorganic Materials\",\"volume\":\"3 8\",\"pages\":\"Pages 1143-1146\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00145-3\",\"citationCount\":\"46\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Inorganic Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1466604901001453\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1466604901001453","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Typical features of nitrogen in nitride-type compounds
Nitride and oxynitride materials have attractive properties directly related to the role played by nitrogen. In particular, a comparison between oxynitrides and oxides highlights the characteristics of a nitrogen N3−/oxygen O2− substitution: an increase in the anionic formal charge, a greater covalent character, a higher cross-linking density in glasses, a reducing character due to the N3−/N0 redox couple, and modified acid–base properties. Each specific character is illustrated by appropriate examples.
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