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Experimental investigation and analysis for the bubble size distribution during alkaline water electrolysis by using a wire electrode 利用线电极对碱性水电解过程中的气泡大小分布进行实验研究和分析
DeCarbon Pub Date : 2024-09-01 Epub Date: 2024-06-17 DOI: 10.1016/j.decarb.2024.100052
Yang Liu , Shuang Li , Honglu Wu , Yixiang Shi
{"title":"Experimental investigation and analysis for the bubble size distribution during alkaline water electrolysis by using a wire electrode","authors":"Yang Liu ,&nbsp;Shuang Li ,&nbsp;Honglu Wu ,&nbsp;Yixiang Shi","doi":"10.1016/j.decarb.2024.100052","DOIUrl":"https://doi.org/10.1016/j.decarb.2024.100052","url":null,"abstract":"<div><p>The determination of bubble size distribution is a prerequisite for the study of gas-liquid two-phase flow characteristics in electrolytic cells. Here the departure diameter of hydrogen bubbles and oxygen bubbles and their detachment process from a nickel wire electrode during water electrolysis are studied using high-speed photography. The results show that in industrial alkaline environment, the departure diameters of most hydrogen bubbles and oxygen bubbles are generally smaller than 60 ​μm and 250 ​μm with the current density ranges from 0.15 to 0.35 ​A/cm<sup>2</sup>. The adhesion force of hydrogen bubbles on a nickel wire is found to be so weak that they can separate with a tiny size. The diameters of oxygen bubbles conform to normal distribution, and its distribution range widens with the increase of current density. The theoretical analysis show that the comprehensive conversion rate of current-to-bubble is unexpectedly low especially at low current densities, which may be attributed to the loss of gas components caused by bubble detachment mode. The majority of oxygen bubbles detach by a sudden bounce after coalescence, which may bring strong disturbance to the concentration boundary layer. This also indicates the coalescence-induced bubble departure mode may occupy a dominant position in the electrolyzers.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"5 ","pages":"Article 100052"},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000180/pdfft?md5=29e09bb4a4ffb0f43ae2d97b3b7ceac7&pid=1-s2.0-S2949881324000180-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141485433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly conductive solid-solid phase change composites and devices enhanced by aligned graphite networks for solar/electro-thermal energy storage 通过排列石墨网络增强的高导电固固相变复合材料和设备,用于太阳能/电热能量存储
DeCarbon Pub Date : 2024-09-01 Epub Date: 2024-06-13 DOI: 10.1016/j.decarb.2024.100051
Yiqi Zhao , Pengfei Zhang , Yu Qiu , Qing Li , Hongjie Yan , Zhaolong Wang , Ciwei Wu
{"title":"Highly conductive solid-solid phase change composites and devices enhanced by aligned graphite networks for solar/electro-thermal energy storage","authors":"Yiqi Zhao ,&nbsp;Pengfei Zhang ,&nbsp;Yu Qiu ,&nbsp;Qing Li ,&nbsp;Hongjie Yan ,&nbsp;Zhaolong Wang ,&nbsp;Ciwei Wu","doi":"10.1016/j.decarb.2024.100051","DOIUrl":"10.1016/j.decarb.2024.100051","url":null,"abstract":"<div><p>Phase change materials (PCMs) are widely considered as promising energy storage materials for solar/electro-thermal energy storage. Nevertheless, the inherent low thermal/electrical conductivities of most PCMs limit their energy conversion efficiencies, hindering their practical applications. Herein, we fabricate a highly thermally/electrically conductive solid-solid phase change composite (PCC) enabled by forming aligned graphite networks through pressing the mixture of the trimethylolethane and porous expanded graphite (EG). Experiments indicate that both the thermal and electrical conductivities of the PCC increase with increasing mass proportion of the EG because the aligned graphite networks establish highly conductive pathways. Meanwhile, the PCC4 sample with the EG proportion of 20 ​wt% can achieve a high thermal conductivity of 12.82 ​± ​0.38 ​W·m<sup>−1</sup>·K<sup>−1</sup> and a high electrical conductivity of 4.11 ​± ​0.02 ​S·cm<sup>−1</sup> in the lengthwise direction. Furthermore, a solar-thermal energy storage device incorporating the PCC4, a solar selective absorber, and a highly transparent glass is developed, which reaches a high solar-thermal efficiency of 77.30 ​± ​2.71% under 3.0 suns. Moreover, the PCC4 can also reach a high electro-thermal efficiency of 91.62 ​± ​3.52% at a low voltage of 3.6 ​V, demonstrating its superior electro-thermal storage performance. Finally, stability experiments indicate that PCCs exhibit stabilized performance in prolonged TES operations. Overall, this work offers highly conductive and cost-effective PCCs, which are suitable for large-scale and efficient solar/electro-thermal energy storage.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"5 ","pages":"Article 100051"},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000179/pdfft?md5=28ff15b9c0cf5c23e2aabca8d04f1f68&pid=1-s2.0-S2949881324000179-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141413141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of nanomaterials with excellent purification potential for the removal of micro- and nanoplastics from liquid 综述具有卓越净化潜力的纳米材料,用于去除液体中的微塑料和纳米塑料
DeCarbon Pub Date : 2024-09-01 Epub Date: 2024-07-24 DOI: 10.1016/j.decarb.2024.100064
Tingting Yu , Xiong Huang , Xin Fang Zhang , Kailin Li , Shu Pei Liu , Nan Dai , Kai Zhang , Yu Xin Zhang , Hong Li
{"title":"A review of nanomaterials with excellent purification potential for the removal of micro- and nanoplastics from liquid","authors":"Tingting Yu ,&nbsp;Xiong Huang ,&nbsp;Xin Fang Zhang ,&nbsp;Kailin Li ,&nbsp;Shu Pei Liu ,&nbsp;Nan Dai ,&nbsp;Kai Zhang ,&nbsp;Yu Xin Zhang ,&nbsp;Hong Li","doi":"10.1016/j.decarb.2024.100064","DOIUrl":"10.1016/j.decarb.2024.100064","url":null,"abstract":"<div><p>Microplastics (MPs) and nanoplastics (NPs) pose a significant threat to human health due to their slow degradation, high toxicity, and potential to react with organic pollutants, forming even more hazardous substances. However, traditional methods for removing MPs/NPs have limitations. Nanomaterials are extensively utilized in water treatment for their easily modifiable properties and ability to effectively bind to contaminants. This review critically examines various nanomaterials employed as adsorbents, catalysts, and membranes for the removal of MPs and NPs. By delving into the sources of these pollutants, we aim to encourage further research focusing on source reduction. Furthermore, key areas for potential future research directions are highlighted.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"5 ","pages":"Article 100064"},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000301/pdfft?md5=5497c4d87f12f4cee53cac4c5fb8e657&pid=1-s2.0-S2949881324000301-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141848671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of surface nanostructure and wettability on CO2 nucleation boiling: A molecular dynamics study 表面纳米结构和润湿性对二氧化碳成核沸腾的影响:分子动力学研究
DeCarbon Pub Date : 2024-09-01 Epub Date: 2024-06-22 DOI: 10.1016/j.decarb.2024.100054
Yongfang Huang, Xianqiang Deng, Yongxiang Duan, Chao Liu, Xiaoxiao Xu
{"title":"Effects of surface nanostructure and wettability on CO2 nucleation boiling: A molecular dynamics study","authors":"Yongfang Huang,&nbsp;Xianqiang Deng,&nbsp;Yongxiang Duan,&nbsp;Chao Liu,&nbsp;Xiaoxiao Xu","doi":"10.1016/j.decarb.2024.100054","DOIUrl":"https://doi.org/10.1016/j.decarb.2024.100054","url":null,"abstract":"<div><p>Nanostructured tubes hold great potential for enhancing heat transfer in refrigeration/heat pump systems. Therefore, it is essential to study the effects of nanostructured surface characteristics on refrigerant boiling heat transfer. In this paper, the nucleation boiling behavior of CO<sub>2</sub> on the nanostructured surface is simulated using molecular dynamics. The effect mechanism of nanostructure size and surface wettability on CO<sub>2</sub> bubbles nucleation and growth is investigated. At first, the nucleation boiling processes of both smooth surfaces and nanostructured surfaces featuring three different wide grooves are simulated. The results show that the local thermal aggregation effect is the key for nanostructures to promote CO<sub>2</sub> bubble nucleation. The bubble nucleation efficiency is highest on the nanostructured surface with 5 ​nm wide groove. Then, based on a 5 ​nm wide nanostructured wall surface, the wettability effect on nucleation boiling is investigated by adjusting the potential energy factor <em>α</em>. The results show that the hydrophilic walls enhance the solid-liquid heat transfer and the collision of atoms within the liquid, resulting in boiling heat transfer capacity improvement between CO<sub>2</sub> and the walls. The average temperature, average heat flux and critical heat flux in the liquid phase are also improved. A significant temperature gradient between the layers of CO<sub>2</sub> liquid is noted on hydrophilic wall, where intermolecular forces and molecular advection dominate the heat transfer mechanism. In contrast, on hydrophobic wall, intermolecular forces dominate the heat transfer process.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"5 ","pages":"Article 100054"},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000209/pdfft?md5=c6cd9bf616c3b22b74831ad8538ce16e&pid=1-s2.0-S2949881324000209-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141485435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The potential of hyperbolic films for radiative heat transfer in micro/nanoscale 双曲膜在微米/纳米尺度辐射传热中的潜力
DeCarbon Pub Date : 2024-06-01 Epub Date: 2024-04-22 DOI: 10.1016/j.decarb.2024.100047
Xiaohu Wu , Yang Hu , Haotuo Liu , Yao Hong
{"title":"The potential of hyperbolic films for radiative heat transfer in micro/nanoscale","authors":"Xiaohu Wu ,&nbsp;Yang Hu ,&nbsp;Haotuo Liu ,&nbsp;Yao Hong","doi":"10.1016/j.decarb.2024.100047","DOIUrl":"10.1016/j.decarb.2024.100047","url":null,"abstract":"<div><p>Thin films exhibit substantial potential in energy management and utilization as the development of micro- and nanofabrication technologies. It is well known that thermal radiation is one of the fundamental ways of energy transfer. However, the potential of hyperbolic films for radiative heat transfer is always ignored. Whether the radiative heat flux between hyperbolic films surpasses that of the bulk materials remains insufficiently explored. In this work, we theoretically investigate the radiative heat transfer between hexagonal boron nitride (hBN) at a separation from 20 ​nm to 2 ​μm. The results show that when the optical axis of hBN is oriented in-plane, the near-field radiative heat flux of hBN with a thickness of 10 ​nm exceeds that of hBN bulk by 47% and exceeds the blackbody limit by two orders of magnitude at a gap distance of 20 ​nm. The physical mechanism is attributed to the volume-confined hyperbolic polaritons can be excited in a higher wavevector space. Conversely, when the gap distance is 600 ​nm, the heat flux between films is considerably lower than that of bulk material. This work opens up potential avenues for developing hyperbolic film-dependent thermal devices and strategies for thermal management.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"4 ","pages":"Article 100047"},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000131/pdfft?md5=9a4613bd5fbd4d96c9a40ec086703a65&pid=1-s2.0-S2949881324000131-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140794835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review from fundamental research to device applications for graphene-based thermal rectifier 石墨烯基热整流器从基础研究到设备应用的综述
DeCarbon Pub Date : 2024-06-01 Epub Date: 2024-05-09 DOI: 10.1016/j.decarb.2024.100048
Hengbin Ding , Jiarui He , Liming Ding , He Tian
{"title":"A review from fundamental research to device applications for graphene-based thermal rectifier","authors":"Hengbin Ding ,&nbsp;Jiarui He ,&nbsp;Liming Ding ,&nbsp;He Tian","doi":"10.1016/j.decarb.2024.100048","DOIUrl":"10.1016/j.decarb.2024.100048","url":null,"abstract":"<div><p>Thermal rectification (TR) is a phenomenon akin to electrical rectification. It has a high thermal conductivity (<em>k</em>) in one direction, enabling efficient heat dissipation, as well as a low <em>k</em> in the opposite direction, impeding heat influx. With the rapid development of nanotechnology in recent years, the active control and regulation of heat conduction on the nanoscale has become a critical mission. Graphene, a prominent two-dimensional (2D) material, is highly regarded for its exceptional thermal transport characteristics. There have been studies and achievements both theoretically and experimentally since its discovery. In this review, we establish a bridge between fundamental research and application studies for graphene-based thermal rectifier as follows. Firstly, we summarize the established 2D heat conduction theories and low-dimensional simulation methods. Secondly, we review the progress of experimental techniques and device structures based on 2D theories for graphene-based thermal rectifier. Then, we discuss several applications of thermal rectifier, including thermal logic circuits and thermoelectric power generation system. Finally, we present the potential applications of graphene-based thermal rectifiers previously unexplored, such as microelectronic thermal management and thermal decoupling for flexible equipment. We hope that advancements in morphology and fabrication techniques will lead to widespread use of graphene-based thermal rectifiers in various thermal systems to solve diverse thermal management problems in the near future.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"4 ","pages":"Article 100048"},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000143/pdfft?md5=aad2e7b388f545b2f1d69fbbb8f6cf3f&pid=1-s2.0-S2949881324000143-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141032563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of ions on liquid-solid interface investigated by charge sensitive direct current droplet-based electricity generator 利用电荷敏感直流液滴式发电装置研究离子对液固界面的影响
DeCarbon Pub Date : 2024-06-01 Epub Date: 2024-04-10 DOI: 10.1016/j.decarb.2024.100045
Wenfei Mao , Shijing Yang , Gaobo Xu , Ping Liu , Tao Zhong , Jun Dong , Zhe Li , Hongyu Zhou , Cunyun Xu , Qunliang Song
{"title":"The effect of ions on liquid-solid interface investigated by charge sensitive direct current droplet-based electricity generator","authors":"Wenfei Mao ,&nbsp;Shijing Yang ,&nbsp;Gaobo Xu ,&nbsp;Ping Liu ,&nbsp;Tao Zhong ,&nbsp;Jun Dong ,&nbsp;Zhe Li ,&nbsp;Hongyu Zhou ,&nbsp;Cunyun Xu ,&nbsp;Qunliang Song","doi":"10.1016/j.decarb.2024.100045","DOIUrl":"10.1016/j.decarb.2024.100045","url":null,"abstract":"<div><p>The contact electrification (CE) between DI water and SiO<sub>2</sub> or fluorinated polymer has been proven to be mainly due to electron transfer, which is significantly influenced by ions in solution. However, how these ions in water affect the charge transfer at the liquid-solid (L-S) interface is still unresolved, especially for the already charged friction layer. Here, a direct current droplet-based electricity generator (DC-DEG) which is sensitive to the change of charge transfer at the L-S interface is adopted to detect the effects of ions in the neutral salt solution on the charged PTFE surface. The distribution of ions on the charged L-S interface (the change of electric potential on the solid surface) and its effects on the output of DC-DEGs have been studied. The results indicate that the charge transfer of droplets and then the output of DC-DEGs are closely related to the concentrations of salt solutions. Anions can enhance the surface potential of PTFE due to their adsorptions on PFTE while cations can reduce it due to their screen effect. At low ionic concentrations, the surface potential enhancement caused by anion adsorption is larger than that surface potential reduction caused by screen effect from cations. At high ionic concentrations, the electrostatic screen effect of cations increases a lot to weaken the surface potential and reducing the charge separation of droplets induced by electrostatic induction (EI). This work explains the redistribution process of ions at the L-S interface and also provides a clever solution for improving the electrical output performance of DEGs.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"4 ","pages":"Article 100045"},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000118/pdfft?md5=8953b4aaa299fad3829e9c0d49a6baea&pid=1-s2.0-S2949881324000118-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140778158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Machine learning assisted prediction for hydrogen production of advanced photovoltaic technologies 先进光伏技术制氢的机器学习辅助预测
DeCarbon Pub Date : 2024-06-01 Epub Date: 2024-06-10 DOI: 10.1016/j.decarb.2024.100050
Qiang Yang , Zhu Ma , Lihong Bai , Qiuyue Yuan , Fuchun Gou , Yanlin Li , Zhuowei Du , Yi Chen , Xingchong Liu , Jian Yu , Xiaoqian Zhou , Cheng Qian , Zichen Liu , Zilu Tian , Anan Zhang , Kuan Sun , Liming Ding , Chun Tang , Taoli Meng , Fan Min , Ying Zhou
{"title":"Machine learning assisted prediction for hydrogen production of advanced photovoltaic technologies","authors":"Qiang Yang ,&nbsp;Zhu Ma ,&nbsp;Lihong Bai ,&nbsp;Qiuyue Yuan ,&nbsp;Fuchun Gou ,&nbsp;Yanlin Li ,&nbsp;Zhuowei Du ,&nbsp;Yi Chen ,&nbsp;Xingchong Liu ,&nbsp;Jian Yu ,&nbsp;Xiaoqian Zhou ,&nbsp;Cheng Qian ,&nbsp;Zichen Liu ,&nbsp;Zilu Tian ,&nbsp;Anan Zhang ,&nbsp;Kuan Sun ,&nbsp;Liming Ding ,&nbsp;Chun Tang ,&nbsp;Taoli Meng ,&nbsp;Fan Min ,&nbsp;Ying Zhou","doi":"10.1016/j.decarb.2024.100050","DOIUrl":"10.1016/j.decarb.2024.100050","url":null,"abstract":"<div><p>The photovoltaic (PV) water electrolysis method currently stands as the most promising approach for green hydrogen production. The rapid iteration of photovoltaic technologies has significantly affected on the technical and economic evaluation for photovoltaic hydrogen production. In this work, the photovoltaic hydrogen production of three most advanced silicon photovoltaic technologies is systematically compared for the first time under the climatic conditions of the Kucha region. All-weather stable hydrogen production control system with optimal charging and discharging strategies is constructed to realize stable and efficient hydrogen energy production. Seven machine learning (ML) algorithms are used to forecast the performance in power generation and hydrogen production of a 100 ​MW photovoltaic hydrogen production and energy storage (PH-S) system throughout its operational life. The long short-term memory (LSTM) algorithm exhibits the best performance, achieving mean absolute error (MAE) of 0.0415, root mean square error (RMSE) of 0.0891, and coefficient of determination (R<sup>2</sup>) of 0.8402. In terms of cost-effectiveness, heterojunction with intrinsic thin layer (HJT) PV technology achieves the lowest levelized cost of electricity (LCOE) and hydrogen (LCOH) at 0.025 $/kWh and 6.95 $/kg, respectively. According to the sensitivity analysis, when the cost of proton exchange membrane electrolysis (PEMEC) reduced 50%, the LCOH for PH-S system decreased 21.40%. This study provides valuable insights for the practical implementation of large-scale photovoltaic hydrogen production and cost reduction in PH-S systems.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"4 ","pages":"Article 100050"},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000167/pdfft?md5=52c6f21d98127ed5fdad45da1d4c6b4d&pid=1-s2.0-S2949881324000167-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141395314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Host-guest regulations in functionalized metal and covalent organic frameworks raise the performance of lithium sulfur batteries 功能化金属和共价有机框架中的主客体规则提高了锂硫电池的性能
DeCarbon Pub Date : 2024-06-01 Epub Date: 2024-05-15 DOI: 10.1016/j.decarb.2024.100049
Qilin Huang , Yulin Gao , Jianguo Sun , Binbin Liu , Ximeng Liu , Yuepeng Pang , Yu Liu , John Wang
{"title":"Host-guest regulations in functionalized metal and covalent organic frameworks raise the performance of lithium sulfur batteries","authors":"Qilin Huang ,&nbsp;Yulin Gao ,&nbsp;Jianguo Sun ,&nbsp;Binbin Liu ,&nbsp;Ximeng Liu ,&nbsp;Yuepeng Pang ,&nbsp;Yu Liu ,&nbsp;John Wang","doi":"10.1016/j.decarb.2024.100049","DOIUrl":"10.1016/j.decarb.2024.100049","url":null,"abstract":"<div><p>Lithium sulfur batteries (LSBs) show great promise as next-generation batteries due to their high energy density. However, commercialization is hindered by limited cycle life, fast capacity decay and poor sulfur utilization, primarily due to the intricate phase evolution during battery operation and insulating characteristics of sulfur, leading to uncontrollable sulfur and polysulfide distribution and inefficient conversion kinetics. Therefore, the incorporation of metal and covalent organic frameworks (MOFs and COFs) has been widely employed in LSBs to serve as hosts, enabling the regulation of conversion and diffusion behavior of guest species, including lithium ions, sulfur and polysulfides, within their well-defined nanosized cavities. Nevertheless, pristine frameworks often fail to meet the requisite standards, and framework functionalization offers unique opportunities to tailor desired attributes and facilitate selective host-guest interactions in LSBs. However, a thorough understanding on how to precisely customize the nano-channels with functional groups to promote such interactions remains largely unexplored. In this review, we provide a systematic discussion on how the grafting of functional groups containing various active sites can play a role in host-guest chemistry, and focus on the latest advancements in engineering functionalized MOFs and COFs as charged-species regulators to tackle the problems causing poor LSB electrochemical performance. The concepts of electrophilic and nucleophilic effects are proposed, uncovering the mechanisms of framework functionalization in LSBs and serving as guidance for future developments.</p></div>","PeriodicalId":100356,"journal":{"name":"DeCarbon","volume":"4 ","pages":"Article 100049"},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949881324000155/pdfft?md5=90cc215860762122a99121ea094b0c64&pid=1-s2.0-S2949881324000155-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141031924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Separation of molten electrolyte from the graphene nanocarbon product subsequent to electrolytic CO2 capture 电解捕获二氧化碳后熔融电解液与石墨烯纳米碳产品的分离
DeCarbon Pub Date : 2024-06-01 Epub Date: 2024-04-16 DOI: 10.1016/j.decarb.2024.100044
Gad Licht , Kyle Hofstetter , Stuart Licht
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