Colloids and Surfaces C: Environmental Aspects最新文献_第2页

Ag-decorated Al2O3-CeO2 spherical composite as an efficient adsorbent for removal of ciprofloxacin in aqueous media ag修饰Al2O3-CeO2球形复合材料对水中环丙沙星的高效吸附

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-05-31 DOI: 10.1016/j.colsuc.2025.100072

Lorenzo Iván Salamanca-Córdoba , Pamela Nair Silva-Holguín , Félix Antonio Naranjo-Castañeda , Erasto Armando Zaragoza-Contreras , Refugio Rodríguez-Vázquez , Simón Yobanny Reyes-López

{"title":"Ag-decorated Al2O3-CeO2 spherical composite as an efficient adsorbent for removal of ciprofloxacin in aqueous media","authors":"Lorenzo Iván Salamanca-Córdoba , Pamela Nair Silva-Holguín , Félix Antonio Naranjo-Castañeda , Erasto Armando Zaragoza-Contreras , Refugio Rodríguez-Vázquez , Simón Yobanny Reyes-López","doi":"10.1016/j.colsuc.2025.100072","DOIUrl":"10.1016/j.colsuc.2025.100072","url":null,"abstract":"<div><div>The search for ceramic materials with chemical stability, mechanical resistance, and high adsorption capacity has led to the proposal of several structural modifications, such as combining two oxides in a single material, and surface modifications, such as incorporating metallic nanoparticles upon the surface of a ceramic material. This study presents the synthesis, characterization, and adsorption capacity of ciprofloxacin of porous spherical composites of Al₂O₃, Al₂O₃-CeO₂ and Al₂O₃-CeO₂-Ag. Polystyrene (PS) nanospheres were employed as a sacrificial template to enhance porosity, and silver nanoparticles (Ag-Nps) were used for surface decoration. The phase transformations of Al₂O₃ and CeO₂ into their stable crystalline forms were confirmed through FTIR and XRD analysis. Scanning electron microscopy (SEM) revealed a homogeneous polycrystalline morphology, while zeta potential (pζ) analysis indicated an increase in negative surface charge, reaching values of −87 mV for Ag-decorated spheres at pH 5. Adsorption studies demonstrated ciprofloxacin removal capacities of 0.25 mg g⁻¹ for Al₂O₃, 1.02 mg g⁻¹ for Al₂O₃-CeO₂ and 0.39 mg g⁻¹ for Al₂O₃-CeO₂-Ag at pH 5. Kinetic analyses fit well to pseudo-second-order and Elovich models, with determination coefficients ranging from 0.89 to 0.99, due to a mixed chemisorption mechanism. Freundlich and Temkin models confirmed the affinity of the three materials for ciprofloxacin, with Freundlich coefficients exceeding 1.0 and Temkin adsorption heats exceeding 26,000 J mol<sup>−1</sup>, findings that highlight the potential of Al₂O₃, Al₂O₃-CeO₂ and Al₂O₃-CeO₂-Ag as efficient adsorbent materials for pharmaceutical contaminants, like ciprofloxacin, in water treatment applications.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100072"},"PeriodicalIF":0.0,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144212461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

rGO/NF as anode electrocatalytically activates persulfate combined coagulation process for tetracycline hydrochloride wastewater removal 还原氧化石墨烯/纳滤膜作为阳极电催化激活过硫酸盐联合混凝工艺去除盐酸四环素废水

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-05-12 DOI: 10.1016/j.colsuc.2025.100071

Linglong Li , Yonggang Zhang

{"title":"rGO/NF as anode electrocatalytically activates persulfate combined coagulation process for tetracycline hydrochloride wastewater removal","authors":"Linglong Li , Yonggang Zhang","doi":"10.1016/j.colsuc.2025.100071","DOIUrl":"10.1016/j.colsuc.2025.100071","url":null,"abstract":"<div><div>In this paper, reduced graphene oxide-modified nickel foam (rGO/NF) was utilised as an activator for peroxymonosulfate (PMS) in the electrocatalytic oxidation reaction and combined with a coagulation process to form the combined system of E-rGO/NF-PMS and coagulation in order to improve the pollutant degradation efficiency and shorten the reaction residence time. Various analytical methods were employed to characterise the electrode materials and the formed flocs in detail, and the effects of key parameters, such as applied voltage, PMS dosage, pH, and coagulant dosage, on the whole system were investigated by orthogonal experimental design. The results showed that the coagulation performance of the wastewater was enhanced by the electrocatalytic oxidation treatment, and tetracycline hydrochloride was effectively degraded by the addition of coagulant through adsorption of electro-neutralisation and net trapping and sweeping, and the concentration and chemical oxygen demand (COD) removal were 97.19 % and 91.97 %, respectively. In addition, the intermediate products generated from the degradation of pollutants were analysed in depth by using electron spin resonance (ESR), liquid chromatography-mass spectrometry (LC-MS), Fourier transform infrared spectroscopy (FTIR) and other techniques, focusing on the mechanism of action and degradation pathway of the combined coagulation process of electrocatalysis. In conclusion, the combined system of E-rGO/NF-PMS and coagulation overcame the shortcomings of long electrocatalytic oxidation time and coagulation time, and poor COD treatment effect, and provided new ideas and technical references for the future practical wastewater treatment engineering.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100071"},"PeriodicalIF":0.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144072054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bimetallic MOFs for the effective removal of organic contaminants: Dyes and antibiotics 用于有效去除有机污染物：染料和抗生素的双金属mof

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-04-14 DOI: 10.1016/j.colsuc.2025.100070

Pamthingla Ragui , Anita Yadav , Shalu Goyal , Swati Rani , Vijay Kumar Goel , Rakesh Kumar Sharma

{"title":"Bimetallic MOFs for the effective removal of organic contaminants: Dyes and antibiotics","authors":"Pamthingla Ragui , Anita Yadav , Shalu Goyal , Swati Rani , Vijay Kumar Goel , Rakesh Kumar Sharma","doi":"10.1016/j.colsuc.2025.100070","DOIUrl":"10.1016/j.colsuc.2025.100070","url":null,"abstract":"<div><div>We report the successful solvothermal synthesis of Iron-Nickel bimetallic MOFs (F:N@BTC) as a heterogeneous catalyst without high-temperature annealing. F:N@BTC demonstrated superior catalytic activity in the removal of Organic Contaminants (OCs) attributed to the synergistic effects of two metals (Fe-Ni), high specific surface area (673 m<sup>2</sup> g<sup>−1</sup>), and mesoporous structure. The negatively charged surface of F:N@BTC (zeta potential ∼-30 mV) enhances adsorption, particularly for the cationic OCs. The adsorption capacity (q<sub>e</sub>, mg g<sup>−1</sup>) of F:N@BTC for OCs follows the order: Toluidine Blue (TB, 962) > Rhodamine B (RB, 842) > Ciprofloxacin (CF, 808) > Nalidixic acid (NA, 616) > Rose Bengal (RoB, 595) within 2 hours without using reducing agent. This result indicates the order of higher adsorption capacity towards cationic to anionic surface charge of the OCs. Comparative studies confirm F:N@BTC’s superiority over monometallic analogs (F@BTC, N@BTC). Kinetic analysis reveals the adsorption of OCs on F:N@BTC followed pseudo-second-order kinetics indicating chemisorption with intraparticle diffusion contributing co-operatively. This work highlights the potential of F:N@BTC MOFs as an efficient adsorbent for the wastewater treatment across diverse Organic Contaminants.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100070"},"PeriodicalIF":0.0,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143838535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanofiltration membranes containing CHA zeolite with pompom-like morphology 含CHA沸石的纳滤膜，具有球团状形态

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-04-10 DOI: 10.1016/j.colsuc.2025.100069

Shengchao Wei , Alexander J. Cunliffe , James Redfern , Hailing Guo , Lubomira Tosheva

{"title":"Nanofiltration membranes containing CHA zeolite with pompom-like morphology","authors":"Shengchao Wei , Alexander J. Cunliffe , James Redfern , Hailing Guo , Lubomira Tosheva","doi":"10.1016/j.colsuc.2025.100069","DOIUrl":"10.1016/j.colsuc.2025.100069","url":null,"abstract":"<div><div>Thin-film composite (TFC) nanofiltration membranes are widely used for water treatment due to their energy efficiency and high salt rejection, however they are highly susceptible to biological fouling. CHA zeolite with pompom-like morphology was prepared from an organic structure-directing template-free synthesis gel in the presence of sodium and cesium. The zeolite was added to the polyamide (PA) layer of TFC membranes prepared via interfacial polymerization. M-0.01 and M-0.05 TFC membranes prepared with addition of 0.01 wt% and 0.05 wt% CHA zeolite to the aqueous piperazine monomer solution, displayed a thinner PA layer and higher permeability compared to zeolite-free M-0 membranes. The rejection of 2000 ppm Na<sub>2</sub>SO<sub>4</sub> and MgSO<sub>4</sub> solutions of the M-0.05 membrane was slightly reduced compared to M-0 and M-0.01 but nevertheless remained higher than 90%. Ag-CHA zeolite suspensions showed antibacterial activity against <em>Escherichia coli</em>, whereas CHA zeolite was inactive. Following bacterial exposure, M-0 control membranes exhibited bacterial growth after 24 h compared to the 0 h count, which was not observed for M-0.05 membranes, where there was no significant difference in the count between 0 h and 24 h. As a bacterial population reduction was not observed in either case, these materials are considered not to be antimicrobial. No bacteria survived on the surface of Ag-treated M-0 and M-0.05 membranes, demonstrating antimicrobial activity. The methodology described in this work could be used to increase the resistance of TFC membranes to biological fouling and increase their operational lifetime.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100069"},"PeriodicalIF":0.0,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143828854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microorganism research advances from a novel bibliometric method 微生物研究从一种新的文献计量方法中取得进展

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-04-07 DOI: 10.1016/j.colsuc.2025.100068

Shan Chen , Yuanzhao Ding

引用次数: 0

Transport and retention of titanium dioxide nanoparticles in a drinking water treatment plant. Effects of coagulation, filtration and raw water properties on the removal efficiency 二氧化钛纳米颗粒在饮用水处理厂的运输和滞留。混凝、过滤和原水性质对去除率的影响

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-04-05 DOI: 10.1016/j.colsuc.2025.100067

Lina Ramirez-Arenas , Robin Noyer , Stéphan Ramseier Gentile , Stéphane Zimmermann , Pauline Perdaems , Pascal Ramaciotti , Wei Liu , Serge Stoll

{"title":"Transport and retention of titanium dioxide nanoparticles in a drinking water treatment plant. Effects of coagulation, filtration and raw water properties on the removal efficiency","authors":"Lina Ramirez-Arenas , Robin Noyer , Stéphan Ramseier Gentile , Stéphane Zimmermann , Pauline Perdaems , Pascal Ramaciotti , Wei Liu , Serge Stoll","doi":"10.1016/j.colsuc.2025.100067","DOIUrl":"10.1016/j.colsuc.2025.100067","url":null,"abstract":"<div><div>Increasing the use and release of titanium dioxide nanoparticles (TiO<sub>2</sub> NPs) into aquatic systems, including water compartments used to produce drinking water, represent a risk for human health through direct NPs ingestion. Since drinking water treatment plants (DWTPs) must provide and guarantee the quality of the water for human consumption, in this study, TiO<sub>2</sub> NPs removal efficiency of a DWTP which provides drinking water for half million consumers is investigated. For that purpose, a pilot-scale designed to closely reproduce each treatment process of the main DWTP is considered. Experiments were first conducted without considering the coagulation process to evaluate the efficiency of the filtration processes (sand and granular activated carbon) and the specific impact of the coagulation with Polyaluminum Chloride on NPs removal. Using an original and novel combination of different analytical techniques (turbidity, ζ-potentials, size distribution measurements, electron microscopy, total organic carbon determination) we found that filtration processes through sand and GAC achieve an overall NPs removal of 96.3 % ± 1.0. NPs removal is mainly attributed to straining and adsorption processes during filtration. Then experiments were conducted in presence of PACl to quantify the impact of coagulation on the TiO<sub>2</sub> NPs removal efficiency. It was found that the addition of coagulant significantly improves TiO<sub>2</sub> NPs removal with a global removal efficiency greater than 99.5 % ± 0.5. The higher removal efficiency in presence of coagulant was related to a significant TiO<sub>2</sub> NPs surface charge reduction and subsequent formation of aggregates increasing their retention and attachment in the filter media.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100067"},"PeriodicalIF":0.0,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comprehensive Review of Hybrid Absorption-Adsorption Techniques for Chromium Removal from Wastewater Using Magnetite-Zeolite Suspended in Glycol Slurry 悬浮在乙二醇浆中的磁铁矿-沸石复合吸附-吸附法去除废水中铬的研究进展

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-03-25 DOI: 10.1016/j.colsuc.2025.100066

Yudha Gusti Wibowo , Dedy Anwar , Hana Safitri , Aris Setiawan , Sudibyo Sudibyo , Ahmad Tawfiequrrahman Yuliansyah , Himawan Tri Bayu Murti Petrus

{"title":"Comprehensive Review of Hybrid Absorption-Adsorption Techniques for Chromium Removal from Wastewater Using Magnetite-Zeolite Suspended in Glycol Slurry","authors":"Yudha Gusti Wibowo , Dedy Anwar , Hana Safitri , Aris Setiawan , Sudibyo Sudibyo , Ahmad Tawfiequrrahman Yuliansyah , Himawan Tri Bayu Murti Petrus","doi":"10.1016/j.colsuc.2025.100066","DOIUrl":"10.1016/j.colsuc.2025.100066","url":null,"abstract":"<div><div>Chromium is a highly toxic heavy metal linked to severe chronic respiratory diseases, including asthma, rhinitis, pulmonary fibrosis, and chronic obstructive pulmonary disease. Despite extensive research on chromium removal techniques such as adsorption, phytoremediation, and constructed wetlands, each method has inherent limitations in efficiency, selectivity, and long-term applicability. This review introduces a novel hybrid absorption-adsorption approach utilizing magnetite-zeolite suspended in glycol slurry as a promising alternative for chromium remediation. This is the first comprehensive review to systematically analyze this method, highlighting the unique physicochemical properties of magnetite-zeolite and its adsorption mechanisms. Furthermore, the review critically evaluates recent advancements, challenges, and potential improvements in this technique while providing recommendations for future research and practical applications. The insights presented in this study are expected to drive further experimental investigations and contribute to the development of more effective and sustainable strategies for chromium removal from wastewater.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100066"},"PeriodicalIF":0.0,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143738026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Taguchi optimized electrocoagulation technology: A sustainable approach to oil-water separation in large scale applications 田口优化电絮凝技术：大规模应用中油水分离的可持续方法

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-03-24 DOI: 10.1016/j.colsuc.2025.100065

Hansa Muvel , Manoj Kumar Jindal , Pradip Kumar Tewari , Semyon Mareev , Vikky Anand

{"title":"Taguchi optimized electrocoagulation technology: A sustainable approach to oil-water separation in large scale applications","authors":"Hansa Muvel , Manoj Kumar Jindal , Pradip Kumar Tewari , Semyon Mareev , Vikky Anand","doi":"10.1016/j.colsuc.2025.100065","DOIUrl":"10.1016/j.colsuc.2025.100065","url":null,"abstract":"<div><div>Electrocoagulation (EC) method used for eliminating oil from oily wastewater, though it encounters challenges such as high operational costs and electrode passivation. The novelty of this research is its development of a cost-effective and highly efficient EC process, specifically optimized for sunflower oil wastewater. The effectiveness of EC in reducing turbidity was evaluated through experimental analysis. The Taguchi methodology was employed to optimize critical process parameters: pH, operating voltage, EC duration, electrode spacing, and sodium chloride concentration. The Optimal conditions identified were pH 6, 30 V, 80 minutes of EC duration, 5 cm electrode spacing, and 0.2 g/L NaCl, achieving an impressive oil removal rate of 94.46 %, along with high energy efficiency. Characterization of the electrodes using UV spectroscopy, SEM, and EDX under these optimal conditions further supported the findings. The study also examined the operating cost (OC) associated with the EC process using aluminium electrodes. Energy consumption ranged from 0.96 kWh/m³ to 22.61 kWh/m³ , while aluminium electrode consumption varied between 0.06 kgAl/m³ and 0.275 kgAl/m³ . The OC fluctuated from 0.252 to 4.654 USD per 1000 litres of oil wastewater treatment across nine orthogonal array experiments. This research contributes to advancing sustainable EC technology for separating emulsified oil-water mixtures, aligning with circular economy principles for responsible industrial wastewater management.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100065"},"PeriodicalIF":0.0,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143705294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Citric acid facilitates diisopropylamine separation from water: A potential solution for groundwater remediation 柠檬酸促进二异丙胺从水中分离：地下水修复的潜在解决方案

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-03-11 DOI: 10.1016/j.colsuc.2025.100064

Nour Kashlan , Caitlyn Hsiung , Erica Pensini

引用次数: 0

Solid transformation synthesis of zeolites and their applications 沸石的固体转化合成及其应用

Colloids and Surfaces C: Environmental Aspects Pub Date : 2025-02-27 DOI: 10.1016/j.colsuc.2025.100063

Wei Shu , Haowen Lin , Xintong Chen , Yi Yang , Zhicong Chen , Minyi Liu , Xintong You , Ying Li

{"title":"Solid transformation synthesis of zeolites and their applications","authors":"Wei Shu , Haowen Lin , Xintong Chen , Yi Yang , Zhicong Chen , Minyi Liu , Xintong You , Ying Li","doi":"10.1016/j.colsuc.2025.100063","DOIUrl":"10.1016/j.colsuc.2025.100063","url":null,"abstract":"<div><div>Zeolites have been widely studied due to their excellent adsorption and catalytic properties. However, the single microporous structure of traditional zeolites limits their reaction activity and selectivity. Hierarchical zeolites effectively overcome these limitations and enhance the mass transfer and heat transfer, increasing their applicability and stability. Hierarchical zeolites are prepared by two typical strategies including \"bottom-up\" and \"top-down\" strategies. However, these strategies usually require high energy consumption, long preparation processes, and generate acidic and alkaline waste. Solid transformation synthesis offers an efficient and green route for hierarchical zeolite preparation. Hierarchical zeolites can enhance activity and/or selectivity in catalysis (e.g. MTO and MTG reactions) and adsorption (e.g. VOCs, methylene blue removal) compared to traditional microporous zeolites. This review aims to illustrate the state-of-art development of hierarchical zeolites synthesized by solid transformation methods, concerning their production and application. Hierarchical zeolite synthesized by solid transformation method has shown promising potential in many fields, such as environmental remediation, catalysis production, energy storage and so on. Therefore, it is of great significance to pave its way to the practical application, and their synthetic conditions and structural changes are worth further investigation.</div></div>","PeriodicalId":100290,"journal":{"name":"Colloids and Surfaces C: Environmental Aspects","volume":"3 ","pages":"Article 100063"},"PeriodicalIF":0.0,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0