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Evaluating environmental and economic sustainability of engineered chitosan particles for water treatment 评价工程壳聚糖水处理颗粒的环境和经济可持续性
Cleaner Materials Pub Date : 2025-05-09 DOI: 10.1016/j.clema.2025.100319
Fatima Iqbal , Astha Upadhyay , Rouzbeh Tehrani , Lewis S. Rowles
{"title":"Evaluating environmental and economic sustainability of engineered chitosan particles for water treatment","authors":"Fatima Iqbal ,&nbsp;Astha Upadhyay ,&nbsp;Rouzbeh Tehrani ,&nbsp;Lewis S. Rowles","doi":"10.1016/j.clema.2025.100319","DOIUrl":"10.1016/j.clema.2025.100319","url":null,"abstract":"<div><div>The global water demands have prompted the development of sustainable treatment solutions, with adsorptive chitosan composites emerging as promising alternatives to petroleum-based materials. As a cleaner material, chitosan offers significant advantages over conventional adsorbents, including biodegradability, biocompatibility, and the potential to create a circular economy in water treatment applications. This study presents a comprehensive sustainability assessment of three novel porous chitosan particles synthesized using low-toxicity solvents, focusing solely on the production of pure chitosan scaffolds without additional adsorptive materials for targeted removal. Integrating techno-economic analysis and life cycle assessment, we evaluate the economic viability and environmental impact of methylpentane, azocarboxamide, and tween porous chitosan particles. Our analysis, normalized to both production mass and methylene blue removal efficiency, reveals complex tradeoffs among costs, environmental impacts, and performance. Azocarboxamide particles was the most cost-effective in production at 32.89 [26.13-41.00] USD/g, while having greater environmental impacts and less removal (&lt; 20 %). In contrast, methylpentane particles demonstrated superior environmental sustainability, achieving a removal efficiency of &gt; 90 % with moderate production cost of 104.07 [80.76-135.07] USD/g. This divergence in results highlights the critical importance of considering both production costs and functional performance when evaluating the sustainability of these materials. Sensitivity analysis identified key sustainability drivers, including precursor costs, synthesis yield, material quantities, and energy consumption. These findings underscore the importance of optimizing synthesis conditions and considering full life cycle impacts in developing chitosan-based adsorbents. This study provides a robust framework for evaluating the sustainability of biopolymer-based materials and supports informed decision-making in advancing water treatment technologies and promoting a circular economy.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100319"},"PeriodicalIF":0.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143935803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-friendly water barrier coating for paper packaging: Harnessing bio-calcium carbonate from mussel shell waste 纸包装用环保防水涂料:利用贻贝废料中的生物碳酸钙
Cleaner Materials Pub Date : 2025-05-08 DOI: 10.1016/j.clema.2025.100318
Lunjakorn Amornkitbamrung , Atichar Thanawinitcharoen , Chutiparn Lertvachirapaiboon , Cheol-Hee Ahn , Sanong Ekgasit , Sarawut Rimdusit
{"title":"Eco-friendly water barrier coating for paper packaging: Harnessing bio-calcium carbonate from mussel shell waste","authors":"Lunjakorn Amornkitbamrung ,&nbsp;Atichar Thanawinitcharoen ,&nbsp;Chutiparn Lertvachirapaiboon ,&nbsp;Cheol-Hee Ahn ,&nbsp;Sanong Ekgasit ,&nbsp;Sarawut Rimdusit","doi":"10.1016/j.clema.2025.100318","DOIUrl":"10.1016/j.clema.2025.100318","url":null,"abstract":"<div><div>In this study, we addressed the issue of non-recyclable and slow-to-biodegrade waste from paper packaging coated with plastic, along with the local problem of accumulating mussel shell waste in Thailand. To improve the water barrier properties of paper, we developed a bio-based coating using ethyl cellulose (EC) and biogenic calcium carbonate (bio-CaCO<sub>3</sub>) particles sourced from discarded green mussel shells. Chemical and mechanical treatments were applied to the shells, resulting in plate-like particles with a diameter of 2–5 μm and a thickness of 0.5 μm. Treating the particles with stearic acid (SA) enhanced their surface hydrophobicity, increasing the water contact angle (WCA) from 31 to 110°. Paper samples were coated with a dispersion of bio-CaCO<sub>3</sub> particles in an EC solution, and their molecular characteristics, morphology, thermal stability, and mechanical properties were characterized. Investigation of the effects of SA treatment and coating content revealed significant improvements in water resistance. The water absorptivity (Cobb test) of filter paper decreased from 150 to 9 g/m<sup>2</sup>, and for packaging paper, it decreased from 43 to 7 g/m<sup>2</sup> after coating. Furthermore, the WCA of filter paper increased from non-measurable to 122°, while the WCA of packaging paper increased from 109 to 132°. These improvements could be attributed to the reduced porosity and increased surface hydrophobicity by coating. Overall, this bio-based coating demonstrated a promising potential as an eco-friendly solution for water barrier coating of packaging paper.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100318"},"PeriodicalIF":0.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143941866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of concrete containing wind-turbine wastes following mechanical, environmental and economic indicators 根据机械、环境和经济指标对含有风力涡轮机废料的混凝土进行优化
Cleaner Materials Pub Date : 2025-05-07 DOI: 10.1016/j.clema.2025.100317
Nerea Hurtado-Alonso , Javier Manso-Morato , Víctor Revilla-Cuesta , Vanesa Ortega-López , Marta Skaf
{"title":"Optimization of concrete containing wind-turbine wastes following mechanical, environmental and economic indicators","authors":"Nerea Hurtado-Alonso ,&nbsp;Javier Manso-Morato ,&nbsp;Víctor Revilla-Cuesta ,&nbsp;Vanesa Ortega-López ,&nbsp;Marta Skaf","doi":"10.1016/j.clema.2025.100317","DOIUrl":"10.1016/j.clema.2025.100317","url":null,"abstract":"<div><div>The decommissioning of wind farms produces two primary waste materials: Recycled Concrete Aggregate (RCA) derived from the foundation concrete, and Raw-Crushed Wind-Turbine Blade (RCWTB) obtained through the crushing and sieving of the blades. Incorporating these materials into concrete enhances sustainability and, in some cases, improves mechanical properties while reducing the final environmental impact and cost compared to conventional concrete. A comprehensive characterization of the mechanical properties of concrete mixtures with varying RCA (0–100%) and RCWTB (0–10%) contents was conducted, these mixes being designed with increased water and admixture contents to compensate for the expected loss of workability caused by the addition of these waste materials. A Life-Cycle Assessment (LCA) and cost evaluation were also performed. The optimization of these mixtures was addressed using the Response Surface Method (RSM). The optimization process revealed that intermediate combinations of RCA (50%) and RCWTB (5%) yielded maximum flexural-tensile properties. However, achieving optimal performance proved more challenging when simultaneous optimization included compressive strength and deformability properties, such as modulus of elasticity and Poisson’s coefficient. For these properties, the optimal mix incorporated 88% RCA and 0% RCWTB. The RSM analysis demonstrated the feasibility of incorporating both RCA and RCWTB into concrete mixtures, mainly intended to work under bending stresses, but it also highlighted the complexities of achieving optimal performance when all mechanical properties were simultaneously considered. This research underscores the potential for these recycled materials to contribute to more sustainable concrete production while addressing the trade-offs in mechanical performance optimization.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100317"},"PeriodicalIF":0.0,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143937356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A systematic review on the role of reclaimed asphalt pavement materials: Insights into performance and sustainability 系统回顾再生沥青路面材料的作用:对性能和可持续性的见解
Cleaner Materials Pub Date : 2025-05-05 DOI: 10.1016/j.clema.2025.100316
Mayank Sukhija, Erdem Coleri
{"title":"A systematic review on the role of reclaimed asphalt pavement materials: Insights into performance and sustainability","authors":"Mayank Sukhija,&nbsp;Erdem Coleri","doi":"10.1016/j.clema.2025.100316","DOIUrl":"10.1016/j.clema.2025.100316","url":null,"abstract":"<div><div>Recycling practices have become stringent, essentially to overcome scarcity and higher cost of natural resources such as asphalt binder and mineral aggregates. The desire to conserve these natural resources and achieve sustainability in road construction has paved the way for the application of reclaimed asphalt pavement (RAP) material for paving purposes. This state-of-the-art review intends to provide a comprehensive overview of RAP-inclusive asphalt binders and mixtures based on laboratory and field investigations. The review covers various aspects of RAP utilization, starting with a detailed methodology for characterizing RAP material. This includes the extraction and recovery process, the effectiveness of solvents, and associated risk factors. Understanding these processes is crucial for assessing the suitability of RAP in asphalt mixtures. As per the review, the most commonly used extraction and recovery methods are centrifuge extraction and rotavapor with trichloroethylene and n-propyl bromide solvents. Emphases were given on the extent of change in chemical and morphological properties of asphalt binder with the application of RAP material. In addition, this review addresses the impact of using RAP material on the cost and environmental burdens. Based on the literatures, with the use of RAP, the reduction in cost can range from 5% to 68%, along with 3%-95% lower impact on the environment relative to the no RAP condition. As a whole, the compiled literature underscores the feasibility of using RAP as a major step towards constructing new asphalt pavements with adequate mechanical performance while promoting economic and environmental stewardship.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100316"},"PeriodicalIF":0.0,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143917522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elaborating the knowledge structure and emerging research in the utilization of metal–organic formwork in engineering applications: A scientometric analysis from 2004 to 2024 阐述金属有机模板在工程应用中的知识结构和新兴研究:2004年至2024年的科学计量分析
Cleaner Materials Pub Date : 2025-05-04 DOI: 10.1016/j.clema.2025.100314
Mohamed H. Alzard, Reem H. Alzard, Mohamed Abdellah
{"title":"Elaborating the knowledge structure and emerging research in the utilization of metal–organic formwork in engineering applications: A scientometric analysis from 2004 to 2024","authors":"Mohamed H. Alzard,&nbsp;Reem H. Alzard,&nbsp;Mohamed Abdellah","doi":"10.1016/j.clema.2025.100314","DOIUrl":"10.1016/j.clema.2025.100314","url":null,"abstract":"<div><div>Metal–organic frameworks (MOFs) have emerged as versatile materials with broad applications in engineering, from energy storage and environmental remediation to biomedical and sensing technologies. This study combines bibliometric analysis with an in-depth review of selected highly cited papers to examine MOF applications across multiple disciplines. The bibliometric analysis highlights significant research trends, including a dominant focus on energy and environmental engineering, a solid international collaboration, and the rapid growth of interdisciplinary applications. The keyword analysis identifies underexplored areas such as biomedicine, sensing, and unconventional uses like smart textiles and agriculture, highlighting potential directions for future research. Selected papers reveal key findings in fields such as energy storage, chemical engineering, and civil engineering. Applications range from enhancing cementitious materials to improving wastewater treatment and advancing battery technologies. Recommendations emphasize scalable synthesis methods, enhanced testing protocols, and interdisciplinary collaboration to address identified gaps. This study provides a roadmap for advancing MOF research and industrial implementation by aligning bibliometric findings with research recommendations. Future efforts should focus on expanding MOF applications, addressing scalability challenges, and integrating novel testing methods to maximize their potential in solving global engineering challenges.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100314"},"PeriodicalIF":0.0,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143937355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficacy of expansive soil stabilisation using un-calcinated Kaolinite-Based Alkali-Activated binders 未煅烧高岭石碱活化黏合剂稳定膨胀土的效果
Cleaner Materials Pub Date : 2025-05-01 DOI: 10.1016/j.clema.2025.100315
Mengyuan Zhu , Chin Leo , Qinghua Zeng , Daniel J. Fanna , Jeff Hsi , Reza Karimi , Antonin Fabbri , Samanthika Liyanapathirana , Pan Hu , Hadeel Alzghool
{"title":"Efficacy of expansive soil stabilisation using un-calcinated Kaolinite-Based Alkali-Activated binders","authors":"Mengyuan Zhu ,&nbsp;Chin Leo ,&nbsp;Qinghua Zeng ,&nbsp;Daniel J. Fanna ,&nbsp;Jeff Hsi ,&nbsp;Reza Karimi ,&nbsp;Antonin Fabbri ,&nbsp;Samanthika Liyanapathirana ,&nbsp;Pan Hu ,&nbsp;Hadeel Alzghool","doi":"10.1016/j.clema.2025.100315","DOIUrl":"10.1016/j.clema.2025.100315","url":null,"abstract":"<div><div>In recent years, alkali-activation and geopolymerisation have emerged as sustainable alternatives for stabilising expansive soils, traditionally treated with lime or cement. While most studies focus on high-temperature-processed materials such as fly ash, slag, and metakaolin, this study investigates the potential of using un-calcinated kaolinite as a precursor to produce an alkali-activated binder (U-KAB) slurry for expansive soil stabilisation. The U-KAB slurry, prepared by mixing un-calcinated kaolinite with NaOH solution, was applied at dosages ranging from 1.6% to 9.6% to a synthetic expansive soil composed of kaolinite, montmorillonite, and quartz. Two phases of experimental testing and characterisation provided valuable insights into its stabilisation potential, highlighting a new pathway for the development of cleaner soil stabilisation binders by avoiding the high energy consumption and carbon emissions associated with thermal calcination. The paper also emphasises the critical importance of carefully monitoring NaOH dosage and allowing for an adequate curing period—incorporating both sealed curing and air-drying—to enhance stabilisation effectiveness. Furthermore, while the results underscore the stabilisation potential of the U-KAB slurry, they also highlight the potential presence of excess unreacted alkali when aiming to achieve well effective dissolution of aluminosilicates at higher dosages. Unreacted alkali can adversely affect the stabilisation process, particularly in causing unsought swelling or negative swelling (consolidation) in the treated soils depending on the curing conditions. This indicates there may be a need in some cases to further optimise U-KAB mix design to mitigate these issues. The goal is to achieve an optimised U-KAB slurry with effective dissolution of the precursor to enhance geopolymerisation while ensuring adequate workability for mixing to stabilise the expansive soil.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100315"},"PeriodicalIF":0.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143906121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorizing urban pruning wastes and recycled polyethylene towards sustainable natural fiber-reinforced polymer composites 将城市修剪废弃物和回收聚乙烯转化为可持续的天然纤维增强聚合物复合材料
Cleaner Materials Pub Date : 2025-04-29 DOI: 10.1016/j.clema.2025.100313
Dayana Gavilanes , Vladimir Valle , Francisco Quiroz , Francisco Cadena , José I. Iribarren
{"title":"Valorizing urban pruning wastes and recycled polyethylene towards sustainable natural fiber-reinforced polymer composites","authors":"Dayana Gavilanes ,&nbsp;Vladimir Valle ,&nbsp;Francisco Quiroz ,&nbsp;Francisco Cadena ,&nbsp;José I. Iribarren","doi":"10.1016/j.clema.2025.100313","DOIUrl":"10.1016/j.clema.2025.100313","url":null,"abstract":"<div><div>The current research presents the elaboration of lignocellulosic reinforced polymer composites based on urban pruning wastes (UPW), recycled high-density polyethylene (rHDPE) and water-based acrylic resin. In doing so, UPW fibers were placed in acrylic resin bath. The “embedded” UPW fibers were called EUPW and used as reinforcement. Then, composites were formulated through a 3x2x2 experimental design: EUPW content (5, 10, and 15 wt%), natural fiber size (425 and 1000 µm) and coupling agent presence (none and polyethylene-graft-maleic anhydride). After extrusion and compression molding manufacturing, composites were characterized in terms of FTIR, TGA, and tensile behavior. The FTIR results showed a band at 1700 cm<sup>−1</sup> of the composites, representing the acrylate group of acrylic polymer (AP) in EUPW. Additionally, TGA determined that AP provided thermal protection to UPW. Furthermore, it was found that elastic modulus of the composites was increased compared to the neat polymer matrix; however, modulus of elasticity decreased with EUPW addition. According to the statistical analysis, coupling agent effect was the most significant factor on elastic modulus and tensile strength. Finally, the results revealed that combining UPW, acrylic polymer resin, rHDPE and polyethylene-graft-maleic anhydride, composites with relatively positive balanced properties were obtained.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100313"},"PeriodicalIF":0.0,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Upcycling waste glass bottles as a binder within engineered cementitious composites (ECCs): Experimental investigation and environmental impact assessment 在工程胶凝复合材料(ECCs)中作为粘合剂的废弃玻璃瓶的升级回收:实验调查和环境影响评估
Cleaner Materials Pub Date : 2025-04-19 DOI: 10.1016/j.clema.2025.100311
Avik Kumar Das , Jiacheng Xiao
{"title":"Upcycling waste glass bottles as a binder within engineered cementitious composites (ECCs): Experimental investigation and environmental impact assessment","authors":"Avik Kumar Das ,&nbsp;Jiacheng Xiao","doi":"10.1016/j.clema.2025.100311","DOIUrl":"10.1016/j.clema.2025.100311","url":null,"abstract":"<div><div>Single-use waste glass bottles (WGB) pose significant environmental challenges in urban areas, and this study explores their upcycling into powdered glass (GP) as a supplementary cementitious material (SCM) in engineered cementitious composites (ECCs). Through, systematic investigation of their mechanical performance, durability, early age properties and shrinkage for different levels of GP replacement a sustainable ECC mix (GP-ECC) was developed. GP-ECC demonstrates excellent mechanical and durability performance, including high ductility (∼4%), tensile strength (∼4 MPa), narrow crack widths (∼60 μm), and manageable shrinkage (∼1700 με). Optimal results were observed at 20–30 % GP replacement, where improved particle packing and pozzolanic activity enhanced performance. In contrast, at higher replacement levels (50 %) led to increased porosity and reduced durability due to suppressed hydration. The inclusion of natural seawater further accelerated early hydration and strength gain, though slight compromises were noted in crack control due to ionic interference, overall their performance are comparable to GP-ECC. Microstructural analyses (SEM, XRD) confirmed denser matrices and stronger fiber–matrix bonding at 30 % GP, particularly in seawater-mixed ECCs thereby, confirming the feasibility and high-perfromance of sea based materials (SBM)-GP-ECCs. A novel framework for life cycle analysis (LCA) for ECCs considering regional variations, including transportation emissions and energy mix, thereby reflecting intercity differences. GP-ECC and SBM-GP-ECC mixes achieved notable reductions in CO2 (∼8–10 %) emission<!--> <!-->and costs<!--> <!-->other ecological impacts, but such effects is a function<!--> <!-->of the location outperforming normal concrete and GP-concrete by up to 100x in tensile and durability properties. By systematically evaluating mechanical, rheological, durability, and microstructural properties, this study establishes a robust foundation for future research and practical deployment of GP-marine ECCs derived from waste materials, contributing to circular economy strategies and the development of cleaner, high-performance construction materials.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100311"},"PeriodicalIF":0.0,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143867823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating Torsional Recovery test for interlinkage with deformation-recovery measurement metrics of polymer modified bitumen 评估扭转恢复试验与聚合物改性沥青变形恢复测量指标的相互联系
Cleaner Materials Pub Date : 2025-04-17 DOI: 10.1016/j.clema.2025.100309
Nazmus Sakib , Sabrina Islam , Shahriar Bin Kabir , Shamima Yasmin , Md. Mamun Kaysar , Joy Prakash Chowdhury , Md. Mahbubur Rahman
{"title":"Evaluating Torsional Recovery test for interlinkage with deformation-recovery measurement metrics of polymer modified bitumen","authors":"Nazmus Sakib ,&nbsp;Sabrina Islam ,&nbsp;Shahriar Bin Kabir ,&nbsp;Shamima Yasmin ,&nbsp;Md. Mamun Kaysar ,&nbsp;Joy Prakash Chowdhury ,&nbsp;Md. Mahbubur Rahman","doi":"10.1016/j.clema.2025.100309","DOIUrl":"10.1016/j.clema.2025.100309","url":null,"abstract":"<div><div>Elastic recovery of polymer modified bitumen (PMB) is considered an effective parameter to evaluate its capacity to resist permanent deformation through recovering some part of load-related deformation. Conceptually, it is represented as the ratio of recovered strain (measured under zero loading after a fixed duration) to maximum strain (under loading) on a bitumen sample, using various devices and loading types. Recovery tests also indicate the presence of polymer as well as degree of polymerization. Hence, such tests can be useful as rapid quality control and verification tool during field inventory inspections by procuring agencies. Traditional method, that is, ductilometer-based Elastic Recovery (ER-DB) relies on an unwieldy large device, delicate sample preparation process, and variable true strain rate. On the other hand, Multiple Stress Creep Recovery (MSCR) test-based Percent Recovery (%R) utilizes creep-recovery from application of shear-stress on a small bitumen sample for obtaining similar information, but it requires a sophisticated and expensive device. Torsional Recovery (TR), which uses an easily portable, manually operable, quick and inexpensive setup, also relies on shear deformation and angular recovery. In the present study, TR was evaluated for its correlation with these established methods using a total of 15 PMBs, prepared with 5 types of SBS and one base bitumen. The results showed strong linear relationships, with linear regression <span><math><msup><mrow><mi>R</mi></mrow><mrow><mn>2</mn></mrow></msup></math></span> values exceeding 0.85 in many cases, especially for PMBs made with the same polymer. Notably, TR and ER-DB exhibited <span><math><msup><mrow><mi>R</mi></mrow><mrow><mn>2</mn></mrow></msup></math></span> more than 0.90, especially within SBS-type specific cases, while global correlation was found to be 0.76. In addition, it was found that TR can be reliably used for preliminary quantification of SBS-dosage with <span><math><msup><mrow><mi>R</mi></mrow><mrow><mn>2</mn></mrow></msup></math></span> of 0.88. Interestingly, Torsional recovery values show good global correlation with Dynamic Modulus values and associated parameters with <span><math><msup><mrow><mi>R</mi></mrow><mrow><mn>2</mn></mrow></msup></math></span> <span><math><mrow><mo>≥</mo><mn>0</mn><mo>.</mo><mn>8</mn></mrow></math></span>. In fact, SBS dosage, Torsional Recovery and Dynamic Modulus parameters also displayed excellent PMB specific correlation and reasonable global correlation. Other factors and correlations also indicate that TR results align well with existing test methods and hence, can be used for preliminary assessment of PMB quality and quantitative presence of polymer, with particular suitability for site deployment.</div></div>","PeriodicalId":100254,"journal":{"name":"Cleaner Materials","volume":"16 ","pages":"Article 100309"},"PeriodicalIF":0.0,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143844655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydraulic concrete durability studies with the addition of two industrial byproducts, stone aggregate filler, and foundry sand: A collaborative solution for three large industries 加入两种工业副产品——石料填料和铸造砂——的水工混凝土耐久性研究:三大工业的协同解决方案
Cleaner Materials Pub Date : 2025-04-16 DOI: 10.1016/j.clema.2025.100312
Guilliana Agudelo , Carlos A. Palacio , Sergio Neves Monteiro , Henry A. Colorado
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