China Particuology最新文献

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Fluidization in combined acoustic-magnetic field for mixtures of ultrafine particles 超细颗粒混合的声-磁复合流态化
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2007.01.007
Huie Liu, Qingjie Guo
{"title":"Fluidization in combined acoustic-magnetic field for mixtures of ultrafine particles","authors":"Huie Liu,&nbsp;Qingjie Guo","doi":"10.1016/j.cpart.2007.01.007","DOIUrl":"10.1016/j.cpart.2007.01.007","url":null,"abstract":"<div><p>Four kinds of SiO<sub>2</sub> (5–10<!--> <!-->nm)<!--> <!-->+<!--> <!-->Fe<sub>3</sub>O<sub>4</sub> (44.8<!--> <!-->μm) particle were fluidized in a sole acoustic field, a sole magnetic field and a combined acoustic-magnetic field. Introduction of a single field, 100<!--> <!-->dB/40–60<!--> <!-->Hz acoustic or 10<!--> <!-->mT magnetic, could suppress plugging and channeling and reduce the superficial minimum fluidization gas velocities, <em>U</em><sub>mf</sub>. Combination of both acoustic and magnetic fields demonstrated even more promising results, especially more significant reduction of <em>U</em><sub>mf</sub>.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 111-115"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.01.007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78609964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Ferrimagnetic ceramic adsorbents for cleanup of H2S from exhaust gases 用于清除废气中硫化氢的铁磁陶瓷吸附剂
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2007.01.002
Bernd Halbedel , Apostolos Kontogeorgakos
{"title":"Ferrimagnetic ceramic adsorbents for cleanup of H2S from exhaust gases","authors":"Bernd Halbedel ,&nbsp;Apostolos Kontogeorgakos","doi":"10.1016/j.cpart.2007.01.002","DOIUrl":"10.1016/j.cpart.2007.01.002","url":null,"abstract":"<div><p>Adsorbents that exhibit magnetic properties in addition to other required process-relevant characteristics open up new perspectives for the dry reduction and/or elimination of H<sub>2</sub>S and other sulfur compounds from exhaust gases. These adsorbents eliminate the sulfur compounds from exhaust gases by virtue of their coatings and their magnetic property which makes it possible the use of magnetically assisted and stabilized fluidization in an externally applied magnetic field.</p><p>In the present paper, the feasibility of the sorptive function of porous ceramic ferrimagnetic beads is ensured by sol–gel coating of zinc oxide without the formation of Zn–Fe-oxides and without considerable decrease of available pore volume. The results of material characterization by SEM, Auger electron spectroscopy, X-ray and mercury-porosity measurements and the loading capacity of a H<sub>2</sub>S/N<sub>2</sub> model gas are presented and discussed. The resulting H<sub>2</sub>S loading of the functionalized adsorbent beads is more than 10 times larger than that of the starting material.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 156-161"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.01.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73684885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Synthesis and characterization of monosize magnetic poly(glycidyl methacrylate) beads 单粒径磁性聚甲基丙烯酸缩水甘油酯微球的合成与表征
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2007.01.004
Evrim Banu Altıntaş, Lokman Uzun, Adil Denizli
{"title":"Synthesis and characterization of monosize magnetic poly(glycidyl methacrylate) beads","authors":"Evrim Banu Altıntaş,&nbsp;Lokman Uzun,&nbsp;Adil Denizli","doi":"10.1016/j.cpart.2007.01.004","DOIUrl":"10.1016/j.cpart.2007.01.004","url":null,"abstract":"<div><p>Monosize, 1.6<!--> <!-->μm, magnetic beads of poly(glycidyl methacrylate) [M-poly(GMA)], were prepared by dispersion polymerization in the presence of Fe<sub>3</sub>O<sub>4</sub> nano-powder. Monosize M-poly(GMA) beads were characterized by swelling tests, density measurements, electron spin resonance (ESR), vibrating sample magnetometer (VSM) and scanning electron microscopy (SEM). The characteristic functional groups of M-poly(GMA) beads were analyzed by Fourier transform infrared spectrometer (FTIR). The M-poly(GMA) beads are highly uniform in size and have a spherical shape and non-porous structure. Polydispersity index (PDI) of M-poly(GMA) beads was calculated to be around 1.008. The hydrated density of the M-poly(GMA) beads measured at 25<!--> <!-->°C was 1.14<!--> <!-->g/cm<sup>3</sup>. The content of oxirane groups on the surface of the M-poly(GMA) sample was found to be 3.46<!--> <!-->mmol/g by using perchloric acid titration. The specific surface area of the M-poly(GMA) beads was determined to be 3.2<!--> <!-->m<sup>2</sup>/g. The equilibrium swelling ratio was 52%. The volume fraction of magnetite nanopowder in the M-poly(GMA) beads was found to be 4.5%. The g factor, that can be considered as a quantity characteristic of the molecules in which the unpaired electrons are located, was found to be 2.28 for M-poly(GMA). The external magnetic field at resonance was calculated to be 2055<!--> <!-->Gs which was found sufficient to excite all of the dipole moments present in 1.0<!--> <!-->g of M-poly(GMA) sample.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 174-179"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.01.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74984347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Ferrofluid magnetoviscous control of wall flow channeling in porous media 多孔介质壁面流道的铁磁流体磁粘性控制
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2006.12.001
Faïçal Larachi, Damien Desvigne
{"title":"Ferrofluid magnetoviscous control of wall flow channeling in porous media","authors":"Faïçal Larachi,&nbsp;Damien Desvigne","doi":"10.1016/j.cpart.2006.12.001","DOIUrl":"10.1016/j.cpart.2006.12.001","url":null,"abstract":"<div><p>We analyzed the phenomenon of ferrofluid magnetoviscosity in high-permeability wall-region non-magnetic porous media of the Müller kind. After upscaling the pore-level ferrohydrodynamic model, we obtained a simplified volume-average zero-order axisymmetric model for non-Darcy non-turbulent flow of steady-state isothermal incompressible Newtonian ferrofluids through a porous medium experiencing external constant bulk-flow oriented gradient magnetic field, ferrofluid self-consistent demagnetizing field and induced magnetic field in the solid. The model was explored in contexts plagued by wall flow maldistribution due to low column-to-particle diameter ratios. It was shown that for proper magnetic field arrangement, wall channeling can be reduced by inflating wall flow resistance through magnetovisco-thickening and Kelvin body force density which reroute a fraction of wall flow towards bed core.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 50-60"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2006.12.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89368314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Magnetically modified microbial cells: A new type of magnetic adsorbents 磁修饰微生物细胞:一种新型磁性吸附剂
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2006.12.003
Ivo Safarik, Mirka Safarikova
{"title":"Magnetically modified microbial cells: A new type of magnetic adsorbents","authors":"Ivo Safarik,&nbsp;Mirka Safarikova","doi":"10.1016/j.cpart.2006.12.003","DOIUrl":"10.1016/j.cpart.2006.12.003","url":null,"abstract":"<div><p>Microbial cells, either in free or immobilized form, can be used for the preconcentration or removal of metal ions, organic and inorganic xenobiotics or biologically active compounds. Magnetic modification of these cells enables to prepare magnetic adsorbents that can be easily manipulated in difficult-to-handle samples, such as suspensions, in the presence of external magnetic field. In this review, typical examples of magnetic modifications of microbial cells are presented, as well as their possible applications for the separation of organic xenobiotics and heavy metal ions.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 19-25"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2006.12.003","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88505641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 48
Magnetically rotational reactor for absorbing benzene emissions by ionic liquids 用于吸收离子液体释放苯的磁旋转反应器
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2006.12.002
Yangyang Jiang , Chen Guo , Huizhou Liu
{"title":"Magnetically rotational reactor for absorbing benzene emissions by ionic liquids","authors":"Yangyang Jiang ,&nbsp;Chen Guo ,&nbsp;Huizhou Liu","doi":"10.1016/j.cpart.2006.12.002","DOIUrl":"10.1016/j.cpart.2006.12.002","url":null,"abstract":"<div><p>A magnetically rotational reactor (MRR) has been developed and used in absorbing benzene emissions. The MRR has a permanent magnet core and uses magnetic ionic liquid [bmim]FeCl<sub>4</sub> as absorbent. Benzene emissions were carried by N<sub>2</sub> into the MRR and were absorbed by the magnetic ionic liquid. The rotation of the permanent magnet core provided impetus for the agitation of the magnetic ionic liquid, enhancing mass transfer and making benzene better dispersed in the absorbent. 0.68<!--> <!-->g benzene emissions could be absorbed by a gram of [bmim]FeCl<sub>4</sub>, 0.27 and 0.40<!--> <!-->g/g higher than that by [bmim]PF<sub>6</sub> and [bmim]BF<sub>4</sub>, respectively. The absorption rate increased with increasing rotation rate of the permanent magnet.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 130-133"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2006.12.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88649891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 33
Magnetic filtration with magnetized granular beds: Basic principles and filter performance 磁化颗粒床磁过滤:基本原理和过滤性能
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2007.01.014
Teymuraz Abbasov
{"title":"Magnetic filtration with magnetized granular beds: Basic principles and filter performance","authors":"Teymuraz Abbasov","doi":"10.1016/j.cpart.2007.01.014","DOIUrl":"10.1016/j.cpart.2007.01.014","url":null,"abstract":"<div><p>This study is devoted to the explanation of different characteristics of magnetic filtration and the way these characteristics affect the important filtration parameters. Magnetic fields in pores and the force effect of these fields on magnetic particles and the magnetization properties of packed beds composed of ferromagnetic spheres and metal chips are evaluated. The profile of accumulation and capture regions of the particles, the variation of the fluid velocity in these regions and analytic expressions of particle capture radius are presented. The effects of filtration regime parameters on magnetic filter performance were investigated. An analytical expression has been obtained for the dependence of the logarithmic efficiency coefficient on filtration velocity, the geometry of filter elements, the particle size and other parameters of filtration. The stationary and non-stationary equations of the magnetic filtration processes are given. An expression of magnetic filter performance is shown with dimensionless parameters obtained from the filtration system. These relations are useful for calculations in engineering practice, including the design of magnetic filters, provision of suggestions on construction, and optimization and control of filter operation.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 71-83"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.01.014","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81512499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 26
Audio-frequency heating of particulate magnetic systems 颗粒磁系统的音频加热
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2006.12.004
B.E. Kashevsky, I.V. Prokhorov, S.B. Kashevsky
{"title":"Audio-frequency heating of particulate magnetic systems","authors":"B.E. Kashevsky,&nbsp;I.V. Prokhorov,&nbsp;S.B. Kashevsky","doi":"10.1016/j.cpart.2006.12.004","DOIUrl":"10.1016/j.cpart.2006.12.004","url":null,"abstract":"<div><p>This paper presents theoretical and experimental studies on the magnetodynamics and energy dissipation in suspensions of small ferromagnetic particles with magnetic hysteresis and mechanical mobility in an AC magnetic field. Energy absorption by particles suspended in a solid, liquid or gas environment and subjected to high frequency magnetic fields is of great interest for cancer treatment by hyperthermia, chemical technology, biotechnology and smart materials science.</p><p>Sub-micron needle-like γ-Fe<sub>2</sub>O<sub>3</sub> particles dispersed in liquid were subjected in this study to a 430<!--> <!-->Hz magnetic field with an intensity of up to 10<sup>5</sup> <!-->A/m. Dynamic magnetization loops were measured in parallel to the energy dissipated in the samples. Combined magnetomechanical dynamics of particle dispersions was simulated by using a chain-of-spheres model allowing for incoherent magnetic field reversal. In liquid dispersions, within the kilohertz frequency range, the mechanical mobility of particles does not interfere with their hysteretic magnetic reversal that makes heat release comparable to that observed with solids; for instance, in the present study using γ-Fe<sub>2</sub>O<sub>3</sub> particles in liquid subjected to 10<sup>4</sup> <!-->Hz field exhibited heat release rates from 250 up to 600<!--> <!-->W per 1<!--> <!-->cm<sup>3</sup> of the dry particle content.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 84-92"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2006.12.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76907523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
An overview of separation by magnetically stabilized beds: State-of-the-art and potential applications 磁稳定床分离综述:最新的和潜在的应用
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2007.01.010
Jordan Hristov , Ludmil Fachikov
{"title":"An overview of separation by magnetically stabilized beds: State-of-the-art and potential applications","authors":"Jordan Hristov ,&nbsp;Ludmil Fachikov","doi":"10.1016/j.cpart.2007.01.010","DOIUrl":"10.1016/j.cpart.2007.01.010","url":null,"abstract":"<div><p>This article deals with problems relevant to implementation of magnetically stabilized beds (MSB) as separation devices. The main issues discussed are: bed mechanics, bed structure, possibilities to create controllable filter media, etc. As examples several separation techniques are discussed: dust filtration—magnetic and non-magnetic, ion-exchange, copper cementation, yeast filtration from biological liquids, particle separation by density and magnetic properties, dangerous wastes removal. Only key publications will be quoted that provide a basis for further reading and study and relevant information.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 11-18"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.01.010","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81233286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 49
Sedimentation acceleration of remanent iron oxide by magnetic flocculation 磁絮凝加速残余氧化铁沉降
China Particuology Pub Date : 2007-02-01 DOI: 10.1016/j.cpart.2007.01.005
Mathias Stolarski , Christian Eichholz , Benjamin Fuchs , Hermann Nirschl
{"title":"Sedimentation acceleration of remanent iron oxide by magnetic flocculation","authors":"Mathias Stolarski ,&nbsp;Christian Eichholz ,&nbsp;Benjamin Fuchs ,&nbsp;Hermann Nirschl","doi":"10.1016/j.cpart.2007.01.005","DOIUrl":"10.1016/j.cpart.2007.01.005","url":null,"abstract":"<div><p>Sedimentation based processes are widely used in industry to separate particles from a liquid phase. Since the advent of the “Nanoworld” the demand for effective separation technologies has rapidly risen, calling for the development of new separation concepts, one of which lies in hybrid separation using the superposition of a magnetic field for magnetic particles. Possible product portfolio of such separation consists of pigment production, nanomagnetics production for electronics and bio separation. A promising step in that direction is magnetic field enhanced cake filtration, which has by now progressed from batch to continuous operation.</p><p>In sedimentation processes in a mass force field the settling behaviour of particles strongly depends on physico-chemical properties, concentration and size distribution of the particles. By adjusting the pH, the interparticle forces, in particular the electrostatic repulsion, can be manipulated. For remanent magnetic particles such as magnetite, pre-treatment in a magnetic field could lead to a change of interparticle interactions. By magnetizing the particles apart from van der Waals attraction and electrostatic repulsion, an additional potential is induced, the magnetic attraction, which could easily dominate the other potentials and result in agglomeration in the primary minimum. By sedimentation analysis, a wide spectrum of parameters like pH, magnetic field strength and concentration have been investigated. The results show a strong increase of sedimentation velocity by magnetic flocculation of the raw suspension. This leads to a rise in throughput due to the acceleration of sedimentation kinetics by imparting a non-chemical interaction to the physico-chemical properties in the feed stream of the separation apparatus.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 1","pages":"Pages 145-150"},"PeriodicalIF":0.0,"publicationDate":"2007-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.01.005","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78254612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 30
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