ACS Sustainable Resource Management最新文献

{"title":"Self-Driven SiO2/C Nanocomposites from Cultured Diatom Microalgae for Sustainable Li-Ion Battery Anodes: The Role of Impurities","authors":"Kesavan Thangaian*,&nbsp;Anders Gaarud,&nbsp;Inger-Emma Nylund and Maria Valeria Blanco*,&nbsp;","doi":"10.1021/acssusresmgt.4c0031210.1021/acssusresmgt.4c00312","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00312https://doi.org/10.1021/acssusresmgt.4c00312","url":null,"abstract":"<p >Nanostructured SiO₂ shells from diatom microalgae are a promising feedstock for the production of high-performance SiO₂ anodes for next-generation lithium-ion batteries (LIBs), and diatom biomass has been proposed as a carbon source for producing SiO₂/C nanocomposites of improved cyclability. A standard approach before implementing diatoms as an anode material involves an acid washing step for removing minor impurities from diatom shells. In this work, we perform the first comprehensive analysis on the effect of minor chemical species present on diatom shells on the electrochemical properties of diatom-SiO₂/C anodes. Unwashed and acid-washed single species cultured diatoms containing their original biomass content were subjected to thermal treatments at 600, 700, 800, and 900 °C, and the resulting SiO₂/C composites were fully characterized by XRD, BET, TGA, Raman, SEM/EDX, and TEM techniques. The electrochemical performance of the resulting anodes reveals the key role of impurities in improving the cycling properties. While acid-washed SiO₂/C composites displayed higher surface area, their electrochemical performance was comparable to non-coated SiO₂. On the other hand, unwashed SiO₂/C anodes exhibited a specific capacity up to twice that of SiO₂. The best-performing SiO₂/C anode was the unwashed diatom-SiO₂ heat-treated at 800 °C, showing a specific capacity of 661 mAh·g^–1 after 100 cycles at a current density of 200 mA·g^–1. Results on the beneficial effects of impurities on SiO₂/C anodes are crucial for an effective implementation of diatoms in LIB technology.</p><p >Nanostructured carbon-coated SiO₂ from biomass-derived diatom microalgae are promising candidates for high-performance next-generation lithium-ion battery anodes.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2284–2293 2284–2293"},"PeriodicalIF":0.0,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acssusresmgt.4c00312","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142550646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Core/Shell-Like Magnetic Structure and Optical Properties in CuO Nanoparticles Synthesized by Green Route","authors":"Latika Mishra*,&nbsp;Vinod Kumar Dwivedi*,&nbsp;Hanuma Kumar Dara,&nbsp;Vishal Kumar Chakradhary,&nbsp;Sairam Ithineni,&nbsp;Akila G. Prabhudessai and Shamshun Nehar,&nbsp;","doi":"10.1021/acssusresmgt.4c0032510.1021/acssusresmgt.4c00325","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00325https://doi.org/10.1021/acssusresmgt.4c00325","url":null,"abstract":"<p >We report a core/shell-like magnetic structure at room temperature in nonstoichiometric CuO nanoparticles (NPs) synthesized by a green route using <i>Phyllanthus niruri</i> whole plant extract over leaf extract. The XRD pattern analyzed by Rietveld refinement confirms single phase formation of CuO NPs crystals in a monoclinic structure with space group C2/C. SEM and TEM microstructures reveal agglomeration of NPs, spherical in shape with an average particle size of 20 nm. The FTIR spectrum confirms the plant derivatives and its biomolecules and functional group associated with the CuO NPs. The core level XPS of Cu-2p and O-1s suggests the presence of oxygen vacancies and coexistence of mixed oxidation states of Cu, i.e., Cu²⁺ and Cu³⁺. UV–visible absorption spectra show enhancement in the optical band gap energy (<i>E</i>_<i>g</i> ∼ 2.9 eV) along with a strong absorption peak at wavelength ∼244 nm, which is not observed in previously reported literature [Kalarani, G.; Lekha, N. C.; Arunkumar, G. <i>Ann. Romanian Soc. Cell Biol.</i> <b>2021</b>, <i>25</i>, 12900; Hemashree, S.; Pruthvi, M. L.; Mahesh, M. K. <i>Int. J. Res. Appl. Sci. Eng. Technol.</i> <b>2023</b>, <i>11</i>, 459]. It is likely due to the surface plasmon resonance. The investigation of magnetization of CuO NPs synthesized by PN extract is entirely missing [Kalarani, G.; Lekha, N. C.; Arunkumar, G. <i>Ann. Romanian Soc. Cell Biol.</i> <b>2021</b>, <i>25</i>, 12900; Hemashree, S.; Pruthvi, M. L.; Mahesh, M. K. <i>Int. J. Res. Appl. Sci. Eng. Technol.</i> <b>2023</b>, <i>11</i>, 459]. M-H results reveal room temperature ferromagnetism at a low field (0.3 T) with a coercive field of 0.02 T along with the absence of saturation magnetization. The M-T result indicates a magnetic transition temperature beyond 350 K with a significant bifurcation between both branches of magnetic susceptibilities χ_<i>FC</i> and χ_<i>ZFC</i>. Overall results suggest a core/shell-like magnetic structure, where the inner part exhibits a strong antiferromagnetic order and the outer surface behaves like a weak disordered ferromagnet due to uncompensated surface spins. The room temperature ferromagnetic ordering is likely due to the virtual hopping of electrons from the Cu²⁺(3d⁹) site to the Cu³⁺(3d⁸) site.</p><p >Eco-friendly and sustainable approach for the synthesis of CuO nanomaterials using whole plant extract of <i>Phyllanthus niruri</i> for the study of its magnetic and optical properties.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 11","pages":"2472–2481 2472–2481"},"PeriodicalIF":0.0,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acssusresmgt.4c00325","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142736035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Agro-Waste from Gladiolus hybrida Plants: Effects of Alkaline Processing on a New Natural Cellulosic Fiber Derived for Polymer Composites","authors":"Mohammad Abul Hasan Shibly*,&nbsp;Md. Hasin Arman,&nbsp;Md. Abdus Sabur and Mohammad Amir Hossain Bhuiyan,&nbsp;","doi":"10.1021/acssusresmgt.4c0034810.1021/acssusresmgt.4c00348","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00348https://doi.org/10.1021/acssusresmgt.4c00348","url":null,"abstract":"<p >This study investigates the potentiality of <i>Gladiolus hybrida</i> leaf fibers (GHLFs) as an eco-friendly reinforcing substance for polymer-based composites. Novel natural fibers were harvested from <i>Gladiolus hybrida</i> leaves (GHL) and treated with NaOH alkali (T-GHLF) to assess their influence on physical, strength, molecular, and heat-related properties. Initially, the obtained fibers had a diameter of 0.3084 mm, which reduced to 0.2524 mm following alkali treatment. Chemical investigation indicated that the cellulose content increased to 57.16 wt %, an enhancement of 11.38% over the untreated fibers, which had a cellulose content of 51.32 wt %. The degree of crystallinity percentage of the raw and processed fibers was 57.85% and 60.82%, respectively, without significant change in the cellulose phase. The thermogravimetric analysis indicated that T-GHLF exhibited improved thermal stability up to 257.77 °C, with the kinetic activation energy (Ea) measured at 81.56 kJ/mol. Fourier transform infrared spectroscopy (FTIR) has been employed to observe the distribution of different chemical groups on the fiber surface. Scanning electron microscopy (SEM) revealed that the fibers had a roughened surface. According to tensile testing of a single fiber, the Young’s modulus values for GHLFs and T-GHLFs were 2.08 and 2.21 GPa, respectively. These evidences suggested that GHLFs exhibited characteristics comparable to those of presently used natural fibers, positioning them as a strong contender to replace organic fibers in resin matrix composites. As a result, these novel natural resources may assist in achieving the Sustainable Development Goals of the United Nations through the sustainable utilization of agricultural waste in polymer matrix composites.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2314–2326 2314–2326"},"PeriodicalIF":0.0,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142550951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Semi-Rational Engineering of Aldoxime Dehydratase for Conducting a Chemoenzymatic Sequence to Prepare 2-Furonitrile from Xylose","authors":"Yumin Feng,&nbsp;Li Chen,&nbsp;Siyu Jiang,&nbsp;Qiuyan Wang,&nbsp;Pengfei Zhang,&nbsp;Anming Wang* and Xiaolin Pei*,&nbsp;","doi":"10.1021/acssusresmgt.4c0022610.1021/acssusresmgt.4c00226","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00226https://doi.org/10.1021/acssusresmgt.4c00226","url":null,"abstract":"<p >Exploiting efficient methods for converting biomass-based resources into high-value-added chemicals has attracted extensive interest in sustainable development in the chemical industry. Here, we have developed a chemoenzymatic sequence for synthesizing 2-furonitrile (2-FN) from xylose, a biobased five-carbon monosaccharide derived from agricultural waste. Firstly, a 1,2-dichloroethane (DCE)/H₂O biphasic system (1:1, v/v) was adopted to produce 2-furaldehyde oxime (2-FOx) from xylose by integrating two steps of dehydration and oximation in a one-pot sequence using a temporal compartmentalization strategy, resulting in a yield of 2-FOx from xylose over 78%. Secondly, the catalytic efficiency of aldoxime dehydratase from <i>Pseudomonas putida</i> F1 (OxdF1) was significantly improved by engineering the substrate access tunnel and a distal residue. The activity of an optimal mutant L318I–N266S has reached 3.94 U·mg^–1 towards 2-FOx, approximately 6 times higher than that of the wild-type OxdF1 (0.65 U·mg^–1). Consequently, 2-FN was prepared in a 400 mL reaction mixture at room temperature using a continuous feeding strategy. After 1.5 h, 100 mM 2-FOx was completely converted to 2-FN with a space-time yield of 6.2 g·L^–1·h^–1. The chemoenzymatic process proposed an alternative strategy for synthesizing 2-FN from biomass-based materials under mild conditions without using highly toxic cyanide.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2214–2224 2214–2224"},"PeriodicalIF":0.0,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142517262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Comparative Study on the Sustainable Management of Phenolic Content and Antioxidant Residues from Waste Tamarind and Litchi Shells through Optimized Extraction Methods","authors":"Ram Kumar Deshmukh,&nbsp;Shefali Tripathi,&nbsp;Lokesh Kumar and Kirtiraj K. Gaikwad*,&nbsp;","doi":"10.1021/acssusresmgt.4c0032810.1021/acssusresmgt.4c00328","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00328https://doi.org/10.1021/acssusresmgt.4c00328","url":null,"abstract":"<p >The growing global emphasis on sustainability and waste reduction has led to a thorough investigation of agricultural by-products, especially those containing valuable bioactive chemicals. The study was conducted to optimize solvent and extraction methods to compare tamarind and litchi shell extracts’ total phenolic contents and antioxidant capacities. The extracts were evaluated for the total phenolic content (TPC) and antioxidant activity using various assays from maceration, microwave-assisted extraction (MAE), and ultrasound-assisted extraction (UAE). The litchi shell extract TPC was highest for MAE with 29.93 ± 0.21 mg of GAE/g of DW for acetone:water (50:50; v/v) followed by UAE with 27.41 ± 0.09 mg of GAE/g of DW, whereas 16.90 ± 0.15 mg of GAE/g of DW TPC was reported, which is 43.54 and 38.34% higher than the values from maceration. The tamarind shell has contradictorily the highest TPC of 29.40 ± 0.15 mg of GAE/g of DW in maceration compared to MAE and UAE. With a mixture of methanol, water, and acetic acid, the MAE technique demonstrated the highest diphenyl-2-picrylhydrazyl (DPPH) antioxidant activity (94.86%), followed by 94.78% with a methanol/water combination. The greatest ferric-reducing ability of plasma (FRAP) value of 6.60 mg of TE/g for acetone:water in maceration was observed for 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) values varying between 0.824 and 0.974 mg of TE/g for all extraction techniques. A moderately positive correlation was observed in the TPC and different antioxidant assays. A strong positive correlation was noticed between the extraction method and the antioxidant activity of litchi and tamarind shell extracts. The study concludes that the optimized extraction method can obtain high-quality extracts from tamarind and litchi shells that can potentially be used as natural antioxidants in various applications.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2304–2313 2304–2313"},"PeriodicalIF":0.0,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142551176","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Modification Strategy of Biomass-Derived Full-Color Carbon Dots and Its Applications to Warm White Light-Emitting Diodes with Ultra-High CRI-96.2","authors":"Haozhe Wang,&nbsp;Xilang Jin*,&nbsp;Yuchen He,&nbsp;Haiyan Bai,&nbsp;Liyuan Ma,&nbsp;Lihang Zhao,&nbsp;Liu Ding,&nbsp;Hongwei Zhou,&nbsp;Qingfa Si and Weixing Chen*,&nbsp;","doi":"10.1021/acssusresmgt.4c0029810.1021/acssusresmgt.4c00298","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00298https://doi.org/10.1021/acssusresmgt.4c00298","url":null,"abstract":"<p >The white light-emitting diode (W-LED) is a new generation of lighting devices, and its key technology is light-emitting materials. Biomass-derived carbon dots (CDs) are expected to be favorable candidates for a new generation of environmentally friendly fluorescent materials. However, the insufficient absolute photoluminescence quantum yield (PLQY) and lack of effective emission bands of most biomass-derived CDs limit their further applications. Herein, Defatted Sichuan pepper seed, an inexpensive biowaste, was used for the raw materials of fluorescent CDs. The preparation of highly efficient panchromatic (415–650 nm) CDs by a simple one-step solvothermal method were reported. Defatted Sichuan pepper seed biowaste was used as a carbon source, and 1,4-dihydroxynaphthalene was used as a modifier to modulate the formation of conjugated domains in CDs, and the surface structures of CDs were modified in different solvents. Meanwhile, optical trichromatic CDs with high absolute PLQY (blue CDs: 82%, green CDs: 62%, and red CDs: 48%) were selected for characterization and analysis and further mixed to prepare white CDs (W-CDs). Then, the W-CDs were embedded in starch and a PVP matrix to construct solid phosphors with excellent photoluminescence (PL) thermal stability and resistance to photobleaching. The phosphors can be used as color conversion layers for light-emitting diodes (LEDs). The final packages realized blue LED (B-LED), green LED (G-LED), red LED (R-LED), and warm W-LEDs. What’s more, the R-LED shows a high color purity of 93.7%, and the W-LED exhibits a high color rendering index (CRI) of 96.2, with a color coordinate (CIE) of (0.40, 0.39). This work provides a new way for exploring biomass-derived high-efficiency CDs to build low-cost, high-performance, and environmentally friendly LED devices.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2255–2265 2255–2265"},"PeriodicalIF":0.0,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142517503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Spatial Modeling and Economical Evaluation of Water Corrosion and Scaling in Water Distribution Network","authors":"Mokhtar Mahdavi,&nbsp;Ensiyeh Taheri,&nbsp;Ali Fatehizadeh*,&nbsp;Mohammad Ghasemian,&nbsp;Bahar Akbari,&nbsp;Nabisab Mujawar Mubarak and Mashallah Rezakazemi*,&nbsp;","doi":"10.1021/acssusresmgt.4c0009510.1021/acssusresmgt.4c00095","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00095https://doi.org/10.1021/acssusresmgt.4c00095","url":null,"abstract":"<p >The purpose of this research is to assess the corrosion and scaling the potential of a water distribution network (WDN) using Geostatistics (GS⁺) software, and to estimate the operation and maintenance costs of some home appliances (heating and cooling units). The inquiry scheme was to monitor the water quality of WDN of Saveh City (Iran), and 40 points from four districts on the WDN were sampled. The pH, temperature, electrical conductivity (EC), total dissolved solids (TDS), total alkalinity (TA), total hardness (TH), and calcium hardness (CH) were all measured and used to calculate various corrosion and scaling indices such as the Langlier saturation index (LSI), Ryznar stability index (RSI), Puckorius scaling index (PSI), and aggressive index (AI). The pH value for all districts follows EPA standards and WHO guidelines, with an average value of 7.92 ± 0.34. Overall, values of TDS (1728.83 ± 167.83 mg/L) and EC (3.53 ± 0.31 mS/cm) are relatively high, indicating brackish water quality. Furthermore, the TH and CH values are 519.55 ± 65.33 and 297.70 ± 69.44 mg/L, respectively, indicating a tendency to precipitate calcium carbonate (CaCO₃) and scale formation. According to spatial modeling, the highest R² = 0.640 achieved was related to the exponential model for the RIS index and showed a high confidence level for RIS data set and forecasted trends. The results of the spatial analysis demonstrated that the variation of the scaling tendency of water in the four districts of Saveh WDN followed the different sources of water supply. According to the cost estimates, people in the study area spend about 212,652 USD per year on the maintenance of household appliances. To provide better customer service, the water company needs to chemically improve water quality by modifying CH and TA concentrations for stable water and rethink network management strategies.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2184–2193 2184–2193"},"PeriodicalIF":0.0,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142551072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Navigating the Legislative Interventions, Challenges, and Opportunities in Revolutionizing Textile Upcycling/Recycling Processes for a Circular Economy","authors":"Maria Saif,&nbsp;Rubén Blay-Roger,&nbsp;Muhammad Zeeshan,&nbsp;Luis F. Bobadilla,&nbsp;Tomás Ramírez Reina,&nbsp;Muhammad Asif Nawaz* and José Antonio Odriozola*,&nbsp;","doi":"10.1021/acssusresmgt.4c0024210.1021/acssusresmgt.4c00242","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00242https://doi.org/10.1021/acssusresmgt.4c00242","url":null,"abstract":"<p >Embracing a circular economy in the textile industry represents a crucial step toward sustainability, where fashion and textile sectors contribute significantly to CO₂ emissions. However, transitioning from a linear “take-make-waste” model to circularity, poses multifaceted challenges, that highlight the staggering volume of annual textile waste surpassing industry predictions, thus emphasizing the urgent need for comprehensive strategies. Despite advancements in recycling technologies, challenges persist in collecting and sorting textile waste, where fragmentation in waste management and recycling processes hinders effective management of post-consumer waste. Addressing these challenges demands elevated efforts in collection, sorting, and pre-processing, alongside regulatory interventions to drive enhanced waste collection and circular business models. Efforts are underway to promote sustainable textile recycling, with initiatives like the EU’s Sustainable and Circular Textiles Strategy aiming to reduce reliance on virgin resources. However, achieving a circular textile market in the near future requires collaborative action and innovative solutions. Though challenges in scaling and technological limitations still remain, recent breakthroughs in textile-recycling technologies offer promise, signaling a shift toward scalable and sustainable alternatives to virgin fibers, where bio-based chemical processes, and thermochemical recycling processes present transformative opportunities. Where, bold scaling targets, collaborative efforts, and short-term funding support narrated in this perspective article are imperative to accelerate the transition to a circular textile economy, thus delving into the pivotal role of textile recycling, tracing the evolution of recycling technologies, and addressing critical challenges hindering widespread adoption.</p><p >This study emphasizes the efficient textile waste management, innovative recycling technologies, and legislative frameworks to promote environmental sustainability and resource conservation in the textile industry for circular economy.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 11","pages":"2338–2349 2338–2349"},"PeriodicalIF":0.0,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acssusresmgt.4c00242","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142736034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimization of Cosolvent Enhanced Lignocellulosic Fractionation for Isolating Switchgrass Lignin with Distinct Structural Features Using Response Surface Methodology","authors":"James A. Godwin,&nbsp;Hojae Yi,&nbsp;Kendhl Seabright,&nbsp;David P. Harper and Stephen C. Chmely*,&nbsp;","doi":"10.1021/acssusresmgt.4c0030210.1021/acssusresmgt.4c00302","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00302https://doi.org/10.1021/acssusresmgt.4c00302","url":null,"abstract":"<p >Pretreatment and fractionation technologies have been used to separate and isolate biomass polymers for conversion into fuels, chemicals, and other products. A great deal of work has focused on dialing in reaction conditions (e.g., time, temperature, acid concentration, etc.) that are amenable to isolating an uncondensed lignin product that could be converted into high value aromatic platform molecules. Pretreatment severity emerged as a term that combines time, temperature, and acid concentration into a single value that can be used to compare various pretreatment technologies. However, combining the effects of these conditions into a single term, while convenient, confounds the effects that these conditions have on lignin quality, both individually and when they are combined with each other. Moreover, pretreatment and fractionation reactors do not have a severity “knob,” and several different sets of conditions could mathematically achieve the same severity but have different effects on the resulting lignin product slate. In this study, we set out to model the effects of time (10–30 min), temperature (140–180 °C), and acid concentration (0.025–0.1 M H₂SO₄) on lignin yield (up to quantitative), molecular weight (Mw = 700–2000 g/mol), and hydroxyl group content (3.55–6.06 mmol OH/g) using the co-solvent enhanced lignocellulosic fractionation (CELF) process on switchgrass. Our results show that the lignin yield is most sensitive to acid concentration, with an additional 4.96% yield per 10 mM of acid. In addition, molecular weight is sensitive to acid concentration and temperature, with a decrease of 77.9 g/mol per 10 mM of acid and a decrease of 19.3 g/mol per °C. Moreover, total hydroxyl group content decreases at a rate of 89 μmol total OH per g lignin per min at short time (<i>t</i> = 12 min, <i>T</i> = 160 °C) and is increases at a rate of 125 μmol total OH per g lignin per min at long time (<i>t</i> = 28 min, <i>T</i> = 160 °C). Finally, our results demonstrate that the residence time does not have a statistically significant effect on yield or molecular weight within the studied ranges, which could have implications for continuous and flow-through processes, where short residence times could lead to substantial cost savings. Overall, these results demonstrate that practitioners can design a process that maximizes one or more of the industrially relevant lignin properties by exerting careful control of fractionation conditions, which could ultimately lead to greater utilization of lignin for fuels, chemicals, and other products.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2266–2275 2266–2275"},"PeriodicalIF":0.0,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142550984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Upcycling Post-Consumer Recycled Polypropylene Using a “Tailor-Made” Dynamic Cross-Linker with Controlled “Cross-Link Distribution”","authors":"Indranil Dey,&nbsp;Ketaki Samanta*,&nbsp;Siddhesh Sadashiv Rege,&nbsp;Samir Mandal,&nbsp;Sk Safikul Islam,&nbsp;Ria Sen Gupta,&nbsp;Amit Malakar,&nbsp;Ashok Misra and Suryasarathi Bose*,&nbsp;","doi":"10.1021/acssusresmgt.4c0027110.1021/acssusresmgt.4c00271","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00271https://doi.org/10.1021/acssusresmgt.4c00271","url":null,"abstract":"<p >Controlling the distribution of cross-links within a polymeric network is challenging using conventional methods, which often involve random chain scission to achieve a higher gel fraction. Here, we engineer a molecule to facilitate “homo-cross-linking”, enabling precise control over the cross-link distribution and micro phase separation. Establishing a closed-loop circular economy within the plastics or polymer industry is imperative. However, efficiently managing post-consumer recycled (PCR) plastics, including their collection, sorting, and processing, remains a significant challenge. While dynamic cross-linking of virgin polypropylene (PP) has advanced plastic upcycling, its application to PCR PP is limited. This study presents a simple and scalable approach to convert PCR PP into cross-linked PCR PP, enhancing their mechanical strength and rheological properties and enabling circular upcycling. Utilizing a designer dynamic cross-linker, imine installed castor oil (iCO), we establish a dual dynamic covalent adaptable network (CAN) that bridges fragmented maleated-PP chains within the PCR PP matrix besides rendering “homo-cross-linking” in the cross-linked polymer. This local “cross-link distribution” within the “global” matrix (PCR PP) overcomes challenges in upcycling PCR PP, which often undergoes global chain scission during network formation, as observed in other reports. Even at higher cross-linker concentrations (up to 30 wt %), there is minimal impact on percentage crystallinity, promoting amorphous miscibility within the PCR PP and no significant phase separation which has been observed by SAXS and SEM analysis. Cross-linked PCR PP exhibits superior dimensional stability and re-processability, retaining over 90% of their mechanical properties after three rounds of rigorous recycling involving extrusion followed by injection molding techniques. The ability to transform waste PP into a thermoformable material with reprocessing capabilities and favorable thermomechanical properties expands upcycling opportunities, thereby advancing circularity within the industry.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"1 10","pages":"2241–2254 2241–2254"},"PeriodicalIF":0.0,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142551436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}