化学最新文献

{"title":"Architectural modulation of binary metal-organic frameworks upcycled from waste polyethylene terephthalate for high-performance supercapacitors.","authors":"Yunxing Zhao, Denian Li, Pengcheng Cai, Xuanyuan Ni, Guanghao Chen, Dongsheng Xia, Zixu Sun, Haoran Yuan","doi":"10.1016/j.jcis.2025.138666","DOIUrl":"10.1016/j.jcis.2025.138666","url":null,"abstract":"<p><p>The widespread and uncontrolled disposal of polyethylene terephthalate (PET) plastics poses a significant environmental challenge. In this study, we propose a sustainable upcycling strategy to convert waste PET into high-value bimetallic nickel/cobalt-1,4-benzenedicarboxylate metal-organic frameworks (NiCo-BDC MOFs) via a one-pot solvothermal method. By tuning the Ni/Co precursor ratio, the morphology of the resulting NiCo-BDC transitions controllably from stacked nanowires to nanorods, forming a hybrid crystalline-amorphous architecture with a large specific surface area and well-developed hierarchical porosity. Among the synthesized materials, Ni_1.5Co_0.5-BDC exhibits outstanding electrochemical performance, delivering a specific capacitance of 949 F g^-1 at 2 A g^-1 and maintaining 820 F g^-1 at 20 A g^-1. When assembled into an asymmetric supercapacitor with biomass-derived nano‑carbon, the device achieves an energy density of 22 Wh kg^-1 at a power density of 1613 W kg^-1, with 83 % capacitance retention over 5000 cycles at 10 A g^-1. Notably, this upcycling approach demonstrates broad adaptability to various types of PET waste, offering a versatile platform that integrates plastic valorization with the development of high-performance electrode materials for next-generation energy storage systems.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138666"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144833658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fluorination of Fe, Sn, N atoms doped carbon enables the balance of activity and stability for oxygen reduction.","authors":"Yimin Chen, Jiayi Niu, Chaozhong Guo, Chenyang Shu, Jianglin Chen, Jinyan Wu, Rong Jin, Yao Liu, Hao Wang, Yujun Si, Xiaoyu Dong","doi":"10.1016/j.jcis.2025.138619","DOIUrl":"10.1016/j.jcis.2025.138619","url":null,"abstract":"<p><p>The development of highly active and durable carbon-based electrocatalysts for the oxygen reduction reaction (ORR) is of critical importance. In this study, a heteroatom-doped carbon catalyst (FeSn-NFC) was synthesized through the chelation of Fe³⁺ and dopamine hydrochloride, followed by Sn/F co-doping and carbonization. The resulting FeSn-NFC catalyst exhibits an ultrahigh specific surface area of 2387.9 m² g^-1, with micropores accounting for 79 % of its structure. The incorporation of Sn enhances the pyridinic nitrogen content and facilitates the elimination of reactive oxygen species (ROS). Electrochemical evaluations reveal exceptional ORR performance, with a half-wave potential (E_1/2) of 0.857 V and a minimal degradation (ΔE_1/2 = 11 mV) after accelerated aging tests. When integrated into a zinc-air battery, the FeSn-NFC catalyst delivers a peak power density of 217 mW cm^-2 and an energy density of 880 Wh kg^-1 (Zn), maintaining 93.2 % of its initial energy density after ∼115 h of continuous operation. This work offers a novel strategy for fabricating efficient, stable, and cost-effective ORR electrocatalysts, advancing the field of energy conversion technologies.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138619"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144797784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction of S-scheme Sb₂O₃/g-C₃N₄ heterojunctions for photocatalytic CO₂ and Cr(VI) reduction.","authors":"Penghui Yang, Jiaqi Yang, Xinyu Zen, Yuyang Gong, Junbo Zhong","doi":"10.1016/j.jcis.2025.138648","DOIUrl":"10.1016/j.jcis.2025.138648","url":null,"abstract":"<p><p>Photocatalytic CO₂ reduction is a promising strategy to address excessive CO₂ emissions. g-C₃N₄ photocatalyst has attracted widespread attention due to its appropriate bandgap and low toxicity. However, the rapid recombination of electron-hole pairs and the limited number of active sites severely restrict its practical application. In this study, we reported S-scheme Sb₂O₃/g-C₃N₄ heterojunctions. Introducing Sb₂O₃ onto g-C₃N₄ enhances active sites and adsorption capacity, and improves photogenerated carriers separation efficiency via heterojunction formation. Under simulated solar light irradiation, the Sb₂O₃/g-C₃N₄ heterojunctions exhibits superior photocatalytic CO₂ reduction performance relative to the reference Sb₂O₃ and g-C₃N₄. In-situ X-ray photoelectron spectroscopy (In-situ XPS), surface photovoltage spectroscopy (SPS), electron paramagnetic resonance (EPR) and ultraviolet photoelectron spectroscopy (UPS) further reveal the electron transfer mechanism in heterojunctions. In-situ diffuse reflectance Fourier transform infrared (DRIFTS) spectroscopy provides insight into the dynamic behavior of CO₂ into CO and CH₄. This work offers a feasible strategy for developing high-performance g-C₃N₄ photocatalysts to address environmental challenges.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138648"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144811471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Revealing the dynamic arrangement mechanism of SiCw under combined AC-DC electric fields for composite performance enhancement: Modeling, analysis, and experiments.","authors":"Huanmin Yao, Haibao Mu, Maoqun Shen, Wenrui Tian, Wendong Li, Daning Zhang, Haoxiang Zhao, Andrea Cavallini, Guanjun Zhang","doi":"10.1016/j.jcis.2025.138632","DOIUrl":"10.1016/j.jcis.2025.138632","url":null,"abstract":"<p><p>Employing electric fields to induce directional arrangement of one-dimensional nanofillers within specific regions is a powerful strategy for enhancing the performance of composites. However, conventional single-mode electric fields (AC or DC) exhibit inherent \"orientation-distribution\" contradiction. Specifically, AC fields are effective for orientation but lack spatial control, while DC fields promote filler enrichment but fail to optimize orientation state. This study presents an innovative approach by establishing a theoretical framework that integrates both AC and DC electric fields along with a corresponding microscale dynamic model. This approach enables the precise and flexible manipulation of complex filler arrangements, thereby expanding opportunities for advanced material design. The model refines classical dielectrophoresis theory, incorporating interfacial charge and local electric field effects, elucidating the dynamic mechanisms of fillers under combined AC-DC electric fields. Numerical simulations reveal that AC fields primarily control orientation through dielectrophoresis, while DC fields regulate spatial distribution via electrophoresis. The synergistic combination of these two electric fields yields a pronounced \"orientation-enrichment\" effect, enabling the controlled and orderly arrangement of fillers within targeted areas. Moreover, high-aspect-ratio fillers promote chain formation but restrict rotation and migration, and frequencies above 1 kHz suppress alignment and interparticle attraction. Preliminary material design and preparation for enhanced electrical properties of renewable energy transmission device further indicate that this method is effective and flexible for complex application scenarios. This work advances our understanding of complex filler behavior in hybrid electric fields and offers a novel strategy for designing high-performance composites, paving the way for future innovations in material design.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138632"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144820187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The single-particle dynamics of square platelets on an inner spherical surface.","authors":"Yue Shi, Fuzhou Liu, Yanran Li, Jianan Zhu, Mingcheng Yang, Kun Zhao, Yiwu Zong","doi":"10.1016/j.jcis.2025.138513","DOIUrl":"10.1016/j.jcis.2025.138513","url":null,"abstract":"<p><strong>Hypothesis: </strong>The diffusion of colloidal particles on curved surfaces is crucial for understanding mass transport in a wide range of biological and physical systems. To date, most experimental studies on colloid diffusion on curved surfaces have focused on the behavior of isotropic colloids diffusing on soft oil-water interfaces. However, there has been no experimental work reported on how anisotropic colloids diffuse on hard spherical surfaces.</p><p><strong>Experiments: </strong>Herein, we report a first experimental study of the single-particle dynamics of micro-sized Brownian square platelets on solid spherical surfaces with four different curvatures. Utilizing video microscopy and particle-tracking techniques, we investigated both the translational and rotational motion of the square platelets. An analytical model based on Smoluchowski equations was developed to explain the observed diffusion behaviors.</p><p><strong>Findings: </strong>The translational motion of the square platelets was found to be sub-diffusive at time scales comparable to their relaxation time, with the power-law exponent of the mean square displacement (MSD) decreasing as the curvature increased. In contrast, the rotational diffusion of the platelets exhibited minimal variation with changes in curvature. The developed analytical model based on Smoluchowski equations could explain the observations in both translational and rotational diffusion, highlighting the crucial role of surface geometry in determining the diffusion dynamics. This research provides new insights into the diffusion of anisotropic particles on hard spherical curved surfaces, which will pave the way for understanding mass transport problems on curved surfaces in various fields.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138513"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144803098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enrichment of γ-NiOOH in ultrathin metal-organic framework nanosheet arrays by linker engineering for urea-assisted natural seawater electrolysis.","authors":"Nguyen Duy Hai, Nhat Duy Tran, Thuy Tien Nguyen Tran, Jianmin Yu, Lishan Peng, Thi Anh Le, Phuong Dung Ngoc Tran, Nhu Hoa Thi Tran, Thang Bach Phan, Ngoc Quang Tran","doi":"10.1016/j.jcis.2025.138618","DOIUrl":"10.1016/j.jcis.2025.138618","url":null,"abstract":"<p><p>Metal-organic frameworks have been widely considered a potential alternative for noble metal catalysts for green hydrogen from seawater electrolysis, yet their performance is often limited by low activity and poor stability. Here, we propose a linker engineering strategy to optimize the phase composition of ultrathin Ni-MOF nanosheet arrays, aiming to enhance both activity and stability. We found that partial substitution of terephthalic acid (BDC) with electron-withdrawing tetrafluoroterephthalate (TFBDC) ligand alters the electronic structure and significantly promotes the formation of the catalytically active γ-NiOOH phase in Ni-TFBDC-2. This results in a 90 mV reduction in the overpotential for the oxygen evolution reaction at 50 mA cm^-2, surpassing the performance of a state-of-the-art RuO₂ catalyst, and is accompanied by an increased corrosion potential in seawater. Furthermore, the enrichment of the γ-NiOOH phase in Ni-TFBDC-2 effectively suppresses the passivation during urea oxidation reaction (UOR) in a seawater electrolyte, enabling the achievement of an industrially relevant current density of 0.8 A cm^-2. Operando characterizations reveal that Ni-TFBDC-2 undergoes an electrooxidation process to form Ni³⁺ species, which subsequently act as the active catalytic sites for the OER. Additionally, the urea-assisted natural seawater electrolyzer assembled with Ni-TFBDC-2 requires a low voltage of 1.76 V at 400 mA cm^-2 and demonstrates excellent durability over 170 h of continuous operation. This work offers a novel strategy to enrich the catalytically active phase in MOF-based electrocatalysts, aiming to achieve high activity and long-term stability during urea-assisted natural seawater electrolysis. It is noteworthy that different notable aspects, such as the durability of the materials after prolonged reaction, should be more thoroughly considered for practical applications on larger scales.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138618"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144803154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assembling graphene quantum dots on NiFe-LDH provokes ligand effect for electrocatalytic oxygen evolution reaction at industrial-level current density.","authors":"Longcheng Xu, Sheng Qian, Jingying Wei, Tengfei Jiang, Hua Zhang, Jingqi Tian","doi":"10.1016/j.jcis.2025.138659","DOIUrl":"10.1016/j.jcis.2025.138659","url":null,"abstract":"<p><p>Electrocatalytic oxygen evolution reaction (OER) plays a key role in water splitting owing to the kinetically more difficult multi-electron transfer process, but the performance is still limited at industrial scale ampere-level current densities. Herein, we develop a surface modification strategy to assemble amino-functionalized graphene quantum dots on NiFe LDH (NiFe LDH/NGQDs) via the coordination between metallic centers with the amino groups in NGQDs. As a nanosized ligand, surface-assembled NGQDs feature sp² conjugation to induce electron redistribution in the coordinated metallic centers, which optimizes OO coupling as a rate-determining step (RDS) in OER. Moreover, edge-aligned NGQDs electrostatically repel from each other to enlarge the interlayered space, allowing abundant OH^- diffusion to facilitate OER kinetics. Such NiFe LDH/NGQDs exhibit an outstanding OER performance with an overpotential of 336mV to achieve a current density of 1.0 A cm^-2 with long-term stability. This work proposes a surface assembly-based catalyst design concept to achieve industrial-level current density in water splitting.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138659"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144815487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrigendum to \"Redox homeostasis disruptors enhanced cuproptosis effect for synergistic photothermal/chemodynamic therapy\" [J. Colloid. Interface Sci. 678 (2025) 1060-1074].","authors":"Zhen Liu, Junhong Ling, Nan Wang, Xiao-Kun Ouyang","doi":"10.1016/j.jcis.2025.138608","DOIUrl":"10.1016/j.jcis.2025.138608","url":null,"abstract":"","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138608"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144803152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hierarchically aligned reduced graphene oxide/MXene foam enabling Marangoni-driven salt-resistant desalination via bidirectional ion reflux.","authors":"Haimin Yang, Wei Li, Yanni Gao, Guangtao Zhong, Hongqi Wang, Yongqin Han","doi":"10.1016/j.jcis.2025.138617","DOIUrl":"10.1016/j.jcis.2025.138617","url":null,"abstract":"<p><p>Interfacial solar desalination has emerged as a sustainable pathway for treating high-salinity brines, but the non-equilibrium phase transition at the evaporation frontier inevitably induces self-amplifying crystallization to reduce purification efficiency. Herein, a hierarchically aligned reduced graphene oxide/MXene (Mr) foam is fabricated to optimize ion transport channels while reducing optical scattering interfaces that enhance solar energy utilization. The aligned layered structure with interconnected anisotropic microchannels is built under dual temperature gradients with the ice crystal exclusion, which significantly shortens the water transport path and facilitates diffusion and reflux of salt ions. The finite element simulations validate the exceptional photon-to-thermal energy efficiency of Mr foam coupled with inherently low thermal conductivity, synergistically suppressing heat dissipation through thermal localization strategy. The steep thermal gradient originating from the liquid-vapor interface propagates through the subsurface aqueous phase, establishing a localized surface tension differential that activates spontaneous Marangoni convection currents, which drives self-sustaining hydrodynamic patterns to suppress salt accumulation. Consequently, the Mr foam achieves a water evaporation rate of 2.04 kg m^-2 h^-1 under 1 sun irradiation. Importantly, it maintains a stable evaporation rate of 1.76 kg m^-2 h^-1 over 100 h in 25 wt% NaCl solution, which demonstrates a great potential for efficient and long-term solar desalination.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138617"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144803156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ni₃S₂/NiFe-MOF heterostructure for efficient water/seawater oxidation.","authors":"Zixiong Wang, Xiaofei Jing, Qi Zhang, He Zhu, Shiping Zhu","doi":"10.1016/j.jcis.2025.138601","DOIUrl":"10.1016/j.jcis.2025.138601","url":null,"abstract":"<p><p>The development of efficient and corrosion-resistant electrocatalysts is critical for advancing seawater electrolysis as a sustainable hydrogen production strategy. Here, we report a partial sulphuration method to construct a Ni₃S₂/NiFe-btz heterostructure (btz: 1,4-bis(4H-1,2,4-triazol-4-yl)benzene), optimized by tuning the hydrothermal duration. This unique structure affords sufficient metal-organic framework (MOF)/sulfide interfaces, providing numerous active sites, optimized electronic configurations, and rapid charge transfer. Theoretical calculations confirm that the heterostructure lowers the energy barrier of the rate-determining step, improving oxygenated species adsorption and intrinsic activity. Moreover, water oxidation induces a protective sulfate layer, effectively mitigating chloride corrosion and ensuring long-term stability in natural seawater electrolysis. As a result, the optimized Ni₃S₂/NiFe-btz requires an overpotential of 359 mV to reach 500 mA cm^-2 in alkaline natural seawater, which is much lower than that of 447 mV for single-phase NiFe-btz. In addition, it demonstrates remarkable durability, maintaining stable operation for over 200 h at 500 mA cm^-2 with minimal overpotential increase. This work offers insight into designing high-performance oxygen evolution reaction electrocatalysts for industrial seawater electrolysis.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 Pt 3","pages":"138601"},"PeriodicalIF":9.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144797786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}