The Royal Society of Chemistry最新文献_第3页

CO2 responsive materials in oilfield engineering: synthesis, mechanisms, and applications 油田工程中的CO2响应材料：合成、机理及应用

IF 3.9 3区化学

RSC Advances Pub Date : 2025-06-30 DOI: 10.1039/D5RA03359D

Qiang Li, Xuanze Zhu, Jiuyi Chen and Xionghu Zhao

{"title":"CO2 responsive materials in oilfield engineering: synthesis, mechanisms, and applications","authors":"Qiang Li, Xuanze Zhu, Jiuyi Chen and Xionghu Zhao","doi":"10.1039/D5RA03359D","DOIUrl":"https://doi.org/10.1039/D5RA03359D","url":null,"abstract":"The increasing demand for oil and gas resources, coupled with growing concerns over the environmental impact of conventional chemical agents, has heightened the need for sustainable alternatives. CO2 responsive materials, which utilize CO2 as an environmentally friendly stimulus, have emerged as promising solutions for improving chemical performance while minimizing environmental impact in petroleum engineering. This review systematically examines the functional groups, response mechanisms, and synthesis strategies of CO2 responsive polymers in oil and gas operations, with particular emphasis on their applications in drilling and reservoir engineering. The review explores the relationship between the reversibility of CO2 responsive materials and their environmental adaptability, focusing on applications in cementing, oil–water separation, gas channeling plugging, viscosity modification, and enhanced oil recovery. By evaluating response mechanisms and environmental adaptability, this work offers valuable insights into the optimization of CO2 responsive materials for practical use in petroleum operations. Additionally, challenges such as response sensitivity and long-term stability are critically explored, and potential solutions and strategies are proposed. The findings aim to support the low-carbon transformation of the oil industry and promote the adoption of sustainable practices in hydrocarbon extraction.","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 28","pages":" 22228-22249"},"PeriodicalIF":3.9,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d5ra03359d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144519531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly selective catalytic pathway utilizing metal oxide nanoparticles to produce formic acid through methanol oxidation 利用金属氧化物纳米颗粒通过甲醇氧化生成甲酸的高选择性催化途径

IF 3.9 3区化学

RSC Advances Pub Date : 2025-06-30 DOI: 10.1039/D4RA06524G

Mina Arshad, Iram Mahmood, Ali Sarosh, Asim Umer, Muhammad Athar and Mahboob Ahmed Aadil

{"title":"Highly selective catalytic pathway utilizing metal oxide nanoparticles to produce formic acid through methanol oxidation","authors":"Mina Arshad, Iram Mahmood, Ali Sarosh, Asim Umer, Muhammad Athar and Mahboob Ahmed Aadil","doi":"10.1039/D4RA06524G","DOIUrl":"https://doi.org/10.1039/D4RA06524G","url":null,"abstract":"An emerging alternative energy source is formic acid, which has low toxicity and high hydrogen-carrying capacity. Metal-containing nanoparticles are very attractive for many applications, allowing large-scale and environmentally friendly production. This study proposes liquid-state synthesis for clean and facile formic acid production via methanol oxidation over metal oxide nanoparticles. MoO3, Fe2O3, TiO2 and V2O5 nanocatalysts were prepared through sol–gel, solvothermal, reflux condensation and ball milling techniques, respectively, and their efficacy in formic acid production via methanol oxidation was assessed. The synthesized nanoparticles were further characterized through scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. The performance of laboratory-prepared nanoscale metal oxide catalysts for formic acid production was evaluated through batch reactions under ambient temperature and pressure conditions to enhance energy efficiency and maximize conversion. Formic acid was quantitatively analyzed using high-performance liquid chromatography (HPLC). Results revealed that the nanocatalysts considerably promoted the generation of formic acid, especially MoO3, which provided a 91% product acid yield, which was the greatest among the other nanocatalysts under the employed reaction conditions.","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 27","pages":" 22076-22085"},"PeriodicalIF":3.9,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d4ra06524g?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and anticancer activity of Pt(iv) prodrugs containing 3-bromopyruvic acid as an axial ligand† 以3-溴丙酮酸为轴位配体的Pt（iv）前药的合成及抗癌活性研究

IF 3.9 3区化学

RSC Advances Pub Date : 2025-06-30 DOI: 10.1039/D5RA02064F

Peng Zhou, Qingfeng Xiong, Ling Zhang, Jing Jiang, Yan Song, Weiping Liu, Limei Zhang, Anli Gao and Chen Qing

{"title":"Synthesis and anticancer activity of Pt(iv) prodrugs containing 3-bromopyruvic acid as an axial ligand†","authors":"Peng Zhou, Qingfeng Xiong, Ling Zhang, Jing Jiang, Yan Song, Weiping Liu, Limei Zhang, Anli Gao and Chen Qing","doi":"10.1039/D5RA02064F","DOIUrl":"https://doi.org/10.1039/D5RA02064F","url":null,"abstract":"A Pt(IV) prodrug of oxaliplatin incorporating the glycolysis inhibitor 3-bromopyruvic acid, BrPt3, was designed and investigated. The prodrug is reduced in the presence of ascorbic acid, releasing its active Pt(II) species and axial ligand. In cytotoxicity studies, BrPt3 exhibited stronger anticancer activity than oxaliplatin against all tested cancer cell lines, particularly in oxaliplatin-resistant A549/OXP cells. By effectively inhibiting glycolysis, BrPt3 induced greater DNA damage in tumor cells. It arrested the cell cycle at the G0/G1 phase, leading to increased apoptosis and significantly reduced cell invasiveness. BrPt3 resulted in higher platinum accumulation in the genomic DNA of MKN28, HCT116, and HT29 cells, though no significant difference in DNA-platinum adduct formation was observed in A549/OXP cells. Compared to oxaliplatin, BrPt3 more effectively impaired the glycolytic capacity of tumor cells, as evidenced by significantly reduced levels of pyruvate, lactate, ATP, and HK2 enzyme expression. In vivo studies using an HCT116 xenograft tumor mouse model demonstrated that BrPt3 achieved a higher tumor inhibition rate and lower toxicity than oxaliplatin. Although gavage administration resulted in a lower tumor inhibition rate than intraperitoneal administration, it still exhibited substantial antitumor activity. Overall, this Pt(IV) prodrug holds potential for development as an oral anticancer agent through its dual mechanisms of inducing DNA damage and inhibiting glycolysis.","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 27","pages":" 22063-22075"},"PeriodicalIF":3.9,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d5ra02064f?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Applications of flexible materials in health management assisted by machine learning 机器学习辅助下柔性材料在健康管理中的应用

IF 3.9 3区化学

RSC Advances Pub Date : 2025-06-30 DOI: 10.1039/D5RA02594J

Song Zhou, Jiayu Li, Fanlun Meng, Mengqin Chen, Jing Cao and Xusheng Li

{"title":"Applications of flexible materials in health management assisted by machine learning","authors":"Song Zhou, Jiayu Li, Fanlun Meng, Mengqin Chen, Jing Cao and Xusheng Li","doi":"10.1039/D5RA02594J","DOIUrl":"https://doi.org/10.1039/D5RA02594J","url":null,"abstract":"In recent years, the demand for improved health management has become increasingly higher; however, the existing medical resources have made it difficult to meet this demand. The field of health management is in urgent need for self-help monitoring equipment, intelligent identification technology and personalized medical services. This article reviews the application of flexible materials in health management, particularly the application of flexible wearable sensing devices combined with machine learning technology in various medical scenarios, and classifies them into several types of applications such as health monitoring and prevention, disease diagnosis and treatment, rehabilitation treatment and assistance. Flexible materials can be used to fabricate or integrate various types of high-sensitivity sensors with the characteristics of high flexibility and self-adhesion, resulting in a wealth of health monitoring equipment. These devices can self-monitor various physiological indicators in various parts of the human body. The integration of machine learning (ML) makes it possible to analyze and identify subtle, massive, multi-channel and multi-modal sensor data, accelerating the intelligent process of health management and personalized medicine. This paper not only elaborates on various flexible materials and ML algorithms commonly used in the field of health management, but also focuses on discussing the application of ML-assisted flexible materials in different stages of health management, and puts forward prospects for the future development direction, providing reference and inspiration for major changes in the field of health management.","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 28","pages":" 22386-22410"},"PeriodicalIF":3.9,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d5ra02594j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144519595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spin-scaled double hybrids with long-range correction solve the TD-DFT overestimation problem in BODIPY dyes: benchmarking and experimental validation† 具有远程校正的自旋缩放双杂化解决了BODIPY染料中TD-DFT过高估计问题：基准测试和实验验证

IF 3.9 3区化学

RSC Advances Pub Date : 2025-06-30 DOI: 10.1039/D5RA01408E

Shebual Sebastian, Vaughan Riley, Binuki Wanniarachchi, Chris Ritchie and Lars Goerigk

{"title":"Spin-scaled double hybrids with long-range correction solve the TD-DFT overestimation problem in BODIPY dyes: benchmarking and experimental validation†","authors":"Shebual Sebastian, Vaughan Riley, Binuki Wanniarachchi, Chris Ritchie and Lars Goerigk","doi":"10.1039/D5RA01408E","DOIUrl":"https://doi.org/10.1039/D5RA01408E","url":null,"abstract":"It has been established in the literature that time-dependent density functional theory (TD-DFT) methods systematically overestimate the electronic excitation energies in boron-dipyrromethene (BODIPY) dyes. Herein, we present the new SBYD31 benchmark set for BODIPY absorption energies and assess 28 different TD-DFT methods, most of which have not been tested on BODIPY dyes before. We show how functionals belonging to the class of recently developed spin-scaled double hybrids with long-range correction (J. Chem. Theory Comput., 2021, 17, 5165) overcome the overestimation problem and provide more robust results that have met the chemical accuracy threshold of 0.1 eV. To our knowledge, these are the most accurate absorption energies for BODIPY dyes reported for TD-DFT methods. In passing, we also point out how previous recommendations of “DSD” double hybrids, incl. one published in this journal (RSC. Adv., 2022, 12, 1704; Comput. Theor. Chem., 2022, 1207, 113531), were based on incorrect interpretations of the results. Our top-three recommended methods are SOS-ωB2GP-PLYP, SCS-ωB2GP-PLYP and SOS-ωB88PP86 and we verify our recommendations by making predictions, which we confirm with experimental measurements of newly synthesised BODIPY dyes. Our results add to existing evidence how time-dependent double hybrids with spin-component scaling and long-range correction solve notoriously hard cases for conventional TD-DFT methods and we are confident that our recommendations will assist in future developments of BODIPY dyes.","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 28","pages":" 22419-22431"},"PeriodicalIF":3.9,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d5ra01408e?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144519597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Asymmetric total syntheses of passifetilactones A, C, E and 4-epi-passifetilactone B. 钝化内酯A、C、E和4-外钝化内酯B的不对称全合成。

IF 2.9 3区化学

Organic & Biomolecular Chemistry Pub Date : 2025-06-27 DOI: 10.1039/d5ob00756a

Sagar B Khandekar, Naga Raju Barnala, Rodney A Fernandes

引用次数: 0

Combining synthetic biology with synthetic electrochemistry to expand the chemical space of the indolocarbazole family. 将合成生物学与合成电化学相结合，拓展吲哚咔唑家族的化学空间。

IF 2.9 3区化学

Organic & Biomolecular Chemistry Pub Date : 2025-06-27 DOI: 10.1039/d5ob00766f

Le-Le Zhu, De-Gao Wang, Luo Niu, Yue-Zhong Li, Hai-Yan Sui, Changsheng Wu

{"title":"Combining synthetic biology with synthetic electrochemistry to expand the chemical space of the indolocarbazole family.","authors":"Le-Le Zhu, De-Gao Wang, Luo Niu, Yue-Zhong Li, Hai-Yan Sui, Changsheng Wu","doi":"10.1039/d5ob00766f","DOIUrl":"https://doi.org/10.1039/d5ob00766f","url":null,"abstract":"Indolocarbazoles, a class of highly privileged scaffolds, hold immense significance in medicinal chemistry due to their diverse biological activities. In this study, we have demonstrated the environmentally benign synthesis of indolocarbazoles by integrating the strengths of synthetic biology and synthetic electrochemistry. Through pathway reconstruction in Escherichia coli, a sustained supply of the prototype indolocarbazole k252c (1) was achieved, which could be efficiently N-rhamnosylated to produce k252d (2) via modular coculture engineering. An appreciable yield (∼20 mg L-1) was obtained through in vitro enzymatic glycosylation of compounds 1 and 2, yielding derivatives 3-8 with diverse glycosyl linkages. Additionally, under exceptionally mild conditions, the electrochemical conversion of compounds 1 and 2 enabled the synthesis of derivatives 9-17 with tunable functionalization. Notably, the N-N homodimerization observed in compounds 9 and 10 is unprecedented within the structural family of indolocarbazoles. The antiproliferative activity of compounds 1-17 was assessed against twenty different human tumor cell lines. Overall, the combination of multistep biocascades with electrocatalysis represents a novel green synthetic approach to expand the repertoire of xenobiotic compounds available to chemists.","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144504241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective photocatalytic reduction of nitrobenzene to anilines, azoxybenzene, and azobenzene: a solvent-dependent and light-induced process mediated by a CdS/NH₂-MIL-125 nanocomposite. 硝基苯选择性光催化还原为苯胺、偶氮氧苯和偶氮苯：CdS/NH2-MIL-125纳米复合材料介导的溶剂依赖和光诱导过程

IF 2.9 3区化学

Organic & Biomolecular Chemistry Pub Date : 2025-06-27 DOI: 10.1039/d5ob00705d

Mina Tavakolian, Saeede Saki, Mona Hosseini-Sarvari

{"title":"Selective photocatalytic reduction of nitrobenzene to anilines, azoxybenzene, and azobenzene: a solvent-dependent and light-induced process mediated by a CdS/NH2-MIL-125 nanocomposite.","authors":"Mina Tavakolian, Saeede Saki, Mona Hosseini-Sarvari","doi":"10.1039/d5ob00705d","DOIUrl":"https://doi.org/10.1039/d5ob00705d","url":null,"abstract":"While photocatalytic selective transformations have advanced significantly, selective reduction reactions remain less developed. This study investigated the photocatalytic reduction of nitrobenzene using a previously characterized CdS/MOF photocatalyst, focusing on the selective formation of aniline, azoxybenzene, and azobenzene. It was found that various parameters, mostly the solvent and base, strongly affect reaction selectivity. Employing hydrazine as a hydrogen source, we achieved high yields and selectivity for aniline in methanol, azoxybenzene in tetrahydrofuran, and azobenzene in ethanol. Notably, the presence of K2CO3 proved critical for obtaining high selectivity towards azobenzene. We successfully extended the reaction scope to produce various anilines and azobenzene derivatives from their corresponding aromatic nitro compounds, obtaining the desired products in moderate to good yields. The CdS/MOF photocatalyst exhibited good reusability, maintaining a high yield and selectivity over several cycles with only a slight decrease in performance.","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144504242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Freedericksz transitions in the nematic and smectic Z_A phases of DIO. DIO向列相和近晶ZA相的fredericksz跃迁。

IF 2.9 3区化学

Soft Matter Pub Date : 2025-06-27 DOI: 10.1039/d5sm00238a

J T Gleeson, S N Sprunt, A Jákli, P Guragain, R J Twieg

{"title":"Freedericksz transitions in the nematic and smectic ZA phases of DIO.","authors":"J T Gleeson, S N Sprunt, A Jákli, P Guragain, R J Twieg","doi":"10.1039/d5sm00238a","DOIUrl":"https://doi.org/10.1039/d5sm00238a","url":null,"abstract":"The remarkable material DIO presents fascinating behaviors. It has been extensively studied as one of the first materials exhibiting a ferroelectric nematic phase. However, at higher temperatures it exhibits what has been termed the smectic ZA: identified as an orientationally ordered, antiferroelectric phase with a density modulation in direction perpendicular to the optic axis. At even higher temperatures, this transitions to an apparently normal nematic phase. We have studied the splay-bend Freedericksz transition in the nematic and SmZA phases of the material DIO. Both the magnetic and electric field transitions were utilized. We observed the transitions by measuring effective birefringence and capacitance as well as with polarizing light microscopy. In both the nematic and the SmZA states the field induced transitions resemble (in numerous aspects) the classical Freedericksz transition. These enable determinations of several fundamental material parameters and also reveal intriguing aspects of the SmZA phase, including the surprising behavior of the elastic constants and the dielectric anisotropy. Detailed comparison with Frank elastic theory of the Freedericksz transition shows that the N phase behaves largely as expected, but the transition in the SmZA phase differs significantly. Two specific examples of this are the onset of striations in the Freedericksz distorted state, and the presence of optical biaxiality. The former may be related to the periodic Freedericksz transition as it coincides with a large increase in the splay elastic constant. The latter has been predicted for the SmZA phase, but not previously observed.","PeriodicalId":103,"journal":{"name":"Soft Matter","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144504245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optimization of the mechanical performance of TDI-based polyurethanes via orthogonal design and response surface methodology 正交设计和响应面法优化tdi基聚氨酯的力学性能

IF 3.9 3区化学

RSC Advances Pub Date : 2025-06-27 DOI: 10.1039/D5RA02295A

Tianjiao Hong, Yan Kang, Pengfei Tian and Fuzhen Xuan

{"title":"Optimization of the mechanical performance of TDI-based polyurethanes via orthogonal design and response surface methodology","authors":"Tianjiao Hong, Yan Kang, Pengfei Tian and Fuzhen Xuan","doi":"10.1039/D5RA02295A","DOIUrl":"https://doi.org/10.1039/D5RA02295A","url":null,"abstract":"The mechanical properties of polyurethane elastomers are primarily determined by their formulations and synthetic processes. Here, we present an in-depth investigation into the optimization of the mechanical performance of a toluene diisocyanate (TDI)-based polyurethane using orthogonal design and response surface methodology (RSM). The utmost mechanical performance with a tensile strength of 14.67 MPa and an elongation at break of 1160% was achieved. The model reliability in predicting the mechanical strength was validated with a reasonable accuracy error of 2.2%. The correlation between mechanical properties of the TDI-based polyurethane and factors including NCO/OH ratio (R-value), chain extension coefficient, crosslinking coefficient, and curing temperature was elucidated through a combination of Fourier transform infrared (FTIR) and Raman spectroscopy with RSM. A net positive interactive effect among the R-value, chain extension coefficient, and curing temperature was observed. Additionally, a volcano-shaped relationship was identified between tensile strength and the crosslinking coefficient, while a similar non-monotonic trend was found between elongation at break and curing temperature. Through multiple characterization experiments including equilibrium swelling measurements, differential scanning calorimetry (DSC) and scanning electron microscopy (SEM), the relationship between elastomer crosslink density and mechanical properties was systematically examined. This work provides valuable insights for the rational design of high-performance polymer materials.","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 27","pages":" 22023-22034"},"PeriodicalIF":3.9,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d5ra02295a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0