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Rotational-state-selected Carbon Astrochemistry. 旋转状态选择碳天体化学。
IF 1.2 4区 化学
Chimia Pub Date : 2024-02-28 DOI: 10.2533/chimia.2024.40
Jutta Toscano
{"title":"Rotational-state-selected Carbon Astrochemistry.","authors":"Jutta Toscano","doi":"10.2533/chimia.2024.40","DOIUrl":"https://doi.org/10.2533/chimia.2024.40","url":null,"abstract":"<p><p>The addition of individual quanta of rotational excitation to a molecule has been shown to markedly change its reactivity by significantly modifying the intermolecular interactions. So far, it has only been possible to observe these rotational effects in a very limited number of systems due to lack of rotational selectivity in chemical reaction experiments. The recent development of rotationally controlled molecular beams now makes such investigations possible for a wide range of systems. This is particularly crucial in order to understand the chemistry occurring in the interstellar medium, such as exploring the formation of carbon-based astrochemical molecules and the emergence of molecular complexity in interstellar space from the reaction of small atomic and molecular fragments.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"78 1-2","pages":"40-44"},"PeriodicalIF":1.2,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140012286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simplifying Nitration Chemistry with Bench-stable Organic Nitrating Reagents. 使用台式稳定有机硝化试剂简化硝化化学。
IF 1.2 4区 化学
Chimia Pub Date : 2024-02-28 DOI: 10.2533/chimia.2024.32
Subrata Patra, Vasiliki Valsamidou, Dmitry Katayev
{"title":"Simplifying Nitration Chemistry with Bench-stable Organic Nitrating Reagents.","authors":"Subrata Patra, Vasiliki Valsamidou, Dmitry Katayev","doi":"10.2533/chimia.2024.32","DOIUrl":"https://doi.org/10.2533/chimia.2024.32","url":null,"abstract":"<p><p>Nitro compounds play a crucial role in academia and industries, serving as building blocks for the synthesis of drugs, agrochemicals, and materials. Nitration, a fundamental process in organic synthesis, has undergone significant evolution since the 19th century. While electrophilic nitration dominates historically, recent decades have seen a focus on new reagents and their reactivity modes for achieving mild and robust synthesis of nitro compounds. Our group has a longstanding interest in developing cost-effective, readily available, recyclable nitrating reagents derived from organic scaffolds. These reagents serve as a controllable source of nitryl radical and nitronium ion species, enabling mild and practical nitration of hydrocarbons with exceptional functional group tolerance. This account details the development of nitrating reagents and their diverse applications in catalytic nitration across various classes of organic molecules.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"78 1-2","pages":"32-39"},"PeriodicalIF":1.2,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140012287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ/In vivo Optical Microspectroscopy to Probe the Emergence of Morphology. 利用原位/活体光学显微光谱探究形态的形成。
IF 1.2 4区 化学
Chimia Pub Date : 2024-02-28 DOI: 10.2533/chimia.2024.50
Natercia Barbosa, Oscar Urquidi, Johanna Brazard, Takuji B M Adachi
{"title":"In situ/In vivo Optical Microspectroscopy to Probe the Emergence of Morphology.","authors":"Natercia Barbosa, Oscar Urquidi, Johanna Brazard, Takuji B M Adachi","doi":"10.2533/chimia.2024.50","DOIUrl":"10.2533/chimia.2024.50","url":null,"abstract":"<p><p>Morphology governs function. Yet, understanding and controlling the emergence of morphology at the molecular level remains challenging. The difficulty in studying the early stage of morphology formation is due to its stochastic nature both spatially and temporally occurring at the nanoscale. This nature has been particularly detrimental for the application of optical spectroscopy. To overcome this problem, we have been developing new in situ/in vivo optical spectroscopy tools, which are label-free and non-invasive. This account highlights several examples of how optical spectroscopy can become an important tool in studying the birth of morphology.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"78 1-2","pages":"50-58"},"PeriodicalIF":1.2,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140012283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable Materials: Production Methods and End-of-life Strategies. 可持续材料:生产方法和报废策略。
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.848
Arpa Ghosh, Remy Buser, Florent Héroguel, Jeremy Luterbacher
{"title":"Sustainable Materials: Production Methods and End-of-life Strategies.","authors":"Arpa Ghosh, Remy Buser, Florent Héroguel, Jeremy Luterbacher","doi":"10.2533/chimia.2023.848","DOIUrl":"https://doi.org/10.2533/chimia.2023.848","url":null,"abstract":"<p><p>All three natural polymers of biomass and the monomer platforms derived from them present multiple avenues to develop products from specialty to bulk markets, which could serve as entry points into the industry for bio based sustainable materials. However, several roadblocks still exist in the pathway of technology development of these materials due to challenges related to cost-competitiveness, scalability, performance and sustainability. This review outlines these major technical challenges as four key checkpoints (cost-competitive, scalability, sustainability, performance) to be addressed for successful market entry of a new sustainable material.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"77 12","pages":"848-857"},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138828400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluorescently Labelled Tau Protein 荧光标记的 Tau 蛋白
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.
Saurabh Awasthi, Liviana Mummolo, Yuanjie Li, Louise Bryan, P. Nirmalraj, Sandor Balog, Jerry Yang, Michael Mayer
{"title":"Fluorescently Labelled Tau Protein","authors":"Saurabh Awasthi, Liviana Mummolo, Yuanjie Li, Louise Bryan, P. Nirmalraj, Sandor Balog, Jerry Yang, Michael Mayer","doi":"10.2533/chimia.2023.","DOIUrl":"https://doi.org/10.2533/chimia.2023.","url":null,"abstract":"","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"27 6","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138955807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SCNAT Ethics Series on Recognizing and Overcoming Bias 关于认识和克服偏见的 SCNAT 道德系列课程
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.883
Sandra Hofmann
{"title":"SCNAT Ethics Series on Recognizing and Overcoming Bias","authors":"Sandra Hofmann","doi":"10.2533/chimia.2023.883","DOIUrl":"https://doi.org/10.2533/chimia.2023.883","url":null,"abstract":"The Ethics Series is a workshop tour on the wide-ranging topic of ethics in chemistry organized on a regular basis by the Platform Chemistry of the Swiss Academy of Sciences (SCNAT). The Ethics Series addresses all researchers in chemistry and has the aim to sensitize the audience for timely topics on issues such as the previously addressed topics of scientific integrity, social responsibility or overselling in publications. Internationally renowned speakers are invited to give a series of lectures at Swiss universities and federal institutes of technology, jointly with local speakers.\u0000The format is similar to the \"world café\" style: short introductory lectures, break-out sessions to discuss specific topics, reports to the plenary followed by a discussion with audience participation. This year’s topic was on Recognizing and Overcoming Bias and took place from June 7 – June 9, 2023. Prof. Lee Penn and local panellists discussed a variety of questions arising around bias.","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"3 17","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138956497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Symposium of Theoretical Chemistry in Zurich 苏黎世理论化学研讨会
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.887
Jeremy O. Richardson, Sandra Luber
{"title":"Symposium of Theoretical Chemistry in Zurich","authors":"Jeremy O. Richardson, Sandra Luber","doi":"10.2533/chimia.2023.887","DOIUrl":"https://doi.org/10.2533/chimia.2023.887","url":null,"abstract":"In September 2023, the Symposium of Theoretical Chemistry (STC) was held at ETH Zurich. This was the 59th installment of the conference series held annually in Germany, Austria or Switzerland, although it had not previously been held in Zurich since 1966. This year’s event was organized by Sandra Luber (Univ. Zurich) and Jeremy Richardson (ETH Zurich) with a focus on quantum and classical dynamics in chemistry.","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"80 10","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138956648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Significance of Plastic Recycling with the Focus on Polyesters - Creating a Circular Economy. 以聚酯为重点的塑料回收利用的意义--创建循环经济。
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.836
F Pelin Uran, Hale Bila, Shaista Shah, Mohamed Hlaiem, Bardiya Valizadeh, Samantha Anderson, Christopher P Ireland
{"title":"Significance of Plastic Recycling with the Focus on Polyesters - Creating a Circular Economy.","authors":"F Pelin Uran, Hale Bila, Shaista Shah, Mohamed Hlaiem, Bardiya Valizadeh, Samantha Anderson, Christopher P Ireland","doi":"10.2533/chimia.2023.836","DOIUrl":"https://doi.org/10.2533/chimia.2023.836","url":null,"abstract":"<p><p>Plastics materials are essential in every part of our lives, resulting in their increasing production and consumption. Consequently, recycling of plastics has been of great importance in the last decades. Among all types of plastics, polyesters have become very appealing for numerous kinds of applications, making their recycling crucial. Several techniques have been developed for the recycling of plastics with the aim of eliminating the waste accumulated, as well as to create a circular economy.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"77 12","pages":"836-841"},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138828398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conference on Artificial Photosynthesis and Green Catalysis 人工光合作用和绿色催化会议
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.881
Jing Gao, Lukas Pfeifer, Paula Dias, Adélio Mendes, Michael Graetzel
{"title":"Conference on Artificial Photosynthesis and Green Catalysis","authors":"Jing Gao, Lukas Pfeifer, Paula Dias, Adélio Mendes, Michael Graetzel","doi":"10.2533/chimia.2023.881","DOIUrl":"https://doi.org/10.2533/chimia.2023.881","url":null,"abstract":"","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"54 15","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138957152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biorefining Twin Transition: Digitalisation for Bio-based Chemicals/Materials - Discovery, Design and Optimisation. 生物精炼双过渡:生物基化学品/材料的数字化--发现、设计和优化。
IF 1.2 4区 化学
Chimia Pub Date : 2023-12-20 DOI: 10.2533/chimia.2023.816
Matej Žula, Miha Grilc, Andrii Kostyniuk, Giorgio Tofani, Edita Jasiukaitytė-Grojzdek, Tina Ročnik Kozmelj, Ramesh Kumar Chowdari, Žan Lavrič, Janvit Teržan, Brigita Hočevar, Ana Jakob, Emilija Rakić, Brett Pomeroy, Miša Mojca Cajnko, Filipa A Vicente, Dana Marinič, Ana Oberlintner, Uroš Novak, Davide Benedetto Tiz, Matej Huš, Blaž Likozar
{"title":"Biorefining Twin Transition: Digitalisation for Bio-based Chemicals/Materials - Discovery, Design and Optimisation.","authors":"Matej Žula, Miha Grilc, Andrii Kostyniuk, Giorgio Tofani, Edita Jasiukaitytė-Grojzdek, Tina Ročnik Kozmelj, Ramesh Kumar Chowdari, Žan Lavrič, Janvit Teržan, Brigita Hočevar, Ana Jakob, Emilija Rakić, Brett Pomeroy, Miša Mojca Cajnko, Filipa A Vicente, Dana Marinič, Ana Oberlintner, Uroš Novak, Davide Benedetto Tiz, Matej Huš, Blaž Likozar","doi":"10.2533/chimia.2023.816","DOIUrl":"https://doi.org/10.2533/chimia.2023.816","url":null,"abstract":"<p><p>The article discusses the production of platform chemicals from various biological sources, including glycerol, lignin, cellulose, bio-oils, and sea products. It presents the results of catalytic and downstream processes involved in the conversion of these biomass-derived feedstocks. The experimental approaches are complemented by numerical descriptions, ranging from density functional theory (DFT) calculations to kinetic modellingof the experimental data. This multi-scale modelling approach helps to understand the underlying mechanisms and optimize the production of platform chemicals from renewable resources.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"77 12","pages":"816-826"},"PeriodicalIF":1.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138828394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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