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Insight into the Coupling of HgS and CuO with Metal-Organic Frameworks Support in Electrocatalytic Oxygen Evolution Reaction.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-05 DOI: 10.1002/cphc.202400956
Mitali Hupele, Ritu Raj, Shikha Rai, Tapasi Sen, Krishna Kanta Haldar
{"title":"Insight into the Coupling of HgS and CuO with Metal-Organic Frameworks Support in Electrocatalytic Oxygen Evolution Reaction.","authors":"Mitali Hupele, Ritu Raj, Shikha Rai, Tapasi Sen, Krishna Kanta Haldar","doi":"10.1002/cphc.202400956","DOIUrl":"10.1002/cphc.202400956","url":null,"abstract":"<p><p>This study investigates the coupling of mercury sulfide (HgS) and copper oxide (CuO) nanoparticles with metal-organic frameworks (MOFs) as a support material for enhancing the electrocatalytic oxygen evolution reaction (OER). The integration of HgS and CuO into the MOF framework aims to leverage the unique electronic and structural properties of both the nanoparticles and the MOFs to improve catalytic performance. Metal-organic frameworks (MOFs), particularly ZIF-67, are investigated for their potential to catalyze water-splitting reactions due to their high porosity and large specific surface areas. The strategic incorporation of HgS and CuO into ZIF-67 significantly enhances its electrocatalytic properties, resulting in remarkable performance metrics: a low overpotential of 246 mV at 10 mA/cm<sup>2</sup>, a Tafel slope of 123 mV/dec, an expanded electrochemical active surface area (ECSA) of 23.56 cm<sup>2</sup>, and a reduced charge transfer resistance of 34.86 Ω. This integration enhances porosity and increases active surface area, which is crucial for improved catalytic performance. This investigation introduces an innovative methodology for fabricating highly efficient electrocatalysts, positioning HgS/CuO/ZIF-67 as a promising candidate for oxygen evolution reactions in alkaline media. The findings highlight the potential of this novel nanocomposite in future clean energy applications, particularly in the realm of water-splitting technologies.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400956"},"PeriodicalIF":2.3,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143188275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanistic Insights into the Photocatalytic Indigo Carmine Dye Decolorization by Co3O4/TiO2.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-04 DOI: 10.1002/cphc.202400688
Mirjam E de Graaf, Nejc Godec, Bram T Kappé, Roos L Grote, Jitte Flapper, Eline M Hutter, Bert M Weckhuysen
{"title":"Mechanistic Insights into the Photocatalytic Indigo Carmine Dye Decolorization by Co<sub>3</sub>O<sub>4</sub>/TiO<sub>2</sub>.","authors":"Mirjam E de Graaf, Nejc Godec, Bram T Kappé, Roos L Grote, Jitte Flapper, Eline M Hutter, Bert M Weckhuysen","doi":"10.1002/cphc.202400688","DOIUrl":"10.1002/cphc.202400688","url":null,"abstract":"<p><p>TiO<sub>2</sub> is widely studied as an efficient UV-light photocatalyst for organic compound degradation through reactive oxygen species (ROS) generation. TiO<sub>2</sub> can be modified to show photocatalytic activity under visible light illumination by combining with visible-light absorbing metal oxides. Here, we investigated Co<sub>3</sub>O<sub>4</sub>/TiO<sub>2</sub> composite materials as visible-light absorbing photocatalysts, with various weight loadings of Co<sub>3</sub>O<sub>4</sub>, for the decolorization of wastewater pollutant indigo carmine. Under green LED light, 1.4 wt% Co<sub>3</sub>O<sub>4</sub>/TiO<sub>2</sub> showed the highest decolorization rate compared to other weight loadings and bare TiO<sub>2</sub>. While UV-Vis spectroscopy indicated that Co<sub>3</sub>O<sub>4</sub>/TiO<sub>2</sub> composite materials and bare TiO<sub>2</sub> cause similar dye decolorization behavior, NMR spectroscopy showed that after 24 h, reaction products were present in the reaction mixture for 1.4 wt% Co<sub>3</sub>O<sub>4</sub>/TiO<sub>2</sub>, while TiO<sub>2</sub> showed no reaction products. The lack of photocatalytic activity of Co<sub>3</sub>O<sub>4</sub>/zeolite and other Co<sub>3</sub>O<sub>4</sub>/oxide composite materials suggests a synergistic effect between Co<sub>3</sub>O<sub>4</sub> and TiO<sub>2</sub>, where a small amount of Co<sub>3</sub>O<sub>4</sub> enables TiO<sub>2</sub> to utilize visible light without compromising the surface area available for ROS creation. Lastly, we emphasize the need to be cautious when drawing conclusions regarding the dye degradation, since we showed that decolorization does not necessarily equate to full degradation, using a unique combination of UV-Vis and nuclear magnetic resonance spectroscopy.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400688"},"PeriodicalIF":2.3,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143188278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2H,3H-Decafluoropentane Endorsed Localized High Concentration Electrolyte for Low-Temperature Lithium-Metal Batteries. 2H,3H-decafluoropentane endorsed localized high concentration electrolyte for low temperature lithium-metal batteries(用于低温锂金属电池的局部高浓度电解质)。
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-04 DOI: 10.1002/cphc.202400920
Jie Wang, Yubin Liu, Haikuo Lei, Wenbin Sun, Xiaoyu Huang, Yanli Ruan
{"title":"2H,3H-Decafluoropentane Endorsed Localized High Concentration Electrolyte for Low-Temperature Lithium-Metal Batteries.","authors":"Jie Wang, Yubin Liu, Haikuo Lei, Wenbin Sun, Xiaoyu Huang, Yanli Ruan","doi":"10.1002/cphc.202400920","DOIUrl":"10.1002/cphc.202400920","url":null,"abstract":"<p><p>A lithium-metal battery's electrochemical performance is affected by the kinetics of desolvation and ion transport at low temperatures. Here, we propose a low-temperature lithium-metal battery electrolyte. 1,2-Dimethoxyethane (DME) is used as the solvent, 2H,3H-decafluoropentane (HFC) as the diluent, and a high concentration of lithium bis(fluorosulfonyl)imide (LiFSI) as the solute. The addition of HFC diluent increases the number of anions bound to lithium ions and decreases the number of solvents in the solvation structure, which is conducive to the desolvation process at low temperatures. In addition, the anion-dominated solvation structure is conducive to the formation of an inorganic rich solid electrolyte interface (SEI), which effectively enhances the compatibility of LHCE-HFC electrolyte with lithium metal. The LHCE-HFC achieves ultra-high coulombic efficiency of lithium metal anode in Li||Cu batteries (99.31 %) and Li||Li batteries (1080 h) that have strong fluorine content in the interface. The Li||LiFePO<sub>4</sub> (LFP) cells provide a discharge-specific capacity of 92.1 mAh g<sup>-1</sup> at 0.2 C at -20 °C and capacity retention of 89.6 % after 200 cycles.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400920"},"PeriodicalIF":2.3,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143188270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Feature: Multi-Layer Kesterite-Based Photocathodes for NH3 Photosynthesis from N2 Reduction Reaction (ChemPhysChem 3/2025)
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-04 DOI: 10.1002/cphc.202580302
Juliana Ferreira de Brito, Marina Medina, Hugo Leandro Sousa Santos, Mileny dos Santos Araujo, Marcos Antônio Santana Andrade Jr., Lucia Helena Mascaro
{"title":"Cover Feature: Multi-Layer Kesterite-Based Photocathodes for NH3 Photosynthesis from N2 Reduction Reaction (ChemPhysChem 3/2025)","authors":"Juliana Ferreira de Brito,&nbsp;Marina Medina,&nbsp;Hugo Leandro Sousa Santos,&nbsp;Mileny dos Santos Araujo,&nbsp;Marcos Antônio Santana Andrade Jr.,&nbsp;Lucia Helena Mascaro","doi":"10.1002/cphc.202580302","DOIUrl":"https://doi.org/10.1002/cphc.202580302","url":null,"abstract":"<p><b>The Cover Feature</b> illustrates a kesterite (CZTS)-based multilayer photocathode for NH<sub>3</sub> photosynthesis through N<sub>2</sub> reduction. The CZTS, CdS, and TiO<sub>2</sub> layers work synergistically to capture sunlight and drive the reaction. Pt nanoparticles on TiO<sub>2</sub> enhance catalysis, visualized as dynamic molecular interactions. The lush green background symbolizes sustainability, while the solar panel emphasizes renewable energy integration for NH<sub>3</sub> production, aligning research on efficient photocatalytic systems. More information can be found in the Research Article by J. Ferreira de Brito and co-workers (DOI: 10.1002/cphc.202400737).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":"26 3","pages":""},"PeriodicalIF":2.3,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cphc.202580302","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143111837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Absorption and Excited-State Coherences of Cryogenically Cold Retinal Protonated Schiff Base in Vacuo (ChemPhysChem 3/2025)
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-04 DOI: 10.1002/cphc.202580301
Nikolaj Klinkby, Anne P. Rasmussen, Anders G. S. Lauridsen, Prof. Lars H. Andersen
{"title":"Front Cover: Absorption and Excited-State Coherences of Cryogenically Cold Retinal Protonated Schiff Base in Vacuo (ChemPhysChem 3/2025)","authors":"Nikolaj Klinkby,&nbsp;Anne P. Rasmussen,&nbsp;Anders G. S. Lauridsen,&nbsp;Prof. Lars H. Andersen","doi":"10.1002/cphc.202580301","DOIUrl":"https://doi.org/10.1002/cphc.202580301","url":null,"abstract":"<p><b>The Front Cover</b> shows light interacting with a rhodopsin protein in the eye. Upon photoabsorption, the retinal chromophore inside the protein isomerizes. The impact of the protein environment on the active vibrations of the retinal chromophore during photoabsorption is still not well understood. In their Research Article (DOI: 10.1002/cphc.202400878), L. H. Andersen and co-workers examine an unperturbed retinal in vacuo at cryogenic temperature, measuring excited-state coherent oscillations by time-resolved action spectroscopy.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":"26 3","pages":""},"PeriodicalIF":2.3,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cphc.202580301","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143111836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valence Electron Count-Based Density Functional Theory to Investigate Structural Stability, Optoelectronic and Thermoelectric Properties of New p-Type Half-Heusler Zryau (Y=B, Al) Alloys.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-03 DOI: 10.1002/cphc.202400921
Radja Nour El Imene Bennoui, Walid Adli, Y Al-Douri, Fadila Belkharroubi, Fatima Sidjilani, Abdelkader Bentayeb, Friha Khelfaoui, Nawal Belmiloud, Sid Ahmed Bendella, Lakhdar Alagui, Anis Samy Amine Dib, Mohammed Noureddine Belkaid
{"title":"Valence Electron Count-Based Density Functional Theory to Investigate Structural Stability, Optoelectronic and Thermoelectric Properties of New p-Type Half-Heusler Zryau (Y=B, Al) Alloys.","authors":"Radja Nour El Imene Bennoui, Walid Adli, Y Al-Douri, Fadila Belkharroubi, Fatima Sidjilani, Abdelkader Bentayeb, Friha Khelfaoui, Nawal Belmiloud, Sid Ahmed Bendella, Lakhdar Alagui, Anis Samy Amine Dib, Mohammed Noureddine Belkaid","doi":"10.1002/cphc.202400921","DOIUrl":"10.1002/cphc.202400921","url":null,"abstract":"<p><p>The full-potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory (DFT) and semi-classical Boltzmann transport theory under the constant relaxation time approximation has been employed to investigate the structural, mechanical, optoelectronic and thermoelectric properties of novel half-Heusler (HH) ZrYAu alloys (where Y=B or Al) with a valence electron count (VEC) of 8. Our results indicate that both compounds are mechanically stable in structure Type 1 and possess negative formation energies. Additionally, ZrBAu and ZrAlAu display semiconducting behavior, with ZrBAu showing a direct band gap, 0.753 eV (0.774 eV) at point Γ→X and ZrAlAu exhibiting an indirect band gap, 0.431 eV (0.482 eV) at point Γ→Γ, using the generalized gradient approximation (GGA) and Modified Becke and Johnson-generalized gradient approximation (mBJ-GGA), respectively. Based on optical properties, both ZrBAu and ZrAlAu exhibit high optical conductivity within the visible spectrum. In terms of visible light absorption, ZrBAu primarily absorbs blue light, while ZrAlAu absorbs yellow, blue-green and violet light. However, both compounds are effective absorbers of UV light. Regarding thermoelectric performance, the thermoelectric parameters reveal that ZrBAu and ZrAlAu demonstrate significant p-type thermoelectric power. These half-Heusler alloys have a high-power factor, making them promising candidates for thermoelectric applications.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400921"},"PeriodicalIF":2.3,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143078734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Charge Transfer Effect on Relaxation Mechanism in Hydrated Pyrrole-Water Systems Following N-2s Ionization.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-03 DOI: 10.1002/cphc.202400962
Ravi Kumar, Kankana Bhattacharjee, Aryya Ghosh, Nayana Vaval
{"title":"Charge Transfer Effect on Relaxation Mechanism in Hydrated Pyrrole-Water Systems Following N-2s Ionization.","authors":"Ravi Kumar, Kankana Bhattacharjee, Aryya Ghosh, Nayana Vaval","doi":"10.1002/cphc.202400962","DOIUrl":"10.1002/cphc.202400962","url":null,"abstract":"<p><p>This study investigates the relaxation mechanisms of pyrrole and pyrrole-water clusters (C<sub>4</sub>H<sub>5</sub>N-(H<sub>2</sub>O)<sub>n</sub>, where <math> <semantics><mrow><mi>n</mi> <mo>=</mo> <mn>0</mn> <mo>-</mo> <mn>3</mn></mrow> <annotation>${n = 0 - 3}$</annotation> </semantics> </math> ) following N-2s ionization of pyrrole. Using various theoretical methods, we focus on the influence of water molecules and charge transfer on these non-radiative relaxation pathways. Our simulations included pyrrole solvated in 494 explicit water molecules equilibrated at 300 K and also employed a polarizable continuum model (PCM) to make the system more realistic and gain additional insights. In hydrated environments, the hydrogen bonding network between pyrrole and surrounding water molecules facilitates enhanced non-radiative relaxation pathways following inner valence ionization. Since these are hydrogen bonding systems, we have explored the possibility of proton transfer, which could occur in conjunction with other electronic decay processes.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400962"},"PeriodicalIF":2.3,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143078713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cyclically Generated Phase Segregation Synergizing with Si Enhances Lithium-Ion Storage Capability.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-03 DOI: 10.1002/cphc.202401007
Haoyuan Zhu, Zaoyan Yu, Yushuai Song, Shun Liu, Luzheng Zhao, Jiancong Guo, Wenruo Li, Xu Han, Zhongsheng Wen
{"title":"Cyclically Generated Phase Segregation Synergizing with Si Enhances Lithium-Ion Storage Capability.","authors":"Haoyuan Zhu, Zaoyan Yu, Yushuai Song, Shun Liu, Luzheng Zhao, Jiancong Guo, Wenruo Li, Xu Han, Zhongsheng Wen","doi":"10.1002/cphc.202401007","DOIUrl":"10.1002/cphc.202401007","url":null,"abstract":"<p><p>Silicon-based materials has been focused as potential candidates for lithium-ion battery anodes due to their sufficient reserves and extremely high specific capacity. However, the drastic volume expansion during the cycling leads to material pulverization and instability of the solid-electrolyte interface resulting in the rapid capacity fading, which restricts their commercial application. In this study, an original synergistic effect resulting from the phase segregation of Mn-based metal organic framework (Mn-MOF) during cycling is proposed to modify silicon via a facile self-assembly method and investigated as an anode material in LIBs. The unique composite structure can effectively improve the reversibility of silicon and enhance the lithium-ion storage capability. After 400 cycles, the Si@Mn-MOF composite exhibits a good electrochemical performance, achieving a high reversible capacity retention of 1234.4 mAh g<sup>-1</sup> at a current density of 200 mA g<sup>-1</sup>.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202401007"},"PeriodicalIF":2.3,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143078727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the Adsorption and Reactions of Methyl Radicals on M(111) Surfaces (M=Cu, Ag, Au): A DFT Study.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-03 DOI: 10.1002/cphc.202400979
Pankaj Kumar, Dan Meyerstein, Amir Mizrahi, Haya Kornweitz
{"title":"Exploring the Adsorption and Reactions of Methyl Radicals on M(111) Surfaces (M=Cu, Ag, Au): A DFT Study.","authors":"Pankaj Kumar, Dan Meyerstein, Amir Mizrahi, Haya Kornweitz","doi":"10.1002/cphc.202400979","DOIUrl":"10.1002/cphc.202400979","url":null,"abstract":"<p><p>It was reported that adsorbed methyl radicals produce ethane with Ag<sup>0</sup>- and Au<sup>0</sup>-nanoparticles in aqueous media, whereas on Cu<sup>0</sup>-powders, the product is methanol. The source of these differences was explored computationally, using the DFT method. The results indicate that up to six radicals can be adsorbed on Ag(111) and Au(111), (top site), while only four can be adsorbed on Cu(111) (fcc site), each surface containing eight atoms. The diffusion of the radicals on the surface is very easy on silver and copper, as this is achieved with a very low barrier (0.06 eV and 0.15 eV for Ag(111) and Cu(111), respectively), while on Au(111), the barrier is higher, 0.51 eV. The formation of ethane via a reaction of two adsorbed radicals is thermodynamically plausible for all studied coverage ratios on the three surfaces, but kinetically, it is plausible at room temperature only on Au(111) and Ag(111) at full coverage. Ethane can also be produced on Au(111) and Ag(111) by a collision of a solvated radical and an adsorbed radical. This is a barrierless process. On Cu(111), the yield of such a process is CH<sub>4</sub>(aq), and an adsorbed CH<sub>2</sub> which reacts further with a non-adsorbed water molecule to produce adsorbed CH<sub>3</sub>OH.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400979"},"PeriodicalIF":2.3,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143078730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In Situ formed Organic Sodium Salt/rGO Nanocomposite as Anode Material for Sodium Ion Batteries.
IF 2.3 3区 化学
Chemphyschem Pub Date : 2025-02-01 DOI: 10.1002/cphc.202400909
Qianwen Xue, Yuansheng Luo, Xiaoxue Tu, Haoyu Yin, Jingfu Chen, Fei Wu, Cheng Zhong, Linna Zhu
{"title":"In Situ formed Organic Sodium Salt/rGO Nanocomposite as Anode Material for Sodium Ion Batteries.","authors":"Qianwen Xue, Yuansheng Luo, Xiaoxue Tu, Haoyu Yin, Jingfu Chen, Fei Wu, Cheng Zhong, Linna Zhu","doi":"10.1002/cphc.202400909","DOIUrl":"10.1002/cphc.202400909","url":null,"abstract":"<p><p>Sodium-ion batteries (SIBs) are expected to be the next-generation large-scale energy storage technology. Organic anode materials are potential for efficient SIBs because they are not sensitive to the size of metal ions. Yet they still suffer from shortcomings such as low electrical conductivity, and solubility in electrolyte. Formation of nanocomposite with carbon materials is an efficient way to address these issues. Herein, we design a thiophene-based carboxylate compound STT, and the STT@rGO nanocomposite is also in situ formed as anode material for SIBs. The reduced graphene oxide (rGO) could improve conductivity and decrease the solubility of the anode material. Compared to the pristine STT electrode, STT@rGO delivers a reversible specific capacity of 178 mAh g<sup>-1</sup>, with a capacity retention rate of 86 % after 1000 cycles. Moreover, full batteries are successfully assembled using the nanocomposite anode and the commercial cathode Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>, manifesting the potential applications of the nanocomposite as organic electrode materials.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400909"},"PeriodicalIF":2.3,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143073935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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