Chemical and Biochemical Engineering Quarterly最新文献

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Adsorptive Removal of Pentavalent Arsenic from Aqueous Solutions by Granular Ferric Oxide 颗粒氧化铁吸附去除水溶液中五价砷
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-07-26 DOI: 10.15255/cabeq.2021.2018
Ronald Zakhar, J. Derco, F. Cacho, Oľga Čižmárová
{"title":"Adsorptive Removal of Pentavalent Arsenic from Aqueous Solutions by Granular Ferric Oxide","authors":"Ronald Zakhar, J. Derco, F. Cacho, Oľga Čižmárová","doi":"10.15255/cabeq.2021.2018","DOIUrl":"https://doi.org/10.15255/cabeq.2021.2018","url":null,"abstract":"Arsenic contamination of water resources, which is characterized by strong carcino-genic and toxic impacts, is a global problem. Therefore, the present study is focused on the isotherm and kinetic studies of pentavalent arsenic As(V) adsorption with initial concentration of 1 000 µg L −1 from aqueous solutions onto granular ferric oxide (GFO). Adsorption experiments were carried out by batch method, and the equilibrium and kinetic data were evaluated by the Langmuir, Freundlich, Dubinin-Radushkevich, Redlich-Peterson and Sips isotherm model, and pseudo-first and pseudo-second order kinetic model. The results obtained from this study imply that the adsorption of As(V) onto GFO was favourable, physical and multilayer process. The Sips and Redlich-Peter-son isotherm and the pseudo-first order kinetic model gave the best fit to experimental data according to the values of correlation coefficient. The maximum theoretical adsorption capacity from Langmuir isotherm model was determined to be 1 900 µg g −1 . In ad-dition, the impact of different operating conditions such as As(V) initial concentration, adsorbent dose, agitation speed, pH, temperature, and presence of phosphates and silica on adsorption capacity of GFO was also investigated. As(V) was efficiently recovered from GFO by 0.1 M NaOH desorbing solution during the three adsorption-desorption cycles.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47102631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Remediation of an Organochlorine Compound in an Unsaturated Zone Using a DL-Limonene Microemulsion System DL-柠檬烯微乳体系修复不饱和区有机氯化合物
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-07-26 DOI: 10.15255/cabeq.2021.2024
V. Campos, D. G. Marques, D. D. Anjos
{"title":"Remediation of an Organochlorine Compound in an Unsaturated Zone Using a DL-Limonene Microemulsion System","authors":"V. Campos, D. G. Marques, D. D. Anjos","doi":"10.15255/cabeq.2021.2024","DOIUrl":"https://doi.org/10.15255/cabeq.2021.2024","url":null,"abstract":"Contamination of the unsaturated zone, and hence, of groundwater by non-aqueous phase liquids has become a problem that arouses great concern due to the environmental damage it causes. Several efficient and economically beneficial techniques for the in situ treatment of contaminated soils have been applied quite frequently, including the so-called soil flushing processes. In this study, microemulsion systems were prepared using limonene, in the search for a formulation that would remove trichloroethene in soil. Limonene, a monocyclic monoterpene, is one of the main constituents of various essential oils of citrus fruits, such as oranges, tangerines and lemons. The results indicated that using a washing fluid containing 15 % DL-limonene microemulsion enabled the removal of 98.85 % of trichloroethene present in the soil after 30 minutes of residence time in the system. Hence, it can be concluded that the use of this microemulsion system is an inter-esting strategy for the remediation of soils contaminated with trichloroethene.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48658479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Byproduct from Triphala Extraction as Tannin and Rutin Sources for Production of Gallic Acid, Isoquercetin and Quercetin by Solid-State Fermentation 桑椹提取副产物作为单宁和芦丁来源固态发酵生产没食子酸、异槲皮素和槲皮素
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-07-26 DOI: 10.15255/cabeq.2021.1967
T. Chysirichote, Pattarabhorn Pakaweerachat
{"title":"Byproduct from Triphala Extraction as Tannin and Rutin Sources for Production of Gallic Acid, Isoquercetin and Quercetin by Solid-State Fermentation","authors":"T. Chysirichote, Pattarabhorn Pakaweerachat","doi":"10.15255/cabeq.2021.1967","DOIUrl":"https://doi.org/10.15255/cabeq.2021.1967","url":null,"abstract":"Byproduct from Triphala extraction process (BTP) was studied as a substrate for gallic acid, isoquercetin and quercetin production by Aspergillus niger fermentation in this research. The results showed that BTP was a good source of tannin and rutin. Neverthe­ less, the activity of A. niger on BTP as a sole substrate was very low. Supplementing nitro­ gen sources was found to be a key to enhancing conversion of tannin to gallic acid, and rutin to isoquercetin or isoquercetin and quercetin. BTP with 0.75 % sodium nitrate was sug­ gested to be an optimal supplemented nitrogen source for the production of gallic acid and isoquercetin in this research, which yielded the highest contents of 61.6±2.16 mg g –1DS and 3.27±0.29 mg g –1DS , respectively. In addition, the highest extraction yields of gallic acid, isoquercetin and quercetin were obtained by an ultrasound­assisted extraction using methanol as an extraction solvent as 12.24±2.12 mg g –1DS which was around 0.5 time higher than the one without ultrasound­assisted extraction (8.84±1.12 mg g –1DS ).","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48873363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Separation of Crocin/Betanin Using Aqueous Two-phase Systems Containing Ionic Liquid and Sorbitol 离子液体-山梨醇双水相体系分离Crocin/Betanin
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-07-26 DOI: 10.15255/cabeq.2021.2038
Roozbeh Madadi, Shahla Shahriari, H. Mozafari
{"title":"Separation of Crocin/Betanin Using Aqueous Two-phase Systems Containing Ionic Liquid and Sorbitol","authors":"Roozbeh Madadi, Shahla Shahriari, H. Mozafari","doi":"10.15255/cabeq.2021.2038","DOIUrl":"https://doi.org/10.15255/cabeq.2021.2038","url":null,"abstract":"Betanin and crocin, two food additives with attractive colors, are bioactive compounds of plants that are widely used in food, pharmaceutical, and medical industries. These bioactive pigments are sensitive to light, heat, organic solvents, and pH. It seems that a benign economic method is needed to extract these biomolecules, especially for industrial applications. The aqueous two-phase system (ATPS) is a liquid-liquid extraction technique that has shown its potential in recent years to extract and separate biomolecules. In this study, an ATPS consisting of carbohydrate (sorbitol) and ionic liquid (tetrabutyl phosphonium bromide) has been proposed as a new separation system with unique properties to study the partition coefficient of crocin and betanin. The results indicated that crocin and betanin had more tendency to the ionic liquid (IL)-rich phase and carbohydrate-rich phase, respectively. The influence of the concentration of IL and sorbitol on the partition coefficient was studied. The results showed that an increase in the tie-line length (concentrations) increased the partition coefficient of crocin and betanin. Enhancement in temperature increased the partition coefficient of crocin. The highest values of crocin recovery (97.55 %) and partition coefficient (39.85) at 308 K show that our proposed ATPS can be considered for crocin one step.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43561041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Novel L-Asparaginase from Enterobacter sp. Strain M55 from Maras Salterns in Peru 秘鲁Maras Salterns产肠杆菌M55株新l -天冬酰胺酶
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-07-26 DOI: 10.15255/cabeq.2022.2064
Abad Hurtado, J. Flores-Santos, C. N. Flores-Fernández, S. Saavedra, João H. P. M. Santos, A. Pessoa-Júnior, M. Lienqueo, M. Bayro, A. Zavaleta
{"title":"A Novel L-Asparaginase from Enterobacter sp. Strain M55 from Maras Salterns in Peru","authors":"Abad Hurtado, J. Flores-Santos, C. N. Flores-Fernández, S. Saavedra, João H. P. M. Santos, A. Pessoa-Júnior, M. Lienqueo, M. Bayro, A. Zavaleta","doi":"10.15255/cabeq.2022.2064","DOIUrl":"https://doi.org/10.15255/cabeq.2022.2064","url":null,"abstract":"L-Asparaginase (ASNase) is used in medicine for neoplasms treatment and in food industry for mitigation of acrylamide in high-temperature processed food. In medicine, commercial ASNases have exhibited side effects and l -glutaminase (GLNase) activity affecting the clinical treatment. The aim of this work was to study a novel ASNase from Enterobacter sp. M55 isolated from Maras Salters in Peru, which was purified and biochemically characterised. This ASNase exhibited a K m of 5.71 mM and a V max of 0.16 µmol mL –1 min –1 , as well as an optimum temperature and pH of 37 °C and 6, respectively. Moreover, a good activity (80 %) was observed at physiological pH. Likewise, the enzyme increased its activity by around 50% in presence of urea, glutathione, and glucose. Whilst in presence of serum compounds, it kept more that 60 % of activity. In addition, this ASNase showed low GLNase activity.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49099461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Machine Learning Approaches for Fault Detection in Semiconductor Manufacturing Process: A Critical Review of Recent Applications and Future Perspectives 半导体制造过程中故障检测的机器学习方法:近期应用和未来展望
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-04-11 DOI: 10.15255/cabeq.2021.1973
V. Arpitha, A. Pani
{"title":"Machine Learning Approaches for Fault Detection in Semiconductor Manufacturing Process: A Critical Review of Recent Applications and Future Perspectives","authors":"V. Arpitha, A. Pani","doi":"10.15255/cabeq.2021.1973","DOIUrl":"https://doi.org/10.15255/cabeq.2021.1973","url":null,"abstract":"In modern industries, early fault detection is crucial for maintaining process safety and product quality. Process data contains information on the entire plant acting as a map for visualization of relationships between various plant units, making data-driven process monitoring a key technology for efficiency enhancement. This article focuses on review of process monitoring techniques reported for metal etching process, which is a batch operation carried out in semiconductor manufacturing industry. Various machine learning (and deep learning) techniques applied to date for fault detection and diagnosis of metal etching process are surveyed. Detailed survey of research work on different techniques and the reported results are presented in graphical (pie chart and bar chart) and tabular format. The review article further presents the pros and cons, gaps and future directions in the techniques applied in metal etching process.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48800283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Chemisorption Role of Clay Surfaces in the Synthesis of Porphyrins from its Raw Materials via Room Temperature Reactions 粘土表面在原料室温反应合成卟啉中的化学吸附作用
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-04-11 DOI: 10.15255/cabeq.2021.2001
J. Hassen, J. Silver
{"title":"Chemisorption Role of Clay Surfaces in the Synthesis of Porphyrins from its Raw Materials via Room Temperature Reactions","authors":"J. Hassen, J. Silver","doi":"10.15255/cabeq.2021.2001","DOIUrl":"https://doi.org/10.15255/cabeq.2021.2001","url":null,"abstract":"","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42644127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis and Application of Cobalt-based Metal-organic Framework for Adsorption of Humic Acid from Water 吸附水中腐殖酸的钴基金属有机骨架的合成及应用
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-04-11 DOI: 10.15255/cabeq.2021.1960
Sana Naseem, H. Aslam, Aamir Abbas, Sara Sumbal, Rizwan Ali, Muhammad Usman
{"title":"Synthesis and Application of Cobalt-based Metal-organic Framework for Adsorption of Humic Acid from Water","authors":"Sana Naseem, H. Aslam, Aamir Abbas, Sara Sumbal, Rizwan Ali, Muhammad Usman","doi":"10.15255/cabeq.2021.1960","DOIUrl":"https://doi.org/10.15255/cabeq.2021.1960","url":null,"abstract":"In this study, the adsorption of humic acid on cobalt based metal-organic framework (Co-MOF) was investigated. Co-MOF was synthesized via solvothermal technique and further characterized using X-ray diffraction (XRD), Fourier transform infrared spectros-copy (FTIR), and scanning electron microscopy (SEM). The characterization results of material confirm the formation of MOF structure. The adsorption kinetics, isotherms, thermodynamics, as well as isosteric heat of adsorption were also investigated by obtaining experimental adsorption data through batch experimentation. Optimum adsorption uptake of ~91 mg g –1 was attained at pH 6 and 305 K. Regression analysis of experimental results revealed that adsorption kinetics follows a pseudo-second-order kinetic model, and adsorption can reach equilibrium at ~20 min. Adsorption isotherm data can be well fitted with Koble Corrigan isotherm. Thermodynamic parameters demonstrated that the adsorption of humic acid is a spontaneous, endothermic, and physical process, while isosteric heat evaluations revealed the heterogeneous nature of the adsorbent. Overall, the Co-MOF was a promising choice to adsorb humic acid from water.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48905066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Gasification of Sewage Sludge in a Rotary Kiln Reactor – A Case Study with Incorporation of Sewage Sludge Ash in Brick Production 污水污泥在回转窑反应器中的气化研究——以污泥灰掺入制砖为例
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-04-11 DOI: 10.15255/cabeq.2021.2030
Anđelina Bubalo, D. Vouk, Danica Maljković, T. Bolanča
{"title":"Gasification of Sewage Sludge in a Rotary Kiln Reactor – A Case Study with Incorporation of Sewage Sludge Ash in Brick Production","authors":"Anđelina Bubalo, D. Vouk, Danica Maljković, T. Bolanča","doi":"10.15255/cabeq.2021.2030","DOIUrl":"https://doi.org/10.15255/cabeq.2021.2030","url":null,"abstract":"The gasification of sewage sludge (SS) was studied in a semi-industrial pilot plant consisting of a rotary kiln reactor. The gasification process was preceded by drying the SS in an integrated tubular rotating structure with built-in worm conveyors, to increase the dry matter (DM) content in the SS (> 90 wt.%). The released hydrogen-rich syngas from the gasification process of SS had low heating value (LHV) of approximately 8.83 MJ N –1 m –3 (equal to 2.45 kWh N –1 m –3 ) due to the high content of combustible gases H 2 (41.5 vol.%) and CH 4 (3.2 vol.%). Also investigated was the incorporation of sewage sludge ash (SSA) generated in the process of gasification as a partial substitute for clay in the production of clay bricks. Amounts of 5 wt.%, 10 wt.%, 20 wt.% of clay were replaced by SSA. By incorporating SSA at 5 wt.%, the new brick product achieved 4.5 % higher compressive strength compared to the control brick.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44026158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Studies on the Adsorption of 2-Chlorophenol onto Rice Straw Activated Carbon from Aqueous Solution and its Regeneration 稻秆活性炭对2-氯酚的吸附及再生研究
IF 1.5 4区 生物学
Chemical and Biochemical Engineering Quarterly Pub Date : 2022-04-11 DOI: 10.15255/cabeq.2021.2004
M. Mahapatra, Arvind Kumar
{"title":"Studies on the Adsorption of 2-Chlorophenol onto Rice Straw Activated Carbon from Aqueous Solution and its Regeneration","authors":"M. Mahapatra, Arvind Kumar","doi":"10.15255/cabeq.2021.2004","DOIUrl":"https://doi.org/10.15255/cabeq.2021.2004","url":null,"abstract":"For this study a low-cost adsorbent, rice straw activated carbon (RSAC) was prepared via thermochemical routes after being impregnated with ZnCl 2 . Characterization studies performed on RSAC have revealed that RSAC is a mesoporous adsorbent with significant affinity towards 2-chlorophenol (2-CP). The optimal values for process parameters were investigated via experimental runs. The optimal values of process parameters such as RSAC dose, pH of 2-CP solution, contact time, and temperature were found to be; 1.25 g L –1 , 8, 125 min, and 303 K, respectively. The Langmuir isotherm and pseu-do-first-order kinetics models were found to be in good agreement with the experimental data for this adsorption system. The adsorption thermodynamics studies have revealed that the adsorption of 2-CP onto RSAC is exothermic and spontaneous. Regeneration studies of RSAC using hydrogen peroxide have revealed that RSAC was effectively regenerated for four consecutive cycles. This research has proved the potential of RSAC for abating 2-CP from aqueous solutions.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48763068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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