Batteries最新文献_第3页

Fabrication and Characterization of Plasma Sprayed TiO2 and Li4Ti5O12 Materials as All Active Material Lithium-Ion Battery Electrodes 等离子喷涂 TiO2 和 Li4Ti5O12 材料作为全活性材料锂离子电池电极的制作与特性分析

IF 4 4区化学

Batteries Pub Date : 2023-12-17 DOI: 10.3390/batteries9120598

Dean Yost, Jonathan Laurer, Kevin Childrey, Chen Cai, Gary M. Koenig

{"title":"Fabrication and Characterization of Plasma Sprayed TiO2 and Li4Ti5O12 Materials as All Active Material Lithium-Ion Battery Electrodes","authors":"Dean Yost, Jonathan Laurer, Kevin Childrey, Chen Cai, Gary M. Koenig","doi":"10.3390/batteries9120598","DOIUrl":"https://doi.org/10.3390/batteries9120598","url":null,"abstract":"Two strategies to increase battery energy density at the cell level are to increase electrode thickness and to reduce the amount of inactive electrode constituents. All active material (AAM) electrodes provide a route to achieve both of those aims toward high areal capacity electrodes. AAM electrodes are often fabricated using hydraulic compression processes followed by thermal treatment; however, additive manufacturing routes could provide opportunities for more time-efficient and geometry-flexible electrode fabrication. One possible route for additive manufacturing of AAM electrodes would be to employ plasma spray as a direct additive manufacturing technology, and AAM electrode fabrication using plasma spray will be the focus of the work herein. TiO2 and Li4Ti5O12 (LTO) powders were deposited onto stainless steel substrates via plasma spray processing to produce AAM battery electrodes, and evaluated with regards to material and electrochemical properties. The TiO2 electrodes delivered low electrochemical capacity, <12 mAh g−1, which was attributed to limitations of the initial feed powder. LTO plasma sprayed AAM electrodes had much higher capacity and were comparable in total capacity at a low rate of discharge to composite electrodes fabricated using the same raw powder feed material. LTO material and electrochemical properties were sensitive to the plasma spray conditions, suggesting that tuning the material microstructure and electrochemical properties is possible by controlling the plasma spray deposition parameters.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"27 5","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138966041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multiagent-Based Control for Plug-and-Play Batteries in DC Microgrids with Infrastructure Compensation 基于基础设施补偿的直流微电网中即插即用电池的多发电机控制

IF 4 4区化学

Batteries Pub Date : 2023-12-15 DOI: 10.3390/batteries9120597

M. Al-Saadi, Michael Short

{"title":"Multiagent-Based Control for Plug-and-Play Batteries in DC Microgrids with Infrastructure Compensation","authors":"M. Al-Saadi, Michael Short","doi":"10.3390/batteries9120597","DOIUrl":"https://doi.org/10.3390/batteries9120597","url":null,"abstract":"The influence of the DC infrastructure on the control of power-storage flow in micro- and smart grids has gained attention recently, particularly in dynamic vehicle-to-grid charging applications. Principal effects include the potential loss of the charge–discharge synchronization and the subsequent impact on the control stabilization, the increased degradation in batteries’ health/life, and resultant power- and energy-efficiency losses. This paper proposes and tests a candidate solution to compensate for the infrastructure effects in a DC microgrid with a varying number of heterogeneous battery storage systems in the context of a multiagent neighbor-to-neighbor control scheme. Specifically, the scheme regulates the balance of the batteries’ load-demand participation, with adaptive compensation for unknown and/or time-varying DC infrastructure influences. Simulation and hardware-in-the-loop studies in realistic conditions demonstrate the improved precision of the charge–discharge synchronization and the enhanced balance of the output voltage under 24 h excessively continuous variations in the load demand. In addition, immediate real-time compensation for the DC infrastructure influence can be attained with no need for initial estimates of key unknown parameters. The results provide both the validation and verification of the proposals under real operational conditions and expectations, including the dynamic switching of the heterogeneous batteries’ connection (plug-and-play) and the variable infrastructure influences of different dynamically switched branches. Key observed metrics include an average reduced convergence time (0.66–13.366%), enhanced output-voltage balance (2.637–3.24%), power-consumption reduction (3.569–4.93%), and power-flow-balance enhancement (2.755–6.468%), which can be achieved for the proposed scheme over a baseline for the experiments in question.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"43 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138999010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Percolation Behavior of a Sulfide Electrolyte–Carbon Additive Matrix for Composite Cathodes in All-Solid-State Batteries 用于全固态电池复合阴极的硫化物电解质-碳添加剂基质的渗流行为

IF 4 4区化学

Batteries Pub Date : 2023-12-15 DOI: 10.3390/batteries9120595

Elias Reisacher, Pinar Kaya, Volker Knoblauch

{"title":"Percolation Behavior of a Sulfide Electrolyte–Carbon Additive Matrix for Composite Cathodes in All-Solid-State Batteries","authors":"Elias Reisacher, Pinar Kaya, Volker Knoblauch","doi":"10.3390/batteries9120595","DOIUrl":"https://doi.org/10.3390/batteries9120595","url":null,"abstract":"To achieve high energy densities with sufficient cycling performance in all-solid-state batteries, the fraction of active material has to be maximized while maintaining ionic and electronic conduction throughout the composite cathode. It is well known that low-surface-area carbon additives added to the composite cathode enhance the rate capability; however, at the same time, they can lead to rapid decomposition of the solid electrolyte in thiophosphate-based cells. Thus, the fraction of such conductive additives has to be well balanced. Within this study we determined the electronic percolation threshold of a conducting matrix consisting of Li6PS5Cl and C65. Furthermore, we systematically investigated the microstructure and effective conductivity (σeff) of the conducting matrix. The percolation threshold pc was determined as ~4 wt.-% C65, and it is suggested that below pc, the ionic contribution is dominant, which can be seen in temperature-dependent σeff and blocked charge transport at low frequencies. Above pc, the impedance of the conducting matrix becomes frequency-independent, and the ohmic law applies. Thus, the conducting matrix in ASSB can be regarded as an electronic and ionic conducting phase between active material particles. Additionally, guidelines are provided to enable electronic conduction in the conducting matrix with minimal C65 content.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"39 5","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139000102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rational Design of a Cost-Effective Biomass Carbon Framework for High-Performance Lithium Sulfur Batteries 为高性能锂硫电池合理设计经济高效的生物质碳框架

IF 4 4区化学

Batteries Pub Date : 2023-12-15 DOI: 10.3390/batteries9120594

Zhongchao Bai, Kai Fan, Meiqing Guo, Mingyue Wang, Ting Yang, Nana Wang

{"title":"Rational Design of a Cost-Effective Biomass Carbon Framework for High-Performance Lithium Sulfur Batteries","authors":"Zhongchao Bai, Kai Fan, Meiqing Guo, Mingyue Wang, Ting Yang, Nana Wang","doi":"10.3390/batteries9120594","DOIUrl":"https://doi.org/10.3390/batteries9120594","url":null,"abstract":"Lithium–sulfur (Li-S) batteries are the most attractive candidates for next-generation large-scale energy storage because of their high theoretical energy density and the affordability of sulfur. However, most of the reported research primarily concentrates on low sulfur loading (below 2 mgs cm−2) cathodes using binders and traditional collectors, thus undermining the expected energy density. Herein, a N, O co-doped carbon nanotube (N, O-CNT) decorated wood framework (WF), denoted as WF-CNT, was designed as a free-standing sulfur host, achieving high sulfur loading of 10 mgs cm−2. This unique cathode featured low tortuosity microchannels and a conductive framework, reducing the diffusion paths for both ions and electrons and accommodating the volume changes associated with sulfur. Moreover, the internal CNT forests effectively captured soluble lithium polysulfides (LiPSs) and catalyze their redox kinetic. Consequently, the S@WF-CNT-800 sample exhibited a high initial discharge capacity of 1438.2 mAh g−1 at a high current density of 0.5 A g−1. Furthermore, a reversible capacity of 404.5 mAh g−1 was obtained after 500 cycles with sulfur loading of 5 mgs cm−2 at 0.5 A g−1. This work may support the development of high sulfur loading cathodes utilizing cost-effective and sustainable biomass materials for Li-S batteries.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"4 8","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139001066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Two-State-Based Hybrid Model for Degradation and Capacity Prediction of Lithium-Ion Batteries with Capacity Recovery 基于双态混合模型的容量恢复型锂离子电池降解和容量预测模型

IF 4 4区化学

Batteries Pub Date : 2023-12-15 DOI: 10.3390/batteries9120596

Yu Chen, Laifa Tao, Shangyu Li, Haifei Liu, Lizhi Wang

{"title":"A Two-State-Based Hybrid Model for Degradation and Capacity Prediction of Lithium-Ion Batteries with Capacity Recovery","authors":"Yu Chen, Laifa Tao, Shangyu Li, Haifei Liu, Lizhi Wang","doi":"10.3390/batteries9120596","DOIUrl":"https://doi.org/10.3390/batteries9120596","url":null,"abstract":"The accurate prediction of Li-ion battery capacity is important because it ensures mission and personnel safety during operations. However, the phenomenon of capacity recovery (CR) may impede the progress of improving battery capacity prediction performance. Therefore, in this study, we focus on the phenomenon of capacity recovery during battery degradation and propose a hybrid lithium-ion battery capacity prediction framework based on two states. First, to improve the density of capacity-related information, the simultaneous Markov blanket discovery algorithm (STMB) is used to screen the causal features of capacity from the initial feature set. Then, the life-long cycle sequence of batteries is partitioned into global degradation regions and recovery regions, as part of the proposed prediction framework. The prediction branch for the global degradation region is implemented through a long short-term memory network (LSTM) and the other prediction branch for the recovery region is implemented through Gaussian process regression (GPR). A support vector machine (SVM) model is applied to identify recovery points to switch the branch of the prediction framework. The prediction results are integrated to obtain the final prediction results. Experimental studies based on NASA’s lithium battery aging data highlight the trustworthy capacity prediction ability of the proposed method considering the capacity recovery phenomenon. In contrast to the comparative methods, the mean absolute error and the root mean square error are reduced by up to 0.0013 Ah and 0.0043 Ah, which confirms the validity of the proposed method.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"221 11","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138996985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optimizing the Location of Frequency Regulation Energy Storage Systems for Improved Frequency Stability 优化频率调节储能系统位置以提高频率稳定性

IF 4 4区化学

Batteries Pub Date : 2023-12-14 DOI: 10.3390/batteries9120592

Jonghoon Lee, Sangwook Han, Dongho Lee

{"title":"Optimizing the Location of Frequency Regulation Energy Storage Systems for Improved Frequency Stability","authors":"Jonghoon Lee, Sangwook Han, Dongho Lee","doi":"10.3390/batteries9120592","DOIUrl":"https://doi.org/10.3390/batteries9120592","url":null,"abstract":"The installation of battery energy storage systems (BESSs) with various shapes and capacities is increasing due to the continuously rising demand for renewable energy. To prepare for potential accidents, a study was conducted to select the optimal location for installing an input BESS in terms of frequency stability when the index assumes the backup input of the BESS. This study builds on the premise that installing a BESS on a bus in an area where active power absorption and transmission are the most active can significantly contribute to increasing the frequency recovery of the power system. Based on this premise, the magnitude of the active power flow and the proportional characteristics of the phase difference between buses were mathematically confirmed. This study also calculated the effective power sensitivity index of a bus with 13 FR-ESSs installed in a domestic system and reviewed the frequency output by establishing a table for each failure scenario. The results indicated that the effect of frequency rise can be estimated at the level of tidal current calculation. Thus, the study suggested a direction for subsequent studies to improve the sensitivity index.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"10 4","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138972011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Traditional and Iterative Group-IV Material Batteries through Ion Migration 通过离子迁移实现传统和迭代式第 IV 组材料电池

IF 4 4区化学

Batteries Pub Date : 2023-12-14 DOI: 10.3390/batteries9120591

Xiaojun He, Xiaoyan Wei, Zifeng Jin, Zhenglin Wang, Ya’nan Yang, Jinsheng Lv, Nan Chen

引用次数: 0

Qualitative Characterization of Lead–Acid Batteries Fabricated Using Different Technological Procedures: An EIS Approach 使用不同技术程序制造的铅酸电池的定性特征：EIS 方法

IF 4 4区化学

Batteries Pub Date : 2023-12-14 DOI: 10.3390/batteries9120593

Olivia Bruj, A. Calborean

{"title":"Qualitative Characterization of Lead–Acid Batteries Fabricated Using Different Technological Procedures: An EIS Approach","authors":"Olivia Bruj, A. Calborean","doi":"10.3390/batteries9120593","DOIUrl":"https://doi.org/10.3390/batteries9120593","url":null,"abstract":"Electrochemical impedance spectroscopy techniques were applied in this work to nine industrially fabricated lead–acid battery prototypes, which were divided into three type/technology packages. Frequency-dependent impedance changes were interpreted during successive charge/discharge cycles in two distinct stages: (1) immediately after fabrication and (2) after a controlled aging procedure to 50% depth of discharge following industrial standards. To investigate their state of health behavior vs. electrical response, three methods were employed, namely, the Q-Q0 total charge analysis, the decay values of the constant-phase element in the equivalent Randles circuits, and the resonance frequency of the circuit. A direct correlation was found for the prediction of the best-performing batteries in each package, thus allowing for a qualitative analysis that was capable of providing the decay of the batteries’ states of health. We found which parameters were directly connected with their lifetime performance in both stages and, as a consequence, which type/technology battery prototype displayed the best performance. Based on this methodology, industrial producers can further establish the quality of novel batteries in terms of performance vs. lifespan, allowing them to validate the novel technological innovations implemented in the current prototypes.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"1985 11","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138973815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Analysis of Ni-Rich Cathode Composite Electrode Performance According to the Conductive Additive Distribution for Application in Sulfide All-Solid-State Lithium-Ion Batteries 根据导电添加剂分布分析硫化物全固态锂离子电池应用中的富镍阴极复合电极性能

IF 4 4区化学

Batteries Pub Date : 2023-12-14 DOI: 10.3390/batteries9120590

Jae Hong Choi, Sumyeong Choi, Tom James Embleton, Kyung-Min Ko, Kashif Saleem Saqib, Mina Jo, Junhyeok Hwang, S. Park, Yoonkook Son, P. Oh

{"title":"Analysis of Ni-Rich Cathode Composite Electrode Performance According to the Conductive Additive Distribution for Application in Sulfide All-Solid-State Lithium-Ion Batteries","authors":"Jae Hong Choi, Sumyeong Choi, Tom James Embleton, Kyung-Min Ko, Kashif Saleem Saqib, Mina Jo, Junhyeok Hwang, S. Park, Yoonkook Son, P. Oh","doi":"10.3390/batteries9120590","DOIUrl":"https://doi.org/10.3390/batteries9120590","url":null,"abstract":"All-solid-state lithium-ion batteries (ASSLBs) represent a promising breakthrough in battery technology owing to their high energy density and exceptional stability. When crafting cathode electrodes for ASSLBs, the solid electrolyte/cathode material interface is physically hindered by the specific morphology of carbon additive materials. In this paper, we examine the distribution of conductive additives within the electrode and its impact on the electrochemical performance of composites incorporating either nano-sized carbon black (CB) or micron-sized carbon nanofibers (CNF) into Ni-rich (LiNi0.8Co0.1Mn0.1O2) cathode material based composites. When nano-sized CB is employed as a conductive additive, it enhances the electrical conductivity of the composite by adopting a uniform distribution. However, its positioning between the solid electrolyte and cathode material leads to an increase in interfacial resistance during charge and discharge cycles, resulting in decreased electrochemical performance. In contrast, using micron-sized CNF as a conductive additive results in a reduction in the composite’s electrical conductivity compared to CB. Nevertheless, due to the comparatively uninterrupted interfaces between the solid electrolyte and cathode materials, it exhibits superior electrochemical characteristics. Our findings are expected to aid the fabrication of electrochemical-enhanced cathode composite electrodes for ASSLBs.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"159 14 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138972887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in the Separation of Graphite from Lithium Iron Phosphate from End-of-Life Batteries Shredded Fine Fraction Using Simple Froth Flotation 从报废电池中的磷酸铁锂中分离石墨的研究进展采用简单的浮选法分离细馏分碎石

IF 4 4区化学

Batteries Pub Date : 2023-12-13 DOI: 10.3390/batteries9120589

O. Renier, Andrea Pellini, J. Spooren

{"title":"Advances in the Separation of Graphite from Lithium Iron Phosphate from End-of-Life Batteries Shredded Fine Fraction Using Simple Froth Flotation","authors":"O. Renier, Andrea Pellini, J. Spooren","doi":"10.3390/batteries9120589","DOIUrl":"https://doi.org/10.3390/batteries9120589","url":null,"abstract":"Olivine-type lithium iron phosphate (LiFePO4, LFP) lithium-ion batteries (LIBs) have become a popular choice for electric vehicles (EVs) and stationary energy storage systems. In the context of recycling, this study addresses the complex challenge of separating black mass of spent LFP batteries from its main composing materials to allow for direct recycling. In this study, 71% copper and 81% aluminium foil impurities were removed by sieving black mass to <250 µm. Next, the application of froth flotation as a separation technique was explored, examining the influence of chemical agents, pre-treatment, and multi-step processes. Frother agent addition improved material recovery in the froth, while collector addition influenced the separation efficiency and enhanced graphite recovery. Pre-treatment, particularly sonication, was found to break down agglomerates and further improve separation. Multi-step flotation increased the purity of recovered fractions. The optimized process for a black mass < 250 µm, involving sonication pre-treatment and double flotation, resulted in enriched carbonaceous material (80.3 mol%) in froth fractions and high LFP concentration (81.9 mol%) in tailings fractions. The recovered spent LFP cathode material contained 37.20 wt% Fe2P2O7, a degradation product of LiFePO4. This research offers valuable insights for the development of efficient battery recycling methods for LFP batteries.","PeriodicalId":8755,"journal":{"name":"Batteries","volume":"42 14","pages":""},"PeriodicalIF":4.0,"publicationDate":"2023-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138976801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0