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Assessing Changes in Permethrin Toxicity to Juvenile Inland Silversides (Menidia beryllina) Under Different Temperature Scenarios 不同温度条件下氯菊酯对内陆银鱼幼鱼的毒性变化
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2025-01-18 DOI: 10.1007/s00244-025-01111-2
McKenna K. Haney, Giovanni S. Molinari, Michael J. Lydy
{"title":"Assessing Changes in Permethrin Toxicity to Juvenile Inland Silversides (Menidia beryllina) Under Different Temperature Scenarios","authors":"McKenna K. Haney,&nbsp;Giovanni S. Molinari,&nbsp;Michael J. Lydy","doi":"10.1007/s00244-025-01111-2","DOIUrl":"10.1007/s00244-025-01111-2","url":null,"abstract":"<div><p>Aquatic systems are impacted by temperature fluctuations which can alter the toxicity of pesticides. Increased temperatures related to climate change have elevated pest activity, resulting in an escalation of pesticide use. One such pesticide class, pyrethroids, has replaced the use of several banned pesticides due to its low mammalian toxicity. The impacts of increased temperatures on the toxicity of a pyrethroid, permethrin, to fish is not yet known. In the current study, juvenile inland silversides (<i>Menidia beryllina</i>) were exposed to permethrin at three temperatures: 10 °C, 20 °C, and 30 °C. Inland silversides were chosen for this study because they are a species used in standardized USEPA whole effluent toxicity testing. Permethrin toxicity showed an inverse relationship with temperature. As temperatures fluctuate, fishes experience a change in respiration, biotransformation, and elimination rates, which can drive the noted difference in toxicity. Based on these findings, toxicity can be temperature-dependent and should be considered when assessing risk of exposure to pesticides in aquatic systems.</p></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 2","pages":"151 - 157"},"PeriodicalIF":3.7,"publicationDate":"2025-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142999199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Accessing the Past: A Sediment Core Revealing Anthropogenic Impacts of Technology-Critical Elements on the Marine Environment 访问过去:揭示技术关键要素对海洋环境的人为影响的沉积物岩心。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2025-01-17 DOI: 10.1007/s00244-024-01110-9
Dominik Wippermann, Ole Klein, Hendrik Wolschke, Tristan Zimmermann, Anna Ebeling, Daniel Pröfrock
{"title":"Accessing the Past: A Sediment Core Revealing Anthropogenic Impacts of Technology-Critical Elements on the Marine Environment","authors":"Dominik Wippermann,&nbsp;Ole Klein,&nbsp;Hendrik Wolschke,&nbsp;Tristan Zimmermann,&nbsp;Anna Ebeling,&nbsp;Daniel Pröfrock","doi":"10.1007/s00244-024-01110-9","DOIUrl":"10.1007/s00244-024-01110-9","url":null,"abstract":"<div><p>One group of elements attracting more and more attention are so-called technology-critical elements (TCEs). In comparison with legacy pollutants, the anthropogenic impact of TCEs on the environment might still be minor, but various applications introduce them to the most remote places in the world including the marine environment. One area prone to pollution is the Baltic Sea, partly due to the lack of water exchange with the North Sea. In this study, a sediment core from the German Baltic Sea was used to analyze a total of 42 elemental mass fractions. Based on radiometric dating of <sup>210</sup>Pb and <sup>137</sup>Cs, results were classified in a recent (2020–2000) and a past period (&lt; 1920), calculating background concentrations based on the Median + 2 Median Absolute Deviation (M2MAD) and the Tukey Inner Fence (TIF). Six legacy pollutants (Ni, Cu, Zn, As, Cd, Pb) and six TCEs (Ga, Ge, Nb, La, Gd, Ta) are discussed in detail. Anthropogenic impacts of both groups were assessed, and local enrichment factors were calculated showing an increase for the legacy pollutants (past period (≤ 0.8); recent period (≥ 1.2)), but also a minor increase for Ga, Ge and Nb (past period (0.9); recent period (1.1)). Values ≥ 1.5, indicating anthropogenic impact, were found for Cu, Zn, Cd and Pb, but also for Ge. Proposed background values may be considered as baseline for future studies.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"1 - 15"},"PeriodicalIF":3.7,"publicationDate":"2025-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11782340/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142999197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chronic Radium-226 Bioaccumulation and Toxicity in the Aquatic Invertebrate Daphnia magna 水生无脊椎动物大水蚤体内镭-226的慢性生物蓄积和毒性。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2025-01-06 DOI: 10.1007/s00244-024-01109-2
Charlotte Lacroix-Durand, David Janz, Karsten Liber
{"title":"Chronic Radium-226 Bioaccumulation and Toxicity in the Aquatic Invertebrate Daphnia magna","authors":"Charlotte Lacroix-Durand,&nbsp;David Janz,&nbsp;Karsten Liber","doi":"10.1007/s00244-024-01109-2","DOIUrl":"10.1007/s00244-024-01109-2","url":null,"abstract":"<div><p>Mining operations in Canada, including uranium mining and milling, generate by-products containing radionuclides, including radium-226 (<sup>226</sup>Ra), a long-lived, bioaccumulative calcium (Ca<sup>2+</sup>) analog. Despite strict discharge regulations, there is limited evidence to suggest that current thresholds for <sup>226</sup>Ra adequately protect aquatic organisms. Furthermore, Canada lacks a federal water quality guideline for <sup>226</sup>Ra, underscoring the need for protective limits to safeguard aquatic ecosystems. Hence, this research aimed to generate data on <sup>226</sup>Ra toxicity to the model aquatic invertebrate <i>Daphnia magna</i>. For this purpose, two 21-day chronic toxicity tests with <i>D. magna</i> were conducted, with survival and reproduction as the endpoints, as well as a reduced water hardness experiment, a multigenerational study, and a bioaccumulation assay. These experiments demonstrated that a high activity concentration (nominal 50 Bq/L) of <sup>226</sup>Ra can significantly impact the survival of <i>D. magna.</i> <sup>226</sup>Ra was also found to bioaccumulate in <i>D. magna</i> with a BAF of 72.8. Since the Canadian <i>Metal and Diamond Mining Effluent Regulations</i> (MDMER) monthly mean effluent limit is currently set at 0.37 Bq <sup>226</sup>Ra /L, the limit for composite samples at 0.74 Bq/L <sup>226</sup>Ra, and the limit for grab samples at 1.11 Bq/L <sup>226</sup>Ra, it is unlikely that toxic effects to aquatic cladocerans like <i>D. magna</i> from <sup>226</sup>Ra will be observed downstream of Canadian mines and mills.</p></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"123 - 133"},"PeriodicalIF":3.7,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143063142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of Toxic Elements Pollution Sources and Crop Health Risks in Soil of Typical Thallium Mining Area 典型铊矿区土壤有毒元素污染源及作物健康风险分析
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2025-01-03 DOI: 10.1007/s00244-024-01108-3
Zhihao Ye, Yanmei Yang, Qiang Zhou, Xin Zhou, Liansheng He, Rui Meng, Longhao Huang
{"title":"Analysis of Toxic Elements Pollution Sources and Crop Health Risks in Soil of Typical Thallium Mining Area","authors":"Zhihao Ye,&nbsp;Yanmei Yang,&nbsp;Qiang Zhou,&nbsp;Xin Zhou,&nbsp;Liansheng He,&nbsp;Rui Meng,&nbsp;Longhao Huang","doi":"10.1007/s00244-024-01108-3","DOIUrl":"10.1007/s00244-024-01108-3","url":null,"abstract":"<div><p>The investigation focused on Tl, Hg, As, and Sb as the targeted contaminants in the soil surrounding a thallium mining region in southwestern China. Potential sources of toxic elements were identified using correlation analysis and principal component analysis. By interpreting the results of correlation and principal component analysis, the potential sources of Tl, Hg, As, and Sb were identified to include the mining and smelting industry. Additionally, Tl, Hg, and As are influenced by agricultural activities, while Sb is also associated with the soil parent material. Various analytical methods including the Nemerow comprehensive pollution index, Hakanson potential ecological risk index and hazard quotient assessment were employed to evaluate the sources of heavy metal pollution and associated health risks to crops. Results indicated elevated exceedance rates of Tl, Hg, and Sb in the farmland soil. Approximately 37.9% and 16.7% of the sampling locations were classified as highly and moderately polluted, respectively. Furthermore, toxic elements posed significant ecological risks to the soil, particularly with substantial contributions from Hg and Tl toward the overall risk index. Crop samples collected showed elevated levels of Tl, Hg, and As, particularly in leafy vegetables compared to cereals. Notably, the hazard quotient (HQ) values for Tl in cabbage and Lotus were 1.462 and 5.511, respectively, whereas the HQ value for Hg in Allium chinense was 1.773, posing a significant threat to human health. These findings offer valuable data and theoretical foundation for further investigations into the sources and risks associated with toxic elements in farmland near thallium mining sites.</p></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"16 - 28"},"PeriodicalIF":3.7,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142920352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating the sensitivity of a chronic plant bioassay relative to an independently derived predicted no-effect thresholds to support risk assessment of very hydrophobic organic chemicals 评估慢性植物生物测定相对于独立推导的预测无效应阈值的敏感性,以支持非常疏水性有机化学品的风险评估。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2024-12-30 DOI: 10.1007/s00244-024-01106-5
Aaron D. Redman, Miriam Leon Paumen, Daniel J. Letinski, Barbara A. Kelley, Cary Sutherland, Bryan M. Hedgpeth, Josh D. Butler, Roger Prince, Gail E. Bragin, Abraham J. Smith
{"title":"Evaluating the sensitivity of a chronic plant bioassay relative to an independently derived predicted no-effect thresholds to support risk assessment of very hydrophobic organic chemicals","authors":"Aaron D. Redman,&nbsp;Miriam Leon Paumen,&nbsp;Daniel J. Letinski,&nbsp;Barbara A. Kelley,&nbsp;Cary Sutherland,&nbsp;Bryan M. Hedgpeth,&nbsp;Josh D. Butler,&nbsp;Roger Prince,&nbsp;Gail E. Bragin,&nbsp;Abraham J. Smith","doi":"10.1007/s00244-024-01106-5","DOIUrl":"10.1007/s00244-024-01106-5","url":null,"abstract":"<div><p>Environmental risk assessments of very hydrophobic organic compounds (VHOCs) in soils are often difficult because multiple processes (e.g., sorption, volatilization, biodegradation) can complicate the interpretation of results. A standardized soil dosing and aging procedure is presented for assessing bioavailability of VHOCs in a synthetic soil, which was used to evaluate the phytotoxicity of VHOCs. The soil preparation protocol resulted in relatively stable freely dissolved concentrations of test substance compared to bulk soil concentrations with some losses likely due to volatility and biodegradation. This dosing method was used in a chronic terrestrial plant toxicity bioassay to evaluate the potential toxicity of VHOCs on complex reproductive endpoints like inflorescence and seed bud formation. Testing included representative hydrocarbons and three very hydrophobic lubricant substances (logKow &gt; 10). The toxicity data were used to evaluate existing predicted no-effect concentrations (PNECs) that had originally been derived with the target lipid model, which did not have these higher order chronic plant endpoints. The initial exposure concentrations were set at the PNECs to provide an independent validation of the PNEC. This evaluation was performed to expand the domain of applicability of the PNEC to VHOCs and for the chronic terrestrial plant endpoints. No effects were observed on plant biomass or inflorescence production at these low exposure concentrations, demonstrating that the established PNEC is protective of long-term plant health. The results of the present study confirm that the new dosing method is fit for purpose, and that the existing PNEC framework can be extended to chronic plant endpoints for VHOCs.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"110 - 122"},"PeriodicalIF":3.7,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11783378/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142909239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Sediment Spatial Distribution and Quality Assessment of Metals in Chinook Salmon and Resident Killer Whale Marine Habitat in British Columbia, Canada 修正:加拿大不列颠哥伦比亚省奇努克鲑鱼和虎鲸海洋栖息地沉积物空间分布和金属质量评估。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2024-12-21 DOI: 10.1007/s00244-024-01101-w
Joseph J. Kim, Kelsey Delisle, Tanya M. Brown, Peter S. Ross, Marie Noël
{"title":"Correction: Sediment Spatial Distribution and Quality Assessment of Metals in Chinook Salmon and Resident Killer Whale Marine Habitat in British Columbia, Canada","authors":"Joseph J. Kim,&nbsp;Kelsey Delisle,&nbsp;Tanya M. Brown,&nbsp;Peter S. Ross,&nbsp;Marie Noël","doi":"10.1007/s00244-024-01101-w","DOIUrl":"10.1007/s00244-024-01101-w","url":null,"abstract":"","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 2","pages":"251 - 251"},"PeriodicalIF":3.7,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142871190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Origin of Tar Balls Along the Beaches of Genaveh Region, Persian Gulf 沿着波斯湾Genaveh地区的海滩焦油球的起源。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2024-12-16 DOI: 10.1007/s00244-024-01105-6
Shirin Mohamadjafari Dehkordi, Alireaza Riyahi Bakhtiari, Mehdi Vafakhah, Abdulvahed Khaledi Darvishan
{"title":"Origin of Tar Balls Along the Beaches of Genaveh Region, Persian Gulf","authors":"Shirin Mohamadjafari Dehkordi,&nbsp;Alireaza Riyahi Bakhtiari,&nbsp;Mehdi Vafakhah,&nbsp;Abdulvahed Khaledi Darvishan","doi":"10.1007/s00244-024-01105-6","DOIUrl":"10.1007/s00244-024-01105-6","url":null,"abstract":"<div><p>Oil spills and tarballs are significant pollutants in marine environments, and identifying their sources is crucial for mitigating environmental impacts. This study aims to determine the primary sources of petroleum spills and tarballs along the shores of Genaveh (northwest of the Persian Gulf) by employing chemical fingerprinting techniques and biomarkers. Specifically, petroleum hydrocarbons were analyzed in 19 tarball samples, 13 surface sediment samples from the Genaveh coast, and reference oil samples from 21 offshore oil platforms located in the Bahregan, Khark, Lavan, Siri, and Hendurabi regions. Samples were extracted using the Soxhlet extraction method, followed by two-step column chromatography, and the compositions of <i>n</i>-alkanes, polycyclic aromatic hydrocarbons (PAHs), hopanes, and steranes were determined using gas chromatography–mass spectrometry (GC–MS). The concentration of PAHs in coastal sediment samples from Genaveh ranged from 345 (S841) to 27,374 ng/g-dw (S852), indicating moderate to very high pollution levels. The total concentration of aliphatic hydrocarbons in coastal sediment samples from Genaveh ranged from 8,694 (S842) to 27,374 µg/g-dw (S851), significantly exceeding <i>n-</i>alkane concentrations reported in surface sediments from many other regions worldwide, suggesting considerable pollution levels. For the 19 collected tarball samples, PAH concentrations varied from 597.5 to 10,173 ng/g-dw, while <i>n</i>-alkane concentrations ranged from 27,136 to 66,341 µg/g-dw, which may indicate differences in age or freshness. Diagnostic indicators, such as undifferentiated complex mixtures (UCM), a carbon preference index (CPI) close to 1 for <i>n-</i>alkanes, diagnostic ratios of PAHs, and ratios of hopanes and steranes, pointed to a predominantly petrogenic origin of hydrocarbons in the coastal sediments of Genaveh. The principal component analysis (PCA) results revealed a distinction between oil samples from the Lavan, Hendurabi, and Siri platforms, indicating oil leakage from the Khark oilfield pipelines (Doroud and Forouzan) and Bahregan oilfields (Bahregansar and Soroosh) as a major pollution source. This implies that both oil spills, observed in the coastal sediments of Genaveh, and episodic spills, represented by tarballs, originate from a similar, homogeneous source. Only sediment samples from stations S841 and S812 were not influenced by tarballs, suggesting pollution from a different source compared to other sediment samples.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"55 - 75"},"PeriodicalIF":3.7,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00244-024-01105-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142827078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomonitoring of atmospheric deposition of potentially toxic elements at rural sites in Tuscany (Central Italy) 意大利中部托斯卡纳农村地区潜在有毒元素大气沉降的生物监测。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2024-12-11 DOI: 10.1007/s00244-024-01107-4
Mehriban Jafarova, Inga Zinicovscaia, Nikita Yushin, Ilaria Bonini, Aldo Winkler, Stefano Loppi
{"title":"Biomonitoring of atmospheric deposition of potentially toxic elements at rural sites in Tuscany (Central Italy)","authors":"Mehriban Jafarova,&nbsp;Inga Zinicovscaia,&nbsp;Nikita Yushin,&nbsp;Ilaria Bonini,&nbsp;Aldo Winkler,&nbsp;Stefano Loppi","doi":"10.1007/s00244-024-01107-4","DOIUrl":"10.1007/s00244-024-01107-4","url":null,"abstract":"<div><p>This study investigated the accumulation (deposition) of 13 potentially toxic elements (PTEs) in moss tissue (dominated by <i>Hypnum cupressiforme</i> at 64% and <i>Pseudoscleropodium purum</i> at 13.4%) collected from 33 rural sites of Tuscany (Central Italy). In addition, the magnetic susceptibility of moss was measured to provide insight into the accumulation of anthropogenic particles. Prior to the analysis, moss samples were washed, and the rinse waters were also analyzed for PTEs. Exploratory spatial analysis and source identification of airborne PTEs were carried out; the results suggest that the main anthropogenic airborne pollutants in the region were Cd and Zn from long-range transport with the mean concentrations of 0.12 mg/kg and 18.2 mg/kg, respectively. Wet deposition was the dominant source for these elements, which were however accumulated by moss in modest amounts. Soil also emerged as an important source for several elements i.e., Al, Fe, Cr and Ni, but its contribution was largely unpredictable, as indicated by the lack of correlation between moss tissue and rinse water concentrations. Further, sample washing of a few seconds was not effective in fully removing soil particles. The sensitivity analysis suggested that the results of the study are reliable and did not depend on the methodology used for data analysis. This is the first comprehensive regional-scale study in rural areas of Tuscany using moss biomonitoring, and as such, it provides important baseline data for future research.</p></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"29 - 38"},"PeriodicalIF":3.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142806000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating Oil Entrance from Hendijan Oil Field in the Northwest of the Persian Gulf Using Chemical Fingerprinting 利用化学指纹技术调查波斯湾西北部Hendijan油田石油入口。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2024-12-09 DOI: 10.1007/s00244-024-01103-8
Mitra Cheraghi, Alireza Riyahi Bakhtiari, Mahmoud Memariani, Jahangard Mohammadi, Stefano Bonduà
{"title":"Investigating Oil Entrance from Hendijan Oil Field in the Northwest of the Persian Gulf Using Chemical Fingerprinting","authors":"Mitra Cheraghi,&nbsp;Alireza Riyahi Bakhtiari,&nbsp;Mahmoud Memariani,&nbsp;Jahangard Mohammadi,&nbsp;Stefano Bonduà","doi":"10.1007/s00244-024-01103-8","DOIUrl":"10.1007/s00244-024-01103-8","url":null,"abstract":"<div><p>Concerning the entrance of oil into the Persian Gulf due to the presence of oil fields in this ecosystem, a wide investigation was carried out in 2017 to evaluate the hydrocarbons source identification and chemical fingerprinting. To this end, surface sediments were collected from the Persian Gulf. In the laboratory, compounds (<i>n</i>-alkanes, PAHs, hopane and sterane) were then extracted with a Soxhlet system and two steps of chromatographic columns and analyzed using a GC–MS instrument. The results showed that the concentrations of the <i>n</i>-alkanes and Σ30 PAHs increased with a reduction in distance from hot spots. This suggests that high concentrations of hydrocarbons in the locations near the hot spots might be due to oil leakage, transportation of and exploration for oil, pipeline fractures and industrial activities. A positive relation between total organic matter (TOM) and hydrocarbons was observed. A common petrogenic hydrocarbon source was strongly implied in most places by the presence of unresolved compounds resolved (UCM), lower molecular weight/higher molecular weight (LMW/HMW) and carbon preference index (CPI) ratios &lt; 1. Typical profiles of petrogenic PAHs with predominant alkyl substituted naphthalene and phenanthrene, various PAH ratios and multivariate analysis showed that PAHs were mainly derived from petrogenic sources. Simultaneous use of <i>n</i>-alkanes and PAHs in source identification can be effective to precisely specify the hydrocarbon sources in complicated mixture ecosystems. Furthermore, using multivariate analysis and chemical fingerprinting of <i>n</i>-alkanes, PAHs, hopanes and sterane confirmed that Hendijan crude oil may be the source of the sediment pollution in the study area.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":8377,"journal":{"name":"Archives of Environmental Contamination and Toxicology","volume":"88 1","pages":"76 - 96"},"PeriodicalIF":3.7,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00244-024-01103-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142799287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of Oxytetracycline and Sulfamethazine Effects Over Root Elongation in Selected Wild and Crop Plants Commonly Present in the Mediterranean Cropland and Pasture Scenarios 比较土霉素和磺胺甲嗪对地中海农田和牧场中常见的野生和作物植物根系伸长的影响。
IF 3.7 4区 环境科学与生态学
Archives of Environmental Contamination and Toxicology Pub Date : 2024-12-07 DOI: 10.1007/s00244-024-01104-7
Carlos Sacristán, Marta Guerrero, Sonia Sánchez, Antonio Rodríguez, Rosa María García, Ana Carolina Ewbank, Meritxell Gros, Sara Rodríguez-Mozaz, Isaura Martín Martínez, Luis Guasch, Ana de la Torre
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