Journal of Materials Chemistry A最新文献

{"title":"Recent advances in zeolite membranes for gas separation and pervaporation in petrochemicals","authors":"Xinhong Han, Wanyi Xu, Fanfei Meng, Zhiyu Liu, Changjian Liao","doi":"10.1039/d4ta08746a","DOIUrl":"https://doi.org/10.1039/d4ta08746a","url":null,"abstract":"Zeolite-based membrane separation technology offers an efficient and sustainable solution to the separation and purification needs of modern industry. This review highlights advancements in zeolite membranes, focusing particularly on LTA, CHA, and DDR type small-pore zeolite membranes, as well as MFI type medium-pore zeolite membranes. Recent developments and innovations in membrane preparation technologies are first analyzed. Next, optimization strategies for zeolite membrane structures are summarized, emphasizing improvements in permeability, selectivity, and stability. These membranes demonstrate significant application potential in petrochemical processes, including hydrogen recovery, natural gas purification, carbon dioxide capture, hydrocarbon mixture separation, organic solvent dehydration, and membrane reactors. Finally, the challenges and opportunities associated with the synthesis and application of zeolite membranes are discussed, providing insights for future research directions.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"30 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Elucidating the Role of Fe Substitution on Structural and Redox Stability of Na2Mn3O7","authors":"Hugh Barrett Smith, Gi-Hyeok Lee, Bachu Sravan Kumar, Aubrey N. Penn, Victor Venturi, Yifan Gao, Ryan Davis, Kevin H Stone, Adrian Hunt, Iradwikanari Waluyo, Eli Stavitski, Wanli Yang, Iwnetim Iwnetu Abate","doi":"10.1039/d4ta08203f","DOIUrl":"https://doi.org/10.1039/d4ta08203f","url":null,"abstract":"Sodium-ion batteries have the potential to meet the growing demand for energy storage due to their low costs stemming from natural resource abundances, but their cathode energy densities must be improved to be comparable to those of lithium-ion batteries. One strategy is accessing high voltage capacity through high-valent redox reactions. Such reactions usually cause instability in cathode materials, but Na<small>₂</small>Mn<small>₃</small>O<small>₇</small> (NMO) has demonstrated excellent performance and reversibility in the high-valent regime due to its unique lattice structure with ordered Mn vacancies. This work expands the universality of the ordered vacancy as a design principle and increases the material candidates with such exceptional electrochemical behavior. Our approach involves synergizing cationic ordered vacancies with tunable metal-ligand hybridization through partial metal substitution. In particular, we successfully incorporated Fe<small>³⁺</small> for Mn<small>⁴⁺</small> in NMO to make Na<small>_2.25</small>Mn<small>_2.75</small>Fe<small>_0.25</small>O<small>₇</small> and achieved improved high-valent redox behavior. Fe substitution leads to larger specific capacities (171 vs 159 mAh/g first cycle), enhanced cycle stability (97 vs 60 mAh/g after 50 cycles), and superior rate performance. This study lays the foundation for developing new cathode materials with stable high-valent redox through substitution of redox-active transition metals by employing cationic ordered vacancies and partial transition metal substitution as design principles in tandem.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"8 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Suppressing Nonradiative Energy Loss in Ternary Organic Solar Cells Through Elaborate Disruption of Planarity of Guest Acceptor","authors":"Qi Liang, Xiaodong Wang, Hongxiang Li, Huanxiang Jiang, Hao Lu, Yahui Liu, Andong Zhang, Zhishan Bo","doi":"10.1039/d5ta00232j","DOIUrl":"https://doi.org/10.1039/d5ta00232j","url":null,"abstract":"The relatively large non-radiative energy loss (ΔEnr) in organic solar cells (OSCs) remains a major obstacle for improving the power conversion efficiency (PCE). Therefore, it is imperative to minimize ΔEnr through rational molecular design and device engineering. In this work, three small molecular acceptors with different terminal steric hindrance groups (Y-PH-H, Y-PH-CH3, and Y-PH-2CH3) are designed as the third components to elaborately reduce the π-π interactions in the acceptor phase and improve the photoluminescence quantum yield (PLQY). All the third components effectively improve the fluorescence quantum yield of the acceptor phase and inhibit ΔEnr. Among these systems, the Y-PH-CH3 ternary system exhibits remarkable suppression of non-radiative energy loss, coupled with refined charge transport capabilities. Consequently, it achieves an impressive power conversion efficiency (PCE) of 18.63%, accompanied by a low non-radiative energy loss of merely 0.178 eV. Moreover, by adopting this third component design strategy into D18:L8-BO system, significantly improved open circuit voltage (VOC) of 0.924 V, and high PCE of 19.18% can be achieved. This study confirms that appropriately manipulating the planarity of acceptor by terminal steric hindrance groups is an effective approach for designing third component toward highly efficient ternary OSCs with low ΔEnr.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"20 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143589964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A new quaternary sphalerite-derivative compound for thermoelectric applications: Cu7VSnS8","authors":"Shuya Kozai, Koichiro Suekuni, Seiya Takahashi, Eiji Nishibori, Hidetaka Kasai, Ilaria Siloi, Marco Fornari, Hikaru Saito, Philipp Sauerschnig, Michihiro Ohta, Pierric Lemoine, Emmanuel Guilmeau, Bernard Raveau, Michitaka Ohtaki","doi":"10.1039/d4ta08137d","DOIUrl":"https://doi.org/10.1039/d4ta08137d","url":null,"abstract":"Cu–S-based multinary compounds with sphalerite-derivative structures have received attention due to their potential as thermoelectric materials. Recently, we proposed a strategy to design Cu–S-based quaternary compounds, “the pseudo-binary approach”. Within the Cu<small>₃</small>SbS<small>₄</small>–Cu<small>₄</small>TiS<small>₄</small> (Cu<small>_3+<em>x</em></small>Sb<small>_{1−<em>x</em>}</small>Ti<small>_<em>x</em></small>S<small>₄</small>) system, this new approach led us to discover Cu<small>₃₀</small>Ti<small>₆</small>Sb<small>₂</small>S<small>₃₂</small>, at <em>x</em> = 0.75. In this study, we adopted the same approach for the “Cu<small>₃</small>SnS<small>₄</small>”–“Cu<small>₄</small>VS<small>₄</small>” and (Cu<small>_3+<em>x</em></small>Sn<small>_{1−<em>x</em>}</small>V<small>_<em>x</em></small>S<small>₄</small>) system. Although the ordered end-point compounds are not known, a semiconducting quaternary phase, Cu<small>₇</small>VSnS<small>₈</small>, was discovered at <em>x</em> = 0.5. Single crystal X-ray diffraction has revealed that this new compound crystallizes in a tetragonal sphalerite derivative structure with space group <em>P</em><img alt=\"[4 with combining macron]\" border=\"0\" src=\"https://www.rsc.org/images/entities/char_0034_0304.gif\"/><em>m</em>2. Electronic and phonon/vibrational properties were investigated by combining experiments and theory. Cu<small>₇</small>VSnS<small>₈</small> allows partial substitution of Ti for V, leading to the increase of the hole carrier concentration and the thermoelectric power factor. The relatively large power factor of 0.5 mW K<small>⁻²</small> m<small>⁻¹</small>, combined with a low lattice thermal conductivity of 0.5 W K<small>⁻¹</small> m<small>⁻¹</small>, yields a large dimensionless figure of merit <em>ZT</em> = 0.6–0.7 at 673 K for unoptimized hot-pressed samples of Cu<small>₇</small>V<small>_{1−<em>y</em>}</small>Ti<small>_<em>y</em></small>SnS<small>₈</small> (<em>y</em> = 0.25, 0.5, 0.75). High-temperature stability was also examined by thermogravimetry and X-ray diffraction.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"40 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unlocking the potential of semi-transparent Ta3N5 photoelectrodes for high performing and reproducible solar redox flow cells","authors":"Filipe Moisés M. Francisco, Paula Dias, A. Mendes","doi":"10.1039/d4ta08136f","DOIUrl":"https://doi.org/10.1039/d4ta08136f","url":null,"abstract":"A solar redox flow cell (SRFC) is singular in its ability to use a photoelectrochemical (PEC) cell for efficiently converting solar energy into electrochemical storable energy and heat. The generated solar fuels can be easily converted into electrical power at a redox flow battery (RFB). However, the SRFCs remain at a low Technology Readiness Level (TRL) mainly due to the low semiconductor efficiency, system durability, and lack of validated demonstrators. By leveraging the unique properties of tantalum nitride (Ta3N5) photoelectrodes, this work studies the role of this semiconductor material for the development of high performing SRFC devices. Opaque Ta3N5 photoelectrodes reached special interest for PEC water splitting due to the impressive photocurrent density achieved so far. However, for SRFC applications based on coloured electrolytes, Ta3N5 needs to be semi-transparent to allow backside sunlight illumination. Electrophoretic deposition (EPD) stands out as a suitable method for preparing semi-transparent Ta3N5 films. For the first time, the synthesis conditions were optimized, focusing on the EPD cycle time and annealing temperature, in an NH3 atmosphere, as well as employing a Ta‑doped TiO2 (TTO) underlayer for addressing simultaneously reproducibility and high efficiency. The best-performing bare Ta3N5 photoelectrodes were prepared with an electrophoretic deposition time of 7 min and annealed at 425 ºC, displaying an unprecedented photocurrent density of ca. 4.0 mA⸳cm-2 and a maximum power density of ca. 1.1 mW⸳cm-2, using a ferrocyanide-based electrolyte. These conditions allowed improving charge transfer kinetics and reducing recombination rates, as observed by electrochemical impedance spectroscopy. The optimized Ta3N5 photoelectrode was then paired with a perovskite solar cell, in a PEC-PV arrangement, to demonstrate 100 h operation of an aqueous alkaline SRFC, based on ferrocyanide (K4Fe(CN)6) and anthraquinone-2,7-disulphonate (2,7-AQDS) redox pairs both dissolved in KOH solutions.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"86 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A comparative computational and scanning electrochemical microscopy study of factors influencing electron transfer at the hydrogenated and pristine graphite – propylene carbonate electrochemical interface","authors":"Jason Howard, Dipobrato Sarbapalli, Abhiroop Mishra, Nannan Shan, Garvit Agarwal, Jingjing Zhang, Michael J. Counihan, Lu Zhang, Rajeev S. Assary, Larry A. Curtiss, Joaquín Rodríguez-López","doi":"10.1039/d4ta07050j","DOIUrl":"https://doi.org/10.1039/d4ta07050j","url":null,"abstract":"Nonaqueous redox flow batteries are a promising technology that utilize redox-active species (<em>i.e.</em>, redoxmers) in solution to store energy <em>via</em> electron-transfer (ET) reactions with electrodes. However, electron transfer (ET) phenomena at the interface of graphitic electrodes and nonaqueous media are poorly understood, with several non-idealities in the use of conventional models such as the Butler–Volmer model reported. Possibilities for these non-idealities include the adsorption of redox species at the electrode, fundamental ET limitations related to the density of states at the electrode, and the presence of chemical and spatial heterogeneities at the surface of the electrode. To this point, we present a computational and experimental approach to comparatively investigate the ET behavior of two redoxmers, ferrocene (Fc) and 2,3-dimethyl-1,4-dialkoxybenzene (C7) on single layer graphene (SLG), hydrogen-functionalized SLG (H-SLG), and pristine and hydrogen-functionalized graphite electrodes. Scanning electrochemical microscopy (SECM) experiments revealed enhanced ET kinetics for both redoxmers on H-SLG electrodes compared to pristine SLG electrodes, with the degree of functionalization playing a key role in this enhancement. Electrodes such as boron-doped diamond and hydrogenated graphite mirrored these enhancements. Density functional theory (DFT) calculations indicate only small differences in the binding strengths for Fc and C7 redoxmers on SLG and H-SLG surfaces, but Marcus–Hush–Chidsey (MHC) kinetic theory analysis suggests that the density of states (DOS) of the carbon electrode likely plays a crucial role in the observed ET enhancement. These findings refine our initial assumption of binding energy (BE) as a dominant factor for interfacial behavior in the case of Fc and C7 redoxmers. Our findings create new opportunities to explore systems with varying degrees of surface modification to understand and design better redox flow batteries.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"41 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Extreme pH-tolerant FeOOH@NiAl-LDH nanohybrid adsorbents: Ultra-stable dye adsorption driven by multiple synergistic mechanisms and potent antibacterial performance","authors":"Xiaolang Chen, Yao Chen, Tian Wen, Chengcheng Zhang, Jun Qin","doi":"10.1039/d5ta00570a","DOIUrl":"https://doi.org/10.1039/d5ta00570a","url":null,"abstract":"The discharge and accumulation of organic dyes in the environment have become pressing issues that require urgent attention. Layered double hydroxides (LDH) based adsorbents are emerging as a promising potential for treating wastewater contaminated with difficult-to-remove organic dyes. However, single LDH adsorbents still face serious challenges in practical applications, including low adsorption capacity, poor structural stability, and a narrow pH range. Here, we employed a simple hydrothermal method to fabricate a 3D flower-like structure of FeOOH hybridized nickel-aluminum LDH (FeOOH@NiAl-LDH). The FeOOH derived from MOF-235 possesses a higher specific surface area and pore volume, which provides more adsorption sites and pore space, effectively enhancing the adsorption performance of Congo red (CR). Meanwhile, the interaction between FeOOH and NiAl-LDH enhances the structural stability of the adsorbent, endowing it with efficient adsorption and reproducibility under strongly alkaline conditions, thus achieving a dual enhancement in adsorption capacity (1297.0 mg/L) and stability under extreme pH (2−12) conditions. Additionally, the assessments for antibacterial activity and cytotoxicity confirms that FeOOH@NiAl-LDH exhibits excellent antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Overall, this study not only provides new insights into the application of LDH in the field of water treatment but also offers important theoretical foundations for the design and preparation of high-performance dye adsorption materials.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"36 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Lattice variations in CaTiO3 cubes and cuboids and their use in photocatalytic benzimidazole formation","authors":"Ya-Ting Yang, Bo Hao Chen, Arnab Pal, Chih-Hsueh Li, Zong-hong Lin, Michael H. Huang","doi":"10.1039/d5ta00541h","DOIUrl":"https://doi.org/10.1039/d5ta00541h","url":null,"abstract":"CaTiO3 perovskite cubes with tunable sizes of 90 to 886 nm, as well as 156 and 725 nm cuboids, have been hydrothermally synthesized. Remarkably, despite their similar appearance, only cubes show a preferred orientation effect in X-ray diffraction (XRD) patterns. Peak positions also shift slightly with particle size and shape. Synchrotron XRD analysis reveals the presence of bulk and surface layer lattices with clearly shifted peaks. Unexpectedly, while a CaTiO3 cube presents (002) lattice fringes in transmission electron microscopy (TEM) images, a cuboid shows (001) lattice fringes. They also have discernably different lattice point patterns. These lattice features give rise to dissimilar dielectric constants and optical facet dependence. The cuboid crystals show stronger piezoelectric and ferroelectric responses than cubic particles do. Their surface properties differ completely with cuboidal particles being moderately active toward rhodamine B photodegradation, while cubes are inactive from floating above the dye solution with stirring. The CaTiO3 cuboids are more effective than cubes in photocatalyzing the formation of benzimidazole. This work demonstrates that interior lattice variations can significantly tune various materials properties, so detailed structural analysis is necessary to explain shape-related behaviors.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"31 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Coupling of high ion transport efficiency in hydrogel electrolytes and interfacial fusion for performance enhancement in all-solid-state paper-based self-powered electrochromic devices with low-temperature tolerance","authors":"Guodong Liu, Shuyue Chen, Xiaohong Jiang, Zhuoqing Zhang, Yaoli Wang, Hanbin Liu, Zhijian Li, Patrick Gane","doi":"10.1039/d4ta08719d","DOIUrl":"https://doi.org/10.1039/d4ta08719d","url":null,"abstract":"Self-powered electrochromic devices (ECDs) have gained considerable attention for applications such as smart labels, displays and rechargeable batteries, thanks to their dynamic balance between color display and energy storage capabilities. The electrochemical performance of existing ECDs, however, is often constrained by the conductivity of electrolytes, the contact interface between electrodes and electrolytes, and the severe intolerance of ECDs to low temperature environments. In this study, we couple two approaches. Firstly, we harness the Hofmeister effect to modulate the concentration of an ionic compound within the hydrogel electrolyte. This modulation enhances ion solvation and ionic conductivity, thereby facilitating internal ion transport within the self-powered ECD and accelerating the device's response time. Secondly, we illustrate how it is possible to capitalize on the designable properties of the substrate. Paper offers a unique controllable substrate structure, which can be readily modified in terms of surface micro-roughness, which, in turn, can be utilized during the forming of the gravure printed electrode. This novel optimization can improve the final surface morphology of the paper-based electrode, enhancing its surface area properties. This enhancement subsequently facilitates improved integration of the electrode interface with the hydrogel electrolyte, reducing interface impedance and increasing ion transport efficiency within the ECD. Combining this morphological effect with the increased ion solvation in the hydrogel electrolyte enables an improved electrochemical performance and cyclic stability, maintaining stability even at temperatures as low as −40 °C.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"60 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143589961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two-dimensional covalent triazine frameworks for advanced electrochemical energy storage applications","authors":"Yaping Jiang, Chenhui Yan, Xin Wang, WenXing Miao, Hui Peng, Lei Zhu, Imran Shakir, Guofu Ma, Yuxi Xu","doi":"10.1039/d5ta00860c","DOIUrl":"https://doi.org/10.1039/d5ta00860c","url":null,"abstract":"Two-dimensional covalent triazine frameworks (2D CTFs) are novel conjugated porous polymers created from organic monomers through covalent bonding with triazine structural units, which have emerged as a focal point of research in electrochemical energy storage owing to their distinctive physicochemical characteristics, including high specific surface area, adjustable pore structure, and superior electrochemical stability. The utilization of 2D CTFs in diverse electrochemical energy storage systems, including lithium-, sodium-, potassium- and zinc-ion batteries, as well as supercapacitors, not only demonstrates the enhancement of the energy and power densities of these devices, but also promotes their cycling stability and rate performance. This review aims to discuss the advancements of 2D CTFs in diverse energy storage devices in recent years, focusing on the structure-activity relationship of their unique 2D morphology/structure and physicochemical properties to improve battery performance. Finally, it also provides an outlook on current challenges and future trajectory of 2D CTFs in the field of electrochemical energy storage.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"19 1","pages":""},"PeriodicalIF":11.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}