Applied Spectroscopy Reviews最新文献

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Methods in Raman spectroscopy for saliva studies – a review 唾液拉曼光谱研究方法综述
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-08-30 DOI: 10.1080/05704928.2021.1969944
Mike Hardy, Liam Kelleher, Paulo de Carvalho Gomes, E. Buchan, H. Chu, P. Goldberg Oppenheimer
{"title":"Methods in Raman spectroscopy for saliva studies – a review","authors":"Mike Hardy, Liam Kelleher, Paulo de Carvalho Gomes, E. Buchan, H. Chu, P. Goldberg Oppenheimer","doi":"10.1080/05704928.2021.1969944","DOIUrl":"https://doi.org/10.1080/05704928.2021.1969944","url":null,"abstract":"Abstract The use of Raman spectroscopy combined with saliva is an exciting emerging spectroscopy-biofluid combination. In this review, we summarize current methods employed in such studies, in particular the collection, pretreatment, and storage of saliva, as well as measurement procedures and Raman parameters used. Given the need for sensitive detection, surface-enhanced Raman methods are also surveyed, alongside chemometric techniques. A meta-analysis of variables is compiled. We observe a wide range of approaches and conclude that standardization of methods and progress to more extensive validation Raman-saliva studies is necessary. Nevertheless, the studies show tremendous promise toward the improvement of speed, diagnostic accuracy, and portable device possibilities in applications such as healthcare, law enforcement, and forensics.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90222946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Remote molecular composition analysis of laser-ablated material 激光烧蚀材料的远程分子组成分析
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-08-23 DOI: 10.1080/05704928.2021.1966634
P. Lubin, M. Pelizzo, Jacob Erlikhman, A. Cohen, J. Madajian, P. Meinhold, G. Hughes, Nic Rupert, P. Srinivasan
{"title":"Remote molecular composition analysis of laser-ablated material","authors":"P. Lubin, M. Pelizzo, Jacob Erlikhman, A. Cohen, J. Madajian, P. Meinhold, G. Hughes, Nic Rupert, P. Srinivasan","doi":"10.1080/05704928.2021.1966634","DOIUrl":"https://doi.org/10.1080/05704928.2021.1966634","url":null,"abstract":"Abstract A novel method is described for remotely interrogating bulk molecular composition of rocky materials. Laser energy heats a local area on the substrate; flux is optimized to melt and evaporate target constituents with low rates of molecular dissociation. Substrate temperature rises until an equilibrium is established between incident flux and latent phase-change energies, reaching ˜2500 K in vacuum. A blackbody signal is emitted by the heated spot, traveling outward through the evaporated material; reflective optics direct the signal into a spectrometer. Ro-vibrational absorption in the plume provides a diagnostic for identifying bulk molecular composition of the substrate. Absorption spectra are modeled for compounds with available a priori molecular cross-sections, based on laser and receiver characteristics, and target material properties. Mass ejection flux drives the plume density profile. Qualitative, species-specific spectral profiles are derived by integrating molecular cross section along a path through the plume. Simulations indicate robust absorption profiles.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89320121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of spodumene identification by statistical approach for laser-induced breakdown spectroscopy data of lithium pegmatite ores 利用统计方法对伟晶岩锂矿激光诱导击穿光谱数据进行锂辉石鉴定
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-08-17 DOI: 10.1080/05704928.2021.1963977
Sari Romppanen, I. Pölönen, H. Häkkänen, S. Kaski
{"title":"Optimization of spodumene identification by statistical approach for laser-induced breakdown spectroscopy data of lithium pegmatite ores","authors":"Sari Romppanen, I. Pölönen, H. Häkkänen, S. Kaski","doi":"10.1080/05704928.2021.1963977","DOIUrl":"https://doi.org/10.1080/05704928.2021.1963977","url":null,"abstract":"Abstract Mapping with laser-induced breakdown spectroscopy (LIBS) can offer more than just the spatial distribution of elements: the rich spectral information also enables mineral recognition. In the present study, statistical approaches were used for the recognition of the spodumene from lithium pegmatite ores. A broad spectral range (280–820 nm) with multiple lines was first used to establish the methods based on vertex component analysis (VCA) and K-means and DBSCAN clusterings. However, with a view to potential on-site applications, the dimensions of the datasets must be reduced in order to accomplish fast analysis. Therefore, the capability of the methods in mineral identification was tested with a limited spectral range (560–815 nm) using Li-pegmatites with various mineralogical characters.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87927959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Vibrational spectroscopy and multivariate analysis techniques in the clinical immunology laboratory: a review of current applications and requirements for diagnostic use 临床免疫学实验室中的振动光谱学和多变量分析技术:当前诊断应用和要求的综述
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-08-04 DOI: 10.1080/05704928.2021.1958337
Emma L. Callery, A. Rowbottom
{"title":"Vibrational spectroscopy and multivariate analysis techniques in the clinical immunology laboratory: a review of current applications and requirements for diagnostic use","authors":"Emma L. Callery, A. Rowbottom","doi":"10.1080/05704928.2021.1958337","DOIUrl":"https://doi.org/10.1080/05704928.2021.1958337","url":null,"abstract":"Abstract Laboratory tests are essential for clinicians to reach an accurate diagnosis and informing appropriate treatments. The expansion in the use of immunotherapies has highlighted the gap between the knowledge of molecular pathways and targeted therapies with availability of laboratory tests. The translation of vibrational spectroscopic techniques such as Fourier-transform infrared (FTIR) spectroscopy and Raman spectroscopy into clinical practice offer rapid-, noninvasive and inexpensive methods to obtain information on the molecular composition of biological samples. Advances in instrumentation, data analysis and machine learning techniques are key developments that have permitted the availability of results to clinicians in an appropriate timescale. Immunological disorders are complex, often demonstrating interaction across multiple molecular pathways which results in delayed diagnosis. Vibrational spectroscopy is being applied in many fields and here we present a review of its potential use in clinical immunology. This review addresses the potential use of spectroscopy in clinical immunology. Potential benefits that these novel techniques offer, including enhanced definition of molecular process and its use in disease diagnosis, monitoring and treatment response is discussed. Whilst not covered extensively, an overview of the method principle, quality control processes, and the requirements for multivariate data analysis is included to provide the reader with sufficient understanding of its application in the clinical setting.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74708403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Characterization of cellulose nanocrystals by current spectroscopic techniques 当前光谱技术对纤维素纳米晶体的表征
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-07-26 DOI: 10.1080/05704928.2021.1951283
R. Dassanayake, Niwanthi Dissanayake, J. S. Fierro, N. Abidi, E. Quitevis, Kiran Boggavarappu, Vidura D. Thalangamaarachchige
{"title":"Characterization of cellulose nanocrystals by current spectroscopic techniques","authors":"R. Dassanayake, Niwanthi Dissanayake, J. S. Fierro, N. Abidi, E. Quitevis, Kiran Boggavarappu, Vidura D. Thalangamaarachchige","doi":"10.1080/05704928.2021.1951283","DOIUrl":"https://doi.org/10.1080/05704928.2021.1951283","url":null,"abstract":"Abstract Over the past few years, cellulose nanocrystals (CNCs), also known as nanocrystalline cellulose (NCCs), have received significant attention owing to their diverse spectrum of applications. CNCs are commonly considered in nanomedicine, the food industry, tissue engineering, energy and storage applications, paper and textile industry, polymeric composites, and bio-catalysis. Due to the versatility of CNCs and CNC-derived materials, there is increasing importance in characterizing their properties using spectroscopic techniques. These spectroscopic techniques include solid-state nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron (XPS) spectroscopy, and Raman spectroscopy. This review focuses on the characterization of CNCs and CNCs-derived materials using the aforementioned spectroscopic techniques. This review also discusses the background, experimental procedures, sample preparation, and spectral analysis methods used in these techniques.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77185251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Spectroscopic methods for determination of critical micelle concentrations of surfactants; a comprehensive review 测定表面活性剂临界胶束浓度的光谱方法。全面回顾
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-07-23 DOI: 10.1080/05704928.2021.1955702
M. Mabrouk, Nouran A. Hamed, F. Mansour
{"title":"Spectroscopic methods for determination of critical micelle concentrations of surfactants; a comprehensive review","authors":"M. Mabrouk, Nouran A. Hamed, F. Mansour","doi":"10.1080/05704928.2021.1955702","DOIUrl":"https://doi.org/10.1080/05704928.2021.1955702","url":null,"abstract":"Abstract The applications of surfactants in various fields are gaining more attention, which makes full characterization of surfactants of growing interest. It is fundamental to measure the critical micelle concentration (CMC) as a parameter for characterizing surfactants. Spectroscopic methods for determination of CMC are more common, easier to perform, and in certain applications more accurate. In this review, different spectroscopic techniques and methods used for determination of CMC are discussed. These methods include direct UV/VIS Spectroscopy, which studies liquid surface curvature in thin wells using vertical detecting light beam with the wavelength set at 900 nm. The indirect UV/VIS Spectroscopic methods include using surface plasmon resonance or surface-enhanced Raman scattering of metal nanoparticles. Direct spectrofluorometric methods measure CMC based on the intrinsic fluorescence of the tested surfactants, and it was reserved for surfactants with intrinsic fluorescence such as Triton-X100. Indirect spectrofluorometric methods include measuring the change in fluorescence intensity, spectral shape, lifetime, polarization, or the solvatochromic shift of surfactant-dye solution. Other spectroscopic methods have been reported such as X-ray diffraction, nuclear magnetic resonance spectroscopy and small-angle neutron scattering. This review article discusses the spectroscopic methods developed for CMC determination with emphasis on the principle, applications, advantages, and limitations of each method.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77060688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 27
FTIR spectroscopy in biomedical research: how to get the most out of its potential FTIR光谱学在生物医学研究中的应用:如何最大限度地发挥其潜力
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-07-13 DOI: 10.1080/05704928.2021.1946822
S. Magalhães, B. Goodfellow, A. Nunes
{"title":"FTIR spectroscopy in biomedical research: how to get the most out of its potential","authors":"S. Magalhães, B. Goodfellow, A. Nunes","doi":"10.1080/05704928.2021.1946822","DOIUrl":"https://doi.org/10.1080/05704928.2021.1946822","url":null,"abstract":"Abstract Fourier Transform Infrared (FTIR) Spectroscopy, in particular ATR-FTIR, is a widely used technique that allows, in a very short time, to screen biological samples and to identify its specific spectral signature, being an important tool for clinical diagnosis and biomarker discovery. FTIR spectroscopy is used to screen cells, tissues and biofluids and is already implemented in biomedicine, mainly in pre-clinical setting. Although the experimental procedure is easy to implement, sample preparation, definition of spectra acquisition parameters and spectral analysis are crucial steps to obtain reliable and reproducible results. However, the selection of experimental conditions for spectral analysis can be a difficult task for researchers because the information is dispersed and often the choice is made in an empirical and inaccurate way. This review gathers and summarizes studies using FTIR in pre-clinical and clinical setting and aims to systematize information and propose some guidelines for FTIR spectroscopy studies of biological samples. This will help new users to prepare samples for FTIR analysis and understand the critical steps to correctly perform spectra pretreatment, preprocessing and statistical analysis and to implement appropriate and evidence-based experimental designs.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86446258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Raman spectroscopy in the diagnosis of metabolic syndrome 拉曼光谱在代谢综合征诊断中的应用
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-06-30 DOI: 10.1080/05704928.2021.1944175
Guadalupe Donjuán-Loredo, R. Espinosa‐Tanguma, M. Ramírez-Elías
{"title":"Raman spectroscopy in the diagnosis of metabolic syndrome","authors":"Guadalupe Donjuán-Loredo, R. Espinosa‐Tanguma, M. Ramírez-Elías","doi":"10.1080/05704928.2021.1944175","DOIUrl":"https://doi.org/10.1080/05704928.2021.1944175","url":null,"abstract":"Abstract Metabolic syndrome (MetS) is defined as a set of metabolic disorders, including central obesity, dyslipidemia, arterial hypertension, and hyperglycemia. The prevalence of MetS is increasing in epidemic proportions in both developed and developing countries. MetS increment has been paralleled by the growing epidemic of type-2 diabetes, hypertension, cardiovascular disease, and obesity. Raman spectroscopy is a noninvasive optical technique that has been used in MetS and associated diseases as an alternative to more invasive routine laboratory studies. Raman Spectroscopy's medical diagnosis application is based on the fact that the molecular composition of healthy tissues or biofluids changes due to disease. Identifying biomarkers with this technique can be used for early diagnosis, monitoring disease evolution, and response to treatment. This article reviews recent applications which demonstrate the potential of Raman spectroscopy in the assessment of MetS diseases.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80491666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Vibrational spectroscopy and its future applications in microbiology 振动光谱学及其在微生物学中的应用前景
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-06-28 DOI: 10.1080/05704928.2021.1942894
M. Jansson, Martin Kögler, S. Hörkkö, T. Ala-Kokko, L. Rieppo
{"title":"Vibrational spectroscopy and its future applications in microbiology","authors":"M. Jansson, Martin Kögler, S. Hörkkö, T. Ala-Kokko, L. Rieppo","doi":"10.1080/05704928.2021.1942894","DOIUrl":"https://doi.org/10.1080/05704928.2021.1942894","url":null,"abstract":"Abstract Vibrational spectroscopic techniques, namely Fourier transform infrared (FTIR) and Raman spectroscopy, are based on the study of molecular vibrations, and they are complementary techniques to each other. This review provides an overview of the vibrational spectroscopic techniques applied in microbiology during the past decade. In addition, future applications of the elaborated spectroscopic techniques will be highlighted. The results of this review show that both FTIR and Raman spectroscopy are promising alternatives to conventional diagnostic approaches because they provide label-free and noninvasive bacterial detection, identification, and antibiotic susceptibility testing in a single step. Cost-effective, accurate, and rapid tests are needed in order to improve diagnostics and patient care, to decrease the use of unnecessary antimicrobial agents, to prevent resistant microbials, and to decrease the overall burden of outbreaks. Prior to that, however, the presented approaches need to be validated in a clinical workflow against the conventional diagnostic approaches.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90322200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Application of multiple spectral systems for the tree disease detection: A review 多光谱系统在树木病害检测中的应用综述
IF 6.1 2区 化学
Applied Spectroscopy Reviews Pub Date : 2021-06-12 DOI: 10.1080/05704928.2021.1930552
Shiyan Fang, Ruiyan Cui, Yan Wang, Yanru Zhao, Keqiang Yu, Ao Jiang
{"title":"Application of multiple spectral systems for the tree disease detection: A review","authors":"Shiyan Fang, Ruiyan Cui, Yan Wang, Yanru Zhao, Keqiang Yu, Ao Jiang","doi":"10.1080/05704928.2021.1930552","DOIUrl":"https://doi.org/10.1080/05704928.2021.1930552","url":null,"abstract":"Abstract Tree diseases endanger forestry and fruit tree plantations seriously worldwide in the past decades, leading to significant economic losses for the agricultural production sector. Rapid and accurate detection of tree diseases is crucial in tree protection. Despite molecular biological detection methods have prominent specificity, they are time-consuming and laborious, and are not suitable for large-scale detection of tree diseases. Spectroscopy with nondestructive, rapid, and high throughput characteristics has been applied to plant disease detection. Spectral detection systems are divided into three categories according to the spectrometer's carrying platform: portable hand-held spectrometer, airborne vehicle-mounted spectrometer, and large laboratory spectrometer. This review summarized three main spectral detection systems and their advantages and disadvantages in detecting various diseases of forestry and fruit trees: including detection of the single disease, multiple stress, and early disease using Visible/near-infrared, Raman, and hyperspectral imaging. Finally, spectroscopy detection technology applications of challenges were summarized, highlighting future trends.","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2021-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78834484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
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