Protection of Metals and Physical Chemistry of Surfaces最新文献_第9页

Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose 基于硼酸修饰的2-甲基丙烯酸羟乙酯和乙二醇二甲基丙烯酸酯作为葡萄糖高亲和力配体的选择性吸附剂

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701022

I. S. Garkushina, A. S. Panyuta, P. Yu. Morozova, A. A. Osipenko

引用次数: 0

Low-Temperature N2 and He Separation on a HKUST-1 Membrane hust -1膜的低温氮气和He分离

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123700995

I. V. Grenev, V. Yu. Gavrilov

引用次数: 0

Adsorption Properties of Kaolinite and Montmorillonite Activated by Thermochemical Treatment 热化学活化高岭土和蒙脱土的吸附性能

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701009

A. V. Bondarenko, V. V. Bondarenko, G. A. Petukhova, L. A. Dubinina, M. L. Ruello

{"title":"Adsorption Properties of Kaolinite and Montmorillonite Activated by Thermochemical Treatment","authors":"A. V. Bondarenko, V. V. Bondarenko, G. A. Petukhova, L. A. Dubinina, M. L. Ruello","doi":"10.1134/S2070205123701009","DOIUrl":"10.1134/S2070205123701009","url":null,"abstract":"<div><div><h3>\u0000 <b>Abstract</b>\u0000 </h3><p>The article presents the results of a study of the effect of thermal acid treatment of kaolinite on increasing its adsorption activity. Previous publications have presented the results of a study of the synthesis conditions and properties of the TiO<sub>2</sub>/kaolinite material—a filler of building materials with the function of passive degradation of household organic pollutants; the studies showed a significant increase in the adsorption–structural characteristics of the composite during synthesis compared to kaolinite and titanium dioxide as separate materials. The current article is devoted to study of changes in the sorption activity of potential carriers of titanium dioxide—kaolinite and montmorillonite—as a result of thermal acid treatment, which simulates the synthesis of a composite. A significant increase in the adsorption activity of kaolinite is obtained and the inefficiency of this treatment method for montmorillonite is shown.</p></div></div>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 5","pages":"828 - 836"},"PeriodicalIF":1.1,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138431574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and Sorption Properties of Lithium Aluminosilicate 硅酸铝锂的合成及吸附性能研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701046

P. S. Gordienko, E. V. Pashnina, S. B. Yarusova, E. A. Nekhlyudova, I. G. Zhevtun, I. A. Shabalin, N. V. Zarubina, S. Yu. Budnitsky, V. G. Kuryavyi

引用次数: 0

Adsorption of Methane Vapors on a Micro-Mesoporous Carbon Adsorbent During Long-Term Storage of Liquefied Natural Gas 液化天然气长期储存过程中甲烷蒸气在微介孔碳吸附剂上的吸附

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123700971

A. E. Grinchenko, I. E. Men’shchikov, A. V. Shkolin, A. A. Fomkin

{"title":"Adsorption of Methane Vapors on a Micro-Mesoporous Carbon Adsorbent During Long-Term Storage of Liquefied Natural Gas","authors":"A. E. Grinchenko, I. E. Men’shchikov, A. V. Shkolin, A. A. Fomkin","doi":"10.1134/S2070205123700971","DOIUrl":"10.1134/S2070205123700971","url":null,"abstract":"<div><div><p><b>Abstract</b>—The study investigated the physicochemical and adsorption characteristics of a micro-mesoporous carbon adsorbent obtained from wood waste by a thermochemical method with respect to the processes of the accumulation of liquefied natural gas vapors in long-term storage systems. X-ray diffraction analysis of the adsorbent showed that, as a result of synthesis of the adsorbent, its structure was an amorphous carbon phase, without signs of graphite-like phases characteristic of coal obtained from other types of raw materials. In turn, the developed porous structure of the adsorbent is represented by both micro- and mesopores, with a wide size distribution: the total pore volume was about 1.7 cm<sup>3</sup>/g. The sorption characteristics of the adsorbent at temperatures of 111.7–160 K and pressures up to 0.6 MPa were calculated based on the linearity of experimental isotherms at <i>T</i> from 303 to 333 K and the contribution from adsorption on the surface of mesopores in the monolayer and the capillary condensation effect (CCE). Based on sorption data, it is shown that the presence of mesopores has a predominant effect on the adsorption accumulation efficiency due to the contribution of CCE, providing an active capacity of cryogenic sorption accumulators at a level of 450 m<sup>3</sup>(NTP)/m<sup>3</sup>.</p></div></div>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 5","pages":"801 - 809"},"PeriodicalIF":1.1,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138431607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Equilibrium and Kinetic Characteristics of Tryptophan Sorption onto FIBAN A-1 Fiber 色氨酸在FIBAN A-1纤维上吸附的平衡和动力学特性

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701010

E. A. Azarova, I. V. Voronyuk, T. V. Eliseeva

{"title":"Equilibrium and Kinetic Characteristics of Tryptophan Sorption onto FIBAN A-1 Fiber","authors":"E. A. Azarova, I. V. Voronyuk, T. V. Eliseeva","doi":"10.1134/S2070205123701010","DOIUrl":"10.1134/S2070205123701010","url":null,"abstract":"<div><div><h3>\u0000 <b>Abstract</b>\u0000 </h3><p>In the present study, the possibility of using a strong-base fibrous material FIBAN A-1 (Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Belarus) as a sorbent to remove tryptophan from aqueous solutions is investigated. The capacity characteristics of the anion exchangers in the form of granules and fibers containing quaternary ammonium bases as functional groups with respect to the chosen amino acid are analyzed. The influence of the pH of the medium on the sorption of amino indolylpropanoic acid onto the A-1 fiber is determined. IR spectroscopy confirms the fact of the fixation of amino acids from solutions with pH ~5.0–5.5 due to the charge exchange of the zwitterion by the OH groups of the sorbent. The specific features of both the equilibrium and kinetics of tryptophan sorption from solutions with a pH close to the isoelectric point are studied. Based on the analysis of the isotherms of sorption of the amino acid at different temperatures, a monomolecular mechanism of the sorptive sorption process and its endothermic character are established. The kinetic characteristics of tryptophan sorption indicate a significant contribution of external diffusion to the velocity of the investigated process.</p></div></div>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 5","pages":"837 - 842"},"PeriodicalIF":1.1,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138431608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Mechanism of Desorption of Pertechnetate Ions from Macroporous Vinyl Pyridinium Anion-Exchange Resin Using Tributyl Phosphate 磷酸三丁酯解吸大孔乙烯基吡啶阴离子交换树脂中高盐离子的机理研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S207020512370106X

K. A. Zagidullin, E. V. Belova, M. A. Volkov, K. E. German, B. V. Kuznetsov, S. N. Ryagin, A. Yu. Tsivadze

{"title":"A Mechanism of Desorption of Pertechnetate Ions from Macroporous Vinyl Pyridinium Anion-Exchange Resin Using Tributyl Phosphate","authors":"K. A. Zagidullin, E. V. Belova, M. A. Volkov, K. E. German, B. V. Kuznetsov, S. N. Ryagin, A. Yu. Tsivadze","doi":"10.1134/S207020512370106X","DOIUrl":"10.1134/S207020512370106X","url":null,"abstract":"<p>Based on kinetic studies, a mechanism for the elution of technetium from an anion-exchanger in the form of an extractable complex with tributyl phosphate (TBP) has been suggested for the purpose of improving the ion exchange technology of the technetium extraction by elution of technetium-99 from VP-1AP anion exchange resin with a TBP solution. The effect of diluents and extraction reagents on the quantitative desorption of pertechnetate has been studied. It has been found that the process of desorption of pertechnetate ions from the VP-1AP anion-exchanger can be described by equations characteristic of the film kinetics of elution, which is caused by the presence of an additional stage of transfer of the substance across the phase interface from the phase of an aqueous solution associated with anion-exchanger to the phase of organic extracting eluent. Based on the conducted studies, the possibility of improving the existing sorption technology of technetium isolation has been demonstrated.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 5","pages":"876 - 892"},"PeriodicalIF":1.1,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138431609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Layered Double Zinc and Aluminum Hydroxide Intercalated with Hexacyanoferrate(II) Ions for Extraction of U(VI) from Liquid Media 层状双锌-氢氧化铝插层六氰铁酸盐(II)离子萃取液体介质中铀(VI

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701058

N. P. Ivanov, A. N. Drankov, E. K. Papynov, A. O. Lembikov, V. Yu. Mayorov, A. N. Fedorets, G. D. Kaspruk

{"title":"Layered Double Zinc and Aluminum Hydroxide Intercalated with Hexacyanoferrate(II) Ions for Extraction of U(VI) from Liquid Media","authors":"N. P. Ivanov, A. N. Drankov, E. K. Papynov, A. O. Lembikov, V. Yu. Mayorov, A. N. Fedorets, G. D. Kaspruk","doi":"10.1134/S2070205123701058","DOIUrl":"10.1134/S2070205123701058","url":null,"abstract":"<div><div><p><b>Abstract</b>—Layered double zinc and aluminum hydroxide modified with hexacyanoferrate(II) ions was synthesized for the first time by reverse deposition. The obtained samples were studied by X-ray phase analysis, scanning electron microscopy, and low-temperature nitrogen adsorption, and their sorption characteristics with respect to uranium U(VI) were studied. The sorption capacity for the modified material under static conditions, determined by the Langmuir equation, was <span>(q_{{max }}^{{~l}})</span> = 156.70 ± 12.38 mg/g (at phase ratio <i>V</i>/<i>m</i> = 1000 mL/g, in a monocomponent solution of uranyl nitrate UO<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub> at a temperature <i>T</i> = 25°C and sorption time <i>t</i> = 24 h). Layered double zinc and aluminum hydroxide modified with hexacyanoferrate(II) ions is a promising sorbent for purification of liquid media from uranium U(VI) due to its high capacity and specific surface area, the possibility of effective use in a wide range of pH [4, 10], and low cost.</p></div></div>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 5","pages":"868 - 875"},"PeriodicalIF":1.1,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138431633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Morphology of Phthalocyanine Nanostructures Localized in the Structure of a Latex Polymer 乳胶聚合物结构中酞菁纳米结构的形态

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701101

T. R. Aslamazova, V. A. Kotenev, A. Yu. Tsivadze

引用次数: 0

On the Structure of Thin Spectral-Selective Thermal Oxide Coatings on the Surface of X18N10T Steel X18N10T钢表面薄谱选择性热氧化膜的结构研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-11-24 DOI: 10.1134/S2070205123701071

V. A. Kotenev

引用次数: 0