Microplastics and nanoplastics最新文献

{"title":"Evaluating the effectiveness of the MicroPlastic Sediment Separator (MPSS)","authors":"J. Prume, Hannes Laermanns, Martin G. J. Löder, Christian Laforsch, Christina Bogner, Martin Koch","doi":"10.1186/s43591-023-00073-3","DOIUrl":"https://doi.org/10.1186/s43591-023-00073-3","url":null,"abstract":"","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"114 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139246717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Legacy oceanic plastic pollution must be addressed to mitigate possible long-term ecological impacts","authors":"Camille Richon, Karin Kvale, Laurent Lebreton, Matthias Egger","doi":"10.1186/s43591-023-00074-2","DOIUrl":"https://doi.org/10.1186/s43591-023-00074-2","url":null,"abstract":"Abstract Scientific research over the past decade has demonstrated that plastic in our oceans has detrimental consequences for marine life at all trophic levels. As countries negotiate an international legally binding instrument on plastic pollution, the focus is on eliminating plastic emissions to the environment. Here, we argue that, while this endeavour is urgently needed to limit the negative impacts of plastic on ocean ecosystems, the reduction of the plastic flow to the environment should not be the sole purpose of the negotiations. Legacy oceanic plastic pollution is also a major concern that needs to be addressed in the coming Treaty. Plastic is ubiquitous and persistent in the environment, and its slow degradation produces uncountable amounts of potentially even more impactful micro- and nanoparticles. Thus, plastic that is already present in the oceans may continue to affect ecosystems for centuries. Recent global assessments reveal that microplastics could have a significant impact on biogeochemical cycles and microbial food chains within ocean ecosystems that may be equivalent to those of climate change. Therefore, we argue that cleanup initiatives are essential to avoid further longterm impacts of legacy oceanic pollution. The upcoming international negotiations to develop a new Global Plastics Treaty should aim at urgently reducing the flow of plastic to the marine environment while supporting innovative solutions towards efficient monitoring and cleanup of the legacy oceanic plastic pollution.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"56 9","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136346876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental Validation of the Microplastic Index—Two Approaches to Understanding Microplastic Formation","authors":"Kalouda Grigoriadi, Merel G. A. Nooijens, Ali Emre Taşli, Max M. C. Vanhouttem, Sieger Henke, Luke A. Parker, Jan Harm Urbanus, Arjen Boersma","doi":"10.3390/microplastics2040027","DOIUrl":"https://doi.org/10.3390/microplastics2040027","url":null,"abstract":"The Microplastic Index (MPI) was presented in a previous paper as a method to assess the formation of microplastics during the application of impact and wear stresses, based on selected mechanical and physical properties of polymers. In this paper, the experimental validation of the MPI model is presented. A series of ten polymers was characterized to obtain the relevant parameters for the calculation of the MPI, i.e., the minimum particle size and volume of microplastics formed. The milling (addressing impact stress) and sanding experiments (addressing wear stress) resulted in particle sizes between 3 and 200 μm and 0.3 and 25 μm, respectively. These values were very well predicted by the MPI model, showing smaller particles for brittle polymers and larger ones for ductile polymers. In addition, the experimental-specific wear rates of impact and wear correlated well with the predicted ones, being 0.01–30 mm3/Nm for impact and 0.0002–0.012 mm3/Nm for wear. These results indicate that the MPI can be very well used to predict the tendency of a material to form microplastics. In the search for understanding and mitigating microplastic formation, the MPI can be used by both producers and end users to choose plastic grades that form fewer microplastics.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"9 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135819066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fast Forward: Optimized Sample Preparation and Fluorescent Staining for Microplastic Detection","authors":"Michael Toni Sturm, Erika Myers, Anika Korzin, Sabrina Polierer, Dennis Schober, Katrin Schuhen","doi":"10.3390/microplastics2040026","DOIUrl":"https://doi.org/10.3390/microplastics2040026","url":null,"abstract":"The fast, affordable, and standardized detection of microplastics (MP) remains one of the biggest challenges in MP research. Comparable data are essential for appropriate risk assessments and the implementation of laws and limit values. The fluorescent staining of MP in environmental samples is a possible solution to this problem. This study investigates the optimization of a sample preparation process (hydrogen peroxide digestion) and the staining process (temperature, concentration, time, surfactants as staining aids) for using a specifically developed fluorescent dye for MP detection. The optimization is performed by comparing the sample preparation process and staining of MP from different polymers and natural particles. Further, the suitability of the optimized process for the detection of fluoropolymers and tire abrasion was tested. The results show that the optimized method (increased temperature and optimized stain concentration) can detect microplastics reliably with a total sample preparation and measurement time of 2.5–3 h per sample, reaching recovery rates of 93.3% (polypropylene) to 101.7% (polyester). Moreover, two of the three tested fluoropolymers could be detected reliably. Tire abrasion could not be detected with the here presented method, as the black color leads to strong quenching. A long-term study measuring the MP pollution in the effluent of a municipal wastewater treatment plant compared the optimized and original processes and confirmed the stability of the improved method for routine measurements and contamination control.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"24 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135462031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Comparing Methods for Microplastic Quantification Using the Danube as a Model","authors":"Tim Kiefer, Martin Knoll, Andreas Fath","doi":"10.3390/microplastics2040025","DOIUrl":"https://doi.org/10.3390/microplastics2040025","url":null,"abstract":"This study investigates the impact different mesh-sized filtration methods have on the amount of detected microplastics in the surface water of the Danube River delta. Further, the distribution of microplastics in different size categories (20 µm, 65 µm, 105 µm) and in the water column (0 m, 3 m, 6 m) was analyzed. Our findings show that the Danube River carries 46 p∙L−1 (microplastic particles per liter) with a size larger than 105 µm, 95 p∙L−1 larger than 65 µm and 2677 p∙L−1 that are larger than 20 µm. This suggests a negative logarithmic correlation between mesh size and particle amount. The most abundant polymer throughout all samples was polyethylene terephthalate, followed by polytetrafluorethylene. Overall, the data shows that different sampling methods cannot be compared directly. Further research is needed to find correlations in particle sizes for better comparison between different sampling methods.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135993117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of different Wastewater Treatment Processes on the rate and characteristics of MPs released from WWTPs in Fiji, South Pacific","authors":"Malelili Naulivou Rokomatu, Geetika Bhagwat-Russell, Logeshwaran Panneerselvan, Subash Raju, Viliame Savou, Timaima Waqainabete, Thavamani Palanisami","doi":"10.1186/s43591-023-00068-0","DOIUrl":"https://doi.org/10.1186/s43591-023-00068-0","url":null,"abstract":"Abstract The global effects of MP (MP) pollution on the environment are concerning, and they are exacerbated by the multiple sources of pollution in aquatic environments such as urban runoff, waste mismanagement, industrial pollution, and so on. South pacific islands host a large diversity of aquatic flora and fauna and given its ecological significance it is necessary to identify the sources of MP pollution in the region. To date, very little attention has been given to identify whether effluents from wastewater treatment plants (WWTP) are acting as a significant source of MP in the South Pacific region and its countries. Therefore, the present study analyzed and compared the treatment methods and fate of MPs in the country’s two main WWTPs: 1) the Kinoya WWTP (simple secondary clarifier and trickling filter) and 2) Natabua WWTP (secondary pond treatment system). Sampling locations were based on the different treatment stages, and samples were collected from each stage of treatment before effluents were released into the ocean. Kinoya WWTP had an average of 3.45 ± 0.3 particles/L in the inlet stage and released an average of 0.3 ± 0.26 particles/L of MP through the outlet with 91% removal efficiency (RE) with an output equivalent of 4500 particles per day. The initial stage of treatment from the anaerobic pond outlet at Natabua had an average of 2.9 ± 1.05 particles/L, and the maturation outlet had an average of 0.53 ± 0.42 particles/L, a removal efficiency of 81% and thus an output equivalent of 4558 particles/L of MP. Polymer analysis under FTIR confirmed that cellophane or semi-synthetic cellulose and polypropylene were common polymers in the final effluent in Kinoya WWTP, and Natabua plant has cellophane or semi-synthetic cellulose, polypropylene and polyethylene were observed as common polymers. Although there are numerous study that have compared wastewater treatment processes, this is the first study in Fiji that investigates the efficiency of the two methods of water treatment process in the context of microplastic pollution and emphasizes the effectiveness of the treatment stages in determining the concentration of MP released into the ocean.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"69 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135346022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Estimating species sensitivity distributions for microplastics by quantitively considering particle characteristics using a recently created ecotoxicity database","authors":"Yuichi Iwasaki, Kazutaka M. Takeshita, Koji Ueda, Wataru Naito","doi":"10.1186/s43591-023-00070-6","DOIUrl":"https://doi.org/10.1186/s43591-023-00070-6","url":null,"abstract":"Abstract Estimation of a species sensitivity distribution (SSD) by fitting a statistical distribution to ecotoxicity data is a promising approach to deriving “safe” concentrations for microplastics. However, most existing SSDs do not quantitatively consider the diverse characteristics of microplastics, such as particle size and shape. To address this issue, based on 38 mass-based chronic no observed effect concentrations (NOECs) obtained from a recently created database, we estimated SSDs that quantitatively consider the influences of three types of microplastic characteristics (particle length, shape, and polymer type) and habitat of the test species (freshwater vs. marine) by using Bayesian modeling. We selected the best SSD model among all possible models using the widely applicable information criterion. The best SSD model included particle length (range: 0.05–280 μm) and a binary dummy variable corresponding to the fiber shape. Lower chronic NOECs were associated with decreasing particle size and with toxicity tests that included fibers in this model. Combined with the fact that the null model (i.e., an SSD model with no predictor variable) was ranked 27th among the 64 candidate SSD models, our results support the need to incorporate particle characteristics such as length and shape (e.g., fiber) into estimations of SSDs for microplastics. The medians of the hazardous concentration of 5% of species (HC5) for microplastic spheres and fragments, estimated by the posterior distributions of individual parameters in the best SSD model, ranged from 0.02 to 2 µg/L, depending on the particle length (0.1–100 μm). For microplastic fibers, the HC5 values were estimated to be approximately 100 times lower than those for microplastic spheres and fragments with the same particle length. However, the 95% Bayesian credible intervals for HC5 estimates for fibers were considerable, expanded by up to five orders of magnitude. Despite many remaining challenges, the Bayesian SSD modeling utilized in this study provides unique opportunities to simultaneously investigate the influences of multiple microplastic characteristics on the NOECs of multiple species, which would otherwise be difficult to discern.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135791685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigating the correlation between morphological features of microplastics (5–500 µm) and their analytical recovery","authors":"O. Hagelskjær, A. Crézé, G. Le Roux, J. E. Sonke","doi":"10.1186/s43591-023-00071-5","DOIUrl":"https://doi.org/10.1186/s43591-023-00071-5","url":null,"abstract":"Abstract As a direct result of laboratory sample manipulation required to identify microplastics (MPs) within a given matrix, some MPs are inevitably lost. The extent of this loss can be quite significant and varies greatly depending on the sample matrix, choice of protocol and target MPs in question. Defining analytical MP recovery is therefore a critical component in ensuring the quality of MP protocols. The potential relationship between particle size and recovery rate has been widely discussed but remains uncertain. To determine whether MP loss correlated with particle size, three aliquots of polyethylene fragments in the 5–50 µm size range and three aliquots of polypropylene fragments in the 50–500 µm size range, were consecutively transferred back and forth from filter to liquid. After each individual transfer the analytical recovery within specified size groups, was evaluated by applying high-resolution darkfield microscopy. Average recovery across the entire size range was estimated at 80% with a standard deviation (std. dev.) of 26%. Notably, particle coverage on filters (A%) showed a more significant impact on recovery than particle size. Maintaining A% below 5% on filters for microscopic analysis is advised to prevent excessive loss due to particle agglomeration. To determine whether the use of red polyethylene fragments in the 5–50 µm size range in combination with darkfield microscopy could potentially improve MP recovery evaluation in environmental samples, three aliquots of 0.5 g of dry brown trout muscle tissue were spiked and treated according to a relevant protocol. This size-discriminating approach accurately determined average recovery at 52% with a std. dev. of 4% and demonstrated the potential for correction of the concentration enhancement of smaller MPs resulting from particle breakup during sample pre-treatment, which would otherwise lead to overestimation of smaller size fractions.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134960209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Accuracy of a Simple Microplastics Investigation Method on Sandy Beaches","authors":"Hiroshi Asakura","doi":"10.3390/microplastics2030024","DOIUrl":"https://doi.org/10.3390/microplastics2030024","url":null,"abstract":"Environmental pollution by microplastics (MPs) has become a growing concern, and not only professional researchers but also the citizenry are needed to understand the pollution situation and to confirm the decreasing trend of MP pollution as a result of the global reduction in plastic use. In this study, the author evaluated the accuracy of a simple method of investigating MPs on sandy beaches that can be conducted even by high school students. In a land survey using simple tools such as a tape measure and cardboard, the maximum coefficient of variation is approximately 1%. Even without heavy liquid, 89% of MPs could be recovered using only seawater. An investigation of MP content by sampling 0.5 cm of the surface layer of sand could explain more than half of the MP content when the sand was sampled to a depth of approximately 50 cm below the surface layer. A method in which the recovered MPs are not visually sorted but floating matter after boiling is considered as MPs is acceptable. If there was no concern about pumice contamination, the overestimation was approximately 1.5 times. Simple laboratory equipment such as buckets, sieves, seawater, hot plates, dryers, and electronic balances could achieve lower limits of quantification of MPs of 13 mg-MPs/m2-sand and 2 mg-MPs/kg-sand.","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":"36 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135259551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An assessment of methods used for the generation and characterization of cryomilled polystyrene micro- and nanoplastic particles","authors":"Campbell J. McColley, J. A. Nason, B. Harper, Stacey L. Harper","doi":"10.1186/s43591-023-00069-z","DOIUrl":"https://doi.org/10.1186/s43591-023-00069-z","url":null,"abstract":"","PeriodicalId":74190,"journal":{"name":"Microplastics and nanoplastics","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46934313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}