Adsorption Science & Technology最新文献

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Efficient Removal of Paraquat Pollutants Using Magnetic Biochar Derived from Corn Husk Waste: A Sustainable Approach for Water Remediation 利用玉米壳废弃物提取的磁性生物炭高效去除百草枯污染物:一种可持续的水修复方法
4区 工程技术
Adsorption Science & Technology Pub Date : 2023-09-15 DOI: 10.1155/2023/5512881
Sakonsupa Damdib, Adisak Siyasukh, Bhawaranchat Vanichsetakul, Phamornsiri Phamornpiboon, Chanchana Thanachayanont, Patiparn Punyapalakul, Nattaporn Tonanon
{"title":"Efficient Removal of Paraquat Pollutants Using Magnetic Biochar Derived from Corn Husk Waste: A Sustainable Approach for Water Remediation","authors":"Sakonsupa Damdib, Adisak Siyasukh, Bhawaranchat Vanichsetakul, Phamornsiri Phamornpiboon, Chanchana Thanachayanont, Patiparn Punyapalakul, Nattaporn Tonanon","doi":"10.1155/2023/5512881","DOIUrl":"https://doi.org/10.1155/2023/5512881","url":null,"abstract":"Due to the widespread production of maize, the waste created by this crop has become a serious concern. This study applied the concept of waste circulation to the production of magnetic biochar from corn husk waste to remediate paraquat-contaminated water. Magnetic biochar (MB) was produced by impregnating maize husks with iron and carbonizing the residue in a nitrogen environment. Carbonized MB at the temperature of 850°C (MB-01-850) exhibited a combination of microporous and mesoporous structures ( <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M1\"> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mtext>meso</mtext> </mrow> </msub> <mo>=</mo> <mn>0.30</mn> <mtext> </mtext> <mtext>c</mtext> <msup> <mrow> <mtext>m</mtext> </mrow> <mrow> <mn>3</mn> </mrow> </msup> <mo>/</mo> <mtext>g</mtext> </math> , <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M2\"> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mtext>micro</mtext> </mrow> </msub> <mo>=</mo> <mn>0.12</mn> <mtext> </mtext> <mtext>c</mtext> <msup> <mrow> <mtext>m</mtext> </mrow> <mrow> <mn>3</mn> </mrow> </msup> <mo>/</mo> <mtext>g</mtext> </math> ), while biochar created only a microporous structure ( <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M3\"> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mtext>micro</mtext> </mrow> </msub> <mo>=</mo> <mn>0.11</mn> <mtext> </mtext> <mtext>c</mtext> <msup> <mrow> <mtext>m</mtext> </mrow> <mrow> <mn>3</mn> </mrow> </msup> <mo>/</mo> <mtext>g</mtext> </math> ). According to the findings, Fe(NO3)3 significantly affected the increase in mesopore formation after carbonization. In addition, biochar exhibits excellent magnetic responsiveness. MB-01-850 reached equilibrium within approximately 20 min in synthetic water. Batch adsorption studies showed that MB-01-850 had maximum adsorption capacities ( <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M4\"> <msub> <mrow> <mi>Q</mi> </mrow> <mrow> <mn>0</mn> </mrow> </msub> </math> ) of 34.97 mg/g and 31.63 mg/g for synthetic and natural water, respectively. The unmodified biochar (without mesopores) had a <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M5\"> <msub> <mrow> <mi>Q</mi> </mrow> <mrow> <mn>0</mn> </mrow> </msub> </math> of 4.08 mg/g. This indicates that the presence of mesopores improves the effectiveness of paraquat adsorption. Additionally, the adsorption performance of magnetic biochar exhibited no statistically significant variance when tested under natural water conditions. Furthermore, magnetic biochar demonstrates impressive regeneration capacity, allowing it to be regenerated almost entirely for a minimum of four cycles using a sodium hydroxide (NaOH) solution with a concentration equal to or greater than 0.5 M.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":"96 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135394687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater 原位成形MnFe2O4/D201磁性复合吸附剂对废水中As(V)的高选择性吸附及深度处理
4区 工程技术
Adsorption Science & Technology Pub Date : 2023-04-21 DOI: 10.1155/2023/9084244
Shaopeng Zhang, Jie Ding, Dayong Tian, Feifei Liu, Qiaoling Li, Minghua Lu
{"title":"In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater","authors":"Shaopeng Zhang, Jie Ding, Dayong Tian, Feifei Liu, Qiaoling Li, Minghua Lu","doi":"10.1155/2023/9084244","DOIUrl":"https://doi.org/10.1155/2023/9084244","url":null,"abstract":"A new magnetic adsorbent, namely, MnFe2O4/D201, with deep-treatment ability and high selectivity adsorption for As(V) was prepared. According to isotherm adsorption and kinetics, As(V) adsorption is primarily used for chemical bonding throughout the single-layer adsorbing process. The maximum As(V) adsorption capacity of MnFe2O4/D201 can reach 35.8 mg/g at pH 3. MnFe2O4/D201 also exhibits higher selectivity adsorption against Cl-, NO3-, SO42-, and PO43-. According to the thermodynamic results, the adsorption process was spontaneous and endothermic. The adsorption capacity is maintained at 81% of the initial after ten adsorption-desorption cycles. As(V) concentrations ranging from 1 mg/L to 10 μg/L can be treated in fixed-bed column experiments. The effectual cure volume of As(V) reaches 1332 BV (26.64 L). The removal mechanism primarily comprises electrostatic attraction and complexation.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":"4 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135518803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
NO2 Gas Sensing Properties of Ag-Functionalized Porous ZnO Sheets ag功能化多孔ZnO片的NO2气敏性能
4区 工程技术
Adsorption Science & Technology Pub Date : 2023-01-19 DOI: 10.1155/2023/9021169
Min Young Kim, Jeong Yun Hwang, Ali Mirzaei, Sun-Woo Choi, Sang-il Kim, Hyun-Sik Kim, Sun-Jae Kim, Jong Wook Roh, Myung Sik Choi, Kyu Hyoung Lee, Seung Yong Lee, Changhyun Jin
{"title":"NO2 Gas Sensing Properties of Ag-Functionalized Porous ZnO Sheets","authors":"Min Young Kim, Jeong Yun Hwang, Ali Mirzaei, Sun-Woo Choi, Sang-il Kim, Hyun-Sik Kim, Sun-Jae Kim, Jong Wook Roh, Myung Sik Choi, Kyu Hyoung Lee, Seung Yong Lee, Changhyun Jin","doi":"10.1155/2023/9021169","DOIUrl":"https://doi.org/10.1155/2023/9021169","url":null,"abstract":"Herein, we report a simple and scalable synthesis route to prepare Ag-functionalized porous ZnO sheets and their enhanced NO2 gas sensing properties. Porous ZnO sheets functionalized with well-dispersed submicron Ag particles were prepared by using a hydrothermal method-based one-pot synthesis route from Zn and Ag precursors. NO2 gas sensing performance (response, selectivity, response time, and recovery time) was optimized at 200°C in the gas sensor fabricated with 3 at% Ag-functionalized porous ZnO sheets. We demonstrated a response ( <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M1\"> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>g</mi> </mrow> </msub> </math> / <math xmlns=\"http://www.w3.org/1998/Math/MathML\" id=\"M2\"> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>a</mi> </mrow> </msub> </math> ) of 17.18 to 10 ppm NO2 gas and also obtained a high response of 14.05 even at 60% relative humidity due to the synergetic effect of improved NO2 gas adsorption in the presence of Ag particles and increased resistance by the formation of Schottky barrier at Ag-ZnO heterojunctions.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135250843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
A Brief Review on Heavy Metal Bioaccumulation Studies from Red Sea 红海重金属生物富集研究综述
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-21 DOI: 10.1155/2022/6201299
Hassien M. Alnashiri
{"title":"A Brief Review on Heavy Metal Bioaccumulation Studies from Red Sea","authors":"Hassien M. Alnashiri","doi":"10.1155/2022/6201299","DOIUrl":"https://doi.org/10.1155/2022/6201299","url":null,"abstract":"The Red Sea forms an important marine ecosystem with its rich species diversity and the different ecosystems, including the coral reefs. The region has received relatively less heavy metal pollution owing to comparatively lesser industrial pollution. This study attempts to review the records of heavy metal bioaccumulation reported in the last two decades. This review is an endeavour to audit the heavy metal bioaccumulation, revealed over the past twenty years, such as As, Cr, Cu, Fe, Cd, Hg, Mn, Zn Ni, Co, Se, and Pb, as reported from various regions of the Red Sea in organisms such as plankton, molluscs, crustaceans, and fish. Though the results of various studies reviewed here are not comparable to each other due to differences in organisms, types of tissues studied, and different methods of analysis as well as nature of their inhabiting sites, this review will be a baseline data of the heavy metal bioaccumulation, which can help in future evaluation in the context of the rapid developmental activity prevalent in the coasts of the Red Sea. The findings compiled emphasize the need for a comprehensive biomonitoring program that can conserve the unique biodiversity of the Red Sea.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46649389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Enhanced CO2 Adsorption and Selectivity of CO2/N2 on Amine@ZIF-8 Materials 增强的CO2吸附和CO2/N2在Amine@ZIF-8材料
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-17 DOI: 10.1155/2022/3207986
Zhijuan Zhang, Pengwei Li, Ting Zhao, Yuanhan Xia
{"title":"Enhanced CO2 Adsorption and Selectivity of CO2/N2 on Amine@ZIF-8 Materials","authors":"Zhijuan Zhang, Pengwei Li, Ting Zhao, Yuanhan Xia","doi":"10.1155/2022/3207986","DOIUrl":"https://doi.org/10.1155/2022/3207986","url":null,"abstract":"The ZIF-8 crystals were successfully postsynthetically modified using methylamine (MA), ethylenediamine (ED), and N, N\u0000 \u0000 \u0000 \u0000 \u0000 ′\u0000 \u0000 \u0000 \u0000 -dimethylethylenediamine (MMEN) to improve their adsorption performance toward CO2. Results showed that, compared with the original ZIF-8, the BET specific surface area of MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 has increased by 118.2%, 92.0%, and 29.8%, respectively. In addition, their total pore volume increased separately by 130.8%, 100%, and 48.7%. The adsorption capacities of CO2 on the amine-modified ZIF-8 samples followed the order \u0000 \u0000 MA\u0000 −\u0000 ZIF\u0000 −\u0000 8\u0000 >\u0000 MMEN\u0000 −\u0000 ZIF\u0000 −\u0000 8\u0000 >\u0000 ED\u0000 −\u0000 ZIF\u0000 −\u0000 8\u0000 >\u0000 ZIF\u0000 −\u0000 8\u0000 \u0000 . The CO2 adsorption capacities at 298 K on MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 were increased by 118.2%, 90.2%, and 29.8%, respectively. What is more, the CO2/N2 selectivities calculated using an IAST model of the amine@ZIF-8 samples at 0.01 bar and 298 K were also significantly improved and followed the order \u0000 \u0000 MA\u0000 −\u0000 ZIF\u0000 −\u0000 8\u0000  \u0000 \u0000 \u0000 31.4\u0000 \u0000 \u0000 >\u0000 ED\u0000 −\u0000 ZIF\u0000 −\u0000 8\u0000  \u0000 \u0000 \u0000 25.1\u0000 \u0000 \u0000 >\u0000 MMEN\u0000 −\u0000 ZIF\u0000 −\u0000 8\u0000  \u0000 \u0000 \u0000 14.1\u0000 \u0000 \u0000 >\u0000 ZIF\u0000 −\u0000 8\u0000  \u0000 \u0000 \u0000 11.5\u0000 \u0000 \u0000 \u0000 , which increased by 173.0%, 121.4%, and 22.6%, respectively. The isosteric heat of CO2 adsorption (\u0000 \u0000 \u0000 \u0000 Q\u0000 \u0000 \u0000 st\u0000 \u0000 \u0000 \u0000 ) on the MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 all becomes higher, while \u0000 \u0000 \u0000 \u0000 Q\u0000 \u0000 \u0000 st\u0000 \u0000 \u0000 \u0000 of N2 on these samples was slightly lower in comparison with that on the ZIF-8. Furthermore, after six recycle runs of gravimetric CO2 adsorption-desorption on MA-ZIF-8, the adsorption performance of CO2 is still very good, indicating that the MA-ZIF-8 sample has good regeneration performance and can be applied into industrial CO2 adsorption and separation.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45839127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
On the Behavior of Newly Synthesized Functionalized Imidazolium-Based Ionic Liquids for Highly Efficient Extraction and Separation of Pirimicarb from Orchard Real Wastewater 新合成的功能化咪唑基离子液体对果园工业废水中吡虫威的高效萃取分离性能研究
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-17 DOI: 10.1155/2022/2441212
Sana Zulfiqar, U. Rafique, M. J. Akhtar, H. Hamad
{"title":"On the Behavior of Newly Synthesized Functionalized Imidazolium-Based Ionic Liquids for Highly Efficient Extraction and Separation of Pirimicarb from Orchard Real Wastewater","authors":"Sana Zulfiqar, U. Rafique, M. J. Akhtar, H. Hamad","doi":"10.1155/2022/2441212","DOIUrl":"https://doi.org/10.1155/2022/2441212","url":null,"abstract":"The presence of pirimicarb compounds as pollutants in orchard wastewater has sparked rising worries about their detrimental impacts on the ecosystem and human health, and their removal is critical for Pakistan’s aquatic environment. It not only contaminates fruit, but it also leaches into the soil and contaminates groundwater. However, there is little data on the effective removal of pirimicarb from orchard wastewater. The main purpose of this study is to create a novel family of functionalized imidazolium-based ionic liquids (ILs) using a simple chemical process, which will be utilized for the first time to extract pirimicarb from orchard wastewater in an efficient, cost-effective, and environmentally acceptable manner. FTIR, SEM, XRD, TGA, BET, and 1H NMR spectroscopy were used to characterize the functionalized samples. The impact of the IL substituent on the separation capacity was studied. In addition, the extraction and separation of pirimicarb from orchard wastewater were investigated under a variety of conditions (time, concentration, and temperature) in order to better understand the adsorption behaviors of distinct ILs in an aqueous solution. The adsorption equilibrium was reached in 30 minutes, and the maximum removal of pirimicarb was achieved utilizing the synthesized [C2im][C3H6NH2]Br-, according to the data. The pseudo-first-order model and the Langmuir model both suit well with the adsorption mechanism of pirimicarb with very good adsorptive capacities. Thermodynamic analyses indicated spontaneous, endothermic, and entropy-driven adsorption processes. The synthesized imidazolium-based ILs have good regeneration capability and recycling at least for six adsorption-desorption runs and have also been used to successfully detect pirimicarb orchard wastewater samples. The superior safety of the proposed method nominates it as a promising future strategy for pollution prevention. Consequently, this work has proven that the pirimicarb adsorption to various imidazolium-based ILs was dependent on the structures of the produced imidazolium-based ILs, which specifies its potential for practical applications in water pollutant removal and environmental remediation.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48621453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
The Use of Gigantochloa Bamboo-Derived Biochar for the Removal of Methylene Blue from Aqueous Solution 利用竹衍生生物炭去除水溶液中的亚甲蓝
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-14 DOI: 10.1155/2022/8245797
N. Suhaimi, M. R. R. Kooh, C. Lim, Chung-Ting Chou Chao, Y. Chou Chau, A. H. Mahadi, H. Chiang, Nurul Hazimah Haji Hassan, Roshan Thotagamuge
{"title":"The Use of Gigantochloa Bamboo-Derived Biochar for the Removal of Methylene Blue from Aqueous Solution","authors":"N. Suhaimi, M. R. R. Kooh, C. Lim, Chung-Ting Chou Chao, Y. Chou Chau, A. H. Mahadi, H. Chiang, Nurul Hazimah Haji Hassan, Roshan Thotagamuge","doi":"10.1155/2022/8245797","DOIUrl":"https://doi.org/10.1155/2022/8245797","url":null,"abstract":"In this study, locally grown bamboo (Gigantochloa spp.) was used as feedstock for pyrolysis production of biochar under various pyrolysis temperatures (400–800°C). The resultant biochars were tested for their performance in adsorptive removal of the methylene blue (MB) dye. The scope of the adsorption experiment includes the effects of adsorbent dosage, solution pH, initial adsorbate concentration, and contact time. The adsorption data confirmed that pyrolysis temperature has a significant effect on adsorptive performance, whereas biochar pyrolysed at 500°C (BC500) has the highest adsorptive performance with the maximum adsorption capacity (derived from the Langmuir model) being 86.6 mg g-1. Basic characterisations (SEM, EDX, XRD, FTIR, and BET) were carried out for BC500 where FTIR and SEM confirmed the adsorption of MB onto the biochar, while the BET data showed the reduction of the BET surface area, total pore volume, and pore diameter after the adsorption process.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48114685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 38
Development of Active CO2 Emission Control for Diesel Engine Exhaust Using Amine-Based Adsorption and Absorption Technique 胺基吸附吸收技术用于柴油机尾气主动CO2排放控制的研究进展
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-14 DOI: 10.1155/2022/8803585
S. Muthiya, L. Natrayan, L. Yuvaraj, Mohankumar Subramaniam, J. Dhanraj, Wubishet Degife Mammo
{"title":"Development of Active CO2 Emission Control for Diesel Engine Exhaust Using Amine-Based Adsorption and Absorption Technique","authors":"S. Muthiya, L. Natrayan, L. Yuvaraj, Mohankumar Subramaniam, J. Dhanraj, Wubishet Degife Mammo","doi":"10.1155/2022/8803585","DOIUrl":"https://doi.org/10.1155/2022/8803585","url":null,"abstract":"Diesel-powered transportation is considered an efficient method of transportation; this sees the increase in the demand for the diesel engine. But diesel engines are considered to be one of the largest contributors to environmental pollution. The automobile sector accounts for the second-largest source for increasing CO2 emission globally. In this experiment, a suitable postcombustion treatment to control CO2 emission from IC engine exhaust is developed and tested. This work focuses to control CO2 emission by using the chemical adsorbent technique in diesel engine exhaust. An amine-based liquid is used to adsorb the CO2 molecules first and absorb over the amines from the diesel engine exhaust. Three types of amino solutions (L-alanine, L-aspartic acid, and L-arginine) were prepared for 0.3 mole concentrations, and the CO2 absorption investigation is performed in each solution by passing the diesel exhaust. A suitable CO2 adsorption trap is developed and tested for CO2 absorption. The experiments were performed in a single-cylinder diesel engine under variable load conditions. The eddy current dynamometer is used to apply appropriate loads on the engine based on the settings. The AVL DIGAS analyzer was used to measure the CO2, HC, and CO emissions. An uncertainty analysis is carried out on the experimental results to minimize the errors in the results. The effective CO2 reduction was achieved up to 85%, and simultaneous reduction of HC and CO was also observed.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43884326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 22
Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach 蛋壳改性生物炭吸附剂处理石油化工废水:技术经济和可持续发展的途径
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-14 DOI: 10.1155/2022/2323836
A. Kumi, Mona G. Ibrahim, M. Fujii, M. Nasr
{"title":"Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach","authors":"A. Kumi, Mona G. Ibrahim, M. Fujii, M. Nasr","doi":"10.1155/2022/2323836","DOIUrl":"https://doi.org/10.1155/2022/2323836","url":null,"abstract":"Petrochemical industrial wastewater (PIW)contains toluene and xylene (TX), and various organic and inorganic pollutants, causing severe risks to human health if improperly released into the environmental matrices. For the long-term reliability of environmental conservation, this study illustrates the interlinkage between PIW treatment and the three pillars of sustainable development. Sewage sludge biochar was modified with eggshell, showing a relatively high fixed C content (increase in carbonization degree), and small O/C and N/C ratios. The prepared biochar was employed for TX adsorption in mono-component solutions, giving removal efficiencies of 79.1% (T) and 86.6% (X), at pH =10, adsorbent dosage =2 g/L, and Co =40 mg/L within 60 min. The main adsorption mechanism was physisorption, including precipitation/pore-filling, π-π dispersive interaction, and van der Waals force. The modified biochar also treated real PIW under five adsorption/regeneration cycles, providing essential steps toward large-scale applications. According to an economic feasibility estimation, the biochar application for treating 1 m3 of PIW would offer a payback period of 6.9 yr. The study outputs could be linked to the restoration of water-related ecosystems, biochar modification for industrial applications, and climate change mitigation, adopting the 2030 agenda and its sustainable development goals (SDGs).","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48983697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Zeolite Application in Wastewater Treatment 沸石在废水处理中的应用
IF 2.9 4区 工程技术
Adsorption Science & Technology Pub Date : 2022-02-09 DOI: 10.1155/2022/4544104
Luciano Fernandes de Magalhães, Gilberto Rodrigues da Silva, A. Peres
{"title":"Zeolite Application in Wastewater Treatment","authors":"Luciano Fernandes de Magalhães, Gilberto Rodrigues da Silva, A. Peres","doi":"10.1155/2022/4544104","DOIUrl":"https://doi.org/10.1155/2022/4544104","url":null,"abstract":"As a scarce natural resource, the preservation of water quality is of fundamental importance to guarantee its availability for future generations. Due to the increasing industrial activity, effluents are generated with a series of chemical compounds, such as nitrogenous, phosphoric, and organic compounds, heavy metals, and dyes which, if improperly disposed of, contribute to contamination, followed by significant environmental impacts, in addition to the damage to human health. The adsorption technique is an effective approach for removing contaminants from effluents, showing high versatility, due to the use of various materials as adsorbents. Belonging to a wide variety of materials, zeolites reveal to be a promising adsorbent. Zeolites are minerals found in nature or which can be synthesized from industrial residues, standing out in the treatment of contaminated effluents. Zeolite removal efficiency depends on the contaminant to be removed and can reach up to 96% for heavy metals, 90% for phosphoric compounds, 96% for dyes, 80% for nitrogen compounds, and 89% for organics. Aiming at the identification of the more relevant findings and research gaps to advance the use of zeolites in the large-scale treatment of industrial effluents, a review on the recent application of zeolites is needed. This paper presents a global view of zeolites, and a review is conducted on several recent studies using zeolites as adsorbents for the contaminants considered, indicating the main characteristics of the various adsorption systems, demonstrating the particularities of each process, and aiming to reveal useful information to provide future research, in addition to identifying points that need further investigation.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":"1 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2022-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42113530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 41
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