Adsorption Science & Technology最新文献

{"title":"ZrBDC-Based Functional Adsorbents for Small-Scale Methane Storage Systems","authors":"O. V. Solovtsova, I. Men’shchikov, A. Shkolin, A. Fomkin, E. Khozina, A. Shiryaev","doi":"10.1155/2022/4855466","DOIUrl":"https://doi.org/10.1155/2022/4855466","url":null,"abstract":"Metal-organic frameworks (MOF), potentially porous coordination structures, are envisioned for adsorption-based natural gas (ANG) storage, including mobile applications. The factors affecting the performance of the ANG system with a zirconium-based MOF with benzene dicarboxylic acid as a linker (ZrBDC) as an adsorbent were considered: textural properties of the adsorbent and thermal effect arising upon adsorption. The high-density ZrBDC-based pellets were prepared by mechanical compaction of the as-synthesized MOF powder at different pressures from 30 to 240 MPa at 298 K without a binder and mixed with polymer binders: polyvinyl alcohol (PVA) and carboxyl methylcellulose (CMC). The structural investigations revealed that the compaction of ZrBDC with PVA under 30 MPa was optimal to produce the ZrBDC-PVA adsorbent with more than a twofold increase in the packing density and the lowest degradation of the porous structure. The specific total and deliverable volumetric methane storage capacities of the ZrBDC-based adsorbents were evaluated from the experimental data on methane adsorption measured up to 10 MPa and within a temperature range from 253 to 333 K. It was measured experimentally that at 253 K, an 100 mL adsorption tank loaded with the ZrBDC-PVA pellets exhibited the deliverable methane storage capacity of 172 m3(NTP)/m3 when the pressure dropped from 10 to 0.1 MPa. The methane adsorption data for the ZrBDC powder and ZrBDC-PVA pellets were used to calculate the important thermodynamic characteristic of the ZrBDC/CH4 adsorption system—the differential molar isosteric heat of adsorption, which was used to evaluate the state thermodynamic functions: entropy, enthalpy, and heat capacity. The initial heats of methane adsorption in powdered ZrBDC evaluated from the experimental adsorption isosteres were found to be ~19.3 kJ/mol, and then these values in the ZrBDC/CH4 system decreased at different rates during adsorption. In contrast, the heat of methane adsorption onto the ZrBDC-PVA pellets increased from 19.4 kJ/mol to a maximum with a magnitude, width, and position depended on temperature, and then it fell. The behaviors of the thermodynamic state functions of the ZrBDC/CH4 adsorption system were interpreted as a variation in the state of adsorbed molecules determined by a ratio of CH4-CH4 and CH4-ZrBDC interactions. The heat of adsorption was used to calculate the temperature changes of the ANG systems loaded with ZrBDC powder and ZrBDC pellets during methane adsorption under adiabatic conditions; the maximum integrated heat of adsorption was found at 273 K. The maximum temperature changes of the ANG system with the ZrBDC materials during the adsorption (charging) process did not exceed 14 K that are much lower than those reported for the systems loaded with activated carbons. The results obtained are of direct relevance for designing the adsorption-based methane storage systems for the automotive industry, developing new gas-power robotics sys","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44333838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An Intelligent Carbon-Based Prediction of Wastewater Treatment Plants Using Machine Learning Algorithms","authors":"A. Hilal, Maha M. Althobaiti, T. Eisa, Rana Alabdan, M. A. Hamza, Abdelwahed Motwakel, Mesfer Al Duhayyim, N. Negm","doi":"10.1155/2022/8448489","DOIUrl":"https://doi.org/10.1155/2022/8448489","url":null,"abstract":"Purification of polluted water and return back to the agriculture field is the wastewater treatment for plants. Contaminated water causes illness and health emergencies of public. Also, health risk due release of toxic contaminants brings problem to all living beings. At present, sensors are used in waste water treatment and transfer data via internet of things (IoT). Prediction of wastewater quality content which is presence of total nitrogen (T-N) and total phosphorous (T-P) elements, chemical oxygen demand (COD), biochemical demand (BOD), and total suspended solids (TSS) is associated with eutrophication that should be prevented. This may leads to algal bloom and spoils aquatic life which is consumed by human. The presence of nitrogen and phosphorous elements is in the content of wastewater, and these elements are associated with eutrophication which should be prevented. Adsorption of T-N and T-P activated carbon was predictable as one of the most promising methods for wastewater treatment. Many research works have been done. The issues are inefficiency in the prediction of wastewater treatment. To overcome this issue, this paper proposed fusion of B-KNN with the ELM algorithm that is used. The accuracy of the BKNN-ELM algorithm in classification of water quality status produced the highest accuracy of the highest accuracy which is \u0000 \u0000 K\u0000 =\u0000 9\u0000 \u0000 and \u0000 \u0000 k\u0000 =\u0000 10\u0000 \u0000 with rate of accuracy which is 93.56%, and the lowest accuracy is \u0000 \u0000 K\u0000 =\u0000 1\u0000  \u0000 of\u0000  \u0000 65.34\u0000 %\u0000 \u0000 . Experiment evaluation shows that a total suspended solid predicted by proposed model is 91 with accuracy of 93%. The relative error rate of prediction is 12.03 which is lesser than existing models.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47497710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption-Desorption Surface Bindings, Kinetics, and Mass Transfer Behavior of Thermally and Chemically Treated Great Millet Husk towards Cr(VI) Removal from Synthetic Wastewater","authors":"A. Prajapati, Pushkar Verma, Satyansh Singh, M. Mondal","doi":"10.1155/2022/3956977","DOIUrl":"https://doi.org/10.1155/2022/3956977","url":null,"abstract":"This study reports the efficacy of adsorbents synthesized by thermal (TT-GMH) and chemical (CT-GMH) modification of great millet husk (GMH) for the treatment of synthetic wastewater containing Cr(VI). The chemical modification of raw GMH was done by concentrated H2SO4 to increase the porosity and heterogeneity on the surface. The comparative investigations of physicochemical properties of synthesized adsorbents were examined by point of zero charge (pHpzc), BET surface area, SEM-EDX, FTIR, and XRD analyses. The results revealed that CT-GMH had around three times higher surface area and more porous structure as compared to TT-GMH. The adsorption experiments were executed in batch mode to examine the impact of parameters governing the adsorption process. For Cr(VI) solution of 25 mg/L, adsorbent dose of 4 g/L, temperature of 25\u0000 \u0000 \u0000 \u0000 \u0000 °\u0000 \u0000 \u0000 C\u0000 \u0000 , and shaking speed of 150 RPM, the maximum removal for TT-GMH was attained at pH 1 and contact time 150 min, while for CT-GMH, maximum removal was attained at pH 2 and contact time 120 min. The experimental results fitted to the rate kinetic equations showed that for both TT-GMH and CT-GMH, adsorbents followed the quasi-second-order kinetic model during the adsorption process. Further, results revealed that the adsorption process was endothermic and Sips isotherm model was followed for both TT-GMH and CT-GMH. Based on the Sips isotherm, maximum uptake capacity for TT-GMH and CT-GMH was noted to be 16 and 22.21 mg/g, respectively. Among the tested mass transfer models, liquid film diffusion model was followed during the adsorption process of both the adsorbents. The desorption study revealed that TT-GMH and CT-GMH give 69.45% and 74.48% removal, respectively, up to six cycles.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49520092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption of Pb(II) from Water onto ZnO, TiO2, and Al2O3: Process Study, Adsorption Behaviour, and Thermodynamics","authors":"Nagwan G. Mostafa, Ahmad F. Yunnus, A. Elawwad","doi":"10.1155/2022/7582756","DOIUrl":"https://doi.org/10.1155/2022/7582756","url":null,"abstract":"This study is aimed at comparing the use of zinc oxide (ZnO), titanium dioxide (TiO2), and aluminium oxide (Al2O3) for removing lead ions from water through adsorption. The point of zero charge was obtained for ZnO, TiO2, and Al2O3 and was found to be 7.3, 7.1, and 9.0, respectively. The effect of pH, adsorbent dose, contact time, initial concentrations, and temperature was investigated in batch experiments. The optimal conditions obtained were 7, 2 g/L, 120 mins, 100 ppm, and 41°C, respectively, where the optimal removal efficiencies were 98.43%, 96.45%, and 85.50% for ZnO, TiO2, and Al2O3, respectively. In addition, analyses of adsorption kinetics, mechanisms, isotherms, and thermodynamics were performed. The adsorption kinetics of Pb(II) were compared to popular models, and it was found that the pseudo-second-order (PSO) model best fitted the Pb(II) uptake for all adsorbents at correlation coefficient (\u0000 \u0000 \u0000 \u0000 R\u0000 \u0000 \u0000 2\u0000 \u0000 \u0000 ≥\u0000 0.96\u0000 \u0000 ). The adsorption isotherms of Pb(II) were also compared to popular models, and it was found that the Pb(II) uptake by TiO2 and ZnO was well-described by the Langmuir model (\u0000 \u0000 \u0000 \u0000 R\u0000 \u0000 \u0000 2\u0000 \u0000 \u0000 ≥\u0000 0.96\u0000 \u0000 ) with maximum adsorption capacities of 55.04 and 58.88 mg/g, respectively. On the other hand, the behaviour of Al2O3 is described more accurately by the Dubinin-Radushkevich (D-R) model (\u0000 \u0000 \u0000 \u0000 R\u0000 \u0000 \u0000 2\u0000 \u0000 \u0000 =\u0000 0.96\u0000 \u0000 ), and the maximum adsorption capacity was 53.64 mg/g. The isotherm analysis proved that the limiting step of the adsorption process is the film diffusion mechanism. In addition, studying the heat of adsorption of Pb(II) implied that the adsorption is endothermic due to the positive values of enthalpy (\u0000 \u0000 Δ\u0000 \u0000 \u0000 H\u0000 \u0000 \u0000 °\u0000 \u0000 \u0000 ≥\u0000 30\u0000 \u0000 ) for all adsorbents. The absorbents were characterized using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) to study the morphology of surfaces and the chemical characterization of the adsorbents to ensure that adsorption is achieved. ZnO showed better performance for the uptake of lead followed by TiO2 then Al2O3.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49413313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Graphene Oxide/Fe3O4/Chitosan−Coated Nonwoven Polyester Fabric Extracted from Disposable Face Mask for Enhanced Efficiency of Organic Dye Adsorption","authors":"H. V. Tran, N. T. Hoang, T. D. Le, L. T. Tran, H. T. Dang","doi":"10.1155/2022/8055615","DOIUrl":"https://doi.org/10.1155/2022/8055615","url":null,"abstract":"Owing to the COVID-19 pandemic, huge amounts of disposable face masks have been manufactured and used, and these discarded face masks have to be treated. In this study, we propose a simple approach for reusing the nonwoven polyester fabric (NWPF) from disposable face masks. In this approach, NWPF is utilized as a supporter for coating of a layer of graphene oxide/Fe3O4/chitosan (GFC) to form a GFC/NWPF adsorbent at room temperature via a simple spray coating method that does not require any solvent. The specific properties of GFC, NWPF, and the GFC/NWPF adsorbent were analysed via X-ray diffraction, transmission electron microscopy, ultraviolet–visible spectroscopy, vibrating sample magnetometry, and field-emission scanning electron microscopy. Results showed that the presence of NWPF enhanced the adsorption capacity of GFC towards organic dyes. At high concentrations of the organic dyes, the adsorption efficiency of the GFC/NWPF adsorbent to the dyes reached 100% within 24 h. The adsorption capacity (\u0000 \u0000 \u0000 \u0000 q\u0000 \u0000 \u0000 max\u0000 \u0000 \u0000 \u0000 ) of the GFC/NWPF adsorbent to methylene blue, methyl orange, Congo red, and moderacid red was 54.795, 87.489, 88.573, and 29.010 mg g−1, respectively, which were considerably higher than that of bulk GFC (39.308, 82.304, 52.910, and 21.249 mg g−1, respectively).","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44195701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Comprehensive Insight on Adsorption of Polyaromatic Hydrocarbons, Chemical Oxygen Demand, Pharmaceuticals, and Chemical Dyes in Wastewaters Using Biowaste Carbonaceous Adsorbents","authors":"Hifsa Khurshid, M. R. Mustafa, M. Isa","doi":"10.1155/2022/9410266","DOIUrl":"https://doi.org/10.1155/2022/9410266","url":null,"abstract":"Recent trends in adsorption of hazardous organic pollutants including Polyaromatic Hydrocarbons (PAHs), Chemical Oxygen Demand (COD), Pharmaceuticals, and Chemical Dyes in wastewater using carbonaceous materials such as activated carbon (AC) and biochar (BC) have been discussed in this paper. Utilization of biomass waste in the preparation of AC and BC has gained a lot of attention recently. This review outlines the techniques used for preparation, modification, characterization, and application of the above-mentioned materials in batch studies. The approaches towards understanding the adsorption mechanisms have also been discussed. It is observed that in the majority of the studies, high removal efficiencies were reported using biowaste adsorbents. Regarding the full potential of adsorption, varying values were obtained that are strongly influenced by the adsorbent preparation technique and adsorption method. In addition, most of the studies were concentrated on the kinetic, isotherm equilibrium, and thermodynamic aspects of adsorption, suggesting the dominant isotherm and kinetic models as Langmuir or Freundlich and pseudo-second-order models. Due to development in biosorbents, adsorption has been found to be increasingly economical. However, application of these adsorbents at commercial scale has not been adequately investigated and needs to be studied. Most of the studies have been conducted on synthetic solutions that do not completely represent the discharged effluents. This also needs attention in future studies.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49427332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Citric Acid Promotes the Mobilization of Phosphorus under the Lower Concentration of Low Molecular Weight Organic Acids in Acidic Forest Soil","authors":"He Zhu, H. Bing, Yanhong Wu","doi":"10.1155/2022/5071907","DOIUrl":"https://doi.org/10.1155/2022/5071907","url":null,"abstract":"Low molecular weight organic acids (LMWOAs) secreted by plant roots enhanced the release of inorganic P (Pi) and organic P (Po) into the soil solution and thereby increased plant-available Pi in soils. Not the effect of LMWOAs on inducing organic P (Po) released into soil solution through soil microorganisms at different temperatures was poorly understood, but the transform mechanism for P fraction was also not well explained. This study used three experiments to determine the release of P and the transformation mechanism of P fractions induced by oxalic acid, citric acid, and malic acid in acidic forest soils. The results showed that LMWOAs, as carbon sources for microorganisms, mobilize Po more effectively than glucose. Inorganic P and organic P were released by LMWOAs followed by \u0000 \u0000 oxalic\u0000  \u0000 acid\u0000 >\u0000 citric\u0000  \u0000 acid\u0000 >\u0000 malic\u0000  \u0000 acid\u0000 \u0000 if the substrates of P and LMWOAs were enough. There may be a critical threshold for the concentration of citric acid and oxalic acid between 10 mM and 25 mM to require for the solution of adsorbed and precipitated P, respectively. In all, LMWOAs increased the concentration of labile P by decreasing the concentration of stable P. The results indicated that LMWOAs can significantly promote P availability in acidic forests soils, and the effect of microorganisms on soil available P was more inclined to use LMWOAs than glucose.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49494120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Semiconductor Polymer Carbon Composite Coated Fabric for Warm Beds in Hospital","authors":"Ganapathy Sasikala, V. Mahalakshmi, K. Srihari, Raja Loganathan, R. Jaikumar, ArunSekar Rajasekaran, V. Shanmuganathan, K. Santhosh, S. Sumanth, Venkatesa Prabhu Sundramurthy","doi":"10.1155/2022/2115406","DOIUrl":"https://doi.org/10.1155/2022/2115406","url":null,"abstract":"Patients suffering from diseases that occur due to spreading of virus like fever and cold will have decrease in body temperature. They feel cold in the normal body and room temperature conditions. For the comfort of these patients, an electric under blanket is designed which warms up the patient to maintain the normal body temperature. The heated under body supports include a heater assembly and a layer of compressible support material. The heater assembly includes a flexible heating element, multiplex polyester, and a temperature sensor. The flexible heater element may include a fabric, which coated with a conductive or semiconductive polymer. The heated under body support may also include a water resistant shell, whereas it may encase the heater assembly and the compressible support material. The material used for outer shell and inner heating element has simulated in COMSOL tool for analyzing the heat transfer between them. The proto type model has simulated in PROTEUS software, which includes Arduino UNO and thermistor. This analysis will give the result whether the material can be used as the under garment for warming the patient.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45958788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Improvement of Moisture Management Properties of Face Masks Using Electrospun Nanofiber Filter Insert","authors":"F. Fadil, N. Affandi, A. Harun, Mohammad Khursheed Alam","doi":"10.1155/2022/9351778","DOIUrl":"https://doi.org/10.1155/2022/9351778","url":null,"abstract":"Face coverings such as a face mask are one of the important preventive measures amidst the COVID-19 pandemic, by limiting exhaled particles and reducing expiratory droplet spread. Adding a filter to face masks may offer extra protection against the virus. Nevertheless, there remains a significant concern where thicker, tightly woven materials of masks may reduce the ability to breathe comfortably, due to inadequate moisture management properties of woven fabric in existing disposable surgical face masks. Therefore, the study on the properties of air permeability, water vapor permeability, and flexural rigidity of a face mask fabric is highly essential. This study is aimed at analyzing the potential application of electrospun nanofibers fabricated from electrospinning technique, as filter inserts in commercial surgical face masks. The function of electrospun nanofiber filter (NF) inserted in commercial surgical face masks was introduced in the study. The results indicated the significant reduction in air permeability and water vapor permeability along with the additional usage of electrospun NF within the surgical face masks, due to the smaller fiber size and interspaces in the filter layer as analyzed from FESEM analysis. The percentage of air permeability value was slightly decreased by 15.9%, from 339.5 to 285.5 mm/s, whereas the value of flexural rigidity of surgical face masks with and without electrospun NF insert is 0.1358 and 0.1207 mg/cm, respectively. Hence, the NF inserts are recommended as the potential core component in a face mask.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45649461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Universal Synergistic Rule of Cd(II)-Sb(V) Coadsorption to Typical Soil Mineral and Organic Components","authors":"Min Zhou, Rui-Jia Yang, X. Tan, Boqing Tie, M. Lei, H. Du","doi":"10.1155/2022/9131597","DOIUrl":"https://doi.org/10.1155/2022/9131597","url":null,"abstract":"Heavy metals and metalloids are common cooccurrence in contaminated soils, making their behaviors more complex than their individual presences. Adsorption to soil minerals and organic components determines the solubility and mobility of heavy metals. However, little information is available regarding coadsorbing metals (e.g., Cd) and metalloids (e.g., Sb) to soil components, and whether there is a universal coadsorption rule needs to be illuminated. This study investigated the coadsorption behaviors of Cd(II) and Sb(V) to goethite, kaolinite, and bacteria (Bacillus cereus) at both acidic (pH 4.5) and alkaline pH (pH 8.5). Equilibrium adsorption experiments, coupled with scanning electron microscopy- (SEM-) energy-dispersive X-ray spectrum (EDS) and X-ray photoelectron spectroscopy (XPS), were applied to determine the batch adsorption phenomena and possible mechanisms. Batch results showed that Cd(II) adsorption was greater at pH 8.5 whereas Sb(V) adsorption was greater at pH 4.5. The presence of Cd or Sb promoted each other’s adsorption to goethite, kaolinite, and bacteria, but slight differences were that Sb(V) preferred to enhance Cd(II) adsorption at acidic pH, whereas Cd(II) was more able to increase Sb(V) adsorption at alkaline pH. SEM-EDS analyses further showed that the distribution of Cd and Sb was colocalized. The surface FeOH, AlOH, and COOH groups participated in the binding of Cd(II) and Sb(V), probably through the formation of inner-sphere complexes. Two possible ternary complexes, i.e., sorbent-Cd2+-Sb(OH)6– and sorbent-Sb(OH)6–-Cd2+, were possibly formed. Both the charge effect and the formation of ternary complexes were responsible for the collaborative coadsorbing of Cd-Sb. The universal synergistic rule obtained suggests that current models for predicting Cd(II) or Sb(V) sequestration based on single systems may underestimate their solid-to-liquid distribution ratio in a coexistence situation. The results obtained have important implications for understanding the chemical behavior of Sb and Cd in contaminated soils.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2022-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48705895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}