Enhanced CO2 Adsorption and Selectivity of CO2/N2 on Amine@ZIF-8 Materials

IF 2.8 4区 工程技术 Q2 CHEMISTRY, APPLIED
Zhijuan Zhang, Pengwei Li, Ting Zhao, Yuanhan Xia
{"title":"Enhanced CO2 Adsorption and Selectivity of CO2/N2 on Amine@ZIF-8 Materials","authors":"Zhijuan Zhang, Pengwei Li, Ting Zhao, Yuanhan Xia","doi":"10.1155/2022/3207986","DOIUrl":null,"url":null,"abstract":"The ZIF-8 crystals were successfully postsynthetically modified using methylamine (MA), ethylenediamine (ED), and N, N\n \n \n \n \n ′\n \n \n \n -dimethylethylenediamine (MMEN) to improve their adsorption performance toward CO2. Results showed that, compared with the original ZIF-8, the BET specific surface area of MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 has increased by 118.2%, 92.0%, and 29.8%, respectively. In addition, their total pore volume increased separately by 130.8%, 100%, and 48.7%. The adsorption capacities of CO2 on the amine-modified ZIF-8 samples followed the order \n \n MA\n −\n ZIF\n −\n 8\n >\n MMEN\n −\n ZIF\n −\n 8\n >\n ED\n −\n ZIF\n −\n 8\n >\n ZIF\n −\n 8\n \n . The CO2 adsorption capacities at 298 K on MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 were increased by 118.2%, 90.2%, and 29.8%, respectively. What is more, the CO2/N2 selectivities calculated using an IAST model of the amine@ZIF-8 samples at 0.01 bar and 298 K were also significantly improved and followed the order \n \n MA\n −\n ZIF\n −\n 8\n  \n \n \n 31.4\n \n \n >\n ED\n −\n ZIF\n −\n 8\n  \n \n \n 25.1\n \n \n >\n MMEN\n −\n ZIF\n −\n 8\n  \n \n \n 14.1\n \n \n >\n ZIF\n −\n 8\n  \n \n \n 11.5\n \n \n \n , which increased by 173.0%, 121.4%, and 22.6%, respectively. The isosteric heat of CO2 adsorption (\n \n \n \n Q\n \n \n st\n \n \n \n ) on the MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 all becomes higher, while \n \n \n \n Q\n \n \n st\n \n \n \n of N2 on these samples was slightly lower in comparison with that on the ZIF-8. Furthermore, after six recycle runs of gravimetric CO2 adsorption-desorption on MA-ZIF-8, the adsorption performance of CO2 is still very good, indicating that the MA-ZIF-8 sample has good regeneration performance and can be applied into industrial CO2 adsorption and separation.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":null,"pages":null},"PeriodicalIF":2.8000,"publicationDate":"2022-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Adsorption Science & Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1155/2022/3207986","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 5

Abstract

The ZIF-8 crystals were successfully postsynthetically modified using methylamine (MA), ethylenediamine (ED), and N, N ′ -dimethylethylenediamine (MMEN) to improve their adsorption performance toward CO2. Results showed that, compared with the original ZIF-8, the BET specific surface area of MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 has increased by 118.2%, 92.0%, and 29.8%, respectively. In addition, their total pore volume increased separately by 130.8%, 100%, and 48.7%. The adsorption capacities of CO2 on the amine-modified ZIF-8 samples followed the order MA − ZIF − 8 > MMEN − ZIF − 8 > ED − ZIF − 8 > ZIF − 8 . The CO2 adsorption capacities at 298 K on MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 were increased by 118.2%, 90.2%, and 29.8%, respectively. What is more, the CO2/N2 selectivities calculated using an IAST model of the amine@ZIF-8 samples at 0.01 bar and 298 K were also significantly improved and followed the order MA − ZIF − 8   31.4 > ED − ZIF − 8   25.1 > MMEN − ZIF − 8   14.1 > ZIF − 8   11.5 , which increased by 173.0%, 121.4%, and 22.6%, respectively. The isosteric heat of CO2 adsorption ( Q st ) on the MA-ZIF-8, MMEN-ZIF-8, and ED-ZIF-8 all becomes higher, while Q st of N2 on these samples was slightly lower in comparison with that on the ZIF-8. Furthermore, after six recycle runs of gravimetric CO2 adsorption-desorption on MA-ZIF-8, the adsorption performance of CO2 is still very good, indicating that the MA-ZIF-8 sample has good regeneration performance and can be applied into industrial CO2 adsorption and separation.
增强的CO2吸附和CO2/N2在Amine@ZIF-8材料
用甲胺(MA)、乙二胺(ED)和N,N′-二甲基乙二胺(MMEN)对ZIF-8晶体进行了成功的后合成改性,以提高其对CO2的吸附性能。结果表明,与原始ZIF-8相比,MA-ZIF-8、MMEN-ZIF-8和ED-ZIF-8的BET比表面积分别增加了118.2%、92.0%和29.8%。此外,它们的总孔体积分别增加了130.8%、100%和48.7%。胺改性的ZIF-8样品对CO2的吸附容量依次为MA−ZIF−8>MMEN−ZIF–8>ED−ZIF-8>ZIF−8。298时的CO2吸附能力 MA-ZIF-8、MMEN-ZIF-8和ED-ZIF-8上的K分别增加了118.2%、90.2%和29.8%。此外,使用amine@ZIF-80.01的样本 bar和298 K也显著改善,并遵循MA−ZIF−8的顺序  31.4>ED−ZIF−8  25.1>MMEN−ZIF−8  14.1>ZIF−8  11.5,分别增长173.0%、121.4%和22.6%。MA-ZIF-8、MMEN-ZIF-8和ED-ZIF-8上的CO2吸附等温线(Q st)都变高,而与ZIF-8相比,这些样品上N2的Q st略低。此外,在MA-ZIF-8上进行了6次重量法CO2吸附-解吸循环运行后,对CO2的吸附性能仍然很好,表明MA-ZIF8样品具有良好的再生性能,可应用于工业CO2吸附和分离。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Adsorption Science & Technology
Adsorption Science & Technology 工程技术-工程:化工
CiteScore
5.00
自引率
10.30%
发文量
181
审稿时长
4.5 months
期刊介绍: Adsorption Science & Technology is a peer-reviewed, open access journal devoted to studies of adsorption and desorption phenomena, which publishes original research papers and critical review articles, with occasional special issues relating to particular topics and symposia.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信