Energy & Environmental Science最新文献_第4页

Industrial Decarbonization Potential of Earth-based Particulate High-temperature Thermal Energy Storage 地球颗粒高温热能储存的工业脱碳潜力

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-19 DOI: 10.1039/d5ee02113h

Kewei Xu, Xiaokang Chen, Peng Peng, Lin Yang, Libin Tian, Yushuai Huang, Yun Huang, Yulong Ding, Qingshan Zhu

引用次数: 0

Progress and perspectives on hydrogen storage and release in negative hydrogen medium † 负氢介质储放氢研究进展与展望

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-18 DOI: 10.1039/d5ee04149j

Shuyan Guan, Shijie Shen, Yuhai Dou, Wenwen Chen, Ji Shen, Bochao Ye, Wen-Gang Cui, Wenwu Zhong, Zhenglong Li, Hongge Pan, Dingsheng Wang

{"title":"Progress and perspectives on hydrogen storage and release in negative hydrogen medium †","authors":"Shuyan Guan, Shijie Shen, Yuhai Dou, Wenwen Chen, Ji Shen, Bochao Ye, Wen-Gang Cui, Wenwu Zhong, Zhenglong Li, Hongge Pan, Dingsheng Wang","doi":"10.1039/d5ee04149j","DOIUrl":"https://doi.org/10.1039/d5ee04149j","url":null,"abstract":"Hydrogen energy has attracted much attention as a clean energy source, but its large-scale application faces storage and transportation challenges. Negative hydrogen medium (metal hydrides, borohydrides) materials have become a research hotspot due to their efficient hydrogen storage capacity. Investigating the role of negative hydrogen in the structure of materials can improve our understanding of the various structural properties of hydrogen and provide valuable insights into the design of hydrogen-containing materials with new functionalities. This paper reviews the research progress of negative hydrogen medium in recent years. Specifically, they include the magnesium hydride (MgH2), sodium aluminum hydride (NaAlH4), lithium borohydride (LiBH4), ammonia borane (AB, NH3BH3), sodium borohydride (NaBH4), potassium borohydride (KBH4), and so on. The catalytic performance of different catalysts used for hydrogen storage and release in negative hydrogen medium in the last three years is summarized, and the structure-performance relationship of different catalysts for negative hydrogen medium is also described on the nanoscale and atomic scale, respectively. The reasons for the monolithic catalysts and light-enhanced hydrogen release performance are also described. The research progress on the cycle regeneration of negative hydrogen materials is summarized from both computational and experimental perspectives. Finally, the main challenges and development prospects of negative hydrogen medium in the future are put forward. This review contributes to a basic understanding of the design and mechanistic studies of negative hydrogen medium catalysts and provides effective design principles for overcoming the problems of low rates of hydrogen storage and release and the difficulty of cyclic regeneration.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"2 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145077923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Correction: Covalent organic and metal organic frameworks based single atom catalysts for valorisation of CO2 to value added chemicals 更正：基于共价有机和金属有机框架的单原子催化剂，用于将二氧化碳转化为增值化学品

IF 30.8 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-18 DOI: 10.1039/D5EE90091C

Sowjanya Vallem, Malayil Gopalan Sibi, Rahul Patil, Vishakha Goyal, A. Giridhar Babu, EA. Lohith, K. Keerthi, Muhammad Umer, N. V. V. Jyothi, Matthias Vandichel, Daniel Ioan Stroe, Subhasmita Ray, Mani Balamurugan, Aristides Bakandritsos, Sada Venkateswarlu, Rajenahally V. Jagadeesh and Radek Zboril

引用次数: 0

Toward Practical Lithium Metal Batteries via Solvation Structure Regulation Strategy in In-Situ Polymerized Fluorinated Gel Polymer Electrolytes 原位聚合氟化凝胶聚合物电解质溶剂化结构调控策略研究实用锂金属电池

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-18 DOI: 10.1039/d5ee03662c

Yunpei Lu, Yuezheng Liu, Shichao Zhang, Yong Wu, Hao Cheng, Yingying Lu

{"title":"Toward Practical Lithium Metal Batteries via Solvation Structure Regulation Strategy in In-Situ Polymerized Fluorinated Gel Polymer Electrolytes","authors":"Yunpei Lu, Yuezheng Liu, Shichao Zhang, Yong Wu, Hao Cheng, Yingying Lu","doi":"10.1039/d5ee03662c","DOIUrl":"https://doi.org/10.1039/d5ee03662c","url":null,"abstract":"Developing electrolytes that enable stable lithium metal anodes and high-voltage cathodes is critical for next-generation lithium metal batteries (LMBs). In-situ polymerized gel polymer electrolytes (GPEs) offer notable advantages in high-energydensity LMBs due to their unique rigid-flexible structure and superior interfacial contact. However, the solvation structure of GPEs remains underexplored, which is crucial as it significantly influences ion transport and interfacial stability. Here, we employ fluorinated polymer skeletons TF into a high-concentration ether-based liquid electrolyte (HCE) as pseudo diluent, featuring low Li⁺ desolvation barriers and balanced ion transport via -CF 3 group modulating Li + solvation structures in a noncoordinating manner. Weak solvation structure of TF+HCE promotes uniform deposition, while facilitating the formation of a robust, inorganic-rich solid electrolyte interphase (SEI)/ cathode electrolyte interphase (CEI). Consequently, TF+HCE exhibits high ionic conductivity (4.02 mS cm⁻¹) at 30 °C and supports long-term cycling in Li||Cu cells at 2 mAh cm -2 with 300 cycles and 1 mAh cm -2 with 1000 cycles (CE≥98.96%). Besides, when assembled with lean lithium (45 μm) and high areal capacity (2.09 mAh cm⁻²) in Li||NCM811 full cells, it enables stable cycling under high voltage (4.4 V). Notably, over 500 cycles are achieved at high rates (2 C~3 C) with ≥80% capacity retention. Additionally, a high energy density of 465.63 Wh kg⁻¹ is achieved in pouch cells.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"2 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145077918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-Power Hydrogel-Based Moisture-Electric Generators 大功率水凝胶湿发电机

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-17 DOI: 10.1039/d5ee04512f

Wenjun Ying, Zhoujun Huang, Zixiao Liu, Jinzhu Liu, Nanzhe Pan, Abdullatif Jazzar, Jie Zhang, Hua Zhang, Ximin He, Ruzhu Wang, Jiayun Wang

{"title":"High-Power Hydrogel-Based Moisture-Electric Generators","authors":"Wenjun Ying, Zhoujun Huang, Zixiao Liu, Jinzhu Liu, Nanzhe Pan, Abdullatif Jazzar, Jie Zhang, Hua Zhang, Ximin He, Ruzhu Wang, Jiayun Wang","doi":"10.1039/d5ee04512f","DOIUrl":"https://doi.org/10.1039/d5ee04512f","url":null,"abstract":"Moisture-electric generators (MEGs) represent an emerging off-grid energy technology capable of generating electricity from ambient humidity; however, the power density and operational durability of existing MEG devices remain suboptimal, hindering their practical applications. Herein, we present a high-performance, highly flexible MEG achieved by integrating reduced graphene oxide (rGO) nanosheets and LiCl into a polyacrylamide (PAM) hydrogel matrix (namely PGL). The rGO nanosheets serve as conductive nanochannels that facilitate rapid ion transport and charge redistribution, synergizing with hygroscopic LiCl to boost output. By combining experiments, molecular-level simulations, and theoretical modeling, we establish rational and robust design principles for the intricate electricity generation process governed by chemicalmass transport-electric coupling, effectively guiding device design and enabling performance prediction. The resulting MEG unit achieves a superior open-circuit voltage of 0.6 V and a short-circuit current of 0.58 mA/cm 2 , which previously required hundreds of MEGs connected in parallel. Notably, our MEG banks connected in series and parallel are demonstrated to power wearable devices with integrated electronics. This work highlights a significant advancement in the design and scalability of MEGs, paving the way for their integration into flexible electronics and wearable technologies.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"14 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fluorinated carbon nitrides assisted solvation-regulation engineering toward polyvinylidene fluoride-based electrolytes for long-lifespan solid-state lithium batteries 氟化碳氮化物辅助溶剂调节工程，用于长寿命固态锂电池的聚偏氟乙烯基电解质

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-17 DOI: 10.1039/d5ee03323c

Xiaotong Chang, Ruolin Cheng, Tengfei Wang, Xiaohui Kan, Mengyang Jia, Zhijie Bi, Xiulin Fan, Xiangxin Guo

{"title":"Fluorinated carbon nitrides assisted solvation-regulation engineering toward polyvinylidene fluoride-based electrolytes for long-lifespan solid-state lithium batteries","authors":"Xiaotong Chang, Ruolin Cheng, Tengfei Wang, Xiaohui Kan, Mengyang Jia, Zhijie Bi, Xiulin Fan, Xiangxin Guo","doi":"10.1039/d5ee03323c","DOIUrl":"https://doi.org/10.1039/d5ee03323c","url":null,"abstract":"Polyvinylidene fluoride (PVDF)-based electrolytes show huge potential in applications of solid-state lithium batteries (SSLBs) due to their broad potential windows and reliable mechanical strengths. However, the critical interfacial issues associated with high-reactivity residual solvents enable rapidly deteriorative stability of electrolytes toward long-term cycling. Herein, a solvation-regulation engineering is proposed by introducing two-dimensional fluorinated C3N5 (F-C3N5) with distinct electronic structure for restraining residual solvents. The strong adsorption effect of F-C3N5 contributes to selective capture of residual solvent, thereby enabling more anions being participated in solvation by weakening binding strength between Li+ and solvent. Both anion-rich solvation structures and F-C3N5 fillers are involved in forming inorganic-dominated cathode electrolyte interphase (CEI) and solid electrolyte interphase (SEI) layers, which inhibit undesirable parasitic reactions occurred at electrode/electrolyte interfaces. Consequently, the integration of F-C3N5 with PVDF-based electrolyte endows Li symmetric cell with a high critical current density of 2.3 mA cm−2, and a stable Li plating/stripping cycling of 800 h at 0.5 mA cm−2. The corresponding LiNi0.6Co0.2Mn0.2O2/Li cell delivers an excellent capacity retention of 86.4% after 300 cycles at 1C. This work provides a novel perspective of using functionalized F-C3N5 to tailor solvation structures for stabilization of PVDF-based electrolytes.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"24 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigating the effect of lithiation on polycrystalline NMC811 Li-ion battery cathode cracking using in situ SEM micromechanical testing 利用原位SEM微力学测试研究锂化对多晶NMC811锂离子电池阴极开裂的影响

IF 30.8 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-17 DOI: 10.1039/D5EE00976F

Aigerim Omirkhan, Oriol Gavalda-Diaz, Siyang Wang, Ifan E. L. Stephens, Finn Giuliani and Mary P. Ryan

引用次数: 0

-60 to 50 °C Ultrawide-Temperature Flexible Zinc-Air Batteries Enabled by a Ternary Polar Hydrogel Electrolyte 由三元极性水凝胶电解质实现的-60至50°C超宽温度柔性锌-空气电池

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-17 DOI: 10.1039/d5ee03421c

Jun Wang, Xifan Chen, Song Jin, Ying Zhang, Zhengkun Yang, Junzhong Wang, Juan-Ding Xiao, Xiaoping Gao, Jia Yang

{"title":"-60 to 50 °C Ultrawide-Temperature Flexible Zinc-Air Batteries Enabled by a Ternary Polar Hydrogel Electrolyte","authors":"Jun Wang, Xifan Chen, Song Jin, Ying Zhang, Zhengkun Yang, Junzhong Wang, Juan-Ding Xiao, Xiaoping Gao, Jia Yang","doi":"10.1039/d5ee03421c","DOIUrl":"https://doi.org/10.1039/d5ee03421c","url":null,"abstract":"Flexible zinc-air batteries (FZABs) capable of operating across a broad temperature range are highly desirable for powering next-generation wearable electronics. However, FZABs still suffer from unsatisfied performance under extreme temperature, primarily due to the restricted ion transport caused by the freezing and dehydration of the hydrogel electrolytes (HEs). In this work, a new ternary polar hydrogel electrolyte composed of polyacrylamide, poly(sodium-p-styrenesulfonate) and ethylenediaminetetraacetic acid tetrasodium salt (PAM-PSS-EDTA HE) has been developed for ultrawide-temperature FZABs. Benefiting from the unique synergistic effect of the ternary polar functional groups in PAM-PSS-EDTA HE, stronger and more numerous hydrogen bonds between water and the functional groups are formed, leading to enhanced anti-freezing and water-retention properties. The PAM-PSS-EDTA HE achieves high ionic conductivities of 348 mS cm-1 at 25 °C, 50.2 mS cm-1 at -60 °C, excellent anti-freezing performance with freezing point below -100 °C, and outstanding water-retention ratio of 83.4 % after 200 hours at 25 °C, 77 % after 100 hours at 50 °C, demonstrating a significant superiority over single or double component HEs. Furthermore, FZABs based on PAM-PSS-EDTA HE and NiFe-OLC electrocatalyst demonstrate excellent performance under ultrawide temperature range from -60 °C to 50 °C, and exhibit ultralong cycle lifes of 4000 cycles at -60 °C and 400 cycles at 50 °C. This work offers valuable insights for the development of high-performance hydrogel electrolytes for wide-temperature FZABs.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"52 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancing low-temperature durability and sodium-ion transport of anode-free sodium metal batteries through utilization of a solvent adsorption separator 利用溶剂吸附分离器提高无阳极金属钠电池的低温耐久性和钠离子输运

IF 32.5 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-17 DOI: 10.1039/d5ee03213j

Zewei Hu, Liyang Liu, Xin Wang, Qingqing Zheng, Haiying Lu, Zhenwei Tang, Chao Han, Weijie Li

{"title":"Enhancing low-temperature durability and sodium-ion transport of anode-free sodium metal batteries through utilization of a solvent adsorption separator","authors":"Zewei Hu, Liyang Liu, Xin Wang, Qingqing Zheng, Haiying Lu, Zhenwei Tang, Chao Han, Weijie Li","doi":"10.1039/d5ee03213j","DOIUrl":"https://doi.org/10.1039/d5ee03213j","url":null,"abstract":"A battery with high-energy density at low-temperature has been actively pursued in energy storage systems for decades. Anode-free sodium metal batteries (AFSMBs) have emerged as a promising battery configuration for enhanced energy densities by eliminating conventional anode materials. Nevertheless, their practical implementation in low-temperature environments remains constrained by two critical challenges: insufficient dynamics for sodium plating/stripping processes during cycling and instability of the solid electrolyte interphase. Herein, a strategy of multifunctional separator design by employing a solvent adsorption separator with Na supplementation (SAS-N) is proposed to enhance the low-temperature performance of AFSMBs. SAS-N acts as a supplemental sodium reservoir to mitigate irreversible sodium depletion and enhance interfacial compatibility through improved electrolyte wettability. Furthermore, SAS-N modulates more contact ion pair solvation structures, facilitating the formation of an inorganic-rich solid electrolyte interphase (SEI). This reconstructed interface simultaneously stabilizes electrochemical reactions at the electrode/electrolyte interface and accelerates sodium-ion transport kinetics at low temperature. SAS-based AFSMBs demonstrate ultralong-term cyclability, retaining 95.06% capacity over 600 cycles at 25 °C while sustaining 92.53% capacity retention through 1000 cycles under harsh −20 °C operation. This work provides a new approach of separator engineering to improve the low-temperature performance of AFSMBs.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"50 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Amorphous coordination polymers for versatile Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ cation storage 用于Mg2+， Ca2+, Sr2+， Ba2+和Zn2+阳离子存储的无定形配位聚合物

IF 30.8 1区材料科学

Energy & Environmental Science Pub Date : 2025-09-17 DOI: 10.1039/D5EE02567B

Xiaolong Guo, Robert Markowski, Ashley Black, Petru Apostol, Darsi Rambabu, Olivera Lužanin, Tjaša Pavčnik, Damien Monti, Mengyuan Du, Da Tie, Xiaodong Lin, Vasudeva Rao Bakuru, Raphaël Delogne, Koen Robeyns, Laura Simonelli, Jean-François Gohy, Jan Bitenc, Jiande Wang, Alexandre Ponrouch and Alexandru Vlad

{"title":"Amorphous coordination polymers for versatile Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ cation storage","authors":"Xiaolong Guo, Robert Markowski, Ashley Black, Petru Apostol, Darsi Rambabu, Olivera Lužanin, Tjaša Pavčnik, Damien Monti, Mengyuan Du, Da Tie, Xiaodong Lin, Vasudeva Rao Bakuru, Raphaël Delogne, Koen Robeyns, Laura Simonelli, Jean-François Gohy, Jan Bitenc, Jiande Wang, Alexandre Ponrouch and Alexandru Vlad","doi":"10.1039/D5EE02567B","DOIUrl":"10.1039/D5EE02567B","url":null,"abstract":"Divalent metal-ion batteries hold immense promise for electrochemical energy storage applications, offering advantages in terms of volumetric capacity, cost-efficiency, sustainability, and safety. Despite advances, the lack of high-voltage and high-performance positive electrode materials remains a critical obstacle. Here, we disclose a family of amorphous coordination polymers capable of reversibly storing Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ cations. For Ca2+ and Mg2+ systems, the highest reported working potentials of >3.2 V vs. Ca2+/Ca and 2.8 V vs. Mg2+/Mg are measured, along with fast, stable, and low-hysteresis storage without solvent or ion pair storage. These characteristics stem from the amorphous structure, delocalized anionic charge, and disordered, long bond-distance coordination, enabling weak binding and fast cation diffusion. Using sustainable elements and demonstrating universal divalent cation storage capacity by achieving the first-ever reversible storage of Sr2+ and Ba2+ ions, this work establishes key design principles for divalent cation storage materials and systems.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":" 20","pages":" 9114-9124"},"PeriodicalIF":30.8,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ee/d5ee02567b?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145072371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0