{"title":"Structural, Thermal, and Magnetic Characterization Analysis of Synthesized Fe3O4-Spinel Ferrite Nanoparticles","authors":"B. Gogoi, Upamanyu Das","doi":"10.4028/p-5bb090","DOIUrl":"https://doi.org/10.4028/p-5bb090","url":null,"abstract":"Spinel ferrite nanoparticles are potential candidates for multiple biomedical applications. Spinel ferrite nanoparticles have been studied extensively for understanding physical, chemical, electro-optical as well as magnetic properties which are fascinating due to cationic distributions corresponding to tetrahedral sites and octahedral sites in a cubic phase. Biocompatibility and large magnetic moment are basic requirements in spinel ferrite nanoparticles for efficient functioning in specific application purpose. Fe3O4 (magnetite) is an important member of spinel ferrite group with high chemical stability and ferrimagetic material property at nanodimension. Superparamagnetic state and biocompatibility of magnetite (Fe3O4) spinel ferrite nanoparticle has already been proven. Spinel ferrite magnetite nanoparticles have been developed based on precipitation of iron oxide using ferric and ferrous ions at the ratio 2:1 in alkaline media at and above 100°C. The experimental parameters have been set to synthesize pure and uniformly sized magnetite nanoparticles. No other phases of iron oxides were detected other than magnetite spinel phase in the XRD result. The average crystal size has been determined from XRD peak broadening. Absorption spectra were investigated using UV-Vis Spectrometer and FTIR. Thermal and magnetic measurements were carried out Digital Scanning Calorimeter and SQUID Magnetometer. One sample of the prepared nanoparticles with polymer coating of polyvinyl alcohol has been studied for superparamagnetic nature. Superparamagnetic particles show saturation value of magnetization 51.26 emu/g at 100 K. ZFC-FC curves for two samples with polymer coating of polyvinyl alcohol and hydroxy-propyl methyl cellulose have also been studied. Keywords: Spinel Ferrite, Magnetite, Ferrimagnetism, Transition metal oxide, Superparamagnetism. Statements and declarations Competing Interests: The authors declare that there is no competing financial interest that are related directly or indirectly to the reported work in this paper. Conflict of interest: There is no conflict of interest. Acknowledgements The Authors are grateful to IISER Bhopal, CRF facility for providing instrumentation facility to characterize magnetic properties. We acknowledge thanks to Lovely Professional University for providing us necessary characterization technique for the XRD analysis and thermal analysis.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"467 1","pages":"79 - 98"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79892953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Transition from Reflective to Energy-Storing Self-Illumination in Road Markings: A Review","authors":"Fu Jie Li, Xin Ye Cao, Shuai Heng Liu, L. He","doi":"10.4028/p-v6918o","DOIUrl":"https://doi.org/10.4028/p-v6918o","url":null,"abstract":"Road markings regulate and direct traffic by conveying specific information. It is of great significance to develop new road marking materials and improve the visibility of marking materials for improving traffic efficiency and ensuring traffic safety. This paper summarized the development status of various reflective road markings at home and abroad. In addition, the energy storage luminescent fluorescent/phosphor marking lines in road marking was emphatically generalized to evaluate the advantages and disadvantages of different improvement methods. Overall, strontium aluminate doped with Eu2+ co-doped with Dy3+ (SrAl2O4:Eu2+, Dy3+) phosphors and self-luminous pavement for energy storage had great prospects in improving road safety and reducing energy consumption.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"52 1","pages":"63 - 76"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88120414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anil Pudasaini, D. K. Chaudhary, R. Chalise, Pitamber Shrestha, L. Joshi, R. Khanal
{"title":"Effect of Atmospheric Dielectric Barrier Discharge on Optical, Electrical and Surface Properties of ZnO Film","authors":"Anil Pudasaini, D. K. Chaudhary, R. Chalise, Pitamber Shrestha, L. Joshi, R. Khanal","doi":"10.4028/p-w246q7","DOIUrl":"https://doi.org/10.4028/p-w246q7","url":null,"abstract":"Among the numerous metal oxide semiconductors, zinc oxide (ZnO) is one of the most widely used materials in various fields due to its non-toxic nature, tunable electric and optical properties, and good thermal and chemical stability. This research aims to study the tuning of optical, electrical, and surface properties of ZnO film treated with dielectric barrier discharge (DBD) plasma produced at atmospheric pressure. The result revealed a significant decrease in its optical band gap, but there was an increase in conductivity. The results of contact angle measurement clearly showed the change of surface nature from hydrophobic to hydrophilic for DBD-treated ZnO film.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"34 1","pages":"43 - 50"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75105897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. F. Kerche, Maikson Luiz Passaia Tonatto, L. V. da Silva, S. Amico
{"title":"Analysis of a Vacuum-Infused Carbon Fiber/Epoxy Composite Beam under 3-Point Bending","authors":"E. F. Kerche, Maikson Luiz Passaia Tonatto, L. V. da Silva, S. Amico","doi":"10.4028/p-4v7t4g","DOIUrl":"https://doi.org/10.4028/p-4v7t4g","url":null,"abstract":"In this paper, a hollow square cross-section carbon fiber/epoxy composite beam was designed and manufactured. Evaluation of the beam behavior considered orientation and stacking sequence, aiming to reduce the number of layers and weight. Finite element method (FEM) was used to simulate the performance of the composite beam under 3-point bending and using three failure criteria, Tsai-Hill, Tsai-Wu and maximum stress. In order to identify the input parameters for the model, flat composites were tested under tension and compression. It was concluded that a minimum of 12 layers of unidirectional carbon fiber were required to reach the required load (44.5 kN). The prototype was successfully fabricated by vacuum-infusion process and subjected to 3-point bending test. The experimental failure load was within the predicted range by the Tsai-Hill failure criteria and maximum stress.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"30 1","pages":"131 - 138"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89288619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Possibilities of Artificial Muscles Using Dielectric Elastomers and their Applications","authors":"S. Chiba, M. Waki, M. Takeshita, K. Ohyama","doi":"10.4028/p-jj7z4z","DOIUrl":"https://doi.org/10.4028/p-jj7z4z","url":null,"abstract":"The recent developments in dielectric elastomers (DE) are spectacular. Currently, a DE as an actuator, 0.15 g of acrylic sandwiching SWCNT electrodes, is capable of lifting a weight of 8 kg by more than 1 mm at a speed of 88 msec. In the near future, DE motors could be used to drive electric vehicles. Moreover, the DE can be used as a high-efficiency sensor with the same structure. With a diameter of 20 mm and a thickness of 0.5 mm, it can accurately measure pressure from several kg to 150 kg. In addition, reversing this DE actuator (DEA) movement also enables high-efficiency power generation. In other words, when the DEA is stretched or pushed, it generates electric power. Single wall nanotubes (SWCNTs) were used as an electrode, and an acrylic DE power generation cartridge with a diameter of 80 mm was used. When the center of the DE power generation cartridge is pushed by about 15 mm, a power of 33.6 mJ is generated. Using these two DE cartridges, it was possible to charge a secondary battery through a DC converter. In addition to this power generator, practical research and development of power generation using wave power, wind power, waste heat, and fluids (ocean currents, water currents, etc.) is progressing. In this paper, we have described state-of-the-art DEAs, DE generators (including the case that the power generated locally by microgenerators are consumed locally), and DE sensors and explained their usefulness.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"3 3 1","pages":"99 - 117"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88246349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of Quantum Dots Dispersion on the Structural, Optical, and Thermal Properties of Liquid Crystal System","authors":"S. Mani, S. Khosla, Pradip B. Sarawade","doi":"10.4028/p-82i41e","DOIUrl":"https://doi.org/10.4028/p-82i41e","url":null,"abstract":"Liquid crystal-quantum dot (LC-QD) composites are promising new materials for a number of applications in displays, energy harvesting, and photonics. In the present work, quantum dispersion in the mixture of LCs of cholesteric and nematic phases is reported. The combination of two LCs, namely Cholesteryl Palmitate (cholesteric 97%) and 4′-Pentyl-4-biphenylcarbonitrile (nematic, 98%), were used in equal proportion while CdS quantum dots were added in this mixture. The thermal, optical, and structural properties of this new LC-QD composite system were analyzed using differential scanning calorimetry (DSC), ultra-violet visible (UV-VIS) spectroscopy, Fabry-Perot scattering studies (FPSS), and Fourier transform infrared (FTIR) spectroscopy. Structural studies indicate that the QDs are uniformly dispersed inside the LC matrix rather than on the surface area. It was observed that quantum dot dispersion increases the strength of the LC mixture. It also changes the phase behavior of the LC mixture affecting the overall performance of LC-QD composite systems. The present findings would be very helpful for the design of the display and photonic devices with an improved optical response.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"138 1","pages":"33 - 42"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86526008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Principles of Logic Design with Nanoscale Thin Film Memristive Systems for High Performance Digital Circuit Applications","authors":"M. Chakraverty, V. N. Ramakrishnan","doi":"10.4028/p-90x9b8","DOIUrl":"https://doi.org/10.4028/p-90x9b8","url":null,"abstract":"The characteristic pinched hysteresis behavior of memristors has been reported by stacks of a variety of materials. This paper aims to examine the principles of logic design using such two terminal memristive systems for high performance digital circuit applications. As against logic design with standard CMOS, the benefits of logic design with memristors have been stated. The realization and operation of memristor based AND and OR hybrid logic gates obtained by integrating memristors with standard CMOS logic have been discussed. The IMPLY and MAGIC logic families have been demonstrated by covering MAGIC NOR and NAND logic gate implementation with MAGIC NOR in detail. A qualitative comparison has been drawn towards the end of the paper to conclude on the suitability and application space for each of the logic families studied in this paper. This work also describes the hybrid CMOS-memristive logic family known as MRL (Memristor Ratioed Logic). With the addition of CMOS inverters, this logic family's OR and AND logic gates, which are based on memristive components, are given a full logic structure and signal restoration. The MRL family, in contrast to earlier memristor-based logic families, is compatible with conventional CMOS logic.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"23 1","pages":"19 - 31"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81921634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Sarkar, Himanshu Rajbongshi, S. Baruah, P. Datta
{"title":"Light Induced Synthesis of Ag Nanorods for Potential Application as Optical Filter Tailored to Visible Domain","authors":"A. Sarkar, Himanshu Rajbongshi, S. Baruah, P. Datta","doi":"10.4028/p-10ge5f","DOIUrl":"https://doi.org/10.4028/p-10ge5f","url":null,"abstract":"Monodispersed Ag nanorods were synthesized using a one-pot synthesis method. These Ag nanorods normally manifest dual surface plasmon resonance (SPR) peaks. This work presents a study of the variation of SPR peaks with variation in the shape of Ag nanorods. Shape variation was achieved through the degradation of a shape-controlling agent (PVP in this work) under white light irradiance with silica passivation to halt further shape variations. This paper also reports the growth & characterization of thin films of the synthesized rod-shaped silver nanoparticles on glass slides along with studies on band pass filter characteristics of the as-synthesized nanoparticles.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"3 1","pages":"53 - 61"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83610817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Compact Model Analysis for Low Voltage OFETs with Electrolytic Gate Dielectrics: Toward a Universal Model for Poly(3-Hexylthiophene) P3HT OFETs","authors":"T. Abhinav, G. Chandra, P. Predeep","doi":"10.4028/p-zf01nm","DOIUrl":"https://doi.org/10.4028/p-zf01nm","url":null,"abstract":"The lightweight with flexibility and low-cost processing engineered the rapid growth of organic field-effect transistors (OFET) in the past three decades. Suitable compact models and parameter extraction methods are being developed to further the use of OFETs in integrated circuits, where stimulations are required to optimize the device performance. To simplify the parameter extraction, metaheuristic approaches are usually made, which otherwise is a cumbersome process. Following these, here investigations are made with the help of such a compact model to extract the operational parameters of P3HT (poly (3-hexylthiophene) based OFETs with electrolytic gate dielectrics using the genetic algorithm (GA) method. The result show that the compact model that was essentially developed in line with the successful models for inorganic material based FETs, can be used as an excellent framework for simulating low voltage OFETs made with both low and high mobility organic semiconductors. Mobility and threshold voltage calculated from the extracted parameters using GA for the two devices having mobility value differences of more than four orders are found to be nicely fitting with the experimental values. These results assume significance to the organic electronic industry as this facilitates the real-time circuit application of OFETs. KEYWORDS: Modeling, Low voltage OFET, Genetic algorithm, Ionic liquid, P3HT","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"13 1","pages":"3 - 10"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86060567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanochemical Synthesis of Dendrimers as Nanocarriers: A Review","authors":"Mohammad Alrbaihat","doi":"10.4028/p-a610b7","DOIUrl":"https://doi.org/10.4028/p-a610b7","url":null,"abstract":"The process of mechanically activating chemical bonds usually involves applying external force. Since mechanical chemistry can be performed without solvents or with minimal amounts of solvent (catalytic quantities), it has become an imperative synthetic tool in multiple fields (e.g., physics, chemistry, and materials science) and is an attractive greener method for preparing diverse molecules. Catalysis, organic synthesis, solid-state medicinal preparation, metal complex synthesis, and many other chemistry fields have benefited from sustainable methods. The purpose of this paper is to shed light on the benefits of using mechanochemical methods to produce a pharmaceutical crystal that is composed of dendrimer nanocrystals. Consequently, we describe and examine the importance of mechanical procedures in forming dendrimers and pharmaceutical crystals in this review.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"31 1","pages":"37 - 46"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85066488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}