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Tailoring DNA Origami Protection: A Study of Oligolysine-PEG Coatings for Improved Colloidal, Structural, and Functional Integrity. 剪裁DNA折纸保护：低聚赖氨酸-聚乙二醇涂层改善胶体、结构和功能完整性的研究。
IF 4.7
ACS polymers Au Pub Date : 2024-12-20 eCollection Date: 2025-02-12 DOI: 10.1021/acspolymersau.4c00085
Hugo J Rodríguez-Franco, Pauline B M Hendrickx, Maartje M C Bastings
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引用次数: 0
Tailoring DNA Origami Protection: A Study of Oligolysine-PEG Coatings for Improved Colloidal, Structural, and Functional Integrity 剪裁DNA折纸保护：低聚赖氨酸-聚乙二醇涂层改善胶体、结构和功能完整性的研究
IF 4.7
ACS polymers Au Pub Date : 2024-12-19 DOI: 10.1021/acspolymersau.4c0008510.1021/acspolymersau.4c00085
Hugo J. Rodríguez-Franco, Pauline B. M. Hendrickx and Maartje M. C. Bastings*, 
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引用次数: 0
Chemoenzymatic Synthesis of Poly-l-lysine via Esterification with Alcohol in One-Pot 化学酶法与醇一锅酯化合成聚赖氨酸
IF 4.7
ACS polymers Au Pub Date : 2024-12-16 DOI: 10.1021/acspolymersau.4c0007310.1021/acspolymersau.4c00073
Kayo Terada, Kousuke Tsuchiya, Alexandros Lamprou and Keiji Numata*, 
{"title":"Chemoenzymatic Synthesis of Poly-l-lysine via Esterification with Alcohol in One-Pot","authors":"Kayo Terada,&nbsp;Kousuke Tsuchiya,&nbsp;Alexandros Lamprou and Keiji Numata*,&nbsp;","doi":"10.1021/acspolymersau.4c0007310.1021/acspolymersau.4c00073","DOIUrl":"https://doi.org/10.1021/acspolymersau.4c00073https://doi.org/10.1021/acspolymersau.4c00073","url":null,"abstract":"<p >Chemoenzymatic polymerization (CEP) using enzymes as catalysts is gaining attention as an environmentally friendly method for synthesizing polypeptides. This method proceeds under mild conditions in aqueous solvents and leverages the substrate specificity of enzymes, allowing polymerization reactions to occur without the need to protect reactive side-chain functional groups. However, the monomers used must have esterified C-termini, such as amino acids or oligopeptides. In this study, we used <span>l</span>-lysine (Lys-OH) as a model example and performed one-pot CEP with papain without isolating the esterified lysine. Esterification of Lys-OH was achieved by using hydrochloric acid as a catalyst in ethanol, and one-pot polymerization resulted in poly-<span>l</span>-lysine (polyLys) with a peak top degree of polymerization (DP) of 6 and a maximum DP of 18, with a 31% conversion from the nonesterified lysine. The obtained polyLys was all α-linked, demonstrating that regioselective polymerization was successfully achieved even with one-pot CEP.</p>","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"5 1","pages":"26–34 26–34"},"PeriodicalIF":4.7,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acspolymersau.4c00073","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143385975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemoenzymatic Synthesis of Poly-l-lysine via Esterification with Alcohol in One-Pot. 化学酶法与醇一锅酯化合成聚赖氨酸。
IF 4.7
ACS polymers Au Pub Date : 2024-12-16 eCollection Date: 2025-02-12 DOI: 10.1021/acspolymersau.4c00073
Kayo Terada, Kousuke Tsuchiya, Alexandros Lamprou, Keiji Numata
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引用次数: 0
IF 4.7
ACS polymers Au Pub Date : 2024-12-11
Md. Mahamudul Hasan Rumon, Anwarul Azim Akib, Stephen Don Sarkar, Md. Abu Rayhan Khan, Md. Mosfeq Uddin, Dina Nasrin and Chanchal Kumar Roy*, 
{"title":"","authors":"Md. Mahamudul Hasan Rumon,&nbsp;Anwarul Azim Akib,&nbsp;Stephen Don Sarkar,&nbsp;Md. Abu Rayhan Khan,&nbsp;Md. Mosfeq Uddin,&nbsp;Dina Nasrin and Chanchal Kumar Roy*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00028","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144432849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.7
ACS polymers Au Pub Date : 2024-12-11
Marco Drache, Brunette Audree Tameno Kouanwo, Jan Christoph Namyslo, Sacha Pérocheau Arnaud, Tobias Robert and Sabine Beuermann*, 
{"title":"","authors":"Marco Drache,&nbsp;Brunette Audree Tameno Kouanwo,&nbsp;Jan Christoph Namyslo,&nbsp;Sacha Pérocheau Arnaud,&nbsp;Tobias Robert and Sabine Beuermann*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00071","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144432855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.7
ACS polymers Au Pub Date : 2024-12-11
Philipp Martschin*, Vladimir Atanasov, Simon Thiele and Jochen Kerres*, 
{"title":"","authors":"Philipp Martschin*,&nbsp;Vladimir Atanasov,&nbsp;Simon Thiele and Jochen Kerres*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00059","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144432853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.7
ACS polymers Au Pub Date : 2024-12-11
{"title":"","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/lgv004i006_1876154","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144432852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.7
ACS polymers Au Pub Date : 2024-12-11
Usha Kalra,  and , James E. Hanson*, 
{"title":"","authors":"Usha Kalra,&nbsp; and ,&nbsp;James E. Hanson*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00044","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144432854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.7
ACS polymers Au Pub Date : 2024-12-11
Balzhan Savdenbekova*, Ayazhan Seidulayeva, Aruzhan Sailau, Zhanar Bekissanova, Dilafruz Rakhmatullayeva and Ardak Jumagaziyeva, 
{"title":"","authors":"Balzhan Savdenbekova*,&nbsp;Ayazhan Seidulayeva,&nbsp;Aruzhan Sailau,&nbsp;Zhanar Bekissanova,&nbsp;Dilafruz Rakhmatullayeva and Ardak Jumagaziyeva,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00049","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144432856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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