ACS polymers Au最新文献

Reactivity Ratios of Biobased Dialkyl Itaconate Radical Polymerizations Derived from In-Line NMR Spectroscopy and Size-Exclusion Chromatography 生物基衣康酸二烷基自由基聚合的反应性比来源于在线核磁共振光谱和尺寸排除色谱

IF 4.7

ACS polymers Au Pub Date : 2024-11-26 DOI: 10.1021/acspolymersau.4c0007110.1021/acspolymersau.4c00071

Marco Drache, Brunette Audree Tameno Kouanwo, Jan Christoph Namyslo, Sacha Pérocheau Arnaud, Tobias Robert and Sabine Beuermann*,

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引用次数: 0

Reactivity Ratios of Biobased Dialkyl Itaconate Radical Polymerizations Derived from In-Line NMR Spectroscopy and Size-Exclusion Chromatography. 从在线核磁共振波谱和尺寸排阻色谱法得出的生物基二烷基衣康酸根基聚合反应率。

IF 4.7

ACS polymers Au Pub Date : 2024-11-26 eCollection Date: 2024-12-11 DOI: 10.1021/acspolymersau.4c00071

Marco Drache, Brunette Audree Tameno Kouanwo, Jan Christoph Namyslo, Sacha Pérocheau Arnaud, Tobias Robert, Sabine Beuermann

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引用次数: 0

Photoinduced Rayleigh Light Scattering by Hyperbranched Poly(phenylene sulfide) Solutions: A Model for a Light Scattering Switch 超支化聚苯硫醚溶液的光诱导瑞利光散射：光散射开关模型

IF 4.7

ACS polymers Au Pub Date : 2024-11-08 DOI: 10.1021/acspolymersau.4c0004410.1021/acspolymersau.4c00044

Usha Kalra, and , James E. Hanson*,

引用次数: 0

Photoinduced Rayleigh Light Scattering by Hyperbranched Poly(phenylene sulfide) Solutions: A Model for a Light Scattering Switch. 超支化聚苯硫醚溶液的光诱导瑞利光散射：光散射开关模型。

IF 4.7

ACS polymers Au Pub Date : 2024-11-08 eCollection Date: 2024-12-11 DOI: 10.1021/acspolymersau.4c00044

Usha Kalra, James E Hanson

引用次数: 0

Photocurable Oil-Based Thermosets Containing Modifiers from Renewable Sources for Coating Applications. 含可再生改性剂的光固化油基热固性涂料。

IF 4.7

ACS polymers Au Pub Date : 2024-10-28 eCollection Date: 2024-12-11 DOI: 10.1021/acspolymersau.4c00068

Vojtěch Jašek, Jan Fučík, Otakar Bartoš, Silvestr Figalla, Radek Přikryl

{"title":"Photocurable Oil-Based Thermosets Containing Modifiers from Renewable Sources for Coating Applications.","authors":"Vojtěch Jašek, Jan Fučík, Otakar Bartoš, Silvestr Figalla, Radek Přikryl","doi":"10.1021/acspolymersau.4c00068","DOIUrl":"10.1021/acspolymersau.4c00068","url":null,"abstract":"Coating materials involving nature-inspired compounds or renewable sources have recently attracted vast attention. This article presents the synthesis of modified rapeseed oil (MRO) as a precursor possessing high biobased carbon content suitable for cured thermosets formation. Two reactive diluents based on renewable sources, methacrylated methyl 3-hydroxybutyrate (M3HBMMA) and ethyl 3-hydroxybutyrate (E3HBMMA), were successfully synthesized. Lastly, isosorbide monomethacrylate (MISD) was suggested and produced as a polarity modifier miscible with modified curable oil systems capable of increasing the thermoset surface energy. All synthesized compounds were structurally analyzed via NMR, ESI-MS, and FTIR. The characterized reactive substances were coated on paper, stainless steel, and beech wood to investigate their suitability for forming thin layers. The paper dip coating verified the reactive diluting properties of M3HBMMA, resulting in the average formed coating deviation decrease (87.5% for undiluted MRO and 28.0% for 50 wt % M3HBMMA containing MRO). Also, the additional cured thermoset weight decreased from 350 to 69 wt % for the same systems. The standardized bend test applied on the coated stainless steel specimens revealed the thermoset's flexibility and adhesion increase from a 12 ± 2° bending angle of 100% pure MRO to a 121 ± 2° bending angle measured for 40 wt % E3HBMMA containing the MRO-based thermoset. The coated beech wood samples underwent the standardized cross-hatch test investigating the substrate's coating quality. The 100% MRO reached a level 1 rating (second worst), while the system with 40 wt % of MISD obtained a level 5 rating (the best).","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"527-539"},"PeriodicalIF":4.7,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11638785/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142831032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photocurable Oil-Based Thermosets Containing Modifiers from Renewable Sources for Coating Applications 含可再生改性剂的光固化油基热固性涂料

IF 4.7

ACS polymers Au Pub Date : 2024-10-28 DOI: 10.1021/acspolymersau.4c0006810.1021/acspolymersau.4c00068

Vojtěch Jašek*, Jan Fučík, Otakar Bartoš, Silvestr Figalla and Radek Přikryl,

{"title":"Photocurable Oil-Based Thermosets Containing Modifiers from Renewable Sources for Coating Applications","authors":"Vojtěch Jašek*, Jan Fučík, Otakar Bartoš, Silvestr Figalla and Radek Přikryl, ","doi":"10.1021/acspolymersau.4c0006810.1021/acspolymersau.4c00068","DOIUrl":"https://doi.org/10.1021/acspolymersau.4c00068https://doi.org/10.1021/acspolymersau.4c00068","url":null,"abstract":"Coating materials involving nature-inspired compounds or renewable sources have recently attracted vast attention. This article presents the synthesis of modified rapeseed oil (MRO) as a precursor possessing high biobased carbon content suitable for cured thermosets formation. Two reactive diluents based on renewable sources, methacrylated methyl 3-hydroxybutyrate (M3HBMMA) and ethyl 3-hydroxybutyrate (E3HBMMA), were successfully synthesized. Lastly, isosorbide monomethacrylate (MISD) was suggested and produced as a polarity modifier miscible with modified curable oil systems capable of increasing the thermoset surface energy. All synthesized compounds were structurally analyzed via NMR, ESI-MS, and FTIR. The characterized reactive substances were coated on paper, stainless steel, and beech wood to investigate their suitability for forming thin layers. The paper dip coating verified the reactive diluting properties of M3HBMMA, resulting in the average formed coating deviation decrease (87.5% for undiluted MRO and 28.0% for 50 wt % M3HBMMA containing MRO). Also, the additional cured thermoset weight decreased from 350 to 69 wt % for the same systems. The standardized bend test applied on the coated stainless steel specimens revealed the thermoset’s flexibility and adhesion increase from a 12 ± 2° bending angle of 100% pure MRO to a 121 ± 2° bending angle measured for 40 wt % E3HBMMA containing the MRO-based thermoset. The coated beech wood samples underwent the standardized cross-hatch test investigating the substrate’s coating quality. The 100% MRO reached a level 1 rating (second worst), while the system with 40 wt % of MISD obtained a level 5 rating (the best).","PeriodicalId":72049,"journal":{"name":"ACS polymers Au","volume":"4 6","pages":"527–539 527–539"},"PeriodicalIF":4.7,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acspolymersau.4c00068","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymer Science and Engineering in India 印度高分子科学与工程

IF 4.7

ACS polymers Au Pub Date : 2024-10-23 DOI: 10.1021/acspolymersau.4c0008310.1021/acspolymersau.4c00083

Anindita Das*, and , Tarak K. Patra*,

引用次数: 0

Polymer Science and Engineering in India. 印度高分子科学与工程。

IF 4.7

ACS polymers Au Pub Date : 2024-10-23 eCollection Date: 2024-12-11 DOI: 10.1021/acspolymersau.4c00083

Anindita Das, Tarak K Patra

引用次数: 0

Synthesis and Characterization of Novel Perfluoro Aromatic Side Chain Sulfonated PSU Ionomers 新型全氟芳香侧链磺化PSU离聚体的合成与表征

IF 4.7

ACS polymers Au Pub Date : 2024-10-14 DOI: 10.1021/acspolymersau.4c0005910.1021/acspolymersau.4c00059

Philipp Martschin*, Vladimir Atanasov, Simon Thiele and Jochen Kerres*,

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引用次数: 0

Synthesis and Characterization of Novel Perfluoro Aromatic Side Chain Sulfonated PSU Ionomers. 新型全氟芳香侧链磺化PSU离聚体的合成与表征。

IF 4.7

ACS polymers Au Pub Date : 2024-10-14 eCollection Date: 2024-12-11 DOI: 10.1021/acspolymersau.4c00059

Philipp Martschin, Vladimir Atanasov, Simon Thiele, Jochen Kerres

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引用次数: 0