Nano Research最新文献

筛选
英文 中文
Ligand-mediated synthesis of freestanding room-temperature ferromagnetic CuCr 2 Te 4 nanosheets 配体介导的独立室温铁磁cucr2te纳米片的合成
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2026.94908322
Jingxia Wang, Bin Wang, Zhidan Yan, Yifen Wang, Huan Yang, Lanfang Wang, Ruilong Yang, Fang Wang, Yang Liu
{"title":"Ligand-mediated synthesis of freestanding room-temperature ferromagnetic CuCr <sub>2</sub> Te <sub>4</sub> nanosheets","authors":"Jingxia Wang, Bin Wang, Zhidan Yan, Yifen Wang, Huan Yang, Lanfang Wang, Ruilong Yang, Fang Wang, Yang Liu","doi":"10.26599/nr.2026.94908322","DOIUrl":"https://doi.org/10.26599/nr.2026.94908322","url":null,"abstract":"The synthesis of freestanding, room-temperature ferromagnetic two-dimensional (2D) materials from non-layered 3D lattices, where isotropic bonding resists anisotropic 2D growth, remains a fundamental challenge. Here, we address this by developing a ligand-mediated colloidal strategy to produce freestanding CuCr<sub>2</sub>Te<sub>4</sub> nanosheets with controlled thickness and robust room-temperature ferromagnetism. Unlike substrate-dependent methods like chemical vapor deposition (CVD), our approach leverages facet-selective ligands to drive a Cu<sub>1.43</sub>Te-to-CuCr<sub>2</sub>Te<sub>4</sub> cation exchange pathway, enabling anisotropic growth of ultrathin nanosheets with preserved cubic close-packed order. Mechanistic studies reveal that oleyl alcohol stabilizes (111) facets during the transformation, suppressing strain and phase impurities (e.g., Cr<sub>2</sub>Te<sub>3</sub>) while ensuring ambient stability. Magnetic force microscopy (MFM) and magneto-optical Kerr effect (MOKE) measurements confirm a Curie temperature (T<sub>C</sub>) above 300 K for thin nanosheets. Density functional theory (DFT) reveals that Cu doping enhances Cr-3d/Te-5p hybridization, leading to an increased spin-polarized density of states near the Fermi level, which in turn strengthens ferromagnetic exchange interactions. By decoupling synthesis from substrates and resolving growth pathways, this work establishes a scalable route to air-stable 2D magnets, advancing spintronic materials design with tunable anisotropy and thickness-dependent functionality.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147889185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oriented perovskite ferroelectric wafers for sensitive self-driven X-ray detection 用于灵敏自驱动x射线探测的取向钙钛矿铁电晶片
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2025.94908302
Jianbo Wu, Qiuxiao Yin, Shihai You, Ruiqing Li, Cunjian Lin, Zeng‐Kui Zhu, Zhangtong Han, Lijun Xu, Chang Qu, Zhenyue Wu, Junhua Luo
{"title":"Oriented perovskite ferroelectric wafers for sensitive self-driven X-ray detection","authors":"Jianbo Wu, Qiuxiao Yin, Shihai You, Ruiqing Li, Cunjian Lin, Zeng‐Kui Zhu, Zhangtong Han, Lijun Xu, Chang Qu, Zhenyue Wu, Junhua Luo","doi":"10.26599/nr.2025.94908302","DOIUrl":"https://doi.org/10.26599/nr.2025.94908302","url":null,"abstract":"Maintaining macroscopic ferroelectric polarization in the polycrystalline state is always challenging, due to the random orientation of polar axes. This directly leads to reported perovskite polycrystalline wafer X-ray detectors still rely on external voltage bias, resulting in high energy consumption and limiting integration potential, though the simply-prepared polycrystalline wafers are promising candidates for advanced X-ray detection. Here, oriented ferroelectric wafers made of two-dimensional biaxial perovskite ferroelectric EA<sub>4</sub>Pb<sub>3</sub>Br<sub>10</sub> (EA = ethylamine) were acquired, enabling self-driven X-ray detection. The EA<sub>4</sub>Pb<sub>3</sub>Br<sub>10</sub> ferroelectric wafer exhibits well-oriented (0<em>k</em>0) planes, with four equivalent polarization directions distributed, leading to macroscopic spontaneous polarization in the polycrystalline state. Consequently, a switchable open-circuit voltage of 0.30 V was obtained under the irradiation, enabling impressive self-driven X-ray detection performance, including a remarkable sensitivity of 203.3 μC Gy<sup>-1</sup> cm<sup>-2</sup>, a low detection limit of 17 nGy s<sup>-1</sup>, and the great operational reliability. The sensitivity further reaches a high value of 3779.2 μC Gy<sup>-1</sup> cm<sup>-2</sup> at 100 V mm<sup>-1</sup>, which surpassed many reported perovskite polycrystalline wafers. To our knowledge, this work represents the first realization of self-driven X-ray detection in the perovskite wafer family, offering an available strategy for the simply acquired self-driven radiation detectors.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147890275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solvent-free polymerized carbon nitride dots for light-emitting diode 发光二极管用无溶剂聚合氮化碳点
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2026.94908318
Bingjie Li, Xin‐Yi Wang, Yuan Xu, Mingming Zhang, Fangxu Dai, Jing Xu, Zhan‐Chao Wu, Qiang Cao, Lei Wang, Jun Xing
{"title":"Solvent-free polymerized carbon nitride dots for light-emitting diode","authors":"Bingjie Li, Xin‐Yi Wang, Yuan Xu, Mingming Zhang, Fangxu Dai, Jing Xu, Zhan‐Chao Wu, Qiang Cao, Lei Wang, Jun Xing","doi":"10.26599/nr.2026.94908318","DOIUrl":"https://doi.org/10.26599/nr.2026.94908318","url":null,"abstract":"Carbon nitride dots (CNDs) emerge as a metal-free luminescent material combining earth-abundant precursors, exceptional chemical stability, and tailorable optoelectronic properties. Here we report a solvent-free synthesis of CNDs through thermal polymerization method that achieves unprecedented photoluminescence quantum yields of 72% alongside balanced charge transport characteristics. The CNDs exhibit uniform size distribution and excellent colloidal stability in various solvents. Leveraging these advantages, we demonstrate a solution-processed LED using CNDs as the emissive layer, with a luminance exceeding 1000 cd m<sup>-2</sup> for the first time and a record external quantum efficiency of 0.9% among CNDs -based electroluminescent devices. Our work establishes solution-processable CNDs as promising candidates for low-cost, environmentally benign light-emitting technologies.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring dielectric relaxation time in ultralight graphene aerogels for ultra-broadband microwave absorption and multifunctional applications 为超宽带微波吸收和多功能应用量身定制超轻石墨烯气凝胶的介电弛豫时间
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2026.94908359
Zizhao Ding, Chao Jiang, Zixiang Zhao, Yiting Zhu, Shenglong Huang, Yilun Cheng, Qiancheng Zhang, Mingwei Zhang, Dou Zhang
{"title":"Tailoring dielectric relaxation time in ultralight graphene aerogels for ultra-broadband microwave absorption and multifunctional applications","authors":"Zizhao Ding, Chao Jiang, Zixiang Zhao, Yiting Zhu, Shenglong Huang, Yilun Cheng, Qiancheng Zhang, Mingwei Zhang, Dou Zhang","doi":"10.26599/nr.2026.94908359","DOIUrl":"https://doi.org/10.26599/nr.2026.94908359","url":null,"abstract":"Composite aerogels composed of reduced graphene oxide (RGO), single-walled carbon nanotubes (SWNTs), and polyimide (PI) with an oriented porous structure exhibit flexible, high-performance microwave absorption and a tunable porosity. The polarization relaxation time is varied by adjusting the heat treatment temperature to achieve ultra-broadband microwave absorption at lower thicknesses. SWNTs contribute to the control of aerogel morphology and significantly improve its mechanical toughness. The prepared aerogel has a bulk density of 9.13 mg/cm3 and excellent absorption properties with a minimum absorption peak of -64.5 dB and an effective absorption bandwidth(EAB) of 9.14 GHz. Through experimental comparison and time-domain finite integration calculation, the effect of oriented porous structure on the electromagnetic loss mechanism and performance was elucidated, which can be used for porous wave-absorbing materials. At the same time, the light and flexible PGS composite aerogel fabric is also remarkably flexible, and its excellent mechanical and thermal insulation properties are attributed to its unique orientated microchannel structure. This low-cost, simple and high-performance approach will greatly simplify the application of multifunctional microwave-absorbing materials in wearable and other extreme conditions, including high-temperature environments.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciopen.com/local/article_pdf/10.26599/NR.2026.94908359.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147887607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrothermal modulation of MXene-PVDF textiles for advanced infrared thermal shielding 用于高级红外热屏蔽的MXene-PVDF纺织品的电热调制
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2025.94908291
Jiawei Shao, Xingchen Zhao, Wei Liang, Jiangshan Chen, Yueqin Shi, Minxuan Xu, Qi Zhang, Liang Chu
{"title":"Electrothermal modulation of MXene-PVDF textiles for advanced infrared thermal shielding","authors":"Jiawei Shao, Xingchen Zhao, Wei Liang, Jiangshan Chen, Yueqin Shi, Minxuan Xu, Qi Zhang, Liang Chu","doi":"10.26599/nr.2025.94908291","DOIUrl":"https://doi.org/10.26599/nr.2025.94908291","url":null,"abstract":"MXene-coated textiles (CFs) demonstrate exceptional conductivity, electromagnetic interference shielding, and thermoregulatory performance, which have become prominent in multifunctional wearable technologies. However, inadequate textile-wettability, shielding-induced secondary pollution, and limited thermoregulation still impede their further multifunctional personal protection under extreme temperatures. Herein, we developed an electroactive hydrogel ink by combining MXene with PVDF polymeric matrix, and then impregnated onto the CFs to construct MX-PV-CF. The self-assembled PVDF layer modulates the MXene surface work function by forming a core-shell nanostructure, significantly improving its electro-thermal-magnetic properties. This PVDF-induced low work-function endows MX-PV-CF with remarkable multifunctionalities: 26 dB absorption-dominant electromagnetic radiation protection, high electro-thermal conversion, and a low mid-infrared emissivity (0.65). Mechanistically, the phase transitions of PVDF facilitate efficient heat dissipation, contributing to superior infrared-thermal-shielding. Consequently, MX-PV-CF provides excellent extreme temperature protection, maintaining a human-comfortable temperature (10-40°C) in extremely cold and hot environments. This work enables scalable wearable protection based on MXene-work-function-engineering under extreme temperatures, advancing intelligent protective material technology.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"19 5","pages":"94908291-94908291"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147887320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Immunoengineering strategies using nanoparticles for obesity treatment. 使用纳米颗粒治疗肥胖的免疫工程策略。
IF 9.4 2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/NR.2025.94907707
Neda Mohaghegh, Narges Zargar Balajam, Bahareh Hosseinpour, Claire Buttles, Qiang Huang, Yixuan Huang, Amir Ahari, Neda Farhadi, Saya Davani, Safoora Khosravi, Bahareh Mirmashhouri, Negar Hosseinzadeh Kouchehbaghi, Rohan Sampath, Mohsen Akbari, Vadim Jucaud, Heemin Kang, Ali Khademhosseini, Ryan M Pearson, Alireza Hassani Najafabadi
{"title":"Immunoengineering strategies using nanoparticles for obesity treatment.","authors":"Neda Mohaghegh, Narges Zargar Balajam, Bahareh Hosseinpour, Claire Buttles, Qiang Huang, Yixuan Huang, Amir Ahari, Neda Farhadi, Saya Davani, Safoora Khosravi, Bahareh Mirmashhouri, Negar Hosseinzadeh Kouchehbaghi, Rohan Sampath, Mohsen Akbari, Vadim Jucaud, Heemin Kang, Ali Khademhosseini, Ryan M Pearson, Alireza Hassani Najafabadi","doi":"10.26599/NR.2025.94907707","DOIUrl":"10.26599/NR.2025.94907707","url":null,"abstract":"<p><p>Obesity has emerged as a global epidemic, posing severe challenges to public health and contributing to various complications, including metabolic disorders, cardiovascular disease, and type 2 diabetes. This review provides a comprehensive overview of obesity, its associated comorbidities, and the limitations of conventional treatments. We explore the complex relationship between obesity-induced inflammation, immune dysregulation, and the pivotal role of adipose tissue macrophages (ATMs). Chronic low-grade inflammation in adipose tissues (AT) is a key driver of insulin resistance and metabolic dysfunction. As ATs expand, they undergo significant changes, including increased immune cell infiltration, particularly macrophages (MΦs), which shift from an anti-inflammatory towards a pro-inflammatory phenotype. This review aims to advance the understanding of immunomodulatory strategies by examining MΦ polarization and AT browning as promising therapeutic approaches. We focus on nanoparticles (NPs)-based strategies for immunomodulation, highlighting innovative engineering approaches designed to target the inflammatory pathways underlying obesity. By addressing these mechanisms, this review provides valuable insights into mitigating obesity-associated inflammation and related metabolic disorders, paving the way for novel therapeutic strategies in the fight against the global obesity epidemic.</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"18 12","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12834562/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146058501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-entropy alloy nanosheets engineered aptasensor for ultrasensitive detection of pro gastrin releasing peptide in small-cell lung cancer 高熵合金纳米片设计的超灵敏检测小细胞肺癌胃泌素前释放肽的适体传感器
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2026.94908352
Imamdin Chandio, Yongjian Ai, Qionglin Liang
{"title":"High-entropy alloy nanosheets engineered aptasensor for ultrasensitive detection of pro gastrin releasing peptide in small-cell lung cancer","authors":"Imamdin Chandio, Yongjian Ai, Qionglin Liang","doi":"10.26599/nr.2026.94908352","DOIUrl":"https://doi.org/10.26599/nr.2026.94908352","url":null,"abstract":"Small-cell lung cancer (SCLC) is an aggressive malignancy characterized by rapid progression, early metastasis, and poor prognosis. These features highlight the urgent need for ultrasensitive and non-invasive diagnostic methods. Pro-gastrin-releasing peptide (proGRP) has emerged as a highly specific biomarker for SCLC. However, existing detection techniques are often limited by long assay times and insufficient sensitivity. In this study, we developed a new electrochemical aptasensor based on two-dimensional high-entropy alloy nanosheets (HEANSs) for ultra-precise detection of ProGRP. The HEANSs were synthesized via a salt-templated method, which enabled precise control over composition, enhanced catalytic activity due to lattice distortion, and a uniform nanosheet morphology with high surface area. The HEANSs were functionalized with polydopamine (PDA), thereby introducing a variety of reactive functional groups that improved biocompatibility and markedly enhanced the efficiency of aptamer immobilization. This synergistic design achieved a broad linear detection range from 10 pg/mL to 100 μg/mL, an ultra-low limit of detection (LOD) of 0.874 pg/mL (S/N = 3), and excellent reproducibility with a relative standard deviation (RSD) of 1.78%. Moreover, the sensor retained 3.75% of its initial signal after nine days of storage, demonstrating exceptional stability. This pioneering HEANSs@PDA-based aptasensor provides a scalable and versatile platform for ultrasensitive biomarker detection, holding significant potential for early cancer diagnosis, real-time clinical monitoring, and precision medicine applications.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciopen.com/local/article_pdf/10.26599/NR.2026.94908352.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147334217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-resolved imaging of electrocatalytic and photoelectrocatalytic oxygen evolution processes on two-dimensional transition metal dichalcogenides 二维过渡金属二硫族化合物电催化和光电催化析氧过程的多分辨成像
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2026.94908340
Lisi Wen, Zhuojun Duan, Jiayuan Cheng, Houkai Chen, Bo Liu, Song Liu, Rui Hao
{"title":"Multi-resolved imaging of electrocatalytic and photoelectrocatalytic oxygen evolution processes on two-dimensional transition metal dichalcogenides","authors":"Lisi Wen, Zhuojun Duan, Jiayuan Cheng, Houkai Chen, Bo Liu, Song Liu, Rui Hao","doi":"10.26599/nr.2026.94908340","DOIUrl":"https://doi.org/10.26599/nr.2026.94908340","url":null,"abstract":"The efficient conversion of solar energy into chemical fuels, using solar-energy-generated electricity to drive electrocatalytic (EC) or photoelectrocatalytic (PEC) water splitting, is still a grand challenge in sustainable energy due to the sluggish oxygen evolution reaction (OER). Two-dimensional (2D) semiconductors are promising catalysts in both cases, yet their performance is governed by a complex and heterogeneous landscape of atomic-scale defects that remains convoluted. Here, a multi-resolved imaging strategy, combining <em>in situ</em> electrochemiluminescence (ECL), photoinduced ECL, and photoluminescence imaging modes with <em>ex situ</em> scanning transmission electron microscopy (STEM) analysis, was employed to provide comprehensive insights into the dynamic heterogeneous relationship between catalytic activity, carrier behaviors and active sites on 2D semiconducting materials. By investigating pristine and annealed monolayer MoS₂, we establish a direct link between the distribution of specific defect types and their unique influence on catalytic activity and carrier behavior. We’ve identified molybdenum vacancies (V<sub>Mo</sub>) as bifunctional active sites for both EC and PEC OER, while sulfur vacancies (V<sub>s</sub>), while not primary catalytic centers, uniquely enhance PEC efficiency. This work provides a powerful methodology for elucidating complex, dynamic catalytic mechanisms, paving the way for the defect-level engineering of high-performance 2D materials-based catalysts.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciopen.com/local/article_pdf/10.26599/NR.2026.94908340.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing the Li + –F - electronic seesaw effect in NiFe-layered double hydroxides for balanced oxygen and hydrogen evolution 利用Li + - f -电子跷跷板效应在nife层状双氢氧化物中平衡氧和氢的释放
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2026.94908353
Rongwei Xu, Danhong Li, Shuangshang Tang, Guolong Qiu, Huijuan Zhang, Yu Wang
{"title":"Harnessing the Li <sup>+</sup> –F <sup>-</sup> electronic seesaw effect in NiFe-layered double hydroxides for balanced oxygen and hydrogen evolution","authors":"Rongwei Xu, Danhong Li, Shuangshang Tang, Guolong Qiu, Huijuan Zhang, Yu Wang","doi":"10.26599/nr.2026.94908353","DOIUrl":"https://doi.org/10.26599/nr.2026.94908353","url":null,"abstract":"NiFe layered double hydroxides (NiFe–LDHs) show considerable promise as electrocatalysts for overall water splitting; however, their performance is often limited by sluggish reaction kinetics. In this study, we demonstrate that Li⁺ and F<sup>-</sup> dopants impose opposite electronic effects on NiFe–LDH: Li<sup>+</sup> donates electron density to the metal center and expands the interlayer spacing, thereby facilitating the rapid formation of the active NiOOH phase; conversely, the highly electronegative F<sup>-</sup> stabilizes high-valent Ni species and promotes reactions involving protons. This antagonistic interplay constitutes a Li<sup>+</sup>–F<sup>-</sup> electronic seesaw effect; thus, the incorporation of both ions into NiFe–LDH on nickel foam (Li,F–NiFe–LDH/NF) optimizes the electronic structure, resulting in superior OER and HER activities with overpotentials of 201 and 104 mV, respectively. <em>In situ</em> Raman spectroscopy confirms the earlier onset of reaction and greater extent of NiOOH formation. This dual-ion doping strategy provides a general route to harnessing electronic seesaw effects for the design of high-performance bifunctional electrocatalysts.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147915413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of mutifunctional Cu sphere@ZIF-derived Co particle/carbon fiber composites for high-efficiency microwave absorption 高效微波吸收多功能Cu sphere@ZIF-derived Co颗粒/碳纤维复合材料的构建
2区 材料科学
Nano Research Pub Date : 2025-12-01 DOI: 10.26599/nr.2025.94908309
Sihan Wang, Xin Liu, Yong Juan, Junyang Li, Tingyuan Zhang, Wei Wang
{"title":"Construction of mutifunctional Cu sphere@ZIF-derived Co particle/carbon fiber composites for high-efficiency microwave absorption","authors":"Sihan Wang, Xin Liu, Yong Juan, Junyang Li, Tingyuan Zhang, Wei Wang","doi":"10.26599/nr.2025.94908309","DOIUrl":"https://doi.org/10.26599/nr.2025.94908309","url":null,"abstract":"Currently, the development of artificial intelligence and new-generation high-frequency communication technologies has placed increasingly higher demands on the performance of electromagnetic wave (EMW) absorbing materials with multiple functions in complex application scenarios. In this work, using Cu sphere@ZIF-67 composites as the precursor, the Cu sphere@ZIF-derived Co particles/carbon fiber flexible (CCC) composites<strong> </strong>are designed by electrostatic spinning and high-temperature calcination technique. Herein, a specific cross-linked structure is formed with the inset of ZIF-derived Co particles and Cu spheres into the CNF network, allowing effectively tuning the electromagnetic parameters, optimizing the impedance matching and improving the EMW absorption performance of CCC composites. The as-obtained composites gain a high minimum reflection loss (RL<sub>min</sub>) of -78.33 dB and a broad effective absorption bandwidth (EAB) of 7.60 GHz. Apparently, the three-dimensional interlaced complex network structure endows the composites with enhanced thermal conductivity and superhydrophobic properties, making it conducive to heat transfer and inhibiting the absorption of surface water. Meanwhile, the conductivity of the composites is greatly sensitive to the bending deformation, enabling their applications in flexible sensing. Briefly, this work provides a novel and feasible design thought to fabricate carbon-based composites with multifunctional properties of EMW absorption, heat-conducting, self-cleaning and strain-sensitive conductivity, which opens a route for the potential application of EMW absorbing materials under some extreme conditions.","PeriodicalId":713,"journal":{"name":"Nano Research","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书