Journal of Inorganic and Organometallic Polymers and Materials最新文献

{"title":"Impact of CNTs Incorporation on Structural, Optical and Dielectric Properties of Ag Doped Spinel CoFe2O4 Nanohybrid and Their Photovoltaic Possibilities","authors":"Krutika L. Routray,&nbsp;Sunirmal Saha","doi":"10.1007/s10904-024-03137-w","DOIUrl":"10.1007/s10904-024-03137-w","url":null,"abstract":"<div><p>CNTs decorated Ag-CoFe₂O₄ (ACFO) nanocomposite was synthesized using a simple solvothermal method using green synthesis method by okra plant extract. The prepared materials were micro-analyzed by X-ray diffraction (XRD) measurements, Fourier transform-infrared (FT-IR) spectra, RAMAN, Field emission scanning electron microscope (FESEM) and transmission electron microscopy (TEM) microanalysis. FESEM micrographs show the average diameter of the ACFO nanoparticles is estimated to be about 40 nm and the particles seem to be agglomerated and clustered. With incorporation of CNTs, the luminescence is substantially quenched owing to the interfacial charge transfer between the ferrites and walls of CNTs as evident from room temperature PL measurements. Light dependent electrochemical impedance spectroscopy (EIS) indicates the incidence of a light dependent dielectric relaxation phenomenon. Under illumination, the cole-cole plot seems to be decreasing which is owed to the production of excitons occurring within the system and thereafter it starts to diffuse towards the interface. Massive dielectric values with low loss suggest the CNTs decorated nanohybrid to be well suited for high frequency device application. Interestingly, incorporation of CNTs alters the electronic configuration of the nanocomposites inducing ferromagnetic interaction as observed from the magnetic plot.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2245 - 2256"},"PeriodicalIF":3.9,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of Magnetic Amine Functionalized MIL-101(Fe) Composites and Their Adsorption Properties","authors":"Zong-Li Ren,&nbsp;Xin Ma,&nbsp;Ya-Li Fang","doi":"10.1007/s10904-024-03417-5","DOIUrl":"10.1007/s10904-024-03417-5","url":null,"abstract":"<div><p>Water pollution resulting from organic dyes is a significant environmental challenge. It can pollute water bodies, posing severe risks to both the environment and human health. Adsorption is a widely employed and effective method for removing a diverse range of contaminants in water treatment processes. In this study, amine-functionalized MIL-101(Fe) composites are prepared by solvothermal method. The exceptional adsorption capacity and cycle stability of the amine-functionalized MIL-101(Fe) composites make them effective adsorbents for removing malachite green and methylene blue from wastewater. SEM, TEM, XRD, BET, FTIR, and VSM test the physical and chemical properties of SiO₂@Fe₃O₄-SL@NH₂-MIL-101(Fe). Studying the effects of various parameters on the adsorption process through batch experiments is a crucial step in understanding and optimizing the performance of adsorbent materials for the removal of contaminants such as malachite green (MG) and methylene blue (MB) from wastewater. The observation that the adsorption kinetics fits well with a pseudo-second-order model is significant and indicates that the adsorption procedure follows a second-order reaction mechanism. In the isothermal adsorption model, the adsorption isotherms of malachite green and methylene blue conformed to the Langmuir isotherm model, The results showed that the maximum adsorption capacity (qm) of SiO₂@Fe₃O₄-SL@NH₂-MIL-101(Fe) for MG and MB is 636.94 mg/g and 413.22 mg/g, respectively. In thermodynamic studies, the adsorption of MG and MB by SiO₂@Fe₃O₄-SL@NH₂-MIL-101(Fe) is a spontaneous process that increases with temperature. The composite’s capacity to maintain its high removal efficiency over multiple cycles suggests its potential for practical and sustainable application in water treatment processes.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2721 - 2733"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Anion on Optoelectronic and Thermoelectric Properties Cubic Double Perovskites A2(Sr, Ba)WMgO6 for Low-Cost Energy Technologies: A Computational Simulation Study","authors":"Muhammad Aslam,&nbsp;Zubair Waseem,&nbsp;Muhammad Jamil,&nbsp;Mumtaz Manzoor,&nbsp;Anatoly Zatsepin,&nbsp;Rafa Almeer,&nbsp;Yedluri Anil Kumar,&nbsp;Ramesh Sharma","doi":"10.1007/s10904-024-03376-x","DOIUrl":"10.1007/s10904-024-03376-x","url":null,"abstract":"<div><p>Oxide-based perovskites are promising for solar cell use due to their nontoxicity, inexpensive price, and outstanding optical characteristics. The first-principles research of new double perovskites (DPs) A₂WMgO₆ (A = Sr, Ba) was carried out using Density Functional Theory (DFT) principles. The generalized gradient approximation (GGA) within the Perdew-Burke-Ernzerhof (PBE) functional was used with TB-mBJ to determine the electronic structure. The structural, elastic, electrical, vibratory, and thermoelectric properties have all been studied. The calculated band structure demonstrates the semiconducting nature, which shows indirect bandgaps of 3.15 eV and 2.94 eV for Sr₂WMgO₆ and Ba₂WMgO₆, respectively. Measured mechanical properties, such as the bulk modulus, elastic constants, and Poisson ratio are used to predict elastic durability. The Brillouin zone (BZ) extreme symmetry planes analyze the phonon dispersion curves. Phonon vector visualizations illustrate the dynamic robustness of the materials. The optical properties of real and imaginary dielectric functions, refractive index, and absorption coefficient were computed, indicating that they might be employed in optoelectronic and photovoltaic applications. In addition to these characteristics, Boltzmann’s theory is used to analyze the thermal electricity of Sr₂WMgO₆ and Ba₂WMgO₆. The performance figure for each was computed over the 200–1200 K temperature range and chemical potentials to evaluate these materials’ potential for use in future energy systems. This article aims to inspire experimental investigators to synthesize Sr₂WMgO₆ and Ba₂WMgO₆ for use in modern technology by describing various essential properties of these compounds.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2440 - 2455"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Fluorescent Nanoplatform Based on Tb3+@tartric Acid-Functionalized UiO-67-bpy: A New Strategy of Synergistic Sensitization and its Highly Sensitive Performance toward the Detection of Nitenpyram","authors":"Xiu Pei,&nbsp;Jinchuan Bai,&nbsp;Yaming Li,&nbsp;Xiangbo Kong","doi":"10.1007/s10904-024-03420-w","DOIUrl":"10.1007/s10904-024-03420-w","url":null,"abstract":"<div><p>In this paper, a luminescent metal-organic framework Tb³⁺@tartaric acid-functionalized Zr-MOF (Tb³⁺@UiO-67-bpy-TA, TA = tartaric acid) was prepared by post-synthetic modification (PSM) and used as a fluorescence sensor for the detection of the pesticide nitenpyram (NTP). The fluorescence sensing experiment verified that Tb³⁺@UiO-67-bpy-TA had exceptional sensitivity and selectivity for NTP detection, and the detection limit was calculated to be as low as 1.28 µM. The mechanism studies indicated that competitive UV absorption, photoinduced electron transfer (PET) and dynamic quenching contributed to the fluorescence quenching process. In addition, the detection of NTP in tap water and Yellow River water samples by the Tb³⁺@UiO-67-bpy-TA were also investigated using standard addition method, and satisfactory recoveries were achieved.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2746 - 2756"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Jacaranda Flowers Derived Interconnected 3D Porous Carbon for High-Performance Green Supercapacitor","authors":"Xiyu Deng,&nbsp;Yuchen Han,&nbsp;Hongyu Zhu,&nbsp;Fuming Zhang,&nbsp;Jiajun Zhao,&nbsp;Jinggao Wu,&nbsp;Jing Huang","doi":"10.1007/s10904-024-03416-6","DOIUrl":"10.1007/s10904-024-03416-6","url":null,"abstract":"<div><p>We have explored an environmentally friendly strategy to fabricate porous carbons (JFACs) by means of KOH pre-treatment and direct pyrolysis from jacaranda flowers. The JFACs exhibit a high specific capacitance of ~ 965 F g^− 1 at 1 A g^− 1, outstanding capacitance retention of 98% after 10,000 cycles. The JFACs-based supercapacitor displays a high energy density of 75.28 W h kg^− 1 at a power density of 1200 W kg^− 1 and retains excellent cycling stability with 3.5% loss of capacitance retention after 10,000 cycles at 10 A g^− 1. The facile, efficient and template-free synthesis strategy for novel JFACs from biomass sources may promote commercial application of JFACs in the fields of supercapacitors.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2709 - 2720"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study of Effect of PbO Addition in Bi2Sr2LaxCa1 − xCu2O8+δ Ceramics","authors":"Saadia Mahdjoub,&nbsp;Faiza Bouaïcha,&nbsp;Sonia Attaf,&nbsp;Mohamed-Fayçal Mosbah","doi":"10.1007/s10904-024-03281-3","DOIUrl":"10.1007/s10904-024-03281-3","url":null,"abstract":"<div><p>In this work, two seris samples of superconducting compounds of Bi₂Sr₂Ca_1-xLa_xCu₂O₈₊_δ and Bi_1.95Pb_0.05Sr₂Ca_1-xLa_xCu₂O_8+δ, with different values of (x = 0, 0.01, 0.02, and 0.03), were successufully synthesized by using sol-gel method and then they were characterized by X-ray diffraction, scanning electron, and electrical transport. Ashift in the peaks can be observed in both series when the La content increases, which means a change in the lattice parameters. The SEM photographs show a noticeable change in the grain morphology for the lanthanum substituted samples as compared to undoped sample. The variation of resistivity with temperature for all of the samples exhibit a metallic-like character in the normal state, and increases in the broadening of the superconducting transition indicating an effect on the homogeneity of the samples. The increases in Tc are explained to be due the substitution of La³⁺ in place of Ca²⁺with a consequent change in carrier concentration in the CuO₂ planes.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2344 - 2351"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, Characterization and in Vitro Drug Delivery Applications of a Tin-Based Metal‒Organic Framework","authors":"Akriti Sharma,&nbsp;Archana Thakur","doi":"10.1007/s10904-024-03397-6","DOIUrl":"10.1007/s10904-024-03397-6","url":null,"abstract":"<div><p>This study reports an efficient and fast, microwave-assisted synthesis of a tin-based metal‒organic framework (Sn-MOF), followed by ibuprofen (IBU) drug loading and subsequent encapsulation in carboxymethyl cellulose (CMC) for drug delivery applications. The Sn-MOF was synthesized using trithiocyanuric acid (TCA), stannous chloride dihydrate, and N, N-dimethyl formamide (DMF) at 200 °C within six minutes using microwave-assisted synthesis. The structural and morphological properties of the synthesized Sn-MOF were studied using IR, ¹³C NMR, FESEM (field emission scanning electron microscopy), powder XRD, and TGA analyses. FESEM images revealed the presence of pores on the surface of the complex and flower-shaped microstructures. The ibuprofen drug was effectively loaded into the Sn-MOF structure, as indicated by the shifts in the peaks in the IR spectra. Further encapsulation in carboxymethyl cellulose and crosslinking with ferric chloride resulted in CMC/Sn-MOF@IBU being pH responsive and sustained drug delivery. The demonstrated swelling behaviour, encapsulation efficiency, and in vitro release make CMC/Sn-MOF@IBU a potential candidate for drug delivery of ibuprofen. The kinetics of drug release and predictive modelling further validated the sustained release of the drug from the CMC/Sn-MOF@IBU matrix.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2597 - 2611"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Janus Structured Solar Evaporator with Intrinsic Salt Resistance towards High-Efficient Desalination","authors":"Wei Wang,&nbsp;Xuelong Chen,&nbsp;Ningjing Bai,&nbsp;Jingbo Zhu,&nbsp;Caiyan Zhang,&nbsp;Baozheng Cui,&nbsp;Lina Chen,&nbsp;Huixin Wang,&nbsp;Chenlong Kang,&nbsp;Youmao Tang,&nbsp;Zewen Li,&nbsp;Dongyu Zhao,&nbsp;Haijun Niu,&nbsp;Zhe Wang","doi":"10.1007/s10904-024-03382-z","DOIUrl":"10.1007/s10904-024-03382-z","url":null,"abstract":"<div><p>Utilizing inexhaustible solar energy and seawater resources, solar-driven interfacial steam generation (SSG) offers a straightforward and efficient solution to freshwater scarcity and wastewater reuse. The present study provides a seawater desalination strategy through carbon nanotubes/thermoplastic polyurethane/polydimethylsiloxane (CNTs/TPU/PDMS) composite sponge. This material is engineered for enhanced solar-driven interfacial evaporation, explicitly targeting the mitigation of salt deposition which is detrimental to the efficiency of traditional solar evaporator. Using a commercially available melamine sponge as the base structure, an impregnation-drying technique was adopted for the optimization of light absorber CNTs. The formation of a Janus structure by incorporating a composite layer of PDMS, melamine sponge, and CNTs enhances the salt resistance and water transport capability of the evaporator. Owing to light absorption properties and Janus structure, a maximal evaporation rate of 5.02 kg m^− 2 h^− 1, with a sustained average rate of 4.8 kg m^− 2 h^− 1, as well as proficient ion rejection and organic dye purification efficacy was achieved.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2515 - 2527"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fabrication of Co/Zn Doped Manganese Ferrite Magnetic Nanoparticles: Improving Electrochemical Detection of Antibiotic Through Modification of Reduced Graphene Oxide","authors":"Mehboob Ur Rahman,&nbsp;Rafaqat Ali Khan,&nbsp;Asad Muhammad Khan,&nbsp;Paiboon Sreearunothai,&nbsp;Rimsha Qurratulain,&nbsp;Umar Noor,&nbsp;Toheed Ahmed,&nbsp;Bushra Ismail,&nbsp;Sohaib Hassan","doi":"10.1007/s10904-024-03435-3","DOIUrl":"10.1007/s10904-024-03435-3","url":null,"abstract":"<div><p>A highly sensitive paracetamol detection sensor based on the reduced graphene oxide modified with cobalt- and zinc-doped manganese ferrite nanoparticles coated on glassy carbon electrode (Mn_1-xZn_xFe_2-yCo_yO₄/rGO/GCE) is reported in this work. A range of techniques, including X-ray diffraction, scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), Raman spectroscopy, zeta-sizer, Fourier transform infrared spectrometry, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry are used to evaluate the morphological, structural, and electroanalytical capabilities of the proposed sensor. Under optimal conditions, the sensor exhibited two linear ranges, 30–200 µmol L⁻¹ and 200–1400 µmol L⁻¹. The cobalt and zinc doped magnetic nanoparticles-based composite-modified GCE exhibits a remarkable limit of quantification as 0.12 µmol L⁻¹ and a limit of detection as 0.04 µmol L⁻¹. An evaluation is conducted on the structurally related drug on the anodic current response of paracetamol. The practical application of the constructed sensor is evaluated through an analysis of the current generation of real pharmaceutical samples. The modified GC electrode shows encouraging results that validate its superior analytical performance for paracetamol sensing with high sensitivity and trace-level detection.</p><h3>Graphical Abstract</h3><p>Figure shows the graphical representation of the activity of an electrochemical sensor and its fabrication process</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2943 - 2961"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Magnetic Nanocomposites as Emerging Paradigm for Mitigation of Arsenic from Aqueous Sources","authors":"Mohammed Ahmaruzzaman,&nbsp;Saptarshi Roy,&nbsp;Loveleena Khanikar,&nbsp;Mika Sillanpää,&nbsp;Sami Rtimi","doi":"10.1007/s10904-024-03422-8","DOIUrl":"10.1007/s10904-024-03422-8","url":null,"abstract":"<div><p>The rapid urbanization of modern society has undeniably driven human progress, but it has also introduced a wide array of environmental contaminants, including hazardous heavy metals like arsenic, which adversely affects the public health. The contamination of drinking water and other aquatic sources with elevated concentrations of arsenic is a significant environmental and public health concern. To address this issue, the decontamination of arsenic-containing water is essential. In recent years, nano-adsorbents have emerged as a promising solution for the effective removal of arsenic from water. However, a key challenge lies in the separation of these nano-adsorbents from the treated water, which hinders their practical applications in natural water systems. To mitigate this limitation, researchers have increasingly focused on magnetic nanocomposite adsorbents which offer the dual advantage of surface functionalization– enabling their ability to precisely target and adsorb arsenic– and easy magnetic separation, significantly improving their potential for real-world water treatment applications. Magnetic nano-adsorbents exhibit several key attributes, including high surface area, small particle size, excellent chemical stability, superparamagnetic, and strong magnetic susceptibility, making them ideal candidates for separation via external magnetic fields. This research article provides a comprehensive overview of the recent advancements in magnetic nano-adsorbents, focusing on various modification strategies using different support matrices for the remediation of arsenic-contaminated water. Additionally, an in-depth analysis of the different synthetic methodologies, primary characterization techniques, the underlying adsorption mechanism, and the influence of the different parametric variables that affect the arsenic removal efficiency are systematically presented. Moreover, this study examines the practical applications, regeneration and proper stabilization options of these nano-adsorbents which is crucial for waste management. Furthermore, the toxicological assessment studies, potential research challenges and future perspective pertaining to the large-scale utilization in industries are also highlighted, offering critical insights for the further advancement of magnetic nanocomposites in arsenic-laden wastewater remediation.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2213 - 2244"},"PeriodicalIF":3.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}