Ionic-Liquid (IL) Mediated Microwave-Assisted Synthesis (ILMMAS): A New Synergistic Combination for Nanomaterial Synthesis

IF 4.9 3区化学 Q2 POLYMER SCIENCE

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2025-03-11 DOI:10.1007/s10904-025-03622-w

Sadaf Nazir, Larub Younis, Syed Ubaid Qurashi, Umar Manzoor, Saima Masood, Faheem A Shiekh, Shafquat Majeed

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Abstract

The synergy between ionic liquids (ILs) and microwave (MW) irradiation has sparked a significant interest in material synthesis in general and nanomaterials in particular, revolutionizing the field of materials science. This review explores the fundamental properties and unique attributes of ILs, emphasizing their role as solvents, additives, templates, making them ideal for synthesizing materials, particularly nanomaterials like metals, metal oxides, and doped nanoparticles. The microwave assisted synthesis approach is discussed next vis-à-vis their advantages such as volumetric heating, reduced reaction times, enhanced yields and facile scalability. A new synthetic approach is also expounded on, where in very small quantity of an ionic liquid (IL), as an additive, can be coupled with low heating microwave solvents (non-polar solvents) and subjected to microwave-irradiation. The new strategy of Ionic-liquid (IL) Mediated Microwave Synthesis (ILMMAS), can be particularly important in nanomaterial synthesis, as the non-polar solvents can be heated very quickly under microwave irradiation. This review emphasizes the crucial role of ILs in advancing nanomaterial synthesis and highlights their synergy with microwave irradiation for sustainable and efficient material synthesis processes.

Graphical Abstract

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离子液体（IL）介导的微波辅助合成（ILMMAS）：纳米材料合成的一种新的协同组合

离子液体（ILs）和微波（MW）辐照之间的协同作用引起了人们对材料合成特别是纳米材料的极大兴趣，彻底改变了材料科学领域。本文综述了红外光谱的基本性质和独特属性，强调了它们作为溶剂、添加剂、模板的作用，使它们成为合成材料的理想材料，特别是纳米材料，如金属、金属氧化物和掺杂纳米颗粒。接下来讨论了微波辅助合成方法-à-vis，它们具有体积加热、缩短反应时间、提高收率和易于扩展等优点。本文还阐述了一种新的合成方法，即以极少量的离子液体作为添加剂，与低加热的微波溶剂（非极性溶剂）偶联，进行微波辐照。离子液体（IL）介导微波合成（ILMMAS）的新策略在纳米材料合成中尤为重要，因为非极性溶剂可以在微波照射下快速加热。这篇综述强调了红外光谱在推进纳米材料合成中的重要作用，并强调了它们与微波辐射的协同作用，以实现可持续和高效的材料合成过程。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Inorganic and Organometallic Polymers and Materials 化学-高分子科学

CiteScore

8.30

自引率

7.50%

发文量

335

审稿时长

1.8 months

期刊介绍： Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.