Journal of Electronic Materials最新文献

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Simulation Validation and Performance Optimization of Tandem Perovskite/Silicon Solar Cells Based on Experimental Single-Junction Perovskite Solar Cell 基于实验单结钙钛矿太阳能电池的串联钙钛矿/硅太阳能电池的仿真验证及性能优化
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-17 DOI: 10.1007/s11664-025-12173-2
Mohammed Anes Belbachir, Abderrahmane Zakarya Djennati, Salim Kerai, Mohammed Khaouani, Hichem Rouigueb
{"title":"Simulation Validation and Performance Optimization of Tandem Perovskite/Silicon Solar Cells Based on Experimental Single-Junction Perovskite Solar Cell","authors":"Mohammed Anes Belbachir,&nbsp;Abderrahmane Zakarya Djennati,&nbsp;Salim Kerai,&nbsp;Mohammed Khaouani,&nbsp;Hichem Rouigueb","doi":"10.1007/s11664-025-12173-2","DOIUrl":"10.1007/s11664-025-12173-2","url":null,"abstract":"<div><p>Tandem solar cells have emerged as a promising avenue for achieving higher efficiencies in photovoltaic technologies by combining materials with complementary optical and electrical properties. In this study, we investigate a two-step approach involving the simulation of both a perovskite-based single-junction solar cell and a tandem structure incorporating silicon layers, using Silvaco TCAD tools. Initially, a single-junction perovskite solar cell with the configuration FTO/TO<sub>2</sub>/MAPbl<sub>3</sub>/HTM was simulated. The simulation results showed a short-circuit current density <i>J</i><sub>sc</sub> of 20.057 mA/cm<sup>2</sup>, an open-circuit voltage <i>V</i><sub>oc</sub> of 1.15 V, a fill factor (FF) of 50.03%, and a power conversion efficiency (PCE) of 12.68%. These values were compared with experimental data obtained from an external laboratory <i>J</i><sub>sc</sub> = 20.63 mA/cm<sup>2</sup>, <i>V</i><sub>oc</sub> = 0.96 V, FF = 66.41%, and PCE = 13.15%), highlighting the alignment and deviations between the simulation and physical measurements. To enhance the performance, a tandem structure was developed by incorporating a 3-nm FTO layer as an intermediate contact beneath the HTM layer, followed by a three-layer silicon subcell consisting of donor (n-type), intrinsic, and acceptor (p-type) layers, resulting in significantly improved parameters, with <i>J</i><sub>sc</sub> reaching 36.5 mA/cm<sup>2</sup>, <i>V</i><sub>oc</sub> of 1.05 V, FF of 73.18%, and a PCE of 28.03%. Additional studies were conducted to evaluate the effect of varying the thickness of the intrinsic silicon layer on the device performance and to analyze the temperature-dependent behavior of the tandem structure, providing insights into its stability and operational adaptability. This work underscores the potential of tandem architectures, particularly perovskite–silicon combinations, in advancing photovoltaic efficiency.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 10","pages":"8618 - 8627"},"PeriodicalIF":2.5,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineering Persistent Luminescence in SrAl2O4:Eu2+, Dy3+ for Signage Application 标牌应用中SrAl2O4:Eu2+, Dy3+的工程持续发光
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-16 DOI: 10.1007/s11664-025-12171-4
Kiran Kalkal, Y. Dwivedi
{"title":"Engineering Persistent Luminescence in SrAl2O4:Eu2+, Dy3+ for Signage Application","authors":"Kiran Kalkal,&nbsp;Y. Dwivedi","doi":"10.1007/s11664-025-12171-4","DOIUrl":"10.1007/s11664-025-12171-4","url":null,"abstract":"<div><p>This study presents the synthesis of SrAl<sub>2</sub>O<sub>4</sub>:Eu<sup>2+</sup>, Dy<sup>3+</sup> persistent luminescent phosphors using the combustion method with various fluxing agents to assess their impact on phase formation, morphology, and optical properties. XRD analysis confirmed the formation of a monoclinic crystal phase, while significant changes in surface morphology were noted based on the type of flux employed. Absorption spectroscopy (UV-Visible-IR) indicated a variation in the bandgap value due to structural change, leading to a change in defect levels. The photoluminescence study revealed flux-induced effects on excitation and emission behavior, including a red-region emission peak associated with Eu<sup>3+</sup>, suggesting partial oxidation of Eu ions during synthesis. Thermoluminescence analysis shows that flux type plays a crucial role in determining the density, depth, and distribution of trapping centers in Sr Al<sub>2</sub>O<sub>4</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup> phosphors. To explore practical applications, the optimized phosphor was incorporated into a polydimethylsiloxane (PDMS) matrix, resulting in a flexible PDMS-phosphor composite (PSP) designed for security marking. Phosphorescent decay times of 95 min for LiF, 75 min for H<sub>3</sub>BO₃, and 45 min were observed for tetraethoxyorthosilicate (TEOS) flux samples, highlighting its potential for signage.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 10","pages":"8372 - 8384"},"PeriodicalIF":2.5,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145121977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Scalable Synthesis of WO3 Nanoparticles by Low-Energy Milling for Photodegradation of Methylene Blue from Aqueous Solution 低能研磨可扩展合成用于光降解水溶液亚甲基蓝的WO3纳米颗粒
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-16 DOI: 10.1007/s11664-025-12191-0
Tran Quoc Toan, Nguyen Thi Hai Yen, Dang Van Thanh, Nguyen Long Tuyen, Do Danh Bich, Tran Thi To Uyen, Tran Thi Minh Hang, Hoang Minh Trang, Nguyen Manh Khai
{"title":"Scalable Synthesis of WO3 Nanoparticles by Low-Energy Milling for Photodegradation of Methylene Blue from Aqueous Solution","authors":"Tran Quoc Toan,&nbsp;Nguyen Thi Hai Yen,&nbsp;Dang Van Thanh,&nbsp;Nguyen Long Tuyen,&nbsp;Do Danh Bich,&nbsp;Tran Thi To Uyen,&nbsp;Tran Thi Minh Hang,&nbsp;Hoang Minh Trang,&nbsp;Nguyen Manh Khai","doi":"10.1007/s11664-025-12191-0","DOIUrl":"10.1007/s11664-025-12191-0","url":null,"abstract":"<div><p>The large-scale synthesis of tungsten oxide (WO<sub>3</sub>) nanostructures with high efficiency and benign processing is extremely desirable for practical applications. In this work, we propose a facile method to synthesize WO<sub>3</sub> nanoparticles by liquid-assisted grinding method of commercial WO<sub>3</sub> micron powder in a mixture of double-distilled water and isopropyl alcohol. The as-prepared WO<sub>3</sub> was characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), x-ray diffraction (XRD), UV–Visible (UV–Vis) spectroscopy, and Brunauer–Emmett–Teller (BET) techniques. The obtained results revealed their significantly different morphology of WO<sub>3</sub> micron powder into smaller WO<sub>3</sub> nanoparticles with dimensions of 10–50 nm after milling for 96 h. Moreover, the photocatalytic activity of WO<sub>3</sub> nanoparticles for photodegradation of methylene blue from aqueous solution was higher than that of pristine WO<sub>3</sub>. The results demonstrate a simple, environmentally friendly method for the mass production of WO<sub>3</sub> nanoparticles for various applications.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7003 - 7007"},"PeriodicalIF":2.5,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-Principles Study on the Structural, Mechanical, Electronic Structure, Thermal, and Thermophysical Properties of XS (X = Ge, Sn, Pb) Monochalcogenides XS (X = Ge, Sn, Pb)单硫系化合物结构、力学、电子结构、热学和热物理性质的第一性原理研究
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-16 DOI: 10.1007/s11664-025-12178-x
Muhammad Amir Rafiq, Tahira Batool, Altaf Hussain, Muhammad Haseeb, Muhammad Nasir Rasul, Athar Javed
{"title":"First-Principles Study on the Structural, Mechanical, Electronic Structure, Thermal, and Thermophysical Properties of XS (X = Ge, Sn, Pb) Monochalcogenides","authors":"Muhammad Amir Rafiq,&nbsp;Tahira Batool,&nbsp;Altaf Hussain,&nbsp;Muhammad Haseeb,&nbsp;Muhammad Nasir Rasul,&nbsp;Athar Javed","doi":"10.1007/s11664-025-12178-x","DOIUrl":"10.1007/s11664-025-12178-x","url":null,"abstract":"<div><p>The physical properties of XS (X = Ge, Sn, Pb) monochalcogenides have been studied by means of first-principles calculations. Among the four crystalline phases, orthorhombic GeS, orthorhombic SnS, and trigonal PbS have been found to be the most stable crystal structures, and their mechanical properties have been calculated, revealing that the orthorhombic GeS and SnS fulfill Born’s mechanically stability conditions, while trigonal PbS does not. The calculated Poisson’s ratio and Pugh’s ratio indicate the brittle and ductile nature of orthorhombic GeS and orthorhombic SnS, respectively, while the calculated bulk modulus of GeS shows isotropic behavior. The higher value of the Debye temperature indicates that the orthorhombic GeS has more discrete vibrational modes. Electronic band structure calculations reveal that the XS (X = Ge, Sn) monochalcogenides exhibit a <i>p</i>-type semiconducting nature. Orthorhombic GeS exhibits a direct bandgap of <i>E</i><sub>g</sub> = 1.14 eV, while orthorhombic SnS has an indirect <i>E</i><sub>g</sub> = 1.149 eV.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7109 - 7125"},"PeriodicalIF":2.5,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of an Electrochemical Sensor for L-Tryptophan Detection Using a Novel Iridium–Zirconium-Based Catalyst 基于新型铱锆基催化剂的l -色氨酸电化学传感器的研制
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-16 DOI: 10.1007/s11664-025-12161-6
Omrüye Ozok Arıcı
{"title":"Development of an Electrochemical Sensor for L-Tryptophan Detection Using a Novel Iridium–Zirconium-Based Catalyst","authors":"Omrüye Ozok Arıcı","doi":"10.1007/s11664-025-12161-6","DOIUrl":"10.1007/s11664-025-12161-6","url":null,"abstract":"<div><p>This study focuses on the preparation and characterization of catalysts composed of iridium (Ir) and zirconium (Zr) supported on carbon nanotubes (CNTs) for use in a sensitive electrochemical sensor. The catalysts were synthesized using the NaBH<sub>4</sub> reduction method. The characterization of the Ir-Zr/CNT catalysts was performed using scanning electron microscopy and energy dispersive x-ray spectroscopy, as well as x-ray diffraction techniques. The Ir-Zr/CNT catalyst was then used to modify a glassy carbon electrode (GCE) to develop an electrochemical sensor for the detection of L-Tryptophan (L-Trp). The electrochemical performance of the sensor was evaluated using cyclic voltammetry, linear sweep voltammetry differential pulse voltammetry, and electrochemical impedance spectroscopy. The sensor, Ir-Zr/CNT-GCE, demonstrated excellent performance, including a linear response to L-Trp in the concentration range of 20–500 <i>µ</i>M. The sensor exhibited a current sensitivity of 0.0003 mA/<i>µ</i>M cm<sup>2</sup> and a detection limit of 0.06 <i>µ</i>M, with a signal-to-noise ratio (S/N) of 3, indicating high sensitivity and effectiveness for L-Trp detection.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7244 - 7253"},"PeriodicalIF":2.5,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Piezoelectric Properties of A-Site Na and Ce Co-Substituted Bismuth Titanate-Ferrite (Bi5Ti3FeO15) for High-Temperature Applications a位Na和Ce共取代钛酸铋铁氧体(Bi5Ti3FeO15)高温压电性能研究
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-16 DOI: 10.1007/s11664-025-12169-y
Chao Yu, Yi-Jun Wan, Xin-Yu Yu, En-Meng Liang, Ubaid Ur Rehman, Wei-Jing Kong, Chun-Ming Wang
{"title":"Piezoelectric Properties of A-Site Na and Ce Co-Substituted Bismuth Titanate-Ferrite (Bi5Ti3FeO15) for High-Temperature Applications","authors":"Chao Yu,&nbsp;Yi-Jun Wan,&nbsp;Xin-Yu Yu,&nbsp;En-Meng Liang,&nbsp;Ubaid Ur Rehman,&nbsp;Wei-Jing Kong,&nbsp;Chun-Ming Wang","doi":"10.1007/s11664-025-12169-y","DOIUrl":"10.1007/s11664-025-12169-y","url":null,"abstract":"<div><p>Piezoelectric materials are among the most essential functional materials, with widespread applications across various fields. As the demands of industries such as aerospace continue to evolve, the need for high-temperature piezoelectric materials has become more critical. Bismuth layer-structured ferroelectric (BLSF) bismuth titanate-ferrite (Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub>), is a typical bismuth-layered piezoelectric compound, known for its high Curie temperature (<i>T</i><sub>C</sub> ~ 761°C). Despite its promising properties, the application of Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub> at elevated temperatures is hindered by issues such as a low piezoelectric constant and poor direct-current (dc) electrical resistivity. In this study, we report a significant enhancement in the piezoelectric properties of Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub> at high temperatures through the co-substitution of sodium (Na) and cerium (Ce) into the Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub> lattice. The crystal structure, microstructure, and dielectric, electrical, ferroelectric, and piezoelectric properties of Bi<sub>5−<i>x</i></sub>(NaCe)<sub><i>x</i>/2</sub>Ti<sub>3</sub>FeO<sub>15</sub> (BTF-100<i>x</i>NaCe), were thoroughly investigated. Our results reveal that the piezoelectric constant (<i>d</i><sub>33</sub>) of BTF-14NaCe is significantly improved, reaching 22.8 pC/N, which is three times that of pristine Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub> (7.1 pC/N), while the <i>T</i><sub>C</sub> remains nearly unchanged at approximately 760°C. Furthermore, BTF-14NaCe exhibits significantly enhanced high-temperature dc electrical resistivity, with values of 1.93 × 10<sup>7</sup> Ω·cm at 400°C and 1.28 × 10<sup>6</sup> Ω·cm at 500°C, nearly two orders of magnitude higher than those of Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub> (6.98 × 10<sup>5</sup> Ω·cm at 400°C, 7.63 × 10<sup>4</sup> Ω·cm at 500°C). Additionally, BTF-14NaCe demonstrates remarkable thermal stability of both piezoelectric and electromechanical properties up to 400°C. These findings indicate that the Bi<sub>5</sub>Ti<sub>3</sub>FeO<sub>15</sub>-based ceramic material holds considerable potential as an advanced candidate for high-temperature piezoelectric applications.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7096 - 7108"},"PeriodicalIF":2.5,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-Principles Study of the Electronic Structure and Optical Properties of Sn-Cl Co-doped β-Ga2O3 Sn-Cl共掺杂β-Ga2O3的电子结构和光学性质的第一性原理研究
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-16 DOI: 10.1007/s11664-025-12179-w
Lin Chen, Haixia Li, Shangju Chen
{"title":"First-Principles Study of the Electronic Structure and Optical Properties of Sn-Cl Co-doped β-Ga2O3","authors":"Lin Chen,&nbsp;Haixia Li,&nbsp;Shangju Chen","doi":"10.1007/s11664-025-12179-w","DOIUrl":"10.1007/s11664-025-12179-w","url":null,"abstract":"<div><p>This paper systematically investigates the influence of different Sn-Cl co-doping concentrations on the electronic structure and optical properties of β-Ga<sub>2</sub>O<sub>3</sub> by employing density functional theory (DFT) calculations based on the generalized gradient approximation with Hubbard correction (GGA+U). The results demonstrate that the co-doped systems exhibit excellent thermodynamic stability under oxygen-rich conditions. The synergistic incorporation of Sn<sup>4+</sup> and Cl<sup>−</sup> ions induces microstructural lattice expansion and bond-length adjustments, effectively introducing shallow energy states, significantly reducing the bandgap, and enhancing carrier activity. Particularly, at a doping concentration of 2.5 at.%, the system displays metal-like properties. Furthermore, at doping levels of 1.67 at.% and 2.5 at.%, the materials show remarkable optical absorption performance spanning the visible to ultraviolet region and exhibit notably low reflectivity, with significantly improved optical responses in the spectral range of 150–500 nm, while maintaining structural stability. This study provides theoretical guidance for tuning and optimizing the optoelectronic properties of β-Ga<sub>2</sub>O<sub>3</sub>, offering important reference value for potential practical applications.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7609 - 7619"},"PeriodicalIF":2.5,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuned Structural and Water Diffusion in Single-Walled Carbon Nanotubes Using Molecular Dynamics Simulations 单壁碳纳米管中调谐结构和水扩散的分子动力学模拟
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-15 DOI: 10.1007/s11664-025-12176-z
Ammara Naz, Muhammad Kashif, Qurat ul Ain Asif, Alina Manzoor, Ama tul Zahra, Umedjon Khalilov, Aamir Shahzad
{"title":"Tuned Structural and Water Diffusion in Single-Walled Carbon Nanotubes Using Molecular Dynamics Simulations","authors":"Ammara Naz,&nbsp;Muhammad Kashif,&nbsp;Qurat ul Ain Asif,&nbsp;Alina Manzoor,&nbsp;Ama tul Zahra,&nbsp;Umedjon Khalilov,&nbsp;Aamir Shahzad","doi":"10.1007/s11664-025-12176-z","DOIUrl":"10.1007/s11664-025-12176-z","url":null,"abstract":"<div><p>Single-walled carbon nanotubes (SWCNTs) have garnered a noteworthy role in recent years due to their exceptional strength and flexibility and their wide-range applicability. Alongside promising applications of SWCNTs, concerns regarding the potential tunable structure of nanotubes tagged water diffusion in SWCNTs have emerged. In this present work, we explore the effects of SWCNT nanostructure over water diffusion and the influence of system temperatures and flow rates on bond dynamics. For molecular mechanics, we have performed molecular dynamics (MD) simulations and found that water diffusion increases linearly with an increase in temperature, but a very slow increment is observed at varying flow rates. Using the radial distribution function (RDF), we have revealed that the SWCNTs lead to an improvement of clustered structures and enhanced water diffusion for varying flow rates. The obtained diffusion coefficients have been found to be in good agreement with previously reported MD simulation data, validating the accuracy of the current computational approach. These insights contribute to a deeper understanding of water behavior and are important for applications in nanofluidics and biomedical applications.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7081 - 7095"},"PeriodicalIF":2.5,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145121987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Silver Nanowire Concentration on Electrical and Optical Properties of Polyaniline for Transparent Conductive Sensors 银纳米线浓度对透明导电传感器用聚苯胺电学和光学性能的影响
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-15 DOI: 10.1007/s11664-025-12174-1
Nagaraj Basavegowda, Rishabh Chaturvedi, S. Sunitha, Vinayagam Mohanavel, K Guruprakash, R. Venkatesh, S Sathiyamurthy, Manzoore Elahi M. Soudagar, A. H. Seikh
{"title":"Influence of Silver Nanowire Concentration on Electrical and Optical Properties of Polyaniline for Transparent Conductive Sensors","authors":"Nagaraj Basavegowda,&nbsp;Rishabh Chaturvedi,&nbsp;S. Sunitha,&nbsp;Vinayagam Mohanavel,&nbsp;K Guruprakash,&nbsp;R. Venkatesh,&nbsp;S Sathiyamurthy,&nbsp;Manzoore Elahi M. Soudagar,&nbsp;A. H. Seikh","doi":"10.1007/s11664-025-12174-1","DOIUrl":"10.1007/s11664-025-12174-1","url":null,"abstract":"<div><p>Polyaniline (PANI) stands out as a highly promising conductive polymer, finding extensive applications in optoelectronic and electronic fields due to its lightweight nature, flexibility, exceptional chemical and thermal stability, and impressive conductivity. Despite these advantages, PANI suffers from low transparency, primarily attributable to its opaque film and limited conductivity in neutral environments. This opacity not only reduces optical visibility but also adversely impacts the performance of PANI in transparent conductive sensors. To overcome these challenges, this study explores the influence of incorporating silver nanowires into PANI. PANI was synthesized with varying concentrations of silver nanowires (0%, 10%, 20%, and 30%) through in situ polymerization, using ammonium persulfate as the oxidizing agent. The composite materials were meticulously evaluated by measuring crystalline size, electrical conductivity, sensitivity, optical transparency, and sheet resistance. X-ray diffraction analysis confirmed the successful integration of silver nanowires into the PANI matrix, leading to notable enhancements in crystallinity, conductivity, stability, and sensitivity. The PANI containing 30% silver nanowires achieved an impressive crystalline size of 27 nm and demonstrated remarkable conductivity of 41 S/cm. Moreover, its sheet resistance decreased to an impressive 230 Ω/sq, while optical transparency soared to 63%. The sensitivity of the material also surged to 4.0, reflecting a staggering 400% improvement. The study discusses the trade-off between conductivity and transparency, revealing that the PANI/30% silver nanowire composite could provide balanced performance for transparent conductive sensor applications.</p></div>","PeriodicalId":626,"journal":{"name":"Journal of Electronic Materials","volume":"54 9","pages":"7232 - 7243"},"PeriodicalIF":2.5,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145121882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabulous sensing of N,N-Dimethylformamide (DMF) Vapor Using Hydrothermally Prepared Zinc Oxide/Graphene Nanoplatelets Nanocomposite 水热法制备的氧化锌/石墨烯纳米片纳米复合材料对N,N-二甲基甲酰胺(DMF)蒸气的传感
IF 2.5 4区 工程技术
Journal of Electronic Materials Pub Date : 2025-07-14 DOI: 10.1007/s11664-025-12124-x
Abbas Bagheri Khatibani, Somayeh Saadat Niavol, Samaneh Rasouli Jamnani, Hossain Milani Moghaddam, Alireza Azadbar
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