Iranian Polymer Journal最新文献

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Development of ZnMOF@MGO-modified thin-film nanocomposite nanofiltration membranes for enhanced heavy metal ions removal from water ZnMOF@MGO-modified薄膜纳米复合纳滤膜对水中重金属离子去除效果的研究
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-07-03 DOI: 10.1007/s13726-026-01660-w
Milad Jahan Ara, Assadollah Malekzadeh, Seyedsaman Mousavian, Ali Jelvehgar Filband
{"title":"Development of ZnMOF@MGO-modified thin-film nanocomposite nanofiltration membranes for enhanced heavy metal ions removal from water","authors":"Milad Jahan Ara,&nbsp;Assadollah Malekzadeh,&nbsp;Seyedsaman Mousavian,&nbsp;Ali Jelvehgar Filband","doi":"10.1007/s13726-026-01660-w","DOIUrl":"10.1007/s13726-026-01660-w","url":null,"abstract":"<div><p>This work presents the development of thin-film nanocomposite (TFN) nanofiltration membranes incorporating a Zn-based metal–organic framework/magnetic graphene oxide (ZnMOF@MGO) hybrid nanofiller to enhance the removal of toxic heavy metal ions from water. The ZnMOF@MGO particles were synthesized through a stepwise growth and magnetic integration process and characterized using FTIR, XRD, SEM, and VSM analyses, confirming successful hybrid formation and nanoscale crystallinity. These nanohybrids were dispersed within a polysulfone support and further integrated into the polyamide selective layer via interfacial polymerization to produce TFN membranes with filler loadings ranging from 0.1 to 0.5wt%. The membranes exhibited improved surface hydrophilicity (contact angle reduced from 69.54 to 48.55°), modified morphology, and enhanced structural tightness as evidenced by a decreased MWCO (700 Da for TFN0.2). Performance evaluation showed that the TFN0.2 membrane achieved the best overall separation efficiency, delivering a water flux of 116.3 L/m<sup>2</sup>·h along with high rejection of Pb<sup>2+</sup> (99.14%), Hg<sup>2+</sup> (82.18%), and As<sup>3+</sup> (77.89%). Antifouling tests using BSA demonstrated a significant improvement in flux recovery (FRR = 98.55%) compared to the pristine TFC membrane. Although TFN0.5 exhibited slightly higher flux, excess nanofiller caused agglomeration and reduced selectivity. The results highlight the synergistic effects of ZnMOF@MGO nanohybrids in providing enhanced hydrophilicity, structural stability, permeability, and fouling resistance, confirming their strong potential for advanced nanofiltration applications in heavy-metal-contaminated water treatment.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 11","pages":"2395 - 2415"},"PeriodicalIF":2.9,"publicationDate":"2026-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149219442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hole quality assessment of industrial waste-filled hybrid woven biopolymer composites using diverse coated tools 利用不同涂层工具对工业废物填充混合编织生物聚合物复合材料的孔质量评价
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-06-29 DOI: 10.1007/s13726-026-01670-8
Sasmita Kar, Sarojrani Pattnaik, Mihir Kumar Sutar
{"title":"Hole quality assessment of industrial waste-filled hybrid woven biopolymer composites using diverse coated tools","authors":"Sasmita Kar,&nbsp;Sarojrani Pattnaik,&nbsp;Mihir Kumar Sutar","doi":"10.1007/s13726-026-01670-8","DOIUrl":"10.1007/s13726-026-01670-8","url":null,"abstract":"<div><p>The drilling efficiency of multilayer biofiber-reinforced epoxy composites is examined by focusing on hybrid plain-woven fabric structures enhanced with nano-sized industrial waste (IW) filler. The study evaluates spindle speed, feed rate, and three tungsten carbide-coated tools (TiCrN, TiAlN and TiN) to assess hole quality based on delamination, surface roughness, and circularity error. The experimental procedures, based on Taguchi’s L9 orthogonal array, involve drilling composites reinforced with hybrid interwoven and intra-woven jute, white flax, and brown flax fibers, combined with 2% (by wt) nano-IW filler. Performance is influenced by the coating hardness and the interaction at the tool/composite interface. Delamination, surface roughness, and circularity error were evaluated based on drilling parameters. Results indicate that TiN-coated tools achieve a maximum reduction in delamination by 7.63% at the front, 9.39% at the back of the hole, and surface roughness by 47.16% for IW-filled composite. Meanwhile, TiCrN-coated tools resulted in a 26.04% reduction in circularity error for nano-filled composites. Drill tool coating was identified as the primary factor influencing hole quality, followed by spindle speed and feed rate. ANOVA and regression analyses confirmed the statistical significance and relative contribution of each parameter, highlighting the drilling conditions of the 9th trial as the most effective for enhancing hole quality with the applied coatings.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 12","pages":"2653 - 2675"},"PeriodicalIF":2.9,"publicationDate":"2026-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149375829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and properties of antibacterial composite aerogel based on wheat straw 麦秸抗菌复合气凝胶的制备及性能研究
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-06-12 DOI: 10.1007/s13726-026-01679-z
Xiran Lu, Ai Liu, Weiguang Wang, Xinyu Zhang, Wenbiao Xu, Xixin Duan, Junyou Shi, Xueqin Li, Xiangyu Li
{"title":"Preparation and properties of antibacterial composite aerogel based on wheat straw","authors":"Xiran Lu,&nbsp;Ai Liu,&nbsp;Weiguang Wang,&nbsp;Xinyu Zhang,&nbsp;Wenbiao Xu,&nbsp;Xixin Duan,&nbsp;Junyou Shi,&nbsp;Xueqin Li,&nbsp;Xiangyu Li","doi":"10.1007/s13726-026-01679-z","DOIUrl":"10.1007/s13726-026-01679-z","url":null,"abstract":"<div><p>The issue of waste utilization of wheat straw has been significant, the problem of straw utilization was solved by using waste straw to prepare functional materials. Biomass aerogel materials have great potential in the field of thermal insulation due to their excellent properties of low density, high specific surface area and high porosity. This research develops an antibacterial wheat straw-based aerogel through surface functionalization and demonstrates its extended applicability in multifunctional composites. Nano AgO(n-AgO) was selected as the antibacterial agent to evaluate the antibacterial efficacy of the composite aerogels in this research. XRD analysis confirmed that the prepared material contained Ag<sup>2+</sup> and SEM images revealed the uniform dispersion of n-AgO within the aerogel. The prepared aerogels exhibited a porosity of over 80%, indicating excellent adsorption and thermal insulation properties. When the addition amount of n-AgO was 0.4%, the maximum inhibitory zone diameters against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) were 1.7 and 2.4 cm, respectively, demonstrating the excellent antibacterial performance of the composite aerogels. This research not only provides a new approach for the comprehensive utilization of wheat straw but also offers new insights for the development of novel antibacterial materials.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 12","pages":"2765 - 2776"},"PeriodicalIF":2.9,"publicationDate":"2026-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149375816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of thermal, acoustical and wear properties for effective hybridization of Abutilon Indicum and hemp fiber in the epoxy-based composites 菊苣与大麻纤维在环氧基复合材料中有效杂化的热、声、磨损性能研究
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-06-11 DOI: 10.1007/s13726-026-01688-y
R. Anand, P. Nallasamy
{"title":"Investigation of thermal, acoustical and wear properties for effective hybridization of Abutilon Indicum and hemp fiber in the epoxy-based composites","authors":"R. Anand,&nbsp;P. Nallasamy","doi":"10.1007/s13726-026-01688-y","DOIUrl":"10.1007/s13726-026-01688-y","url":null,"abstract":"<div><p>Growing demand for sustainable composites has driven the exploration of natural materials hybridization. In this study, limitedly explored, <i>Abutilon Indicum</i> fiber was considered as epoxy reinforcement along with hemp. To investigate the effective proportion of <i>Abutilon Indicum</i> fiber in the epoxy composite, the samples were fabricated with balanced (AIHE-1) and unbalanced (AIHE-2 and AIHE-3) proportions of hemp and <i>Abutilon Indicum</i> through the compression moulding process and are compared over the <i>Abutilon Indicum</i> only inducted epoxy composite (AIE). The FTIR confirms the functional groups were consistent irrespective of the proportions of the reinforcements, indicating the stable interfacial bonding. The average crystalline size of the AIHE-1 was found to be 31.5 nm by XRD analysis. The better fiber distribution and interfacial bonding was found through SEM analysis for the AIHE-1. By that, AIHE-1 depicts higher thermal stability up to 374 °C, better sound absorption coefficient (average) of 0.20, and low surface roughness (average) of 55 nm as compared to AIE and unbalanced reinforcement composites. The wear analysis shows that the AIHE-1 has least wear rate of 0.12 mm<sup>3</sup>/N.m at the load of 30 N with the sliding speed of 2.25 m/s. These results suggest the balanced hybridization of <i>Abutilon Indicum</i> and hemp was recommended to use in interior automotive components for offering better thermal, acoustical, and wear properties.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 9","pages":"2059 - 2070"},"PeriodicalIF":2.9,"publicationDate":"2026-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative study on mechanical properties of polypropylene/ethylene-vinyl acetate copolymer blend compatibilized by a graft copolymer or filled with nanosilica 接枝共聚物增容与纳米二氧化硅填充聚丙烯/乙烯-醋酸乙烯共聚物共混物力学性能的比较研究
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-06-03 DOI: 10.1007/s13726-026-01677-1
Jingru Liu, Wei Tan, Yadong Chen
{"title":"Comparative study on mechanical properties of polypropylene/ethylene-vinyl acetate copolymer blend compatibilized by a graft copolymer or filled with nanosilica","authors":"Jingru Liu,&nbsp;Wei Tan,&nbsp;Yadong Chen","doi":"10.1007/s13726-026-01677-1","DOIUrl":"10.1007/s13726-026-01677-1","url":null,"abstract":"<div><p>In current work, the comparative study on mechanical properties of polypropylene/ethylene-vinyl acetate copolymer (PP/EVA) blend with 80/20 weight ratio compatibilized by maleic anhydride grafted polypropylene (PP-<i>g</i>-MAH) or filled with nanosilica was performed. It was found that the blends compatibilized by PP-<i>g</i>-MAH possessed superior mechanical properties, owing to enhanced interfacial adhesion between PP and EVA phases and refined EVA droplets resulting from the bridging effect of PP-<i>g</i>-MAH. By contrast, nanosilica exclusively facilitates morphological compatibilization regardless of their surface properties, due to elevated viscoelasticity of the blends originating from its selective distribution, which is reflected in the refinement of the EVA dispersed phase domains. Silica nanoparticles serve as stress concentration points under the tensile load condition, giving rise to the depression in tensile properties of the blends. However, the incorporation of nanosilica could enhance the impact toughness of the blend through inducing the generation of more cavities and microvoids. Hydrophilic nanosilica has a better toughening effect than its hydrophobic counterpart for a given nanosilica concentration. This could be attributed to its stronger refinement effect on the EVA particles. This work offers a holistic insight into the compatibilization essence of copolymer and nanofiller in PP/EVA blends from the viewpoint of mechanical properties.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 12","pages":"2751 - 2763"},"PeriodicalIF":2.9,"publicationDate":"2026-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149375760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the Effect of modified gum arabic, modified Euphorbia trigona Mill, and their masterbatch on the antimicrobial and mechanical performance of poly(lactic acid) films 改性阿拉伯胶、大戟粉及其母粒对聚乳酸薄膜抗菌性能和力学性能影响的研究
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-06-02 DOI: 10.1007/s13726-026-01683-3
Kasahun Tsegaye Mekonnen, Melaku Tesfaye Alemea, Mulugta Yilma Tsegaye, Birhanu Zeleke Tilinti
{"title":"Study on the Effect of modified gum arabic, modified Euphorbia trigona Mill, and their masterbatch on the antimicrobial and mechanical performance of poly(lactic acid) films","authors":"Kasahun Tsegaye Mekonnen,&nbsp;Melaku Tesfaye Alemea,&nbsp;Mulugta Yilma Tsegaye,&nbsp;Birhanu Zeleke Tilinti","doi":"10.1007/s13726-026-01683-3","DOIUrl":"10.1007/s13726-026-01683-3","url":null,"abstract":"<div><p>The effect of in situ condensation polymerization is studied in relation to the tensile strength, elongation-at-break, light transmittance, thermal stability, and antimicrobial properties of poly(lactic acid) (PLA) films through the modification of gum arabic (OLLA-<i>g</i>-GA) and <i>Euphorbia trigona</i> Mill using lactic acid oligomers (ETML-<i>g</i>-OLLA). During the synthesis of OLLA-<i>g</i>-GA and OLLA-<i>g</i>-ETML, the initially hydrophilic properties of gum arabic and <i>Euphorbia trigona</i> Mill latex were transformed into hydrophobic characteristics owing to the grafting of in situ synthesized hydrophobic lactic acid oligomers (OLLA). Following this, biocomposite films were prepared using the solution casting method with modified gum arabic, <i>Euphorbia trigona</i> Mill latex, and masterbatch dispersed. A blend of modified gum arabica and <i>Euphorbia trigona</i> Mill latex, referred to as a masterbatch, was used. Subsequently, biocomposite films of PLA/OLLA-<i>g</i>-GA, PLA/OLLA-<i>g</i>-ETML, and PLA/masterbatch were produced and analyzed for their mechanical, thermal, transmittance, and antimicrobial characteristics. The addition of OLLA-<i>g</i>-GA (3%), OLLA-<i>g</i>-ETML (5%), and masterbatch OLLA<i>-g</i>-GA (3%) and OLLA-<i>g</i>-ETML (5%) led to an enhancement in tensile strength by 38.31%, 10.47% and 47%, respectively. The elongation-at-break increased by 20.62%, 31% and 34% with the incorporation of OLLA-<i>g</i>-GA (3%), OLLA-<i>g</i>-ETML (5%), and a masterbatch composed of OLLA-<i>g</i>-GA (3%) and OLLA-<i>g</i>-ETML (5%), respectively. The thermal stability of PLA decreased after the addition of the masterbatch; this was due to the filler having a lower thermal stability than the PLA polymer. The antibacterial properties of the biocomposite films were tested against both Gram-positive and Gram-negative bacteria, revealing that the produced films exhibited a greater zone of inhibition, indicating their potential use as antimicrobial packaging materials.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 12","pages":"2777 - 2790"},"PeriodicalIF":2.9,"publicationDate":"2026-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149375817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of different triblock copolymers on physicochemical properties and biodegradability of corn starch/chitosan films 不同三嵌段共聚物对玉米淀粉/壳聚糖薄膜理化性能和生物降解性的影响
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-05-29 DOI: 10.1007/s13726-026-01657-5
Enrique Javier Jiménez-Regalado, Abril Fonseca-García, Rocio Yaneli Aguirre-Loredo
{"title":"Effect of different triblock copolymers on physicochemical properties and biodegradability of corn starch/chitosan films","authors":"Enrique Javier Jiménez-Regalado,&nbsp;Abril Fonseca-García,&nbsp;Rocio Yaneli Aguirre-Loredo","doi":"10.1007/s13726-026-01657-5","DOIUrl":"10.1007/s13726-026-01657-5","url":null,"abstract":"<div><p>The development of environmentally friendly packaging materials is a globally significant issue due to the environmental problems caused by high production, excessive use, and improper disposal of synthetic plastics. Therefore, this study focuses on developing films based on natural polymers, such as starch and chitosan, and assessing the effects of adding different triblock copolymers on their physicochemical properties. The films were developed using the casting method, and their thermal, water adsorption, and wettability properties, as well as their biodegradability in water and compost, were examined at the laboratory level. Translucent, manageable films were obtained, with a thickness range of 53 to 127 μm. The results indicate that all formulated films display a mainly hydrophilic nature, with contact angles between 18° and 44°, and a swelling index from 49% to 65%. Films with triblock copolymers of molecular weight less than 3000 g/mol showed a lower water vapor absorption capacity (19%) under high relative humidity conditions (90%). According to FTIR and XRD analyses, using different triblock copolymers prevented starch retrogradation. However, they did not negatively impact the biodegradation process of these materials, as biodegradation in liquid water ranged from 36% to 40%, and reached 100% in compost at the laboratory level at 70 days. The study results show that adding different triblock copolymers or Pluronics to the starch/chitosan matrix enhances the functional properties of the films without impacting the biodegradation process. Therefore, incorporating uncommon additives like triblock copolymers into packaging material formulations is a feasible option for creating new materials.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 11","pages":"2445 - 2458"},"PeriodicalIF":2.9,"publicationDate":"2026-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149219446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterızatıon of MAT 59 and MAT 55 materıal model parameters of E-glass/epoxy composite material under thermal effect 热效应下e -玻璃/环氧复合材料的模型参数Characterızatıon
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-05-27 DOI: 10.1007/s13726-026-01680-6
Ersan Kirar
{"title":"Characterızatıon of MAT 59 and MAT 55 materıal model parameters of E-glass/epoxy composite material under thermal effect","authors":"Ersan Kirar","doi":"10.1007/s13726-026-01680-6","DOIUrl":"10.1007/s13726-026-01680-6","url":null,"abstract":"<div><p>Composites are materials with high specific strengths. These materials can be examined in terms of mechanical strength by experimental or finite element methods (FEM). It has been determined in the literature that various material models are used in modeling composite materials by finite element method. In order to model composite materials correctly by FEM, it is very important to determine the material model data (physical and non-physical parameters) correctly. However, there are limited studies in the literature on determining the physical and non-physical parameters used for Ls dyna software material models of materials. For this reason, the material model data of unidirectional glass/epoxy composite material in different temperature environments were determined by FEM (Ls dyna software and MAT 55/MAT 59 material models) in the study. Material model data were determined by comparing the experimental results of composite materials with the results obtained by the FEM. As a result of the study, both material model data were obtained and the effect of the thermal environment on the material model data was investigated. It was determined that the material model data also changed with the change of ambient temperatures. Moreover, it was determined that the MAT 59 material model gave better results.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 9","pages":"2043 - 2057"},"PeriodicalIF":2.9,"publicationDate":"2026-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aptitude of cyclodextrin inclusion complexes for the solubility escalation of poorly aqueous soluble drugs 环糊精包合物对难溶性药物溶解度提升的适应性
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-05-25 DOI: 10.1007/s13726-026-01678-0
Priya Dhiman, Vipul Rajput, Ishrat Zahoor
{"title":"Aptitude of cyclodextrin inclusion complexes for the solubility escalation of poorly aqueous soluble drugs","authors":"Priya Dhiman,&nbsp;Vipul Rajput,&nbsp;Ishrat Zahoor","doi":"10.1007/s13726-026-01678-0","DOIUrl":"10.1007/s13726-026-01678-0","url":null,"abstract":"<div><p>Cyclodextrins (CDs) are cyclic oligosaccharides that have gained extensive attention over the past few decades due to their unique molecular structure and versatile applications. Composed of glucose units linked by α-(1,4) glycosidic bonds, CDs possess a hydrophilic exterior and a hydrophobic internal cavity, enabling them to form inclusion complexes with a wide range of poorly water-soluble guest molecules. This encapsulation capability enhances the solubility, stability, dissolution rate, and bioavailability of drugs, making CDs highly valuable pharmaceutical excipients. Among the naturally occurring CDs α-, β-, and γ-CDs and numerous chemically modified derivatives such as hydroxypropyl-β-CD, methylated-β-CD, and sulfo-butylether-β-CD have been developed to improve their physicochemical and complexation properties. In addition to pharmaceuticals, CDs are widely utilized in cosmetics, food, textiles, and agricultural formulations due to their biocompatibility, biodegradability, and ability to mask unpleasant tastes and odors. Their structural flexibility also supports applications in nanotechnology, catalysis, and environmentally friendly “green polymerization” processes. Moreover, the review also focuses on molecular modelling and characterization of CD–drug inclusion complexes to better understand host–guest interactions and optimize controlled drug delivery systems. Overall, cyclodextrins act as multifunctional, eco-friendly carriers capable of improving the performance of diverse bioactive compounds. Their tunable chemistry and sustainable nature make them a bridge between fundamental molecular science and advanced industrial and biomedical technologies, reinforcing their status as indispensable tools in modern formulation and material design.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 12","pages":"2791 - 2806"},"PeriodicalIF":2.9,"publicationDate":"2026-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149375815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical prediction of roughness parameters for rubber surface morphology 橡胶表面形貌粗糙度参数的数值预测
IF 2.9 3区 化学
Iranian Polymer Journal Pub Date : 2026-05-25 DOI: 10.1007/s13726-026-01676-2
Zhengtong Zhou, Zepeng Wang
{"title":"Numerical prediction of roughness parameters for rubber surface morphology","authors":"Zhengtong Zhou,&nbsp;Zepeng Wang","doi":"10.1007/s13726-026-01676-2","DOIUrl":"10.1007/s13726-026-01676-2","url":null,"abstract":"<div><p>Rubber materials are widely employed in sealing, vibration damping, and dynamic contact engineering applications due to their exceptional elasticity and damping properties. The surface morphology roughness of rubber directly influences interfacial tribological behavior, sealing reliability, and fatigue life. Currently, characterization of surface roughness primarily relies on physical testing methods, which lack effective theoretical prediction approaches. However, physical testing significantly increases both temporal cycles and economic costs. To address the demand for efficient prediction of rubber surface roughness parameters, this study innovatively proposes a machine learning-based numerical prediction method. A comparative investigation was conducted on three machine learning models—artificial neural network (ANN), convolutional neural network (CNN), and recurrent neural network (RNN)—focusing on their core performance metrics and predictive capabilities. The results demonstrate that RNN exhibits significant superiority over ANN and CNN in core performance indicators. Regarding final prediction performance, RNN achieved high prediction accuracy rates of 93.6%, 92.9%, 91.88%, and 93.06%, outperforming ANN and CNN models with more precise and stable predictive accuracy. This model effectively resolves the issues of low efficiency and poor repeatability inherent in traditional contact measurement methods, thereby providing a novel approach for intelligent assessment of surface quality in rubber products.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"35 12","pages":"2723 - 2736"},"PeriodicalIF":2.9,"publicationDate":"2026-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149375814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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