Güneş Akın Doğan, Richard Wascher, Georg Avramidis, Wolfgang Viöl, Christoph Gerhard
{"title":"Influence of wood modification on parameter settings and treatment results in CO2 laser structuring of beech veneers","authors":"Güneş Akın Doğan, Richard Wascher, Georg Avramidis, Wolfgang Viöl, Christoph Gerhard","doi":"10.1186/s40712-024-00192-6","DOIUrl":"10.1186/s40712-024-00192-6","url":null,"abstract":"<div><p>In this study, the possible influences of thermal modification of wood on the quality of laser texturing of beech veneers are investigated by comparing native and thermally modified samples. By varying the process parameters of a CO<sub>2</sub> laser, the surfaces of both types of veneer were textured and the resulting surface roughness and aspect ratios were analyzed in order to evaluate the efficiency of the laser texturing and the quality of the textures produced. The main results show that the thermal modification of the wood influences the cutting widths, the removal depths, and the surface roughness, with thermally modified veneers generally having larger cutting widths and different removal depths compared to native veneers, indicating the influence of the wood modifications on the material physical and chemical properties and their interaction with the laser processing. Furthermore, the study shows how the laser processing parameters—feed rate and laser power—influence the surface quality and structural dimensions of the engraved lines, and establishes that the moisture content of the wood has a significant influence on its thermal conductivity and thus on the laser cutting process. The research work highlights the complexity of laser texturing of wood and emphasizes the need to take into account the change in the intrinsic properties of the material as a result of thermal modification.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00192-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142714263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and characterization of titanium oxynitride catalyst via direct ammonia nitridation of titanium polyacrylate for oxygen reduction reaction","authors":"Yushi Tamaki, Satoshi Seino, Naoki Shinyoshi, Yuta Uetake, Takaaki Nagai, Ryuji Monden, Akimitsu Ishihara, Takashi Nakagawa","doi":"10.1186/s40712-024-00189-1","DOIUrl":"10.1186/s40712-024-00189-1","url":null,"abstract":"<div><p>A titanium oxynitride catalyst for the oxygen reduction reaction (ORR) in polymer electrolyte fuel cells was synthesized through the direct ammonia nitridation of titanium complexes. Titanium polyacrylate was employed as the catalyst precursor, and the effect of the calcination temperature between 600 and 1000 °C on the catalyst structure was studied. The catalysts were characterized via X-ray diffraction, X-ray absorption spectroscopy, transmission electron microscopy, cyclic voltammetry, and powder electrical resistivity measurements. The formation of titanium oxynitride particles and deposited carbon was observed for all the samples; however, significant variations in the catalyst structure and catalytic activity were also observed. With an increase in the calcination temperature, nitridation of titanium oxynitride progressed, and the conductivity of the catalyst powder increased. The highest rest potential and ORR current density were achieved with calcination at 800 °C. Importantly, the results suggest that maintaining an optimal nitrogen doping level within the catalyst particles, along with ensuring the formation of electroconductive deposited carbon, is essential for achieving a high ORR current. This work introduces the direct ammonia nitridation of metal complexes as a promising process for designing metal oxynitride catalysts.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00189-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142664473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Some studies on Abelmoschus esculentus (Indian Okra) fiber characteristics","authors":"Prafull Prabhakar Kolte, Vijay Sitaram Shivankar","doi":"10.1186/s40712-024-00188-2","DOIUrl":"10.1186/s40712-024-00188-2","url":null,"abstract":"<div><p>Okra fiber is the bast fiber, extracted from the stem of the Abelmoschus esculentus plant which belongs to the Malvaceae family. In the whole world, India is the largest producer of okra for the cultivation of “okra fruit”, which is one of the main vegetables in the Indian Diet. After collecting vegetables, a huge amount of okra plant stem is discarded on the field annually as agricultural waste. Okra stem is an abundant source of okra fiber which can be used for various textile applications. This study aims understand the basic morphological, thermal and structural characteristics of okra fibre and compare it with other bast fibres generally used for textile application to prove the suitability of okra fibre for textile application.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00188-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Geothermo-mechanical energy conversion using shape memory alloy heat engine","authors":"Abubakar R. A., Nuhu I.","doi":"10.1186/s40712-024-00185-5","DOIUrl":"10.1186/s40712-024-00185-5","url":null,"abstract":"<div><p>The shift towards renewable energy sources like geothermal energy has become desirable due to the recurrent energy crisis and global warming challenges influenced by fossil fuels. Geothermo-mechanical energy conversion using shape memory alloy (SMA) heat engines presents a novel and sustainable approach for harnessing geothermal energy. Shape memory alloys, known for their ability to undergo reversible phase transformations driven by temperature changes, are ideal for thermal-to-mechanical energy conversion. This paper explores the design and performance of an SMA heat engine that utilizes geothermal heat sources to drive mechanical work. The engine operates by cycling between the high-temperature geothermal environment and a cooler sink, exploiting the shape memory effect to generate mechanical motion. By integrating geothermal energy and SMA technology, this system offers a potential solution for renewable energy generation, with applications in remote or off-grid locations. The paper also investigates output power and the thermodynamic efficiency. A model is formulated and the engine behavior is simulated. A series of experiments are conducted for engine output power and efficiency. The model is compared to the experimental data for validation. The engine developed a maximum power of 3.5, 8.5, and 11.5 watts at 60, 80, and 90 °C respectively. The proposed SMA-based geothermo-mechanical energy conversion system offers a promising solution for efficient, reliable, and scalable geothermal energy harvesting. This research contributes to the development of innovative, efficient geothermal energy conversion technologies, supporting global renewable energy goals and reducing greenhouse gas emissions. This innovative energy conversion mechanism could play a key role in the future of sustainable power generation.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00185-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Graphitic carbon nitride-modified cerium ferrite: an efficient photocatalyst for the degradation of ciprofloxacin, ampicillin, and erythromycin in aqueous solution","authors":"Adewale Adewuyi, Rotimi A. Oderinde","doi":"10.1186/s40712-024-00183-7","DOIUrl":"10.1186/s40712-024-00183-7","url":null,"abstract":"<div><p>Incomplete removal of antibiotics by most known wastewater treatment plants is a global challenge. Therefore, graphitic carbon nitride-modified cerium ferrite (CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub>) was synthesized to remove antibiotics (ampicillin, ciprofloxacin and erythromycin) from water. CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub> showed activity in the visible light with a Tauc plot revealing the bandgap energy (2.46 eV). The scanning electron micrograph (SEM) result revealed the surface of CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub> to be heterogeneous, while the transmission electron micrograph (TEM) image confirmed a flaky with rod and oval shaped surface (average particle size of 42.22 nm). CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub> exhibited a 100% removal of all the studied antibiotics from aqueous solution in a photocatalytic degradation that is described by pseudo-1st-order kinetics. CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub> demonstrated a high regeneration capacity, which is above 90% at the 12th cycle of treatment without any observable changes in its phase structure which suggests a promising chemical stability and reusability. CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub> compared favourably with some selected antibiotic degradable photocatalysts suggesting the economic viable of CeFe<sub>2</sub>O<sub>4</sub>@g-C<sub>3</sub>N<sub>4</sub> as photocatalyst for the purification of antibiotics-contaminated water.\u0000</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00183-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142595467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Development of glass sealants for proton conducting ceramic cells: materials, concepts and challenges","authors":"Xanthi Georgolamprou, Ilaria Ritucci, Stéven Pirou, Ragnar Kiebach","doi":"10.1186/s40712-024-00184-6","DOIUrl":"10.1186/s40712-024-00184-6","url":null,"abstract":"<div><p>In this study, we have successfully developed and tested sealing concepts for symmetrical, planar proton-conducting ceramic cells (PCCCs). Three glass sealants from the field of solid oxide cells were investigated as potential compatible sealing materials for PCCCs. The most promising results were obtained with a SiO<sub>2</sub>-MgO-CaO-Na<sub>2</sub>O-Al<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub>-B<sub>2</sub>O<sub>3</sub> glass, which provided a dense, crack-free sealant between the proton-conducting ceramic cells and the Al<sub>2</sub>O<sub>3</sub>-coated ferritic steels. During the sealing process, a reaction layer between the interface of the BaCe<sub>0.2</sub>Zr<sub>0.7</sub>Y<sub>0.1</sub>O<sub>3-δ</sub> contained in the PCCCs and the glass–ceramic, occurred. Here, we propose a reaction mechanism for this interaction and discuss its impact on potential applications. Moreover, next to evaluating potential glass sealants, we have successfully designed and demonstrated a new sealing geometry that prevents a potential gas crossover in the symmetrical proton-conducting ceramic cell.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00184-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohammad Hosein Beheshti, Ali Khavanin, Mostafa Jafarizaveh, Akram Tabrizi
{"title":"A novel acoustic micro-perforated panel (MPP) based on sugarcane fibers and bagasse","authors":"Mohammad Hosein Beheshti, Ali Khavanin, Mostafa Jafarizaveh, Akram Tabrizi","doi":"10.1186/s40712-024-00173-9","DOIUrl":"10.1186/s40712-024-00173-9","url":null,"abstract":"<div><p>Natural materials are becoming a reliable alternative to traditional artificial materials used in sound absorption insulation. The present study was conducted to investigate the acoustic insulation of micro-perforated panel (MPP) based on sugarcane fibers and bagasse as an available and environmentally friendly material. The absorption properties of single- and double-leaf natural micro-perforated panels (MPP) made of bagasse and also nonnatural MPPs made of Plexiglass were measured using an impedance tube based on ISO 10534–2. Then the effect of bagasse and sugarcane fibers composite on the air gap of MPP was investigated. The results showed the peak sound absorption of the bagasse composite is in the range of 1000 to 2000 Hz, and the sugarcane fiber composite has a higher sound absorption coefficient than the bagasse composite. Also, natural MPPs have a higher absorption coefficient than nonnatural MPPs at all frequencies, and as the panel thickness increases, the peak absorption coefficient shifts to lower frequencies. The peak sound absorption coefficient of double-leaf MPPs made of bagasse is 76%, in the range of 160 to 200 Hz. Using sugarcane fiber composite in the air gap of single- and double-leaf natural MPPs causes the absorption peak to shift to frequencies below 100 Hz. According to the results, natural MPPs have a high sound absorption coefficient at low frequencies. These panels can control sounds with much lower frequencies, especially in a double layer and along with cane fiber composite in their air gap.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00173-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142328438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Niranjan Patra, Prathipati Ramesh, Vaishnavi Donthu, Akil Ahmad
{"title":"Biopolymer-based composites for sustainable energy storage: recent developments and future outlook","authors":"Niranjan Patra, Prathipati Ramesh, Vaishnavi Donthu, Akil Ahmad","doi":"10.1186/s40712-024-00181-9","DOIUrl":"10.1186/s40712-024-00181-9","url":null,"abstract":"<div><h2>Abstract\u0000</h2><div><p>Over the past decade, biopolymers made from renewable resources like plants, algae, seashell waste, and seaweed have become increasingly popular as industries strive to reduce their environmental pollution without compromising socioeconomic growth. Biopolymers are often regarded as a significant alternative to conventional materials due to their low weight, great strength, stiffness, biostability, and non-toxicity. Therefore, industries are beginning to adopt the use of biopolymers, including those dealing with packaging, agriculture, automobiles, healthcare, as well as energy harvesting. Supercapacitors and batteries are two examples of electrochemical devices for energy storage that can be made using bespoke biopolymers and their composites. Although biopolymers’ potential uses are restricted, they are nevertheless useful when combined with other materials to create composites. This boosts the electrochemical efficiency of the biologically active molecules and also enhances their inherent physical features. This review focuses on recent developments, specifically the use of diverse biopolymers and composites for batteries and supercapacitor applications, followed by future perspectives.</p></div></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00181-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142328437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Three new reduced forms of synthesized Schiff bases as potent anti-corrosion inhibitors for carbon steel in artificial seawater","authors":"Hojat Jafari, Elham Ameri, Fariba Soltanolkottabi, Avni Berisha","doi":"10.1186/s40712-024-00177-5","DOIUrl":"10.1186/s40712-024-00177-5","url":null,"abstract":"<div><p>As part of the development of a new organic entity, we synthesized three new reduced forms of Schiff bases named 2,2’-(((2,2-dimethylpropane-1,3-diyl)bis(azanediyl)bis(methylene)disphenol (I1), 4,4’-(((2,2-dimethylpropane-1,3-diyl)bis (azanediyl)bis(methylene)bis(2-methoxyphenol) (I2), and 6,6’-(((2,2-dimethylpropane-1,3-diyl) bis(azanediyl)bis(methylene)bis(2-methoxyphenol) (I3). In order to develop new organic ligands to inhibit steel corrosion in 1M HCl solution, various electrochemical methods, such as electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP), along with surface visualization through atomic force microscopy (AFM), were employed. PDP results revealed excellent inhibition by compound I3 (71%) at a concentration of 1 mg/L. These findings were supported by the observation of a protective layer formation during prolonged immersion of steel in a corrosive solution, with or without inhibitors. In addition to gaining insights into the interaction mechanism and adsorption mode, density functional theory, Monte Carlo, and molecular dynamic simulations were conducted, revealing valuable information about the interaction of the inhibitors with the steel surface. Average surface roughness (<i>R</i><sub><i>a</i></sub>) values obtained for the artificial seawater in the absence and presence of inhibitor are 887 nm for blank, 195 nm for I1, 158 nm for I2, and 105 nm for I3.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00177-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320570","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Vanitha, Rithikaa Thanigaiselvan, M. Manivannan, R. Jeyalakshmi, S. N. Megha, M. Kesavan
{"title":"Expounding the application of nano and micro silica as a complementary additive in metakaolin phosphate geopolymer for ceramic applications—micro and nanoscale structural investigation","authors":"N. Vanitha, Rithikaa Thanigaiselvan, M. Manivannan, R. Jeyalakshmi, S. N. Megha, M. Kesavan","doi":"10.1186/s40712-024-00176-6","DOIUrl":"10.1186/s40712-024-00176-6","url":null,"abstract":"<div><p>Metakaolin phosphate geopolymers comprising poly-phospho-siloxo units are known for their structural performance, additionally advancing their microstructure with the transformation of crystalline berlinite phases at elevated temperatures. The intrinsic reaction of Al of metakaolin in the acid exploited, but the reaction of secondary silica phases is limitedly known. Metakaolin as a primary precursor (M) with the addition of 2% and 5% of nano silica (MS2 and MS5) and micro silica (MM2 and MM5) cast using 8-M phosphoric acid was cured at 80 °C. To enhance the utilization of geopolymer in any high-temperature applications, the structural transformations were studied after heating to various temperatures (200, 400, 600 and 800 °C) by XRD, Raman, TGA-DTA, SEM, XPS, FTIR and MAS-NMR. Sample M attained a strength of 46.2 MPa enhanced to 63.6 MPa in MS5 and 54.2 MPa in MM5. This can be ascribed from the transformation of Si–O–Al–O–Si into Si–O–Al–O–P from Raman bands. Comparing the chemical shift of Al (IV) to control, micro silica addition shifts the signal to a lower field (53 to 50 ppm) related to the increase of the number of Al-connected Si to give a tougher network. Nanoindentation is visualized from hardness and elasticity, and the corresponding values are 1.4 to 2.1 GPa and 0.8 to 1.4 GPa for loads ranging from 20 to 100 mN in silica-reinforced samples that are much higher than M. The micro and macro hardness is due to the reinforcement of quartz in micro silica around the gel. TGA-DTA showed that the reduction of mass loss is as high as 25.4% in control whereas 17.2% in MS5 and 15.8% in the MM5. Further, shrinkage rate in MS5 and MM5 was as low as − 1.1% and − 0.8% throughout the temperature range from 25 to 1000 °C and thus provides the way of use of nano and micro form of silica for better thermal resistance.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00176-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}