Glass Physics and Chemistry最新文献

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New Glass-Ceramic of Li–Aegirine Composition Based on β-Quartz Solid Solution and Its Electrochemical Properties 基于β-石英固溶体的新型锂-炔基玻璃陶瓷及其电化学性能
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-11-13 DOI: 10.1134/S1087659625600449
V. V. Rusan, I. P. Alekseeva, O. S. Dymshits, D. V. Shemchuk, S. S. Pashin, D. V. Agafonov, L. S. Polyakova, E. V. Sentsova
{"title":"New Glass-Ceramic of Li–Aegirine Composition Based on β-Quartz Solid Solution and Its Electrochemical Properties","authors":"V. V. Rusan,&nbsp;I. P. Alekseeva,&nbsp;O. S. Dymshits,&nbsp;D. V. Shemchuk,&nbsp;S. S. Pashin,&nbsp;D. V. Agafonov,&nbsp;L. S. Polyakova,&nbsp;E. V. Sentsova","doi":"10.1134/S1087659625600449","DOIUrl":"10.1134/S1087659625600449","url":null,"abstract":"<p>The phase transformations and crystalline phases precipitated in powders of quenched glasses similar in composition to Li–aegirine (LiFeSi<sub>2</sub>O<sub>6</sub>) subjected to heat treatment in the temperature range of 600–1000°C, are studied by differential scaning calorimetry (DSC) and X-ray diffraction analysis (XRD). The formation of a low-temperature metastable hexagonal lithium–iron silicate crystalline phase with a β-quartz structure is demonstrated for the first time. The conditions for obtaining this phase and the electrochemical properties of the developed material are discussed. In the first charge–discharge cycle, the cell containing a crystalline phase with a β-quartz structure as the anode has a specific capacity of ~400 mAh/g, which is more than one-and-a-half times higher than this value for the monoclinic modification of Li–aegirine.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 4","pages":"388 - 399"},"PeriodicalIF":0.6,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145500755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation of Transparent Protective Coatings Based on Mn(II) Biocidal Complexes on a Wood Surface 基于Mn(II)生物杀灭配合物的木材表面透明保护涂层的形成
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-11-13 DOI: 10.1134/S1087659625600474
V. N. Demidov, I. N. Tsvetkova, Chi Van Nguyen, V. I. Voshchikov, Ya. A. Khamidulin, E. V. Bogomolova, T. B. Pakhomova, O. A. Shilova
{"title":"Formation of Transparent Protective Coatings Based on Mn(II) Biocidal Complexes on a Wood Surface","authors":"V. N. Demidov,&nbsp;I. N. Tsvetkova,&nbsp;Chi Van Nguyen,&nbsp;V. I. Voshchikov,&nbsp;Ya. A. Khamidulin,&nbsp;E. V. Bogomolova,&nbsp;T. B. Pakhomova,&nbsp;O. A. Shilova","doi":"10.1134/S1087659625600474","DOIUrl":"10.1134/S1087659625600474","url":null,"abstract":"<p>The formation of a biostable protective coating based on acetate complexes of Mn(II) with 1,10-phenanthroline on a wood surface is described. The synthesis of acetate mono-, bis- and tris-chelate complexes of Mn(II) with 1,10-phenanthroline is described, and they are studied using IR spectroscopy and thermogravimetry. For acetate complexes of Mn(II) with 1,10-phenanthroline, their fungistatic activity in relation to Ulocladium sp. fungi is studied. The physical and mechanical properties of new transparent protective coatings on wood, which contain these compounds as active biocidal components, are studied. The transparent protective coatings are two-layer systems with a primary impregnation layer of an active biocidal component—acetate 1,10-phenanthroline complexes of Mn(II)— applied to the wood surface, followed by a second protective layer of organosilicon varnish KO-921 based on polymethylphenylsiloxane resin. The results of atmospheric weather tests of wood samples (pine sapwood) with the applied transparent protective coatings are presented in terms of their ability to prevent biodegradation of wood in the conditions of the tropical savanna climate of the Joint Russian–Vietnamese Tropical Research and Technology Center (Russian–Vietnamese Tropical Center).</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 4","pages":"423 - 435"},"PeriodicalIF":0.6,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145500750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strength Characteristics of Quartzoid Glasses Doped with Cesium 掺铯石英玻璃的强度特性
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-11-13 DOI: 10.1134/S1087659625600498
T. A. Tsyganova, Ya. P. Lushankin, A. S. Mazur, M. V. Staritsyn, M. S. Mikhailov, L. N. Kurilenko, L. F. Dikaya, E. A. Semenova, I. N. Anfimova, I. A. Drozdova, Yu. M. Markova
{"title":"Strength Characteristics of Quartzoid Glasses Doped with Cesium","authors":"T. A. Tsyganova,&nbsp;Ya. P. Lushankin,&nbsp;A. S. Mazur,&nbsp;M. V. Staritsyn,&nbsp;M. S. Mikhailov,&nbsp;L. N. Kurilenko,&nbsp;L. F. Dikaya,&nbsp;E. A. Semenova,&nbsp;I. N. Anfimova,&nbsp;I. A. Drozdova,&nbsp;Yu. M. Markova","doi":"10.1134/S1087659625600498","DOIUrl":"10.1134/S1087659625600498","url":null,"abstract":"<p>This article presents the results of determining the crack resistance of quartzoid glasses (QGs) doped with cesium. Crack resistance is calculated on the basis of measured values of microhardness and Young’s modulus. The relationship of crack resistance with the content of cesium oxide (Cs<sub>2</sub>O 0.76–2.11 wt %) in glass is analyzed. The results of measuring <sup>11</sup>B and <sup>29</sup>Si NMR spectra are used to interpret the effect of the presence of cesium in glass on the ability of the studied material to resist crack formation.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 4","pages":"400 - 410"},"PeriodicalIF":0.6,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145500751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural Transformation of Porcelain Insulators using Raw Materials 利用原料对瓷绝缘子进行结构改造
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-11-13 DOI: 10.1134/S1087659625600334
Mebrek Alima, Yasmina Taibi, Kotbia Labiod, Sabrina Ladjama, Sihem Benayache, Afef Azzi
{"title":"Structural Transformation of Porcelain Insulators using Raw Materials","authors":"Mebrek Alima,&nbsp;Yasmina Taibi,&nbsp;Kotbia Labiod,&nbsp;Sabrina Ladjama,&nbsp;Sihem Benayache,&nbsp;Afef Azzi","doi":"10.1134/S1087659625600334","DOIUrl":"10.1134/S1087659625600334","url":null,"abstract":"<p>The porcelain insulator was fabricated using a sintering process with raw materials from Algeria, consisting of 45 wt % kaolin, 30 wt % feldspar, and 25 wt % quartz. ZrO<sub>2</sub> nanoparticles were incorporated into the raw materials in varying proportions. The powders were then milled and pressed into pellets with a diameter of 20 mm and a thickness of 2 mm. The green samples were sintered at 1200°C for 2 h, with a heating rate of 10°C/min. The influence of ZrO<sub>2</sub> nanoparticles on the physical and structural properties of the porcelain insulator was thoroughly examined. X-ray diffraction (XRD) analysis revealed that kaolin primarily consists of kaolinite minerals, with sufficient SiO<sub>2</sub> and Al<sub>2</sub>O<sub>3</sub> contents, contributing to reasonable plasticity. The sintered samples exhibited key mineral phases, including mullite, quartz, and anorthite. The porcelain insulator, formulated with 45 wt % kaolin (30 wt % kaolin KT2 + 15 wt % kaolin DD3), 30 wt % feldspar, 25 wt % quartz, and 5 wt % ZrO<sub>2</sub> demonstrated high bulk density and minimal linear shrinkage. The addition of ZrO<sub>2</sub> nanoparticles notably improved the densification and enhanced the overall physical properties of the porcelain insulators.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 4","pages":"443 - 456"},"PeriodicalIF":0.6,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145500753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation and Thermal Stability of the Complex Aluminate Dy2SrAl2O7 络合铝酸盐Dy2SrAl2O7的形成及热稳定性
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-09-23 DOI: 10.1134/S1087659625600061
V. F. Popova, V. L. Ugolkov, E. A. Tugova
{"title":"Formation and Thermal Stability of the Complex Aluminate Dy2SrAl2O7","authors":"V. F. Popova,&nbsp;V. L. Ugolkov,&nbsp;E. A. Tugova","doi":"10.1134/S1087659625600061","DOIUrl":"10.1134/S1087659625600061","url":null,"abstract":"<p>The formation conditions and processes of the complex aluminate Dy<sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> are studied. It is established that solid-state synthesis of Dy<sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> proceeds through the formation of strontium aluminate SrAl<sub>2</sub>O<sub>4</sub>. At temperatures above 1200°C, active interaction begins between the intermediate compound SrAl<sub>2</sub>O<sub>4</sub> and Dy<sub>2</sub>O<sub>3</sub>, associated with the transition of the two-dimensional nonautonomous phase SrAl<sub>2</sub>O<sub>4</sub> into a liquid-like state. The thermal stability of Dy<sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> up to the temperature of incongruent melting at 1750°С is characterized for the first time. The coefficient of thermal expansion (CTE) of Dy<sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> is experimentally determined to be 8 × 10<sup>–6</sup> K<sup>–1</sup> in the temperature range of 400–1300°С. It is shown that active sintering of Dy<sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> begins at 1300°С. A change in the type of melting diagrams is shown in the <i>Ln</i><sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> series, where <i>Ln</i> = La → Gd → Dy, Ho. A decrease in both melting temperatures and CTE values is revealed across the <i>Ln</i><sub>2</sub>SrAl<sub>2</sub>O<sub>7</sub> series (<i>Ln</i> = La → Ho).</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 3","pages":"337 - 343"},"PeriodicalIF":0.6,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Luminescent Properties of Composites Based on Silicate Porous Glasses Activated with Bismuth and Silver 铋和银活化硅酸盐多孔玻璃复合材料的发光性能
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-09-23 DOI: 10.1134/S1087659625600279
M. A. Girsova, I. N. Anfimova, L. N. Kurilenko, T. V. Antropova
{"title":"Luminescent Properties of Composites Based on Silicate Porous Glasses Activated with Bismuth and Silver","authors":"M. A. Girsova,&nbsp;I. N. Anfimova,&nbsp;L. N. Kurilenko,&nbsp;T. V. Antropova","doi":"10.1134/S1087659625600279","DOIUrl":"10.1134/S1087659625600279","url":null,"abstract":"<p>Bismuth-containing composite materials (CMs) with variable silver content are synthesized by impregnating porous silicate glass matrices in acidified aqueous-salt solutions of Bi(NO<sub>3</sub>)<sub>3</sub>·5H<sub>2</sub>O in the presence of AgNO<sub>3</sub> with their subsequent heat treatment at 650 or 870°C and their luminescent properties are studied. The synthesized materials exhibit photoluminescence in a wide spectral range (220–900 nm) due to the presence of various active centers (Bi<sup>3+</sup>, Bi<sup>2+</sup>, Bi<sup>+</sup> ions, bismuth dimers, bismuth active centers (BACs) associated with silicon, Ag<sup>+</sup> ions, silver nanoclusters, silicon oxygen-deficient centers, =Si<sup>0</sup> centers).</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 3","pages":"243 - 254"},"PeriodicalIF":0.6,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure and Microwave Properties of Thick-Film Composite Materials BaSrTiO3/NiFe2O4 厚膜复合材料BaSrTiO3/NiFe2O4的结构与微波性能
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-09-23 DOI: 10.1134/S1087659624601321
A. Tumarkin, N. Tyurnina, Z. Tyurnina, O. Sinelshchikova, D. Tsygankova, A. Drozdovskii, A. Karamov, A. Bogdan
{"title":"Structure and Microwave Properties of Thick-Film Composite Materials BaSrTiO3/NiFe2O4","authors":"A. Tumarkin,&nbsp;N. Tyurnina,&nbsp;Z. Tyurnina,&nbsp;O. Sinelshchikova,&nbsp;D. Tsygankova,&nbsp;A. Drozdovskii,&nbsp;A. Karamov,&nbsp;A. Bogdan","doi":"10.1134/S1087659624601321","DOIUrl":"10.1134/S1087659624601321","url":null,"abstract":"<p>Multiferroic composites consisting of barium–strontium titanate and nickel ferrite have been successfully synthesized by low-temperature sintering in the form of thick films on a dielectric substrate. The crystal structure and composition of the composites were studied by X-ray diffraction and electron microscopy. The electrical and magnetic characteristics of the obtained composites were studied at microwaves. The studied samples demonstrate a dielectric permittivity from 80 to 160 and dielectric losses from 0.05 to 0.1 at a frequency of 1 GHz, as well as the ability to control the magnetization of the composite within 30% by changing the magnetization field in the range 0–2000 Oe. This is the first successful attempt to synthesize a ferroelectric/ferrite composite with both low microwave losses and magnetization controllability.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 3","pages":"283 - 292"},"PeriodicalIF":0.6,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Physical-Chemical Study of Nanopowders and Ceramics in the Gd2O3–La2O3–SrO–Ni(Co)O3 – δ System for Cathode Fuel Cell Materials 阴极燃料电池材料Gd2O3-La2O3-SrO-Ni (Co)O3 - δ体系纳米粉体及陶瓷的合成与物理化学研究
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-09-23 DOI: 10.1134/S1087659625600176
M. V. Kalinina, I. G. Polyakova, S. V. Myakin, A. S. Kovalenko, I. A. Drozdova, O. A. Shilova
{"title":"Synthesis and Physical-Chemical Study of Nanopowders and Ceramics in the Gd2O3–La2O3–SrO–Ni(Co)O3 – δ System for Cathode Fuel Cell Materials","authors":"M. V. Kalinina,&nbsp;I. G. Polyakova,&nbsp;S. V. Myakin,&nbsp;A. S. Kovalenko,&nbsp;I. A. Drozdova,&nbsp;O. A. Shilova","doi":"10.1134/S1087659625600176","DOIUrl":"10.1134/S1087659625600176","url":null,"abstract":"<p>Highly dispersed mesoporous powders of the composition Gd<sub>1 – <i>x</i></sub>Sr<sub><i>x</i></sub>Co<sub>0.5</sub>O<sub>3 – δ</sub> (<i>x</i> = 0.1, 0.15, 0.2, 0.25), Gd<sub>0.4</sub>Sr<sub>0.1</sub>Ni<sub>0.5</sub>O<sub>3 – δ</sub>, and Gd<sub>0.125</sub>La<sub>0.125</sub>Sr<sub>0.25</sub>Co<sub>0.5</sub>O<sub>3 – δ</sub> are synthesized using the method of the cocrystallization of nitrate salts. Ceramic nanomaterials of the given composition with a CSR of ~49–62 nm (1200°С), open porosity of 17–42%, and apparent density of 5–7 g/cm<sup>3</sup> are obtained based on them. Nanopowders and ceramics in the range of 600–1200°C have a tetragonal and orthorhombic structure of the perovskite type in the Gd<sub>2</sub>O<sub>3</sub>‒SrO‒Co<sub>2</sub>O<sub>3 – δ</sub> system. It is established that in order to obtain the optimal characteristics of density and porous structure of ceramics, combined additives of polyvinyl alcohol (PVA) are required in combination with aluminum hydroxide Al(OH)<sub>3</sub>, acting as a pore-forming and sintering additive. The solid solutions have mixed electron-ionic conductivity with transport numbers <i>t</i><sub>e</sub> = 0.92–0.99 and <i>t</i><sub>i</sub> = 0.08–0.01. Due to their physical, chemical, and electrophysical properties associated with the structural features of solid solutions, ceramic materials obtained based on them are promising for use as solid oxide cathodes for medium-temperature fuel cells.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 3","pages":"325 - 336"},"PeriodicalIF":0.6,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Technical and Economic Analysis on Properties of Waste Glass Sand Concrete Based on the Principle of Value Engineering 基于价值工程原理的废玻璃砂混凝土性能技术经济分析
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-09-23 DOI: 10.1134/S1087659624601047
Zhao Yi, Meng Bin, Yin Xiaosan, Bao Yijie
{"title":"Technical and Economic Analysis on Properties of Waste Glass Sand Concrete Based on the Principle of Value Engineering","authors":"Zhao Yi,&nbsp;Meng Bin,&nbsp;Yin Xiaosan,&nbsp;Bao Yijie","doi":"10.1134/S1087659624601047","DOIUrl":"10.1134/S1087659624601047","url":null,"abstract":"<p>The increasing depletion of natural sand resources and the urgent need for sustainable construction materials underscore the significance of this study, which investigates the incorporation of waste glass sand (WGS) into concrete as an eco-friendly and cost-effective alternative. The challenge lies in achieving a balance between the structural performance of concrete and the economic and environmental advantages of utilizing recycled materials. To address this issue, river sand was partially replaced with WGS at varying proportions (0–60 wt %), and the resulting waste glass sand concrete (WGSC) was assessed for workability (slump), mechanical properties (compressive strength and elastic modulus), and economic viability (functional, cost, and value coefficients). The findings indicated that higher WGS replacement rates enhanced flowability while maintaining a stable elastic modulus. Compressive strength, measured in both cubic and prismatic forms, initially increased before declining at higher replacement levels. The functional coefficient increased initially but then decreased, whereas the cost coefficient consistently decreased. The value coefficient displayed a nonlinear trend, initially increasing, then decreasing, and subsequently rising again. A linear regression model revealed a strong correlation between the value coefficient and the WGS replacement rate. Importantly, WGS not only reduced material costs but also mitigated functional deficiencies, demonstrating its potential as a sustainable partial substitute for river sand in concrete.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 3","pages":"255 - 265"},"PeriodicalIF":0.6,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Leaching Kinetics of Nickel Oxide-Doped Sodium Borosilicate Glass 氧化镍掺杂硼硅酸钠玻璃的浸出动力学
IF 0.6 4区 材料科学
Glass Physics and Chemistry Pub Date : 2025-09-23 DOI: 10.1134/S1087659625600280
M. Yu. Konon, F. K. Klyushev, D. P. Danilovich, E. A. Semenova, L. F. Dikaya
{"title":"Leaching Kinetics of Nickel Oxide-Doped Sodium Borosilicate Glass","authors":"M. Yu. Konon,&nbsp;F. K. Klyushev,&nbsp;D. P. Danilovich,&nbsp;E. A. Semenova,&nbsp;L. F. Dikaya","doi":"10.1134/S1087659625600280","DOIUrl":"10.1134/S1087659625600280","url":null,"abstract":"<p>Glass of the composition (mol %, as synthesized) 6Na<sub>2</sub>O·18B<sub>2</sub>O<sub>3</sub>·70SiO<sub>2</sub>·6Ni<sub>2</sub>O<sub>3</sub>, heat-treated at 550°C for 96 h is studied using scanning electron microscopy, and its chemical stability to an aqueous 3 M HCl solution is also studied. It is established that this glass has an interconnected phase-separated structure. The general nature of its leaching process is controlled by diffusion. Compared to iron-containing glass of a similar composition, the extraction rate of Na<sub>2</sub>O and B<sub>2</sub>O<sub>3</sub> is reduced by a factor of 2. Nickel oxide is predominantly found in the chemically unstable glass phase, most of it passing into the leaching solution. The suitability of nickel-containing phase-separated glass for producing porous glass with through porosity (~30%) is demonstrated.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"51 3","pages":"279 - 282"},"PeriodicalIF":0.6,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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