N. G. Tyurnina, Z. G. Tyurnina, O. Yu. Sinelshchikova, E. A. Balabanova, A. V. Tumarkin, D. I. Tsygankova
{"title":"Glass-Ceramic Ferroelectric Composite Material Based on Low-Alkali Aluminoborosilicate Glass and BaTiO3","authors":"N. G. Tyurnina, Z. G. Tyurnina, O. Yu. Sinelshchikova, E. A. Balabanova, A. V. Tumarkin, D. I. Tsygankova","doi":"10.1007/s10717-025-00761-x","DOIUrl":"10.1007/s10717-025-00761-x","url":null,"abstract":"<p>Glass-ceramic composites based on low-alkali aluminoborosilicate glass and barium titanate mixed in various proportions were successfully synthesized using the sintering method in the vicinity of the softening point of the glass used. The electrical properties of the samples were investigated in the microwave range. According to XRD analysis, the synthesized materials are a mixture of barium titanate and an amorphous phase, as well as, under certain heat treatment conditions, products of glass crystallization (SiO<sub>2</sub> – quartz and tridymite) and its interaction with the ferroelectric filler (Ba<sub>2</sub>TiSi<sub>2</sub>O<sub>8</sub> – fresnoite). The level of dielectric permittivity of the studied glass composite samples, measured at a frequency of 1 GHz, ranged from 9.2 to 25.0 with a dielectric loss tangent of 0.007 – 0.012.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"137 - 143"},"PeriodicalIF":0.6,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. A. Korekina, V. M. Ryzhkov, A. N. Savichev, M. V. Shtenberg, A. P. Zhaboyedov, R. S. Morozov, D. A. Artemyev, K. V. Igumentsev
{"title":"Defects and Micro-Impurities in Glass Derived from Natural Milky-White Quartz Deposits in the Southern Urals","authors":"M. A. Korekina, V. M. Ryzhkov, A. N. Savichev, M. V. Shtenberg, A. P. Zhaboyedov, R. S. Morozov, D. A. Artemyev, K. V. Igumentsev","doi":"10.1007/s10717-025-00755-9","DOIUrl":"10.1007/s10717-025-00755-9","url":null,"abstract":"<p>Micro-impurities and defects in glass produced by a two-step method from natural quartz from the Urals have been identified. The study revealed that glass quality is determined by the presence and distribution of mineral and gas-liquid inclusions in natural quartz, as well as the fractional composition of the crushed material. In addition, the conditions of the melting process significantly affect the final product. In particular, almost all trace elements present in the quartz are transferred to the molten glass. Therefore, the trace element composition of the starting quartz is a critical factor in determining its suitability for producing high quality transparent quartz glass.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"98 - 103"},"PeriodicalIF":0.6,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. S. Artyugina, Yu. O. Leonova, D. R. Khayrutdinova, A. G. Kolmakov, M. A. Sevostyanov, A. S. Lysenkov, A. I. Ogarkov, A. A. Ashmarin, A. A. Konovalov, V. G. Leontiev
{"title":"Study of Cerium Dioxide Powder Obtained by Reverse Deposition Method","authors":"D. S. Artyugina, Yu. O. Leonova, D. R. Khayrutdinova, A. G. Kolmakov, M. A. Sevostyanov, A. S. Lysenkov, A. I. Ogarkov, A. A. Ashmarin, A. A. Konovalov, V. G. Leontiev","doi":"10.1007/s10717-025-00764-8","DOIUrl":"10.1007/s10717-025-00764-8","url":null,"abstract":"<p>The process of manufacturing CeO<sub>2</sub> powders by the method of reverse deposition is investigated. The CeO<sub>2</sub> content in the resulting products reached 99.2 wt.%. The main phase was cerium dioxide with a cubic lattice. The average particle size of the powder was about 42 μm, and the specific surface area was about 38.6 m<sup>2</sup>/g. Heating of the material from 50 to 1200°C leads to a mass loss of 18%. This mass loss is accompanied by endothermic effects with peaks on the DTA curve at temperatures of 144, 280, and 374°C. Further research directions include optimization of the properties of the obtained material, in particular its morphology, and determination of prospective application areas.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"156 - 159"},"PeriodicalIF":0.6,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. A. Medennikov, M. A. Egorova, N. P. Shabelskaya, Z. D. Khliyan
{"title":"Heat Treatment Modes of Phosphogypsum for Obtaining Ultraviolet Pigments","authors":"O. A. Medennikov, M. A. Egorova, N. P. Shabelskaya, Z. D. Khliyan","doi":"10.1007/s10717-025-00766-6","DOIUrl":"10.1007/s10717-025-00766-6","url":null,"abstract":"<p>This paper investigates the possibility of heat treatment of phosphogypsum, a waste product of the chemical industry. Partial dehydration of dihydrous calcium sulfate occurs when phosphogypsum is dried, and complete dehydration occurs when it is calcined at temperatures of 600 – 1200°C. The samples were found to actively absorb water after heat treatment below 800°C. During the heat treatment of phosphogypsum in the presence of a reducing agent, two endothermic effects related to the sequential dehydration of CaSO<sub>4</sub>· 2H<sub>2</sub>O were observed, as well as a broad peak of exothermic effect due to the heat degradation of the reducing agent and the formation of calcium sulfide from phosphogypsum. Heat-treated phosphogypsum samples in the presence of the reducing agent acquire the ability to emit yellow-orange luminescence under the action of ultraviolet radiation. Synthesized pigments can be used to produce water-based paints and varnishes.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"165 - 170"},"PeriodicalIF":0.6,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu. V. Spitsyna, A. S. Lipatyev, S. I. Stopkin, Yu. V. Mikhailov, S. S. Fedotov, D. L. Alferov, E. V. Lopatina, V. N. Sigaev
{"title":"Laser Thermal Compaction of Nanoporous Glasses","authors":"Yu. V. Spitsyna, A. S. Lipatyev, S. I. Stopkin, Yu. V. Mikhailov, S. S. Fedotov, D. L. Alferov, E. V. Lopatina, V. N. Sigaev","doi":"10.1007/s10717-025-00754-w","DOIUrl":"10.1007/s10717-025-00754-w","url":null,"abstract":"<p>The processes of thermal compaction of nanoporous glass surfaces using carbon dioxide laser radiation have been investigated. Successful formation of a thermally compacted layer with a thickness of (20 ± 1) μm was demonstrated under the following thermal compaction regime: average radiation power 10.5 W, defocusing ∆<i>f</i> = 16 mm of an F-theta lens with a focal length of 157 mm, scan speed 40 mm/sec, and track spacing 100 μm. It was shown that birefringent structures can be recorded through the thermally compacted layer using femtosecond pulses, with the magnitude of their phase shift serving as an indirect indicator of glass porosity.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"93 - 97"},"PeriodicalIF":0.6,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. V. Ponurko, S. A. Krylova, A. S. Limarev, I. Yu. Mezin
{"title":"Vitreous Copper-Containing Phosphate Compounds for Feed Water Treatment in Central Heating Systems","authors":"I. V. Ponurko, S. A. Krylova, A. S. Limarev, I. Yu. Mezin","doi":"10.1007/s10717-025-00756-8","DOIUrl":"10.1007/s10717-025-00756-8","url":null,"abstract":"<p>The study presents the results of the investigation of the properties (solubility, anti-scaling, anti-corrosion, algicidal, and bactericidal) of a glassy copper-containing phosphate compounds (Cu–Zn phosphate, Cu–Zn–PC). These compounds are obtained using a zero-waste ecological technology for the purpose of corrective treatment of feed water in central heating systems. The study identifies a synergistic effect resulting from the combined presence of long-chain phosphates and alternating copper and zinc cations in the composition. This effect strengthens and evenly distributes the protective film on the surface of the system components, providing maximum effectiveness in combating scale, corrosion, and biofouling.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"104 - 107"},"PeriodicalIF":0.6,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ceramic Waste as an Alternative Source of Aluminosilicate Raw Material for the Production of Portland Cement Clinker","authors":"F. B. Atabaev, M. I. Iskandarova, N. A. Mironyuk","doi":"10.1007/s10717-025-00760-y","DOIUrl":"10.1007/s10717-025-00760-y","url":null,"abstract":"<p>The chemical-mineralogical composition and technological properties of the ceramic production wastes of Kulol JSC, used as a component of the raw mix for the production of Portland cement clinker, have been extensively studied. It was found that full or partial replacement of natural clayey raw material (loess) by ceramic production wastes during firing increases the reactivity of the raw mixes, accelerates the process of CaO absorption and promotes the completion of the mineral formation process with good clinker granulation at a relatively low temperature stage — below 1450°C. Portland cement produced from synthesized clinker is classified as additive-free Portland cement CEM I according to GOST 31108–2020.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"131 - 136"},"PeriodicalIF":0.6,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. A. Kozyukhin, D. V. Pepelyaev, M. A. Teplonogova
{"title":"Morphology and Optical Properties of Amorphous Thin Films (InSe)x(GaSe)100–x","authors":"S. A. Kozyukhin, D. V. Pepelyaev, M. A. Teplonogova","doi":"10.1007/s10717-025-00763-9","DOIUrl":"10.1007/s10717-025-00763-9","url":null,"abstract":"<p>Nanoscale amorphous thin films of the (InSe)<sub>20</sub>(GaSe)<sub>80</sub> and (InSe)<sub>50</sub>(GaSe)<sub>50</sub> compositions were subjected to phase and elemental analysis, as well as to surface morphology studies. The optical transmission analysis of the films established their absorption to correspond to indirect allowed transitions in accordance with the Tauc model under the optical band gap values (<i>E</i><sub><i>g</i></sub>) of 1.26 and 1.07 eV for the (InSe)<sub>20</sub>(GaSe)<sub>80</sub> and (InSe)<sub>50</sub>(GaSe)<sub>50</sub> thin films, respectively.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"150 - 155"},"PeriodicalIF":0.6,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161211","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. E. Suprunchuk, A. A. Kravtsov, V. A. Lapin, D. S. Vakalov, E. V. Medyanik, F. F. Malyavin, D. P. Bedrakov, V. A. Tarala
{"title":"Determination of the Solubility Limit of Ruthenium Ions in the Structure of Yttrium Aluminum Garnet","authors":"V. E. Suprunchuk, A. A. Kravtsov, V. A. Lapin, D. S. Vakalov, E. V. Medyanik, F. F. Malyavin, D. P. Bedrakov, V. A. Tarala","doi":"10.1007/s10717-025-00762-w","DOIUrl":"10.1007/s10717-025-00762-w","url":null,"abstract":"<p>Ceramics based on yttrium aluminum garnet doped with ruthenium ions were synthesized. Ceramic samples were obtained by non-reactive sintering of nanocrystalline powders formed by chemical coprecipitation. The results of XRD and EDX analysis indicated that the yttrium-aluminum garnet matrix can accommodate up to 0.5 àt.% of ruthenium cations without the formation of secondary phases or impurities. Minor deviations from the stoichiometry of the composition did not hinder the incorporation of ruthenium into the structure of yttrium aluminum garnet. In addition, changes in the valence of the sintering additive had no effect on the solubility of ruthenium ions in the ceramic material.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"144 - 149"},"PeriodicalIF":0.6,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. N. İbrahimova, M. A. Xudaverdiyeva, A. A. Aliyeav
{"title":"BDTR-500 Robot: Modern Solutions for Crack Diagnostics in Silicate-Enamel Coated Pipes","authors":"E. N. İbrahimova, M. A. Xudaverdiyeva, A. A. Aliyeav","doi":"10.1007/s10717-025-00759-5","DOIUrl":"10.1007/s10717-025-00759-5","url":null,"abstract":"<p>This paper presents the BDTR-500 robot, which is designed for crack diagnostics in silica-enamel coated pipes. The main achievements of the system include the use of GPS navigation and positioning methods, which ensure accurate location and rapid identification of emergency zones. New algorithms based on artificial intelligence and machine learning enable autonomous robot movement and high-quality data processing. High-megapixel cameras with smart lighting effectively visualize defects, while an intelligent energy management system extends autonomous operation time. Real-time data processing enables rapid damage localization and repair, and built-in sensors improve image stability on uneven surfaces. The robot can detect cracks as small as 0.1 mm. The project results confirm the high efficiency of the BDTR-500 in diagnostics and open up new possibilities for the application of this technology in pipeline monitoring and other challenging operating conditions.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 3-4","pages":"127 - 130"},"PeriodicalIF":0.6,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}