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Analysis of the Influence of Borate and Fluoride Fluxes on the Sintering of Silicate Raw Materials 硼酸盐和氟化物助熔剂对硅酸盐原料烧结的影响分析
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-07-22 DOI: 10.1007/s10717-024-00670-5
B. M. Gol’tsman, E. A. Yatsenko, Yu. A. Bostanov, A. E. Panteleeva, V. A. Smoliy, V. S. Yatsenko
{"title":"Analysis of the Influence of Borate and Fluoride Fluxes on the Sintering of Silicate Raw Materials","authors":"B. M. Gol’tsman,&nbsp;E. A. Yatsenko,&nbsp;Yu. A. Bostanov,&nbsp;A. E. Panteleeva,&nbsp;V. A. Smoliy,&nbsp;V. S. Yatsenko","doi":"10.1007/s10717-024-00670-5","DOIUrl":"10.1007/s10717-024-00670-5","url":null,"abstract":"<p>The effectiveness of using borate (borax) and fluoride (sodium fluoride) fluxes in the sintering of crystalline (sand) and amorphous (diatomite) silicate raw materials was considered. The change in the density and appearance of samples with varying amounts of fluxes during their heat treatment at different temperatures was described. It was shown that the introduction of 4 wt.% of borax reduces the temperature necessary to reach a density of 1500 kg/m<sup>3</sup> by 100°C, and 6 wt.% of borax by 200°C. It was shown that the introduction of fluxes increases the amount of x-ray amorphous glass phase due to depolymerization of the silicon-oxygen network and the formation of a low-temperature melt.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 3-4","pages":"123 - 127"},"PeriodicalIF":0.6,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141775264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Linear and Nonlinear Dielectric Properties of Ceramics Obtained from Barium Titanate Nanopowder 纳米钛酸钡陶瓷的线性和非线性介电性能
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-07-22 DOI: 10.1007/s10717-024-00674-1
S. V. Baryshnikov, A. Y. Milinsky, E. V. Stukova
{"title":"Linear and Nonlinear Dielectric Properties of Ceramics Obtained from Barium Titanate Nanopowder","authors":"S. V. Baryshnikov,&nbsp;A. Y. Milinsky,&nbsp;E. V. Stukova","doi":"10.1007/s10717-024-00674-1","DOIUrl":"10.1007/s10717-024-00674-1","url":null,"abstract":"<p>The results of a study into the dielectric properties and harmonic coefficient for barium titanate ceramics obtained from a powder with a particle size of 50 nm at different sintering temperatures are presented. It is shown that ceramics from nanopowders can be produced at lower sintering temperatures than technical ceramics with a particle size of 1 μm. Ceramics obtained at a sintering temperature of 1200°C have the best linear and nonlinear dielectric properties.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 3-4","pages":"152 - 156"},"PeriodicalIF":0.6,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141775141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physical and Mechanical Properties of Ceramic Tile Based on the Clay – Dune Sand Composition 基于粘土-沙丘砂成分的陶瓷砖的物理和机械性能
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-07-22 DOI: 10.1007/s10717-024-00676-z
A. M. Eminov, I. R. Boyjanov, Dj. S. Djabberganov, Al. A. Eminov
{"title":"Physical and Mechanical Properties of Ceramic Tile Based on the Clay – Dune Sand Composition","authors":"A. M. Eminov,&nbsp;I. R. Boyjanov,&nbsp;Dj. S. Djabberganov,&nbsp;Al. A. Eminov","doi":"10.1007/s10717-024-00676-z","DOIUrl":"10.1007/s10717-024-00676-z","url":null,"abstract":"<p>The article examines the physical, mechanical, and technological properties of ceramic tiles based on Kulatau clay and dune sands from the Tuprakkala massif in the lower Amudarya region of Uzbekistan. Laboratory and semi-production tests revealed that the optimal composition M-7, fired at temperatures of 1000 – 1050°C, can be used to produce unglazed cladding and floor tiles. Similarly, the optimal composition M-9 fired at temperatures of 1000 – 1050°C, can be used to produce facing and cladding tiles with an opaque glaze.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 3-4","pages":"164 - 167"},"PeriodicalIF":0.6,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141775263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Crystallization on Local Structure and Optical Properties of Glass with 12.5Li2O–50GeO2–37.5P2O5 Composition 结晶对 12.5Li2O-50GeO2-37.5P2O5 成分玻璃局部结构和光学特性的影响
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-07-22 DOI: 10.1007/s10717-024-00665-2
M. I. Vlasov, S. V. Pershina, D. M. Tsymbarenko, I. A. Weinstein
{"title":"Effect of Crystallization on Local Structure and Optical Properties of Glass with 12.5Li2O–50GeO2–37.5P2O5 Composition","authors":"M. I. Vlasov,&nbsp;S. V. Pershina,&nbsp;D. M. Tsymbarenko,&nbsp;I. A. Weinstein","doi":"10.1007/s10717-024-00665-2","DOIUrl":"10.1007/s10717-024-00665-2","url":null,"abstract":"<p>The glass with a 12.5Li<sub>2</sub>O–50GeO<sub>2</sub>–37.5P<sub>2</sub>O<sub>5</sub> composition was synthesized by melt quenching. Thermal annealing was used to obtain a single-phase LiGe<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> composition, which is promising as a solid electrolyte for all-solid-state lithium-ion power sources. By using full x-ray scattering with analysis of the pair distribution function, and diffuse reflectance spectroscopy in the UV-Vis range, the local structure and optical properties of initial (amorphous) glass and crystallized glass were studied. An assessment of the influence of glass crystallization on these properties was carried out. It was shown that structuring in the glass is observed only at the level of the first-second coordination sphere of Ge and P atoms. The presence of F<sup>+</sup> centers in the glass was revealed in the optical absorption spectra of the initial glass; their concentration decreases as a result of glass crystallization. The estimated value of the band gap for the crystallized glass, i.e., for the LiGe<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> phase, is 6.15 eV for the case of direct allowed transitions, which exceeds the calculated value known from the literature by approximately 2 times.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 3-4","pages":"101 - 105"},"PeriodicalIF":0.6,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141775262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Sol-Gel Method for Synthesis of Nanostructured Piezoelectric Materials Based on Lead Zirconate-Titanate System — A Review. Part 1. Powders Synthesis 应用溶胶-凝胶法合成基于锆酸铅-钛酸铅体系的纳米结构压电材料 - 综述。第 1 部分：粉末合成粉末合成
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-06-03 DOI: 10.1007/s10717-024-00663-4
N. D. Paramonova, E. A. Danilov, M. A. Vartanyan
{"title":"Application of Sol-Gel Method for Synthesis of Nanostructured Piezoelectric Materials Based on Lead Zirconate-Titanate System — A Review. Part 1. Powders Synthesis","authors":"N. D. Paramonova,&nbsp;E. A. Danilov,&nbsp;M. A. Vartanyan","doi":"10.1007/s10717-024-00663-4","DOIUrl":"10.1007/s10717-024-00663-4","url":null,"abstract":"<p>This study presents a review of progress in the sol-gel method for the synthesis of powders of ferroelectric ceramics based on the PbTiO<sub>3</sub>–PbZrO<sub>3</sub> system, which involves the controlled hydrolysis of the mixtures of salts or organometallic compounds of lead, zirconium, and titanium. To obtain materials based on the PbTiO<sub>3</sub>–PbZrO<sub>3</sub> system, attention is paid to the sol-gel conditions, heat treatment conditions, raw materials, conditions to obtain precursors, gels drying, and PbTiO<sub>3</sub>–PbZrO<sub>3</sub> powder crystallization.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"78 - 84"},"PeriodicalIF":0.6,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141255294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Porous Ceramic Substrates for the Study of Biological Objects by Electron Microscopy 利用电子显微镜研究生物物体的多孔陶瓷基板
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-06-03 DOI: 10.1007/s10717-024-00659-0
K. A. Shabanova, M. V. Pavlov
{"title":"Porous Ceramic Substrates for the Study of Biological Objects by Electron Microscopy","authors":"K. A. Shabanova,&nbsp;M. V. Pavlov","doi":"10.1007/s10717-024-00659-0","DOIUrl":"10.1007/s10717-024-00659-0","url":null,"abstract":"<p>This work discusses ceramic filter materials used as substrates to study biological objects by electron microscopy. The composition, structure, pore sizes, and morphology of ceramic substrates made of foamed silicate prior to and following the application of inverse silicon oxide opals were evaluated by x-ray diffraction analysis and SEM method. Adescription of the use of the obtained filtering substrates in an experiment with biological objects is given. The substrates seem promising for electron microscopy, since they can be used for sample preparation of biological objects with the use of metal spraying or ionic liquid. This technique, together with the filtering porous material and the technical capabilities of the microscope, preserves the physical characteristics of biological objects.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"58 - 61"},"PeriodicalIF":0.6,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141255052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of Chemical Resistance of Oxychloride Lead Borate Glasses Doped with Neodymium and the Stability of Their Luminescent Properties in the Climatic Conditions of South-East Asia 掺杂钕的氧氯化铅硼酸盐玻璃的耐化学性及其发光特性在东南亚气候条件下的稳定性研究
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-06-03 DOI: 10.1007/s10717-024-00657-2
D. A. Butenkov, D. E. Berdieva, A. V. Bakaeva, K. I. Runina, R. I. Avetisov, O. B. Petrova, D. T. Do, T. T. Ta
{"title":"Investigation of Chemical Resistance of Oxychloride Lead Borate Glasses Doped with Neodymium and the Stability of Their Luminescent Properties in the Climatic Conditions of South-East Asia","authors":"D. A. Butenkov,&nbsp;D. E. Berdieva,&nbsp;A. V. Bakaeva,&nbsp;K. I. Runina,&nbsp;R. I. Avetisov,&nbsp;O. B. Petrova,&nbsp;D. T. Do,&nbsp;T. T. Ta","doi":"10.1007/s10717-024-00657-2","DOIUrl":"10.1007/s10717-024-00657-2","url":null,"abstract":"<p>The chemical resistance of glasses based on the PbCl<sub>2</sub>–PbO–B<sub>2</sub>O<sub>3</sub>–NdF<sub>3</sub> system was studied. Oxochloride lead-borate glasses demonstrated satisfactory water resistance and alkali resistance, while low acid resistance. Bulk glass samples were exposed to the tropical climate of Southeast Asia for a year. The spectral-luminescent characteristics of neodymium ions in these matrices maintain good stability in a tropical climate.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"49 - 53"},"PeriodicalIF":0.6,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141272054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Advances in Detection of Failure in Laminated Glass Using Non-Destructive Testing and Structural Health Monitoring Techniques (Review Paper) 利用无损检测和结构健康监测技术检测夹层玻璃故障的最新进展（综述论文）
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-06-01 DOI: 10.1007/s10717-024-00664-3
Elshan Ahani
{"title":"Recent Advances in Detection of Failure in Laminated Glass Using Non-Destructive Testing and Structural Health Monitoring Techniques (Review Paper)","authors":"Elshan Ahani","doi":"10.1007/s10717-024-00664-3","DOIUrl":"10.1007/s10717-024-00664-3","url":null,"abstract":"<p>Using glass as a structural element that could obtain the role of the primary load-bearing elements of iconoclast structures has had a superficial history. Because of its aesthetic and admissible mechanical properties, glass has been considered one of the structural elements in the construction industry. Because of its extrasafety, laminated glass on top of the most widely used elements has been appraised with more depth. The study aimed to evaluate the failure modes in laminated glass and the possibility of detecting the pre-failure status of the surveyed elements, referring to the proffered approaches and image processing (IP) procedures in the literature. The outcomes have compared the peculiarity and strength points of various routes and have reached the inference for proper approaches in every procedure. According to the results, image processing (IP) is the most appropriate method of pre-failure detection in load-bearing laminated glass elements. Among the image processing (IP) techniques, digital image correlation has the widest application. The results of this study, in combination with other pieces of research, may propound a database for evaluating the failure status of glass structures.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"85 - 99"},"PeriodicalIF":0.6,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141197608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Hafnium Diboride Ceramic Powders by Carbothermal Reduction 通过碳热还原法合成二硼化铪陶瓷粉末
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-06-01 DOI: 10.1007/s10717-024-00653-6
N. E. Shchegoleva, Yu. E. Lebedeva, S. G. Kolyshev, M. L. Vaganova, A. S. Chainikova
{"title":"Synthesis of Hafnium Diboride Ceramic Powders by Carbothermal Reduction","authors":"N. E. Shchegoleva,&nbsp;Yu. E. Lebedeva,&nbsp;S. G. Kolyshev,&nbsp;M. L. Vaganova,&nbsp;A. S. Chainikova","doi":"10.1007/s10717-024-00653-6","DOIUrl":"10.1007/s10717-024-00653-6","url":null,"abstract":"<p>The process of obtaining hafnium diboride via the carbothermal reduction of hafnium oxide, which involves heat treatment in a vacuum furnace and a spark plasma sintering unit, was studied. When the charge was heat treated in a vacuum furnace, hafnium diboride powder characterized by the presence of secondary crystalline phases was obtained within a temperature range of 1500 – 1700°C. Monophase hafnium diboride powder having a fine-grained uniform structure was obtained using the spark plasma sintering method at a temperature of 1500°C.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"24 - 33"},"PeriodicalIF":0.6,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141197603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ceramic Body Based on Kaolin – Alumina-Containing Waste – Dolomite System 基于高岭土-含氧化铝废料-白云石系统的陶瓷体
IF 0.6 4区 材料科学
Glass and Ceramics Pub Date : 2024-05-30 DOI: 10.1007/s10717-024-00660-7
Al. A. Eminov, S. S. Tairov, B. T. Sabirov, A. M. Eminov
{"title":"Ceramic Body Based on Kaolin – Alumina-Containing Waste – Dolomite System","authors":"Al. A. Eminov,&nbsp;S. S. Tairov,&nbsp;B. T. Sabirov,&nbsp;A. M. Eminov","doi":"10.1007/s10717-024-00660-7","DOIUrl":"10.1007/s10717-024-00660-7","url":null,"abstract":"<p>The article investigates the high-temperature interaction and sintering processes of samples of low-temperature firing high-alumina for technical ceramics based on the kaolin – alumina-containing component – dolomite ternary system and establishes the areas of formation of high-alumina body for technical ceramics on the ternary diagram. It is shown that as a result of high-temperature interaction, the formation of new crystalline phases of minerals occurs, including mullite, corundum, β-cristobalite, as well as in a small amount of anorthite and an amorphous glassy phase, which impart the necessary physical and mechanical properties to the fired sample. The area of optimal compositions for obtaining low-temperature sintering high-alumina ceramic bodies based on the kaolin – alumina-containing waste – dolomite ternary system was determined.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"62 - 67"},"PeriodicalIF":0.6,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141197935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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