Biofuels Bioproducts & Biorefining-Biofpr最新文献

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The effect of used cooking oil composition on the specific CO2e emissions embodied in HEFA-SPK production 使用过的食用油成分对 HEFA-SPK 生产过程中所体现的具体 CO2e 排放量的影响
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-09 DOI: 10.1002/bbb.2653
Liam A. Mannion, Conor Redington, Mark Kelly, Aron Bell, Stephen Dooley
{"title":"The effect of used cooking oil composition on the specific CO2e emissions embodied in HEFA-SPK production","authors":"Liam A. Mannion,&nbsp;Conor Redington,&nbsp;Mark Kelly,&nbsp;Aron Bell,&nbsp;Stephen Dooley","doi":"10.1002/bbb.2653","DOIUrl":"10.1002/bbb.2653","url":null,"abstract":"<p>In this study, the correlation between the composition, hydrogen/carbon (H/C) ratio, and hydrogen/oxygen (H/O) ratio of a used cooking oil (UCO) and the specific emissions embodied in the derived hydroprocessed esters and fatty acids synthetic paraffinic kerosene (HEFA-SPK) is investigated. It is shown that HEFA-SPK produced from UCOs with low concentrations of C18:1, high concentrations of C18:2, and low H/C ratios utilize less energy and more hydrogen during Fuel Production. Hence, HEFA-SPK produced from such UCOs will embody higher gCO<sub>2</sub>e for fossil hydrogen utilization scenarios, and lower gCO<sub>2</sub>e for green hydrogen utilization scenarios compared with other UCOs. Conversely, it is shown that HEFA-SPK produced from UCOs with high concentrations of C18:1, low concentrations of C18:2 and high H/C ratios utilize more energy and less hydrogen during Fuel Production. Hence, HEFA-SPK derived from such UCOs will embody lower gCO<sub>2</sub>e for fossil hydrogen utilization scenarios, and higher gCO<sub>2</sub>e for green hydrogen utilization scenarios compared with other UCOs. Monte Carlo simulation gives the emissions embodied in Fuel Production a 95% confidence interval for all UCO-derived HEFA-SPK, showing a similar uncertainty for all compositions. A maximum of +1.1 gCO<sub>2</sub>e/MJ<sub>SAF</sub> and −1.0 gCO<sub>2</sub>e/MJ<sub>SAF</sub> is obtained for the upper and lower bounds respectively for the emissions embodied during HEFA-SPK production from UCO. The application of the correlations founded in this study allows for the prediction of the specific emissions embodied in the feedstock-to-fuel conversion of any UCO, providing the C18:1 concentration, C18:2 concentration, H/C ratio and H/O ratio of the UCO is known.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 4","pages":"837-854"},"PeriodicalIF":3.2,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bbb.2653","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141663167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Purification of xylosaccharides from eucalyptus residues for l-lactic acid production by Weizmannia coagulans 从桉树残渣中纯化木糖用于凝结魏茨曼氏菌生产乳酸
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-05 DOI: 10.1002/bbb.2662
María-Noel Cabrera, Eugenia Vila, Alberto Liguori, Constanza D’Andrada, Santiago Moure, Mairan Guigou, Florencia Cebreiros, Juan Martín Rodao, Laura Camesasca, Mario Daniel Ferrari, Claudia Lareo
{"title":"Purification of xylosaccharides from eucalyptus residues for l-lactic acid production by Weizmannia coagulans","authors":"María-Noel Cabrera,&nbsp;Eugenia Vila,&nbsp;Alberto Liguori,&nbsp;Constanza D’Andrada,&nbsp;Santiago Moure,&nbsp;Mairan Guigou,&nbsp;Florencia Cebreiros,&nbsp;Juan Martín Rodao,&nbsp;Laura Camesasca,&nbsp;Mario Daniel Ferrari,&nbsp;Claudia Lareo","doi":"10.1002/bbb.2662","DOIUrl":"10.1002/bbb.2662","url":null,"abstract":"<p>In this work, phosphoric acid pretreatment (0.6% H<sub>3</sub>PO<sub>4</sub>, 160 °C, 40 min) of eucalyptus residues was performed to recover the hemicellulosic fraction for further conversion to <span>l</span>-lactic acid by fermentation with <i>Weizmannia coagulans</i> DSM 2314 (formerly <i>Bacillus coagulans</i>). The hemicellulosic hydrolysate was composed of xylosaccharides 24.8 g L<sup>–1</sup> (mainly xylose, 20.3 g L<sup>–1</sup>), acetic acid 7.8 g L<sup>–1</sup>, furfural 0.7 g L<sup>–1</sup>, and acid-soluble lignin (ASL) 2.1 g L<sup>–1</sup>. It was subsequently purified by using anion exchange or adsorption resins. Different liquor-to-resin ratios were evaluated to obtain a high concentration of xylosaccharides in the eluate and thorough removal of components that inhibit lactic fermentation. The best performance was observed when using Amberlite-XAD-4 resin at a liquor-to-resin ratio of 3:1. An eluted hydrolysate was obtained, preserving 80% of the xylosaccharides and effectively removing almost all furfural, 90% of ASL, and 32% of acetic acid. Subsequently, <span>l</span>-lactic acid production by <i>W. coagulans</i> DSM 2314 was evaluated using concentrated nondetoxified and detoxified hydrolysate obtained with a vacuum oven. For the nondetoxified hydrolysate, 12 g L<sup>–1</sup> of <span>l</span>-lactic acid was obtained after 48 h showing a yield of 0.56 g<sub>lactic acid</sub> g<sub>sugar</sub><sup>–1</sup> and a xylose consumption of 62%. The detoxification of the liquor significantly improved the fermentation performance of <i>W. coagulans</i>, resulting in a concentration of 16 g L<sup>–1</sup> of lactic acid after 24 h, with a yield of 0.73 g<sub>lactic acid</sub> g<sub>sugar</sub><sup>–1</sup>, and almost complete xylose consumption.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 6","pages":"1902-1916"},"PeriodicalIF":3.2,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141674952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Feasibility of using phytoremediation biomass for sustainable biofuel production via thermochemical conversion 通过热化学转化利用植物修复生物质生产可持续生物燃料的可行性
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-05 DOI: 10.1002/bbb.2656
Christopher Kick, Žygimantas Kidikas, Alfreda Kasiulienė, Snežana Maletić, Tijana Zeremski, Mantas Rubežius, Marcus Eschen, Markus Ortner
{"title":"Feasibility of using phytoremediation biomass for sustainable biofuel production via thermochemical conversion","authors":"Christopher Kick,&nbsp;Žygimantas Kidikas,&nbsp;Alfreda Kasiulienė,&nbsp;Snežana Maletić,&nbsp;Tijana Zeremski,&nbsp;Mantas Rubežius,&nbsp;Marcus Eschen,&nbsp;Markus Ortner","doi":"10.1002/bbb.2656","DOIUrl":"10.1002/bbb.2656","url":null,"abstract":"<p>This study explores a novel approach that combines soil recovery with biofuel production, presenting a strategy that addresses the increasing demand for biofuels while sidestepping the food–fuel debate. It also introduces an innovative method for recovering heavy metals from soils through their translocation into the solid product of the conversion process. Phytoremediation trials were conducted under real field conditions, and the thermochemical conversion of the harvested biomass was carried out at lab scale. Field trials took place in 2021–2023 in Lithuania and Serbia. In Serbia, the contamination primarily involved heavy metals, whereas the Lithuanian site was predominantly contaminated with hydrocarbons from petroleum products. The harvested biomass underwent pretreatment and was then used as feedstock for conversion into high-energy carriers. The conversion products were evaluated for their potential to substitute fossil fuels. Finally, the value chain, encompassing key stakeholders and factors impacting the profitability of this approach, was established, and initial estimates were made regarding the size of individual cost components.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 4","pages":"1010-1026"},"PeriodicalIF":3.2,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bbb.2656","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141675203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the catalytic potential of K2ZnF6 fluoroperovskite for glycerol oligomerization 揭示 K2ZnF6 氟硼酸盐在甘油低聚过程中的催化潜力
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-05 DOI: 10.1002/bbb.2660
Fernando José Soares Barros, Ramón Moreno-Tost, Juan A. Cecilia, Francisco Murilo Tavares de Luna, Enrique Rodríguez-Castellón, Rodrigo Silveira Vieira
{"title":"Unveiling the catalytic potential of K2ZnF6 fluoroperovskite for glycerol oligomerization","authors":"Fernando José Soares Barros,&nbsp;Ramón Moreno-Tost,&nbsp;Juan A. Cecilia,&nbsp;Francisco Murilo Tavares de Luna,&nbsp;Enrique Rodríguez-Castellón,&nbsp;Rodrigo Silveira Vieira","doi":"10.1002/bbb.2660","DOIUrl":"10.1002/bbb.2660","url":null,"abstract":"<p>This study systematically evaluates fluorine-containing materials with varying compositions of K, Al, Co, Cu, Mg, and Zn as catalysts for glycerol oligomerization. Comprehensive analyses were conducted for all of the catalysts, considering their structural, compositional, morphological characteristics, and basicity, to understand them in greater depth. Among these analyses, gas chromatography was employed to examine the composition of the reaction products. The investigation extended to a recycling study under optimized conditions. Thermogravimetric analysis and X-ray photoelectron spectroscopy were used to characterize the spent catalysts. Catalytic activity was found to be influenced strongly by the fluorine content, demonstrating remarkable performance for the materials containing fluoroperovskites such as KMgF<sub>3</sub> in the catalyst KMgAFC, and K<sub>2</sub>ZnF<sub>6</sub> in KZAFC. Remarkably, KZAFC with 20% fluorine exhibited superior glycerol conversion (68%) and selectivity for diglycerol (27%). Comparative analysis with ZnAl-layered double hydroxide highlighted the positive impact of fluorine on catalytic activity. Introducing a calcination step in the catalyst recovery process also demonstrated improved activity during recycling. Interestingly, KZAFC exhibited stability over four reaction cycles, presenting an economic advantage over homogeneous catalysts. The study also shed light on the potential fluorine loss at the surface and potassium leaching into reaction products, correlating these phenomena with the observed decline in activity. These comprehensive findings contribute significantly to advancing sustainable glycerol valorization through heterogeneous catalysis.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 5","pages":"1613-1630"},"PeriodicalIF":3.2,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141673300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dry reforming of methane at high temperature and elevated pressure over nickel spinellized powder catalyst and pellets prepared from a metallurgical residue 高温高压下甲烷在镍尖晶化粉末催化剂和冶金残渣制备的颗粒上的干重整反应
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-03 DOI: 10.1002/bbb.2659
Muhammad Irfan Malik, Maroua Rouabah, Nicolas Abatzoglou, Inès Esma Achouri
{"title":"Dry reforming of methane at high temperature and elevated pressure over nickel spinellized powder catalyst and pellets prepared from a metallurgical residue","authors":"Muhammad Irfan Malik,&nbsp;Maroua Rouabah,&nbsp;Nicolas Abatzoglou,&nbsp;Inès Esma Achouri","doi":"10.1002/bbb.2659","DOIUrl":"10.1002/bbb.2659","url":null,"abstract":"<p>The coke deposition on catalysts is a significant problem in the dry reforming of methane at elevated pressures. Understanding and controlling the mechanisms of such deposition is essential in developing a techno-economically viable industrial application for the production of synthesis gas and/or hydrogen. The patent-pending nickel-supported upgraded slag oxide (Ni-UGSO) catalysts, in powder form, have demonstrated excellent performance and achieved equilibrium in dry reforming, steam reforming and mixed methane reforming in a gram-scale laboratory packed bed reactor under barometric pressure. In this extended study, Ni-UGSO pellets were prepared using the wet impregnation method. The pelletized form of said catalyst was studied under elevated pressure to imitate the industrial operating conditions in a kilogram-scale laboratory packed bed reactor. The characterization of the fresh and used catalytic formulation produced data allowing the investigation of the physicochemical properties of catalysts and the effects of metal dispersion, reaction pressure and crystallite size, as well as the role of side reactions on the nature of the coke. The metal support nature favored the interaction between the Ni metal and spinels (UGSO), and the presence of the clay binder (kaolinite, quartz) improved the pellet morphology, provided higher Ni dispersion, maintained the crystallite size, reduced the coke formation and achieved similar or higher performance with respect to Ni-UGSO powder despite having 85% less surface area. The Ni-UGSO pellet showed negligible coke deposits from 1 to 6.5 atm and operated successfully for 24 h at 5.5 atm, 800°C and gas hourly space velocity 810 L/(h kg cat). This study provides new insight into the design of a more efficient and robust catalyst for methane dry reforming at elevated pressures, which is critical for potential future transfer at the industrial level.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 4","pages":"1027-1046"},"PeriodicalIF":3.2,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141682931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pretreatment and saccharification of corn cobs using partially purified fungal ligninozymes 利用部分纯化的真菌木质素酶对玉米棒进行预处理和糖化
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-02 DOI: 10.1002/bbb.2661
Kandukuri Thanuja Reddy, Gurvinder Singh Kocher, Alla Singh
{"title":"Pretreatment and saccharification of corn cobs using partially purified fungal ligninozymes","authors":"Kandukuri Thanuja Reddy,&nbsp;Gurvinder Singh Kocher,&nbsp;Alla Singh","doi":"10.1002/bbb.2661","DOIUrl":"10.1002/bbb.2661","url":null,"abstract":"<p>Corn cobs consist primarily of a lignocellulosic material comprising hemicellulose, cellulose, and lignin in a crystalline state, which is resistant to microbial saccharification. Bioethanol production from corn cobs has rarely been attempted, especially using chemical pretreatment methods.</p><p>The present study deals with the production and purification of fungal (<i>Phanerochaete chrysosporium</i> MTCC 787 and <i>Pleurotus florida</i> PAU 22-01) extracellular ligninolytic enzymes – lignin peroxidase (LiP), manganese peroxidase (MnP), and laccase (Lac) – followed by their utilization for the biological pretreatment of corn cobs along with saccharification using commercial cellulase. Crude LiP, MnP, and Lac demonstrated specific activity of 2.23, 2.1, and 2.63 U/mg, respectively.</p><p>The one-step purification of crude enzyme using diethyl amino ethyl (DEAE) cellulose ion exchange chromatography resulted in 11.3, 10.1 and 8.62-fold purification of LiP, MnP and Lac activity, respectively, with corresponding specific activity of 25.1 U/mg (LiP), 21.2 U/mg (MnP) and 22.7 U/mg (Lac) in the partially purified ligninozymes. Using the latter, biological pretreatment of 2.5 g corn cobs in a reaction volume of 30 mL containing approximately 200 units of Lac, Lip and MnP enzymes (in phosphate buffer, pH 6) resulted in a maximum of 78.4% delignification with a saccharification efficiency of 97.1% using commercial cellulases.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 5","pages":"1631-1638"},"PeriodicalIF":3.2,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141688287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization of groundnut shell biochar produced with different stainless steel combustion compartment volumes 用不同的不锈钢燃烧室容积生产的花生壳生物炭的特征
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-07-02 DOI: 10.1002/bbb.2657
Oluwatoyin Rhoda Ayanwusi, Sulyman A. Abdulkareem, Taiwo Temitayo Michael, Kingsley O. Iwuozor, Ebuka Chizitere Emenike, Hambali Umar Hambali, Adewale George Adeniyi
{"title":"Characterization of groundnut shell biochar produced with different stainless steel combustion compartment volumes","authors":"Oluwatoyin Rhoda Ayanwusi,&nbsp;Sulyman A. Abdulkareem,&nbsp;Taiwo Temitayo Michael,&nbsp;Kingsley O. Iwuozor,&nbsp;Ebuka Chizitere Emenike,&nbsp;Hambali Umar Hambali,&nbsp;Adewale George Adeniyi","doi":"10.1002/bbb.2657","DOIUrl":"10.1002/bbb.2657","url":null,"abstract":"<p>Biochar, a solid material derived from a thermochemical process, has received significant attention due to its usefulness in various sectors. Previous studies have been conducted to improve the properties and quality of this material by altering the thermochemical processes, treating the feedstock, hybridizing the feedstock, and so forth, but little has been done on the effect of varying the reactor's configuration. This research aims to study the effect of varying the stainless-steel-based combustion compartment volume of a biomass-fueled top-lit updraft gasifier on the groundnut shell biochar. The biochar yields for reactors ranged from 34.9% to 51.2%. The sample produced in the smallest combustion compartment volume showed the highest carbon content, according to energy dispersive X-ray spectroscopy (EDX) analysis. Potassium, another major element, decreased as the combustion compartment was reduced. Scanning electron microscopy (SEM) analysis revealed that the biochar samples produced had an irregular shape and rough surfaces, and reducing the combustion compartment volume resulted in larger particles on the surface. Fourier transform infrared (FTIR) spectroscopy analysis showed similarities and differences in peaks observed for all the samples. The biochar samples produced can find applications in wastewater treatment, energy conversion and storage, and soil amendment, and the findings contribute to the design and optimization of biomass-based gasifiers.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 5","pages":"1598-1612"},"PeriodicalIF":3.2,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141687121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation of dairy biogas as fuel for a molten carbonate fuel cell 将乳制品沼气作为熔融碳酸盐燃料电池燃料的实验研究
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-06-30 DOI: 10.1002/bbb.2648
Jarosław Milewski, Karina Michalska, Anna Kacprzak
{"title":"Experimental investigation of dairy biogas as fuel for a molten carbonate fuel cell","authors":"Jarosław Milewski,&nbsp;Karina Michalska,&nbsp;Anna Kacprzak","doi":"10.1002/bbb.2648","DOIUrl":"https://doi.org/10.1002/bbb.2648","url":null,"abstract":"<p>This article presents the results of an experimental study evaluating the performance of a molten carbonate fuel cell (MCFC) using dairy biogas as a fuel source. Dairy biogas, a renewable byproduct of dairy farming, was compared with hydrogen in terms of operational efficiency. The investigation focuses on the performance parameters and efficiency metrics of MCFCs when powered by dairy biogas, relative to natural gas and hydrogen. The results demonstrate that while dairy biogas can power MCFCs, its efficiency and fuel utilization rates are lower than those of conventional fuels. This study contributes to an understanding of alternative, sustainable fuel sources for MCFC operations. During the study, the performance parameters of dairy biogas were compared with hydrogen, which served as a benchmark fuel. It was observed that in comparison with natural gas, commonly used as a fuel, dairy biogas showed lower efficiency rates and reduced fuel-utilization factors. This suggests that although dairy biogas can be used as a fuel source for MCFCs, its effectiveness might not be on par with traditional fuels like natural gas.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 4","pages":"990-999"},"PeriodicalIF":3.2,"publicationDate":"2024-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141730199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Humin-free synthesis of levulinic acid from fructose using heteropolyacid catalysts 使用杂多酸催化剂从果糖合成无杂多酸的乙酰丙酸
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-06-28 DOI: 10.1002/bbb.2654
André Wassenberg, Tobias Esser, Maximilian J. Poller, Dorothea Voß, Jakob Albert
{"title":"Humin-free synthesis of levulinic acid from fructose using heteropolyacid catalysts","authors":"André Wassenberg,&nbsp;Tobias Esser,&nbsp;Maximilian J. Poller,&nbsp;Dorothea Voß,&nbsp;Jakob Albert","doi":"10.1002/bbb.2654","DOIUrl":"https://doi.org/10.1002/bbb.2654","url":null,"abstract":"<p>Levulinic acid (LA) is one of the top bio-based platform molecules that can be converted into many valuable chemicals. Herein, we report the sustainable synthesis of LA acid from various sugars using heteropolyacid catalysts. By using a Box–Behnken design of experiment, both LA yield (up to 69 mol%) and complete suppression of parasitic humin formation could be achieved within a 5 h reaction time at 140°C using fructose as a substrate. The effects of various reaction parameters like temperature, sugar concentration, addition of organic co-solvent and reaction time on LA yield and humin formation were examined in a three-dimensional space. Moreover, the results could be successfully transferred to other sugars like glucose or cellobiose, paving the way for an atom-efficient and sustainable LA synthesis process.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 5","pages":"1585-1597"},"PeriodicalIF":3.2,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bbb.2654","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142123378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improvement of substrate turnover through integrating dark fermentation into existing biogas plants 通过将暗发酵纳入现有沼气厂,提高基质周转率
IF 3.2 4区 生物学
Biofuels Bioproducts & Biorefining-Biofpr Pub Date : 2024-06-28 DOI: 10.1002/bbb.2658
Natascha Eggers, Fabian Giebner, Dustin Heinemann, Martin Wagner, Torsten Birth-Reichert
{"title":"Improvement of substrate turnover through integrating dark fermentation into existing biogas plants","authors":"Natascha Eggers,&nbsp;Fabian Giebner,&nbsp;Dustin Heinemann,&nbsp;Martin Wagner,&nbsp;Torsten Birth-Reichert","doi":"10.1002/bbb.2658","DOIUrl":"https://doi.org/10.1002/bbb.2658","url":null,"abstract":"<p>The decarbonization potential of hydrogen offers increasing usage paths in the fight against climate change resulting in a growing demand for climate-neutral hydrogen. This challenge is met by producing hydrogen microbially from renewable substrates as an alternative to ‘green hydrogen’ from water electrolysis. Initial results have shown that coupling dark fermentation and anaerobic digestion is not only possible but also advantageous. Specifically, by integrating dark fermentation in existing biogas plants, the overall physical efficiency of the process's substrate turnover can be increased by up to 50% through providing hydrogen in addition to biogas. The achieved test results are examined based on limit-oriented physical efficiency evaluation to show the potential for optimization of the substrate turnover in biological concepts based on modeling. Finally an overview of a commissioned demonstration plant is given, which will provide further insights into the feasibility of the dark fermentation on an industrial scale.</p>","PeriodicalId":55380,"journal":{"name":"Biofuels Bioproducts & Biorefining-Biofpr","volume":"18 4","pages":"855-864"},"PeriodicalIF":3.2,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bbb.2658","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141730356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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