{"title":"Numerical simulation of deformation and fragmentation of fractal-like nanoaggregates","authors":"Łukasz Żywczyk, Arkadiusz Moskal, Rafał Przekop","doi":"10.24425/cpe.2019.130213","DOIUrl":"https://doi.org/10.24425/cpe.2019.130213","url":null,"abstract":"A flexible fractal-like aggregate model was used to study deformation and fragmentation of the structure of fractal-like aggregates via their impaction with rigid rough surface. Aggregates were conveyed one at the time towards a surface under vacuum conditions. The number of primary particles remaining in each fragment, ratio of average fragment radius of gyration after impaction to the average fragment initial radius of gyration and ratio of average coordination number to the initial coordination number were monitored for each individual aggregate. Results demonstrate that depending on the impact velocity, the fractal dimension of the aggregate, the strength of bonds between primary particles, the stiffness of the aggregate structure and the diameter of primary particle composing an aggregate, restructuring or breakage of the aggregate occur. Moreover, in the analysis of the ratio of coordination number of aggregates after impaction to the initial coordination number, three regimes were distinguished: first no deformation at low impact velocities, second restructurisation regime and finally fragmentation regime where partial or total fragmentation of aggregates was observed.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"145 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Influence of calcium, magnesium and iron ions on the molecular mass of exoproteins during biogranulation","authors":"","doi":"10.24425/cpe.2020.136011","DOIUrl":"https://doi.org/10.24425/cpe.2020.136011","url":null,"abstract":"In this study, we performed the qualitative analysis of exoproteins during granule formation in the presence or in the absence of cations. The staining of thin granule cryosections showed that nucleic acids, proteins, polysaccharides and calcium cations were the dominant components of the granules. Proteins are the structural components associated with calcium ions. We determined changes in the proteomic profile and tightly bound extracellular polymeric substances (EPS) of the slime. The exopolymeric matrix containing the proteins was extracted using the Dowex resin method. Proteomic profile was analysed by SDS-PAGE method (sodium dodecyl sulphate polyacrylamide gel electrophoresis) using Coomassie blue staining in the samples of the aerobic granule matrix formed in the presence of multivalent cations and compared with that of the aerobic granules cultivated without cations. The results indicate that the granule matrix is predominantly composed of large and complex proteins that are tightly bound within the granular structure. The tightly bound extracellular polymeric substances (TB-EPS) may play a role in improved mechanical stability of aerobic granules. In the supernatant fraction of the sludge, only a small amount of free proteins in the medium molecular mass range was detected. The protein with high molecular mass ( (cid:21) 116 kDa) produced in the reactors with added Ca 2 + . Ca 2 + had a considerable regulatory influence on production of extracellular proteins during aerobic granulation.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"205 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analysis of liquid blending dynamics with Maxblend impellers by Electrical Resistance Tomography","authors":"","doi":"10.24425/cpe.2021.138925","DOIUrl":"https://doi.org/10.24425/cpe.2021.138925","url":null,"abstract":"The aim of the investigation was liquid mixing time measurement in a laboratory scale stirred tank equipped with a metal Maxblend impeller and comparison with the corresponding mixing time obtained with other conventional impellers. The data are collected by Electrical Resistance Tomography, whose applicability in this case is non-trivial, because of the electrical interferences between the large paddles of the impeller and the measuring system. The raw data treatment methodology purposely developed for obtaining the homogenization dynamics curve is presented. A robust approach for a fine and low cost investigation of the mixing performances of close-clearance impellers in opaque systems is suggested. The analysis of the local and averaged conductivity time traces reveals the effect of important variables, such as the fluid viscosity and the vessel configuration, on the mixing time under various agitation conditions. The data collection and post processing procedures open the way to the application of the technique to multiphase and non-Newtonian fluids stirred with close-clearance impellers.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"229 1‐2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Selection of batch process conditions for microbiological production of lactic acid using waste whey","authors":"M. Lech, Anna Trusek","doi":"10.24425/CPE.2019.126101","DOIUrl":"https://doi.org/10.24425/CPE.2019.126101","url":null,"abstract":"The research was focused on the selection of the best conditions for the lactic acid production. As the organic source diluted waste whey was used. Two facultative anaerobic bacteria strains were examined: Lactobacillus rhamnosus and Lactococcus lactis. The neeed of anaerobic conditions as well as mineral supplementation of cultivation were investigated. It turned out that the oxidation was not the key parameter, but cultivation medium needed a supplementation for higher process efficiency. Finally, Lactobacillus rhamnosus strain was selected, for which LA production was app. 45% higher than for Lc. lactis. On the other hand, Lactobacillus rhamnosus was active at higher lactose concentration, thus waste whey needed to be less diluted. Additionally, high values of product/substrate yield coefficient make the process very efficient.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"46 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68946890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Large Eddy Simulation of turbulent flowand heat transfer in a Kenics static mixer","authors":"H. Murasiewicz, B. Zakrzewska","doi":"10.24425/CPE.2019.126103","DOIUrl":"https://doi.org/10.24425/CPE.2019.126103","url":null,"abstract":"CFD modelling of momentum and heat transfer using the Large Eddy Simulation (LES) approach has been presented for a Kenics static mixer. The simulations were performed with the commercial code ANSYS Fluent 15 for turbulent flow of three values of Reynolds number, Re = 5 000, 10 000 and 18 000. The numerical modelling began in the RANS model, where standard k−ε turbulence model and wall functions were used. Then the LES iterations started from the initial velocity and temperature fields obtained in RANS. In LES, the Smagorinsky–Lilly model was used for the sub-grid scale fluctuations along with wall functions for prediction of flow and heat transfer in the near-wall region. The performed numerical study in a Kenics static mixer resulted in highly fluctuating fields of both velocity and temperature. Simulation results were presented and analysed in the form of velocity and temperature contours. In addition, the surface-averaged heat transfer coefficient values for the whole insert length were computed and compared with the literature experimental data. Good compliance of the LES simulation results with the experimental correlation was obtained.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"40 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68946953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of temperature distribution in the ground","authors":"Barbara Larwa, K. Kupiec","doi":"10.24425/CPE.2019.126106","DOIUrl":"https://doi.org/10.24425/CPE.2019.126106","url":null,"abstract":"Knowledge of the temperature distribution in subsurface layers of the ground is important in the design, modelling and exploitation of ground heat exchangers. In this work a mathematical model of heat transfer in the ground is presented. The model is based on the solution of the equation of transient heat transfer in a semi-infinite medium. In the boundary condition on the surface of the ground radiation fluxes (shortand long-wave), convective heat flux and evaporative heat flux are taken into account. Based on the developed model, calculations were carried out to determine the impact of climatic conditions and the physical properties of the ground on the parameters of the Carslaw-Jeager equation. Example results of calculated yearly courses of the daily average temperature of the surface of the ground and the amount of particular heat fluxes on the ground surface are presented. The compatibility of ground temperature measurements at different depths with the results obtained from the Carslaw–Jaeger equation is evaluated. It was found that the temperature distribution in the ground and its variability in time can be calculated with good accuracy.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68946999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Chmielewski, A. Urbaniak, J. Palige, O. Roubinek, K. Wawryniuk, A. Dobrowolski
{"title":"Membrane installation for biogas enrichment – Field tests and system simulation","authors":"A. Chmielewski, A. Urbaniak, J. Palige, O. Roubinek, K. Wawryniuk, A. Dobrowolski","doi":"10.24425/CPE.2019.126116","DOIUrl":"https://doi.org/10.24425/CPE.2019.126116","url":null,"abstract":"The paper presents results of the field tests on membrane biogas enrichment performed with the application of mobile membrane installation (MMI) with the feed stream up to 10 Nm3/h. The mobile installation equipped with four hollow fibre modules with polyimide type membranes was tested at four different biogas plants. Two of them were using agricultural substrates. The third one was constructed at a municipal wastewater plant and sludge was fermented in a digester and finally in the fourth case biogas was extracted from municipal waste landfill site. Differences in the concentration of bio-methane in feed in all cases were observed and trace compounds were detected as well. High selectivity polyimide membranes, in proper module arrangements, can provide a product of high methane content in all cases. The content of other trace compounds, such as hydrogen sulphide, water vapour and oxygen on the product did not exceed the values stated by standard for a biogas as a vehicle fuel. The traces of hydrogen sulphide and water vapour penetrated faster to the waste stream enriched in carbon dioxide, which could lead to further purification of the product – methane being hold in the retentate (H2O > H2S > CO2 > O2 > CH4 > N2). In the investigated cases, when concentration of N2 was low and concentration of CH4 higher than 50%, it was possible to upgrade methane to concentration above 90% in a two-stage cascade.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Influence of shear direction on gelation ability of colloidal chitosan solutions","authors":"","doi":"10.24425/cpe.2019.126113","DOIUrl":"https://doi.org/10.24425/cpe.2019.126113","url":null,"abstract":"This paper discusses the influence of the direction of applied deformation on the ability to gelation of thermosensitive chitosan hydrogels. The application of the shear rate equal in value to the classically performed oscillatory measurements leads to significantly different shapes of experimental curves. It was found that the type of mechanically applied deformation has a significant impact on the gelation ability of colloidal chitosan solutions and conditions of sol-gel phase transition. Simple shear leads to a phase transition at a lower temperature or in a shorter time compared to oscillatory tests. Moreover, based on the final values of dynamic viscosity in rotational measurements, it was found that stronger crosslinking of the polymer structure was observed.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"21 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135684235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Emulsions as vehicles for the controlled release of astaxanthin in topical application","authors":"","doi":"10.24425/cpe.2021.138939","DOIUrl":"https://doi.org/10.24425/cpe.2021.138939","url":null,"abstract":"In the work, the antioxidant activity of astaxanthin (AST) and the influence of the base formulation on the kinetics of AST release were studied. Three stable O/W AST-loaded emulsions, differing in droplet size (12.7 µ m (E1), 3.8 µ m (E2), 3.2 µ m (E3)) and a nanoemulsion (0.13 µ m, NE) were prepared. The results confirmed very strong antioxidant activity of AST. The emulsion internal phase droplet size did not significantly affect the AST release. The amount of released AST was respectively: 13.60% (E1), 11.42% (E2), 9.45% (E3), 9.71% (NE). The best fit to experimental data was obtained using the Higuchi model for emulsions and the Korsmeyer-Peppas model for NE. The results show that the AST release process is limited by the diffusion through carriers and the prepared O/W emulsions can be applied as vehicles for delivery of astaxanthin to the skin, ensuring effective anti-aging action of the cosmetics.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"151 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Principles of modelling of slinky-coil ground heat exchangers","authors":"","doi":"10.24425/cpe.2019.130225","DOIUrl":"https://doi.org/10.24425/cpe.2019.130225","url":null,"abstract":"The paper presents analytical relationships based on the theory of Green’s functions. The relationships refer to instantaneous and continuous as well as point and ring heat sources which are discussed. The relationship relating to continuous ring source is the basis for modelling and designing of spiral ground heat exchangers. Heat transfer in the infinite and semi-infinite body was considered. In the latter case, the image method was discussed. Using the results of measurements regarding heat transfer in the ground with a heat exchanger in the form of a single coil installed, a comparison of calculated ground temperatures with measured values was presented.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"246 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135678749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}