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Testing and improving brGMGTs-based paleotemperature estimates in peat sediments: Evidence from global surface peat samples and two well-dated Holocene peat cores in far Northwest China 基于brgmgts的泥炭沉积物古温度估算的检验与改进:来自全球地表泥炭样品和中国西北远地区两个全新世泥炭岩心的证据
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-02-01 DOI: 10.1016/j.gloplacha.2025.104700
Zhongwei Shen , Minghua Zhao , Tianyan Lin , Xiaoxu Qu , Haichun Guo , Jiantao Cao , Guodong Jia , Zhiguo Rao
{"title":"Testing and improving brGMGTs-based paleotemperature estimates in peat sediments: Evidence from global surface peat samples and two well-dated Holocene peat cores in far Northwest China","authors":"Zhongwei Shen ,&nbsp;Minghua Zhao ,&nbsp;Tianyan Lin ,&nbsp;Xiaoxu Qu ,&nbsp;Haichun Guo ,&nbsp;Jiantao Cao ,&nbsp;Guodong Jia ,&nbsp;Zhiguo Rao","doi":"10.1016/j.gloplacha.2025.104700","DOIUrl":"10.1016/j.gloplacha.2025.104700","url":null,"abstract":"<div><div>BrGMGTs (branched glycerol monoalkyl glycerol tetraethers) are proposed as potential proxies for temperature estimation due to their constrained and consistent biological origin. However, discrepancies observed between brGMGTs-based proxies and MAAT (mean annual air temperature) have raised concerns about their applicability. Here, we analyzed surface samples from three peatlands across China, and two well-dated Holocene peat cores. We found: 1) surface peat samples showed that %brGMGTs (abundance of brGMGTs relative to brGMGTs and brGDGTs; brGDGTs: branched glycerol dialkyl glycerol tetraethers) and H-MBT (methylation degree of brGMGTs) were ineffective to represent temperature. 2) Holocene records of %brGMGTs and H-MBT were uncorrelated with MBT’<sub>5ME</sub> records (previously established as reliable temperature records) in the same cores, as well as with regional other proxy temperature records. Our data, along with the global peat dataset, indicated that brGMGTs are ineffective for temperature estimation under cold conditions (MAAT &lt;10 °C). This ineffectiveness may be due to unfavorable temperature niches, changes in aerobic/anaerobic conditions and microbial communities. By setting a threshold (%brGMGTs &gt;4 %), we found that H-MBT showed a higher positive correlation with MAAT (<em>R</em><sup><em>2</em></sup> = 0.50, <em>p</em> &lt; 0.01, <em>n</em> = 26), compared to all samples (<em>R</em><sup><em>2</em></sup> = 0.47, <em>p</em> &lt; 0.01, <em>n</em> = 72). Although this improvement in correlation is modest, it helps exclude samples with MAAT &lt;10 °C. Our revised method for temperature estimation using brGMGTs could potentially be applied to peat sediments with MAAT ranging from 10 °C to 27 °C, enhancing their application for paleotemperature reconstruction in future research.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"245 ","pages":"Article 104700"},"PeriodicalIF":4.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142975630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Glacial-interglacial changes in Antarctic Intermediate Water advection in the Southeast Pacific during the last 787 kyr 过去787年东南太平洋南极中水平流的冰期-间冰期变化
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-02-01 DOI: 10.1016/j.gloplacha.2025.104695
Karol O. Duarte , Igor M. Venancio , Rodrigo A. Nascimento , Ana Luiza S. Albuquerque , Thiago P. Santos , Stefano Crivellari , Cristiano M. Chiessi , IODP Expedition 383 Shipboard Scientists
{"title":"Glacial-interglacial changes in Antarctic Intermediate Water advection in the Southeast Pacific during the last 787 kyr","authors":"Karol O. Duarte ,&nbsp;Igor M. Venancio ,&nbsp;Rodrigo A. Nascimento ,&nbsp;Ana Luiza S. Albuquerque ,&nbsp;Thiago P. Santos ,&nbsp;Stefano Crivellari ,&nbsp;Cristiano M. Chiessi ,&nbsp;IODP Expedition 383 Shipboard Scientists","doi":"10.1016/j.gloplacha.2025.104695","DOIUrl":"10.1016/j.gloplacha.2025.104695","url":null,"abstract":"<div><div>Southern-sourced intermediate waters play a central role in global ocean oxygenation and nutrient transport to low latitudes. However, the glacial-interglacial variability in their formation rate and geometry are not well constrained. Here we present a new ca. 787 thousand years-long benthic foraminifera stable carbon isotopic record from the Southeast Pacific, near the main formation region of Antarctic Intermediate Water (AAIW), which allows the investigation of changes in the formation rate and transport of AAIW over the last 787 kyr. Our results show glacial-interglacial changes in AAIW transport, with more AAIW being exported towards the Atlantic Ocean during interglacials, and to the low-latitude Pacific Ocean during glacials. We hypothesize that the AAIW exportation from the Pacific to the Atlantic Ocean is controlled by transport through the Drake Passage, which is reduced (increased) during glacial (interglacial) periods. The observed pattern is probably related to a combination of factors, including reduced (increased) sea-ice extent and southward (northward) shift of oceanic fronts and/or the westerlies during interglacials (glacials). Our mechanism reconciles the greater influence of AAIW in the northern Chilean margin during glacial periods, concurrent with the previously suggested decrease in formation rate and shallowing of this water mass. Ultimately, the glacial-interglacial variability in AAIW exportation to the Atlantic Ocean may be closely linked with changes in the stability of Atlantic Meridional Overturning Circulation during these distinct climate background states.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"245 ","pages":"Article 104695"},"PeriodicalIF":4.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142975633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Changes in surface conditions and associated hypoxia since the late Marine Isotope Stage 3, eastern Arabian Sea
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-31 DOI: 10.1016/j.gloplacha.2025.104734
Jeet Majumder , Anil K. Gupta , Prasanta Sanyal , Rudra Narayan Mohanty
{"title":"Changes in surface conditions and associated hypoxia since the late Marine Isotope Stage 3, eastern Arabian Sea","authors":"Jeet Majumder ,&nbsp;Anil K. Gupta ,&nbsp;Prasanta Sanyal ,&nbsp;Rudra Narayan Mohanty","doi":"10.1016/j.gloplacha.2025.104734","DOIUrl":"10.1016/j.gloplacha.2025.104734","url":null,"abstract":"<div><div>This study presents multiproxy record of benthic foraminiferal assemblages, relative abundances of planktic foraminifer <em>Globigerina bulloides</em>, stable isotope ratios in benthic foraminifer <em>Uvigerina peregrina</em>, and signature of pyritization from Core SK291/GC17, located at a water depth of 182 m in the eastern Arabian Sea (EAS). The sediment core covers an age from ∼40,000 to 3500 calibrated years before present (cal yr BP). Distinctly high abundance of <em>G. bulloides</em>, suggests strong upwelling and high productivity driven by intense Indian summer monsoon (ISM) winds in the EAS during ∼40,000–29,000 cal yr BP, corresponding to the late Marine Isotope Stage 3 (MIS3). As the sea level was lower than the recent time in the MIS3, closer proximity of the core to the coast aided high continental influx, which led to eutrophic, oxygen deficient condition at the sediment-water interface. This hypoxic condition is evident from the subjugation of oxic benthic foraminifera and their very low species diversity. Framboidal pyrite aggregates were observed during the MIS 3, suggesting iron-rich continental influx to the study core followed by pyritization in the anoxic environment. During the Last Glacial Maximum (LGM), a lower sea level and weak ISM caused relatively mesotrophic (and better oxygenated) condition over Core SK291/GC17. The extreme eutrophic and associated hypoxic condition in the late MIS 3 at Core SK291/GC17 was never experienced in the younger intervals, with <em>G. bulloides</em> percentages showing continuous decrease.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"246 ","pages":"Article 104734"},"PeriodicalIF":4.0,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143124536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Significant contribution of groundwater to the basalt weathering flux in an inactive volcanic field: Evidence from radiogenic uranium isotope
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-29 DOI: 10.1016/j.gloplacha.2025.104728
Laifeng Li , Shenghui Ouyang , Gen K. Li , David William Hedding
{"title":"Significant contribution of groundwater to the basalt weathering flux in an inactive volcanic field: Evidence from radiogenic uranium isotope","authors":"Laifeng Li ,&nbsp;Shenghui Ouyang ,&nbsp;Gen K. Li ,&nbsp;David William Hedding","doi":"10.1016/j.gloplacha.2025.104728","DOIUrl":"10.1016/j.gloplacha.2025.104728","url":null,"abstract":"<div><div>Chemical weathering of basalt plays a vital role in the long-term carbon cycle and Earth's habitability. Quantifying the magnitude and controlling factors of basalt weathering requires assessing the contribution to weathering solutes from groundwater, which has remained challenging. In this work, we apply radiogenic uranium isotope activity ratios (<sup>234</sup>U/<sup>238</sup>U) to trace groundwater input to riverine weathering solutes in an inactive volcanic field from East China. Dissolved (<sup>234</sup>U/<sup>238</sup>U) is closely tied to the residence time of water bodies on the Earth's surface, allowing us to separate surface weathering solutes and groundwater characterized by distinct flow paths and residence time. We constrain the surface-weathering and groundwater end-members using hillslope-weathering solutes and spring waters, respectively. Based on the (<sup>234</sup>U/<sup>238</sup>U) ratios of the collected end-member samples, we developed a mass balance model and determined that groundwater contributes significantly to riverine solutes (∼41.5 %) but only has a minor contribution (∼10 %) to the water in man-made reservoirs in the study area. The estimated basalt weathering rates based on the alkalinity of river water may deviate from the global trend between basalt weathering rates and temperature if the contribution of groundwater is not corrected. Overall, our findings highlight the necessity to account for the influence of groundwater when estimating basalt weathering rates using river water, whereas man-made reservoirs may be less prone to groundwater inputs.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"246 ","pages":"Article 104728"},"PeriodicalIF":4.0,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143124541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Size-fractionated C:N:P:Si stoichiometry of particulate matter in the subtropical Western North Pacific
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-28 DOI: 10.1016/j.gloplacha.2025.104732
Chaoyong Wang , Kan Zhang , Zhimian Cao , Kuanbo Zhou , Zhongwei Yuan , Junhui Chen , Yifan Ma , Bei Zhou , Xin Liu , Yihua Cai , Dalin Shi , Minhan Dai
{"title":"Size-fractionated C:N:P:Si stoichiometry of particulate matter in the subtropical Western North Pacific","authors":"Chaoyong Wang ,&nbsp;Kan Zhang ,&nbsp;Zhimian Cao ,&nbsp;Kuanbo Zhou ,&nbsp;Zhongwei Yuan ,&nbsp;Junhui Chen ,&nbsp;Yifan Ma ,&nbsp;Bei Zhou ,&nbsp;Xin Liu ,&nbsp;Yihua Cai ,&nbsp;Dalin Shi ,&nbsp;Minhan Dai","doi":"10.1016/j.gloplacha.2025.104732","DOIUrl":"10.1016/j.gloplacha.2025.104732","url":null,"abstract":"<div><div>Particulate C:N:P:Si ratios and their variations in the upper ocean are crucial for understanding carbon export and its coupling with nutrient dynamics and phytoplankton community composition associated with nutrient limitation. Here, we present the first dataset of size-fractionated biogenic particle concentrations and their elemental ratios, including particulate organic carbon (POC), particulate nitrogen (PN), particulate phosphorus (PP), and biogenic silica (BSi), in the upper 500 m of the water column in the subtropical western North Pacific. The highest POC, PN, and PP concentrations consistently occurred in surface water and then decreased with increasing depth, whereas BSi concentration was frequently highest in the subsurface chlorophyll maximum layer at ∼ 120 m. The small size fraction (SSF, 0.8 or 1–51 μm) dominated the total pool of POC, PN, and PP but contributed less to the total BSi pool than the large size fraction (LSF, &gt;51 μm). This feature was accompanied by lower C:N, C:P, and N:P ratios and higher C:Si ratios in the SSF than in the LSF. In the euphotic zone, total particulate C:N, C:P, N:P, and C:Si ratios averaged 8 ± 1, 146 ± 30, 17 ± 3, and 120 ± 48 mol:mol respectively, and exceeded the canonical Redfield and Brzezinski ratio. The three former ratios aligned with cellular C:N:P ratios of <em>Prochlorococcus</em> and <em>Synechococcus</em>. Moreover, these ratios exhibited observable latitudinal gradients; they were generally higher in the gyre center than in its southern boundary occupied by the North Equatorial Current. Below the euphotic zone down to 500 m, there was a distinct increase in SSF molar C:N, C:P, and N:P ratios with depth, while total particulate molar C:Si ratios remained relatively constant. Combined with data collected in the subtropical eastern South Pacific and North Atlantic, our results demonstrate that the composition of the phytoplankton community primarily controls particulate molar C:N:P:Si stoichiometry in the euphotic zone of ocean gyres, in particular in the SSF, below which preferential remineralization of various bioelements plays an important role.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"246 ","pages":"Article 104732"},"PeriodicalIF":4.0,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143349945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evolutionary history of the Malacca Strait driven by sea level changes over the last 16 ka
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-28 DOI: 10.1016/j.gloplacha.2025.104731
Lina Ai , Shengfa Liu , Hui Zhang , Peng Cao , Xiao Wu , Lianhua He , Wenjing Qi , Kaikai Wu , Che Abd Rahim Mohamed , Houjie Wang , Xuefa Shi
{"title":"Evolutionary history of the Malacca Strait driven by sea level changes over the last 16 ka","authors":"Lina Ai ,&nbsp;Shengfa Liu ,&nbsp;Hui Zhang ,&nbsp;Peng Cao ,&nbsp;Xiao Wu ,&nbsp;Lianhua He ,&nbsp;Wenjing Qi ,&nbsp;Kaikai Wu ,&nbsp;Che Abd Rahim Mohamed ,&nbsp;Houjie Wang ,&nbsp;Xuefa Shi","doi":"10.1016/j.gloplacha.2025.104731","DOIUrl":"10.1016/j.gloplacha.2025.104731","url":null,"abstract":"<div><div>The Malacca Strait connects the Sunda Shelf and Andaman Sea, which is a chokepoint for the exchange of both material and energy between two larger bodies of water. However, the evolutionary history of the Malacca Strait is poorly understood, although its development can be closely linked to regional paleoenvironmental changes. In this study, we present multiple new analytical results on the basis of a high-resolution chronology, including grain size, geochemical composition, and Sr<img>Nd isotopic compositions in both labile and detrital fractions of sediments from surface samples as well as core samples. We aim to reveal the evolutionary history of the Malacca Strait by tracing records of the geochemical compositions and Sr<img>Nd isotopic compositions of both labile and detrital fractions of sediments. A provenance transition between ∼10 and ∼7 ka has been identified, with the occurrence of a Sunda Shelf sediment signal at approximately 10 ka. Combining the shifting provenance and varying depositional environment since 16.28 ka allows us to distinguish three distinct evolutionary stages of the Malacca Strait: 1) Stage I, during 10–15 ka, a general estuary and embayment environment with provenances from the Malaysian Peninsula, Sumatra and the eastern shelf of the Andaman Sea; 2) Stage II, during the early Holocene at 10–7 ka, a period of an initial strait configuration with a narrow and shallow channel, which only allowed restricted sediment and water mass influx into the strait; and 3) Stage III, a highstand of sea level since ∼7 ka, a phase of a fully opened strait with a high-energy hydrodynamic environment dominated by tidal and northwestward currents. It suggested that the initial opening of the strait may have been incapable of providing higher-energy depositional environments, such as those present today, whereas the optimal sea level since 7.26 ka promoted throughflow in the Malacca Strait. Our results demonstrate that sea level was the first-order control of sedimentary evolution in the strait, whereas the monsoon climate only played a secondary role.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"246 ","pages":"Article 104731"},"PeriodicalIF":4.0,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143124538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of weakly euxinic basin environments in the Phanerozoic oxic ocean: Insights from Fe speciation and Mo isotopes of Devonian pyrite-bearing black shales, Dajiangping pyrite mine, South China
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-28 DOI: 10.1016/j.gloplacha.2025.104721
Wenhong Johnson Qiu , Mei-Fu Zhou , John Malpas , Jie Li , Zerui Ray Liu , Yafei Wu
{"title":"Development of weakly euxinic basin environments in the Phanerozoic oxic ocean: Insights from Fe speciation and Mo isotopes of Devonian pyrite-bearing black shales, Dajiangping pyrite mine, South China","authors":"Wenhong Johnson Qiu ,&nbsp;Mei-Fu Zhou ,&nbsp;John Malpas ,&nbsp;Jie Li ,&nbsp;Zerui Ray Liu ,&nbsp;Yafei Wu","doi":"10.1016/j.gloplacha.2025.104721","DOIUrl":"10.1016/j.gloplacha.2025.104721","url":null,"abstract":"<div><div>Although the Phanerozoic ocean was generally oxygenated, local euxinic events occurred frequently, as witnessed by the widespread Paleozoic sediment-hosted stratiform sulfide (SHSS) deposits. Here, we use redox-sensitive Fe speciation and Mo isotopes of black shales and pyrite ores of the Devonian Dajiangping stratiform pyrite deposit in the South China Block (SCB) to decipher the linkage between redox conditions, basin restrictions and SHSS mineralization. From bottom to top, the host sedimentary succession on the deposit margin is a transgressive sequence of siltstones, carbonaceous limestones and black shales. The ratios of highly reactive Fe to total Fe (Fe<sub>HR</sub>/Fe<sub>T</sub>: 0.29 to 1.0), Fe in pyrite to highly reactive Fe (Fe<sub>py</sub>/Fe<sub>HR</sub>: 0.09 to 0.91), and δ<sup>98/95</sup>Mo (0.50 ‰ to 1.30 ‰), show consistently increasing trends upward throughout the stratigraphic sequence, indicative of changes in the redox of bottom seawater from oxic, through anoxic, to weakly euxinic, in response to the subsidence of the basin. Black shales and interlayered laminated pyrite ores on the deposit center have δ<sup>98/95</sup>Mo varying from +0.90 to +1.50 ‰ and higher than the host succession, clearly demonstrating the redox condition of bottom seawater in the depocenter is more euxinic than the margin of the basin. These δ<sup>98/95</sup>Mo values lower than those of seawater were resulted from the occurrence of thimolybdates with variable Mo isotopic fractionations in the weakly euxinc conditions. In addition, the positive correlation (R<sup>2</sup> = 0.84) between Mo concentrations and total organic carbon (TOC) of the black shales suggests that Mo was authigenic in origin. These black shales have Mo/TOC of ∼1.7 ppm/wt%, which are much lower than those in poorly or unconfined euxinic basins (Mo/TOC &gt; 11 ppm/wt%) and indicative of a restricted basin environment. The redox conditions of seawater changed from oxic to anoxic on the basin margin but maintained weakly euxinic in the basin center, consistent with a basinal environment showing subsidence and restriction. Such a restricted basin was due to the rifting of a fault-bounded trough on the passive margin of the SCB during the Devonian. Our study highlights the importance of locally restricted basins with euxinic and stratified seawater environments for the extensive development of SHSS deposits in an oxygenated Phanerozoic ocean.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"248 ","pages":"Article 104721"},"PeriodicalIF":4.0,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143421865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reduction in sediment yields from karst terrain in SW China over the past 600+ years
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-27 DOI: 10.1016/j.gloplacha.2025.104724
Yunqi Zhang , Bangrun Guo , Wei Li , Lan Tang , Xinxin Zhang , Yi Long , Xinbao Zhang , Bo Tan , Ziteng Luo , Xun Hu , Yong Wang
{"title":"Reduction in sediment yields from karst terrain in SW China over the past 600+ years","authors":"Yunqi Zhang ,&nbsp;Bangrun Guo ,&nbsp;Wei Li ,&nbsp;Lan Tang ,&nbsp;Xinxin Zhang ,&nbsp;Yi Long ,&nbsp;Xinbao Zhang ,&nbsp;Bo Tan ,&nbsp;Ziteng Luo ,&nbsp;Xun Hu ,&nbsp;Yong Wang","doi":"10.1016/j.gloplacha.2025.104724","DOIUrl":"10.1016/j.gloplacha.2025.104724","url":null,"abstract":"<div><div>Previous studies have examined sediment yields and erosion in karst settings over recent decades, with little consideration of the evolution of rocky desertification over longer timescales. Here we reconstruct sediment yields from karst terrain in SW China over the past 600+ years by dating sediment deposition in a representative karst depression, and assess the contribution of historical sediment yields to rocky desertification. Results indicate that area-specific sediment yields (<em>SSYs</em>) during the early stage of sediment deposition (1368–1652) were the highest, triggered by deforestation and then cultivation associated with the first Hu-Guang Fills Sichuan migration during the Ming Dynasty. The relatively high <em>SSYs</em> during the middle stage (1653–1922) were related mainly to cultivation associated with the second Hu-Guang Fills Sichuan migration rather than deforestation, including the introduction of maize (<em>Zea mays</em>) and sweet potato (<em>Ipomoea batatas</em>) during the Qing Dynasty. <em>SSYs</em> increased again during the modern stage (1923–1962) due to massive deforestation at the end of the 1950s. During the latest stage (1963–2022), <em>SSYs</em> were the lowest as a result of increasing rocky desertification, reduced human disturbance, and the restoration of vegetation. The contributions of sediment yield to rocky desertification decreased across the middle, modern and latest stages, suggesting that the present-day rocky desertification was caused mainly by sediment yield stimulated by human activity over the past 500+ years before 1923, rather than over recent decades. Overall, our study provides more-comprehensive insights into the dynamics of rocky desertification over long timescales.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"246 ","pages":"Article 104724"},"PeriodicalIF":4.0,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143124908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Resistant degradation of petrogenic organic carbon in the weathering of calcareous rocks
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-25 DOI: 10.1016/j.gloplacha.2025.104727
Huiyuan Yang , Jian Ma , Songfan He , Jin Wang , Yongge Sun , Xingqian Cui
{"title":"Resistant degradation of petrogenic organic carbon in the weathering of calcareous rocks","authors":"Huiyuan Yang ,&nbsp;Jian Ma ,&nbsp;Songfan He ,&nbsp;Jin Wang ,&nbsp;Yongge Sun ,&nbsp;Xingqian Cui","doi":"10.1016/j.gloplacha.2025.104727","DOIUrl":"10.1016/j.gloplacha.2025.104727","url":null,"abstract":"<div><div>Weathering of rock-derived organic carbon (OC) is an important source of atmospheric CO<sub>2</sub> in the global carbon cycle, contributing to the long-term regulation of climates. Despite numerous investigations on clastic rocks, weathering behaviors of OC in calcareous rocks remain poorly constrained due to their conventional recognition of organic-lean features. Here, we analyzed bulk OC and biomarkers along weathering profiles of organic-rich calcareous rocks from the Green River Formation. Total OC and ramped-temperature pyrolysis/oxidation results reveal a minimal degradation of OC. Given a substantial fraction of bulk OC and a rich pool of biomolecules preserved in carbonate matrix, our results suggest that the limited bulk-level degradation is attributed to the shielding of OC in carbonate matrix. Furthermore, contrasting biomarker proxies are observed between free and associated forms, implying that carbonate-associated lipids are resistant to degradation during weathering; whereas clearly decreasing patterns of free lipids at the molecular level correspond to weathering-induced microbial degradation of excluded OC. Overall, our findings reveal that calcareous rocks might be an overlooked, yet understudied, carbon pool involved in the global organic carbon cycle.</div></div>","PeriodicalId":55089,"journal":{"name":"Global and Planetary Change","volume":"246 ","pages":"Article 104727"},"PeriodicalIF":4.0,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143124542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High- vs. low-rate of sea level change fluvial floods: Past analogues for future forecast
IF 4 1区 地球科学
Global and Planetary Change Pub Date : 2025-01-23 DOI: 10.1016/j.gloplacha.2025.104723
Juan I. Santisteban , Rosa Mediavilla , Cristina Val-Peón , José Antonio López-Sáez , Klaus Reicherter
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