{"title":"Fabrication of monodisperse droplets and microcapsules using microfluidic chips: a review of methodologies and applications","authors":"Weiguang Su, Bing Han, S. Yeboah, D. Du, Li Wang","doi":"10.1515/revce-2022-0060","DOIUrl":"https://doi.org/10.1515/revce-2022-0060","url":null,"abstract":"Abstract Microfluidics has been applied in the preparation of monodisperse droplets and microcapsules due to its high encapsulation efficiency, its ability to create uniform particle sizes, and its capacity to control core–shell ratio and structure. To bring to the fore methodologies for the fabrication and application of monodisperse microcapsules using microfluidics, we present a review of the design, structure, materials, and surface modification techniques of various microfluidic chips. The review also covers fabrication methods, operating parameters and regulation methods of single and multiple monodisperse emulsion droplets fabricated from various microfluidic devices. Our findings show that particle size of monodisperse droplets depend mainly on microchannel characteristic size and flow rate, with particle size increasing with larger microchannel but decreasing with higher continuous phase flow rate. We additionally reviewed and compared various fabrication methods for monodisperse microcapsules, such as interfacial polymerization, free-radical polymerization, ionic cross-linking, and solvent evaporation. We further reviewed and examined the application of monodisperse microcapsules in biology applications, food engineering, composite materials development, and pharmaceutical industry. We found that high-throughput microfluidics for scale-up monodisperse microcapsule preparation towards uniform degradation and targeted release properties of monodisperse microcapsules would be key innovative direction for future applications.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43547894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Hassan, Iqra Sajid, M. Akmal, Muniba Aslam, P. G. Roy, Shuiqin Zhou, Ahmad Irfan, M. Shahid, R. Begum, Z. H. Farooqi
{"title":"Hollow microgels and their hybrids: classification, synthesis, characterization, properties and applications","authors":"A. Hassan, Iqra Sajid, M. Akmal, Muniba Aslam, P. G. Roy, Shuiqin Zhou, Ahmad Irfan, M. Shahid, R. Begum, Z. H. Farooqi","doi":"10.1515/revce-2022-0074","DOIUrl":"https://doi.org/10.1515/revce-2022-0074","url":null,"abstract":"Abstract Hollow microgels and their hybrids have gained much attention in modern-day research because of their fascinating properties and potential applications. This article gives classification, preparation methods, properties and applications of hollow microgels and their hybrids in modern research. Some of the hollow microgels and their hybrids respond to change in specific environmental stimuli like pH, ionic strength and temperature of the medium. They are called smart polymer hollow microgels and smart hybrid microgels, respectively. This peculiar behaviour makes them a suitable candidate for their use in drug delivery, sensing, catalysis and many other fields. This review represents the current advancement along with future perspectives and suggestions for further research in this particular area.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49411842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wen Xuan Woo, J. Tan, T. Wu, S. Yeap, Abdullah Amru Indera Luthfi, Shareena Fairuz Abdul Manaf, N. S. Jamali, Y. W. Hui
{"title":"An overview on the factors affecting enzymatic saccharification of lignocellulosic biomass into fermentable sugars","authors":"Wen Xuan Woo, J. Tan, T. Wu, S. Yeap, Abdullah Amru Indera Luthfi, Shareena Fairuz Abdul Manaf, N. S. Jamali, Y. W. Hui","doi":"10.1515/revce-2022-0019","DOIUrl":"https://doi.org/10.1515/revce-2022-0019","url":null,"abstract":"Abstract Lignocellulosic biomass (LCB) is a widely available and sustainable energy resource that can be directly or indirectly converted to biofuels and value-added bioproducts. In such LCB conversion, enzymatic saccharification is commonly regarded as a green alternative to chemical hydrolysis due to less energy-intensive, less toxic, and more environment-benign for efficient fermentable sugar recovery. However, enzymatic saccharification faces substantial challenges, since the complex polymeric matrices of LCB necessitates a variety of enzymes for complete and adequate saccharification. Empirical evidence on enzymatic saccharification has paved the way for optimizing the processes and design for enhancing the performance in LCB. This review examines the enzymatic saccharification of LCB, focusing on the important parameters affecting the process, such as pH, temperature, agitation, enzyme/substrate loading, residence time, and the enzymes required to degrade various LCB components. Various strategies have been reported to improve the performance in saccharification and to address the non-productive adsorption of enzymes. A preliminary economic competency valuation of enzyme-derived fermentable sugars is proposed. Wheat straw, sugarcane bagasse and corn stalk appear, in this case, to be the most economic competent LCBs for commercial enzyme-derived fermentable sugar production. Lastly, practical challenges and future research directions on the enzymatic saccharification of LCB are discussed.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47171453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review of the use of giant reed (Arundo donax L.) in the biorefineries context","authors":"Z. Ortega, I. Bolaji, Luis Suárez, E. Cunningham","doi":"10.1515/revce-2022-0069","DOIUrl":"https://doi.org/10.1515/revce-2022-0069","url":null,"abstract":"Abstract The massive availability of biomass generated by the common giant reed (Arundo donax L.) motivates the search for its possible industrial use for the generation of high added-value products through implementing a biorefinery approach. The literature demonstrates the potential of common cane to obtain different high-value compounds, such as levulinic acid, oligosaccharides, fermentable sugars, highly digestible fiber for animal feed, polyphenols, and natural fibers for composite materials, among others. The data shows the upward trend in Europe toward the generation of new green industries, grouped under the biorefinery concept. Therefore, this review summarizes the current knowledge on the use of Arundo to produce materials, fibers, and chemicals. Major environmental concerns related to this plant are also reviewed. Special attention has been paid to the potential use of Arundo to produce chemicals using green chemistry approaches, as a way to contribute to and advance the achievement of Sustainable Development Goals. Recommendations for future research are also outlined.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43187050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Evelien Vermoesen, S. Bodé, Geert Brosens, P. Boeckx, S. van Vlierberghe
{"title":"Chemical strategies towards controlled release in agriculture","authors":"Evelien Vermoesen, S. Bodé, Geert Brosens, P. Boeckx, S. van Vlierberghe","doi":"10.1515/revce-2022-0057","DOIUrl":"https://doi.org/10.1515/revce-2022-0057","url":null,"abstract":"Abstract With an increasing world population of nearly eight billion which is expected to expand towards nine billion by 2050, future food demands will rise unavoidably. Primary productivity of crop is at the center of the food and feed value chain. Excessive and low efficiency fertilization cause severe environmental and ecological problems, along with economic wastage. Next to fertilizers, also pesticides, plant growth regulators and other agrochemicals (e.g., stored animal manure and hormones) pose environmental issues and require specific technologies to ensure security of human health and the global ecosystem while increasing food productions. There is an agronomic, legal and environmental ‘demand’ to develop controlled release solutions to optimize agricultural practices. In this regard, (polymer) chemistry can offer a wide range of strategies to cope with the current issues related to biodegradation, overfertilization, pesticide use, efficient precision agriculture etc. through tailored material design allowing controlled active components release. Therefore, this review focusses on (polymer) chemical strategies to design controlled release systems in the agricultural industry, covering specifically the state-of-the-art from the past four years.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46695453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Frontmatter","authors":"","doi":"10.1515/revce-2023-frontmatter4","DOIUrl":"https://doi.org/10.1515/revce-2023-frontmatter4","url":null,"abstract":"","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"97 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136002481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Role of La-based perovskite catalysts in environmental pollution remediation","authors":"A. Jain, Sarang Tamhankar, Yash Jaiswal","doi":"10.1515/revce-2022-0034","DOIUrl":"https://doi.org/10.1515/revce-2022-0034","url":null,"abstract":"Abstract Since the advent of the industrial revolution, there has been a constant need of efficient catalysts for abatement of industrial toxic pollutants. This phenomenon necessitated the development of eco-friendly, stable, and economically feasible catalytic materials like lanthanum-based perovskite-type oxides (PTOs) having well-defined crystal structure, excellent thermal, and structural stability, exceptional ionic conductivity, redox behavior, and high tunability. In this review, applicability of La-based PTOs in remediation of pollutants, including CO, NO x and VOCs was addressed. A framework for rationalizing reaction mechanism, substitution effect, preparation methods, support, and catalyst shape has been discussed. Furthermore, reactant conversion efficiencies of best PTOs have been compared with noble-metal catalysts for each application. The catalytic properties of the perovskites including electronic and structural properties have been extensively presented. We highlight that a robust understanding of electronic structure of PTOs will help develop perovskite catalysts for other environmental applications involving oxidation or redox reactions.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47849912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Phenolic compounds extraction by assistive technologies and natural deep eutectic solvents","authors":"Yoke Shan Wong, R. Yusoff, G. Ngoh","doi":"10.1515/revce-2022-0043","DOIUrl":"https://doi.org/10.1515/revce-2022-0043","url":null,"abstract":"Abstract Phenolic compounds are known to have a significant effect on human defense system due to their anti-inflammatory efficacy. This can slow down the aging process and strengthen the human immune system. With the growing interest in green chemistry concept, extraction of phenolic compounds from plants has been geared towards a sustainable path with the use of green and environmentally friendly solvents such as natural deep eutectic solvents (NADES). This review discusses both the conventional extraction and the advanced extraction methods of phenolic compounds using NADES with focus on microwave-assisted extraction (MAE) and ultrasound-assisted extraction (UAE) techniques ensued by a rationale comparison between them. Employing choline chloride-based natural deep eutectic solvents (NADES) is highlighted as one of the promising strategies in green solvent extraction of phenolic compounds in terms of their biodegradability and extraction mechanism. The review also discusses assistive extraction technologies using NADES for a better understanding of their relationship with extraction efficiency. In addition, the review includes an overview of the challenges of recovering phenolic compounds from NADES after extraction, the potential harmful effects of NADES as well as their future perspective.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44552487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Frontmatter","authors":"","doi":"10.1515/revce-2023-frontmatter3","DOIUrl":"https://doi.org/10.1515/revce-2023-frontmatter3","url":null,"abstract":"","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"93 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135526486","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carlota Guati, L. Gómez-Coma, M. Fallanza, I. Ortiz
{"title":"Progress on the influence of non-enzymatic electrodes characteristics on the response to glucose detection: a review (2016–2022)","authors":"Carlota Guati, L. Gómez-Coma, M. Fallanza, I. Ortiz","doi":"10.1515/revce-2022-0058","DOIUrl":"https://doi.org/10.1515/revce-2022-0058","url":null,"abstract":"Abstract Glucose sensing devices have experienced significant progress in the last years in response to the demand for cost-effective monitoring. Thus, research efforts have been focused on achieving reliable, selective, and sensitive sensors able to monitor the glucose level in different biofluids. The development of enzyme-based devices is challenged by poor stability, time-consuming, and complex purification procedures, facts that have given rise to the synthesis of enzyme-free sensors. Recent advances focus on the use of different components: metal-organic frameworks (MOFs), carbon nanomaterials, or metal oxides. Motivated by this topic, several reviews have been published addressing the sensor materials and synthesis methods, gathering relevant information for the development of new nanostructures. However, the abundant information has not concluded yet in commercial devices and is not useful from an engineering point of view. The dependence of the electrode response on its physico-chemical nature, which would determine the selection and optimization of the materials and synthesis method, remains an open question. Thus, this review aims to critically analyze from an engineering vision the existing information on non-enzymatic glucose electrodes; the analysis is performed linking the response in terms of sensitivity when interferences are present, stability, and response under physiological conditions to the electrode characteristics.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2023-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46356882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}