ChemNanoMat最新文献_第2页

Bias Selectable Dual Band Detectors Based on Vertically Aligned In2S3-Coated ZnO Nanorod Arrays Grown on p-GaN

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-23 DOI: 10.1002/cnma.202400557

Yu Qi, Lanfeng Li, Yaowen Xu, Guangcheng Gao, Naisen Yu, YunFeng Wu

引用次数: 0

Hierarchical Pore Engineering of Slope-Type Hard Carbon for Enhanced Sodium-Ion Storage

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-23 DOI: 10.1002/cnma.202400562

Yongqi Liu, Yun Zhang, Zhaowei Hu, Wenjie Zhang, Chuan Wang, Jiabiao Lian

引用次数: 0

Fabrication of Ferulic Acid-Cellulose Nanocrystal Enhanced Stretchable and Antibacterial Hydrogels

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-16 DOI: 10.1002/cnma.202400560

Fangyu Li, Yajie Wang, Luchun Xu, Xiaxue Li, Wangcheng Song, Yanyong Mao, Jia Zhou, Hao Shi

{"title":"Fabrication of Ferulic Acid-Cellulose Nanocrystal Enhanced Stretchable and Antibacterial Hydrogels","authors":"Fangyu Li, Yajie Wang, Luchun Xu, Xiaxue Li, Wangcheng Song, Yanyong Mao, Jia Zhou, Hao Shi","doi":"10.1002/cnma.202400560","DOIUrl":"https://doi.org/10.1002/cnma.202400560","url":null,"abstract":"Hydrogels are widely utilized in biomaterials, medicine, and food science due to their versatile properties. This study developed a ferulic acid (FA) and cellulose nanocrystals (CNC) hydrogel within a polyacrylamide matrix, polymerized using ammonium persulfate and crosslinked with N-methylenebisacrylamide. The FA@CNC hydrogel demonstrated exceptional tensile ductility and elasticity. Antibacterial evaluations against Escherichia coli and Staphylococcus aureus revealed significant efficacy, with activity increasing proportionally to FA concentration. Swelling studies indicated a maximum equilibrium swelling ratio of 1210 % after 36 h, showcasing the hydrogel's ability to undergo substantial expansion while maintaining its original shape and structural integrity. It was indicated that the synthesized hydrogels were capable of absorbing large volumes of exudate while preserving a moist environment conducive to accelerated wound healing. Scanning electron microscopy analysis confirmed a regular and dense microstructure, which contributes to the hydrogel's mechanical stability and robustness. The optimized preparation process developed in this study resulted in hydrogels with significantly enhanced performance. These findings underscore the hydrogel's superior mechanical and functional properties, paving the way for innovative applications across biomaterials, medical, and food-related industries.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 2","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143404754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrothermally Synthesized Bi-Cr-Te Nanocomposites With Enhanced Nonlinear Two-Photon Absorption

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-10 DOI: 10.1002/cnma.202400516

S. Supriya, M. Mallik, A. Parida, R. Naik

{"title":"Hydrothermally Synthesized Bi-Cr-Te Nanocomposites With Enhanced Nonlinear Two-Photon Absorption","authors":"S. Supriya, M. Mallik, A. Parida, R. Naik","doi":"10.1002/cnma.202400516","DOIUrl":"https://doi.org/10.1002/cnma.202400516","url":null,"abstract":"This study highlights the importance of exploring BiCrTe nanocomposites to uncover their distinctive properties and potential applications. Three BiCrTe samples were synthesized using hydrothermal methods by varying the concentrations of Bi and Cr while maintaining a constant Te content. X-ray diffraction (XRD) confirmed the presence of Bi₂Te₃ and Cr₂Te₃ phases, supported by transmission electron microscopy (TEM) observations. A reduction in Bi content led to smaller crystallite sizes. Raman spectroscopy revealed characteristic vibrational modes associated with Bi₂Te₃ and Cr. Field emission scanning electron microscopy (FESEM) confirmed the nanoparticle-like morphology of the composites. X-ray photoelectron spectroscopy (XPS) provided detailed surface composition and electronic structure data, verifying the presence of all constituent elements. UV-Vis spectroscopy demonstrated a blueshift in absorbance with decreasing Bi content, with bandgap (Eg) values ranging from 3.31 to 3.61 eV. This increase in bandgap correlated with a reduction in refractive index (n). Nonlinear optical (NLO) studies revealed two-photon absorption behavior, along with a positive nonlinear absorption coefficient (β), third-order susceptibility (χ (3)), and refractive index (n2). These findings indicate that BiCrTe nanocomposites hold significant promise for advanced optoelectronic applications.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 1","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143113693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrothermally Synthesized Cobalt-Doped NiO Nanoflakes: Enhanced Electrochemical Performance for High-Performance Supercapacitors

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-09 DOI: 10.1002/cnma.202400580

Suresh Jayakumar, P. Chinnappan Santhosh, K. V. Rishikesh, A. V. Radhamani

{"title":"Hydrothermally Synthesized Cobalt-Doped NiO Nanoflakes: Enhanced Electrochemical Performance for High-Performance Supercapacitors","authors":"Suresh Jayakumar, P. Chinnappan Santhosh, K. V. Rishikesh, A. V. Radhamani","doi":"10.1002/cnma.202400580","DOIUrl":"https://doi.org/10.1002/cnma.202400580","url":null,"abstract":"This study examines cobalt-doped nickel oxide (Co-NiO) nanomaterials synthesized through a hydrothermal method, focusing on their potential as high-performance electrodes for supercapacitors. By varying cobalt dopant concentrations (X=0, 0.01, 0.05, 0.1), we aimed to enhance the electrochemical properties through strategic Co-doping. The CoxNi1-xO nanomaterials were characterized using several techniques, including X-ray diffraction (XRD), UV-visible spectroscopy, field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), chronopotentiometry (CP), and electrochemical impedance spectroscopy (EIS). The analysis showed that Co-doping preserved the NiO phase structure while significantly altering the morphology and electrochemical characteristics. The sample with (X=0.1) achieved a specific capacitance of 880 F/g at a current density of 1 A/g, significantly outperforming the undoped NiO, which had a capacitance of 335 F/g. Additionally, the Co-NiO demonstrated 83.3 % capacitance retention after 1000 cycles at a current density of 10 A/g. These findings highlight the potential of Co-NiO as an effective electrode material for supercapacitors.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 2","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143404518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Perfectly Hexagonal Sponge-Like NiO-NiCo2O4 with Rich Electromicrostructural Physiognomies for High-Efficiency Electrocatalytic Urea Oxidation

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-09 DOI: 10.1002/cnma.202400476

Siddhant Srivastav, Mahesh Kumar Paliwal, Sumanta Kumar Meher

{"title":"Perfectly Hexagonal Sponge-Like NiO-NiCo2O4 with Rich Electromicrostructural Physiognomies for High-Efficiency Electrocatalytic Urea Oxidation","authors":"Siddhant Srivastav, Mahesh Kumar Paliwal, Sumanta Kumar Meher","doi":"10.1002/cnma.202400476","DOIUrl":"https://doi.org/10.1002/cnma.202400476","url":null,"abstract":"In order to design high-efficiency electrocatalysts for the development of urea oxidation reaction (UOR)-based energy conversion and storage systems, herein, a very facile and kinetically controlled material growth strategy has been strategized to prepare extremely uniform and perfectly hexagonal sponge-like NiO-NiCo2O4 with high BET surface area (126 m2 g−1), monomodal distribution of mesopores (~3.9 nm), hierarchical surface as well as matrix porosity, mixed-phase lattice structure, thorough atomic non-stoichiometry and multiple valency of Ni and Co (i. e. Ni2+, Ni3+, Co2+ and Co3+). The potential of NiO-NiCo2O4 is thoroughly explored for electrocatalytic UOR in alkaline electrolyte medium. The in-depth electrochemical analyses demonstrate rich redox reversibility, high UOR current density, very-low charge transfer and series resistance, and typical Warburg response indicative of facilitated diffusion of electrolyte ions during electrocatalytic UOR. Furthermore, the NiO-NiCo2O4 requires lower overpotential for effective UOR and exhibits minimal current loss during electrocatalytic UOR for prolonged duration. Proposedly, the multiple oxidation states of Ni and Co in NiO-NiCo2O4, combined with its rich physicoelectrochemical physiognomies, offer lowly-impeded electrolyte ion intercalation-deintercalation, good electronic conductivity, higher number of accessible redox active sites, facile adsorption of urea on the electrocatalytic sites and inhibition in the blockage of active sites by side products to augment the overall UOR kinetics. The optimized approach presented in this study is poised to advance the catalyst systems for UOR, which will lead to the development of high-efficiency urea-based energy conversion and storage systems for prospective integration in contemporary electronic architectures.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 2","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143404561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Trichosanthes Cucumerina Derived Activated Carbon: The Potential Electrode material for High Energy Symmetric Supercapacitor (ChemNanoMat 12/2024) 封面：葫芦瓜衍生活性炭：高能对称超级电容器的电位电极材料（ChemNanoMat 12/2024）

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-07 DOI: 10.1002/cnma.202481201

Anit Joseph, Arshitha Mathew, Tiju Thomas

引用次数: 0

Improved Piezocatalytic Performance of Cs/KNN Decorated with CuS Nanoparticles for Dye Degradation

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-02 DOI: 10.1002/cnma.202400543

YuLong Fan, YingJie Chen, Ruihang Zhang, JianMei Ren, Guan Wang

引用次数: 0

Hierarchical Porous Rod-Like In2S3/In2O3 Structures for Trimethylamine Detection

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-12-01 DOI: 10.1002/cnma.202400507

Dan Meng, Yubo Pan, Lei Zhang, Yue Zhang, Chun He, Kai Tao, Size Li, Xiaoguang San

{"title":"Hierarchical Porous Rod-Like In2S3/In2O3 Structures for Trimethylamine Detection","authors":"Dan Meng, Yubo Pan, Lei Zhang, Yue Zhang, Chun He, Kai Tao, Size Li, Xiaoguang San","doi":"10.1002/cnma.202400507","DOIUrl":"https://doi.org/10.1002/cnma.202400507","url":null,"abstract":"Trimethylamine (TMA), a volatile gas possessing a strong, pungent odor, is widely recognized as an indicator for evaluating fish freshness. Despite the importance of TMA detection, the development of sensors that simultaneously possess high sensitivity, fast response kinetics, selectivity, and low-temperature operation remains a challenge. To address this issue, this work presents a novel gas-sensing material composed of porous, rod-like In2S3/ In2O3 structures, synthesized via an in-situ sulfurization process. By precisely modulating the sulfurization state of In2O3 through the adjustment of thioacetamide concentrations, the material's structural and compositional properties were optimized for enhanced sensing performance. Experimental results demonstrate that sulfur incorporation significantly improves sensor capabilities, owing to the synergistic effects of the In2S3/ In2O3 heterojunction, the enhanced adsorption capacity for oxygen molecules, and the distinctive one-dimensional and porous architecture. Notably, the sensor with an S/In molar ratio of 1/3 exhibited exceptional TMA detection at 150 °C, with the highest response values (2.17 for 0.1 ppm and 8.17 for 10 ppm), rapid response/recovery times, excellent selectivity, and a low detection limit of 0.05 ppm. Moreover, the sensor demonstrated outstanding reproducibility and long-term stability, highlighting its potential for practical applications in seafood freshness monitoring.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 1","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143110187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Facile Fabrication of Poly(Acrylic Acid)-Functionalised Nickel-Metal-Organic Frameworks Nanoplates for Electrochemical Immunosensor for the Detection of Prostate-Specific Antigen

IF 2.6 4区材料科学

ChemNanoMat Pub Date : 2024-11-29 DOI: 10.1002/cnma.202400569

John Alake, Zondi Nate, Darko Kwabena Adu, Blessing Wisdom Ike, Ruchika Chauhan, Atal Gill, Rajshekhar Karpoormath

{"title":"Facile Fabrication of Poly(Acrylic Acid)-Functionalised Nickel-Metal-Organic Frameworks Nanoplates for Electrochemical Immunosensor for the Detection of Prostate-Specific Antigen","authors":"John Alake, Zondi Nate, Darko Kwabena Adu, Blessing Wisdom Ike, Ruchika Chauhan, Atal Gill, Rajshekhar Karpoormath","doi":"10.1002/cnma.202400569","DOIUrl":"https://doi.org/10.1002/cnma.202400569","url":null,"abstract":"The Current study proposes the first application of nanoplate poly(acrylic acid)-modified Nickel-2-Amino-1,4-benzene dicarboxylic (PAA−Ni−NH2BDC) for quantifying PSA in serum. The MOF surface was functional with poly(acrylic acid) (PAA) to supply carboxylic groups. Anti-PSA antibodies were immobilised onto the modified electrode using EDC-NHS chemistry facilitated by the carboxylic groups supplied by PAA. Differential pulse voltammetry was used to study the sensor's performance towards prostate-specific antigen using 2.5 mM Fe (CN)6]3−/[Fe(CN)6]4− in 0.01 M PBS as a redox probe. The immunosensor exhibited a detection limit of 1.0×10−13 μg/L with a wide linear range of 10−13 to 10−3 μg/L. The MOF′s high surface area and large pore sizes allowed the material to adsorb large quantities of the anti-PSA antibodies for enhanced performance. Furthermore, the results from the proposed technique were highly reproducible. The PAA-NI-MOF may be useful for early prostate cancer detection in clinical diagnosis and monitoring.","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 1","pages":""},"PeriodicalIF":2.6,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143120547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0